CN106637961B - A kind of anti-bacteria real silk silk fabric and preparation method thereof - Google Patents
A kind of anti-bacteria real silk silk fabric and preparation method thereof Download PDFInfo
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- CN106637961B CN106637961B CN201610827883.2A CN201610827883A CN106637961B CN 106637961 B CN106637961 B CN 106637961B CN 201610827883 A CN201610827883 A CN 201610827883A CN 106637961 B CN106637961 B CN 106637961B
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 37
- 239000004744 fabric Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title description 4
- 230000002421 anti-septic effect Effects 0.000 claims abstract description 52
- 239000002994 raw material Substances 0.000 claims abstract description 24
- 238000001035 drying Methods 0.000 claims abstract description 9
- 239000012043 crude product Substances 0.000 claims abstract description 8
- 238000002242 deionisation method Methods 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000008367 deionised water Substances 0.000 claims abstract description 4
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 4
- 238000007781 pre-processing Methods 0.000 claims abstract description 4
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 48
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 36
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 claims description 18
- -1 polyoxy Polymers 0.000 claims description 13
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 claims description 12
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 12
- YAZSBRQTAHVVGE-UHFFFAOYSA-N 2-aminobenzenesulfonamide Chemical compound NC1=CC=CC=C1S(N)(=O)=O YAZSBRQTAHVVGE-UHFFFAOYSA-N 0.000 claims description 12
- 229920002101 Chitin Polymers 0.000 claims description 12
- 229920001661 Chitosan Polymers 0.000 claims description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 12
- 235000019501 Lemon oil Nutrition 0.000 claims description 12
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 claims description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 12
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 12
- ALSTYHKOOCGGFT-UHFFFAOYSA-N cis-oleyl alcohol Natural products CCCCCCCCC=CCCCCCCCCO ALSTYHKOOCGGFT-UHFFFAOYSA-N 0.000 claims description 12
- 239000010501 lemon oil Substances 0.000 claims description 12
- 239000010446 mirabilite Substances 0.000 claims description 12
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 claims description 12
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 12
- 239000002002 slurry Substances 0.000 claims description 12
- 229910052708 sodium Inorganic materials 0.000 claims description 12
- 239000011734 sodium Substances 0.000 claims description 12
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 claims description 12
- 229940124530 sulfonamide Drugs 0.000 claims description 12
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 claims description 11
- 239000002202 Polyethylene glycol Substances 0.000 claims description 11
- 229920001223 polyethylene glycol Polymers 0.000 claims description 11
- 229940037312 stearamide Drugs 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 4
- JHOKTNSTUVKGJC-UHFFFAOYSA-N n-(hydroxymethyl)octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCO JHOKTNSTUVKGJC-UHFFFAOYSA-N 0.000 claims description 3
- MZAVSXJJSQTGRK-UHFFFAOYSA-N [Cl-].C=C.C[NH+](C)C Chemical compound [Cl-].C=C.C[NH+](C)C MZAVSXJJSQTGRK-UHFFFAOYSA-N 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract description 9
- 229940064004 antiseptic throat preparations Drugs 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 230000003115 biocidal effect Effects 0.000 description 11
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 230000000845 anti-microbial effect Effects 0.000 description 5
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical compound COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 241000251730 Chondrichthyes Species 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
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- D—TEXTILES; PAPER
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
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- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
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- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
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Abstract
A kind of preparation method of anti-bacteria real silk silk fabric, comprises the steps：1. silk broadcloth is immersed to antiseptic I, take out after 5 20 minutes, washed after drying through deionization, then bakeed, the baking time is 3 4min, and stoving temperature is 110 120 DEG C, obtains pre-processing silk broadcloth；2. 1. pretreatment silk broadcloth that step obtains is entered in antiseptic II, take out after 5 20 minutes, washed after drying through deionization, then bakeed, the baking time is 3 4min, and stoving temperature is 110 120 DEG C, obtains crude product silk broadcloth；3. being washed again by deionized water after 2. crude product silk broadcloth that step obtains is soaped, then dry, obtain anti-bacteria real silk silk fabric.The present invention is soaked respectively by two kinds of antiseptics, and silk broadcloth is arranged, and various raw material synergies, effectively improve silk broadcloth antibacterial effect in antiseptic, and for silk broadcloth after repeatedly washing, antibacterial effect remains in that good effect after the present invention is handled.
Description
Technical field
The invention belongs to silk field, specifically a kind of anti-bacteria real silk silk fabric and preparation method thereof.
Background technology
At present, silk broadcloth refers to the silks and satins produced using silk as raw material, is the general designation that silks and satins are processed into silk.Silk broadcloth
Anti-microbial property be influence silk quality an important factor for.At present, existing silk broadcloth is respectively provided with certain after antibiotic finish
Anti-microbial property, but as the increase of silk washing times, anti-microbial property gradually reduce, typically washed by more than 30 times
Afterwards, anti-microbial property only has original general, or even loses anti-microbial property, causes the quality of silk drastically to decline, or even can not make
With.
The content of the invention
The present invention provides a kind of anti-bacteria real silk silk fabric and preparation method thereof, the defects of to solve in the prior art.
The present invention is achieved by the following technical programs：
A kind of preparation method of anti-bacteria real silk silk fabric, comprises the steps：1. silk broadcloth is immersed to antiseptic I, 5-20
To be taken out after minute, wash through deionization after drying, then bakee, the baking time is 3-4min, and stoving temperature is 110-120 DEG C,
Obtain pre-processing silk broadcloth,；2. 1. pretreatment silk broadcloth that step obtains is entered in antiseptic II, 5-20 takes after minute
Go out, washed after drying through deionization, then bakeed, the baking time is 3-4min, and stoving temperature is 110-120 DEG C, obtains crude product
Silk broadcloth；3. being washed again by deionized water after 2. crude product silk broadcloth that step obtains is soaped, then dry, obtain
Anti-bacteria real silk silk fabric；Antiseptic I is made up of the raw material of following weight parts：Chitin 5-15 parts, citric acid 3-8 parts, polyethylene glycol oxide
Trimethyl ammonium chloride 2-6 parts, the sodium 1-5 parts of metaphosphoric acid four, N- methylol stearamide 1-3 parts, 2- sulfanilamide (SN) quinoline uh quinoline 2-5 parts, angle
Shark alkane 1-3 parts, alcohol 20-30 parts；Antiseptic II is made up of the raw material of following weight parts：Chitosan quaternary ammonium salt 5-15 parts, ethene
Radical siloxane 3-6 parts, glauber salt 2-5 parts, monoethanolamine 2-5 parts, 2- amido -4- rosickyite base nitrobenzene 3-6 parts, lemon oil 4-6
Part, oleic alcohol polyoxyethylene（15）Ether 2-5 parts, alcohol 20-30 parts.
A kind of preparation method of anti-bacteria real silk silk fabric as described above, described antiseptic I by following weight parts raw material group
Into：5 parts of chitin, 5.5 parts of citric acid, 6 parts of polyethylene glycol oxide trimethyl ammonium chloride, 1 part of four sodium of metaphosphoric acid, N- methylols 18
2 parts of acid amides, 5 parts of 2- sulfanilamide (SN) quinoline uh quinoline, 1 part of saualane, 25 parts of alcohol.
A kind of preparation method of anti-bacteria real silk silk fabric as described above, described antiseptic I by following weight parts raw material group
Into：10 parts of chitin, 8 parts of citric acid, 2 parts of polyethylene glycol oxide trimethyl ammonium chloride, 3 parts of four sodium of metaphosphoric acid, N- methylols 18
3 parts of acid amides, 2 parts of 2- sulfanilamide (SN) quinoline uh quinoline, 2 parts of saualane, 30 parts of alcohol.
A kind of preparation method of anti-bacteria real silk silk fabric as described above, described antiseptic I by following weight parts raw material group
Into：15 parts of chitin, 3 parts of citric acid, 4 parts of polyethylene glycol oxide trimethyl ammonium chloride, 5 parts of four sodium of metaphosphoric acid, N- methylols 18
1 part of acid amides, 3.5 parts of 2- sulfanilamide (SN) quinoline uh quinoline, 3 parts of saualane, 20 parts of alcohol.
A kind of preparation method of anti-bacteria real silk silk fabric as described above, described antiseptic II by following weight parts raw material group
Into：5 parts of chitosan quaternary ammonium salt, 4.5 parts of vinylsiloxane, 5 parts of glauber salt, 2 parts of monoethanolamine, 2- amido -4- rosickyite base nitre
4.5 parts of base benzene, 6 parts of lemon oil, oleic alcohol polyoxyethylene（15）2 parts of ether, 25 parts of alcohol.
A kind of preparation method of anti-bacteria real silk silk fabric as described above, described antiseptic II by following weight parts raw material group
Into：10 parts of chitosan quaternary ammonium salt, 6 parts of vinylsiloxane, 2 parts of glauber salt, 3.5 parts of monoethanolamine, 2- amido -4- rosickyite base nitre
6 parts of base benzene, 4 parts of lemon oil, oleic alcohol polyoxyethylene（15）3.5 parts of ether, 30 parts of alcohol.
A kind of preparation method of anti-bacteria real silk silk fabric as described above, described antiseptic II by following weight parts raw material group
Into：15 parts of chitosan quaternary ammonium salt, 3 parts of vinylsiloxane, 3.5 parts of glauber salt, 5 parts of monoethanolamine, 2- amido -4- rosickyite base nitre
3 parts of base benzene, 5 parts of lemon oil, oleic alcohol polyoxyethylene（15）5 parts of ether, 20 parts of alcohol.
A kind of preparation method of anti-bacteria real silk silk fabric as described above, the preparation method of described antiseptic I include following steps
Suddenly：The all components of antiseptic I are added in mixer, slurries is mixed into, by slurries by vacuum filter, produces.
A kind of preparation method of anti-bacteria real silk silk fabric as described above, the preparation method of described antiseptic II include following steps
Suddenly：The all components of antiseptic II are added in mixer, slurries is mixed into, by slurries by vacuum filter, produces
A kind of anti-bacteria real silk silk fabric prepared using the above method is claimed simultaneously in the application.
It is an advantage of the invention that：The present invention is soaked respectively by two kinds of antiseptics, silk broadcloth is arranged, in antiseptic
Various raw material synergies, the antibacterial effect of silk broadcloth is effectively improved, also, the silk broadcloth after the present invention is handled is passing through
Repeatedly after washing（Antibiotic rate remains able to reach more than 95% after 100 washings）, antibacterial effect remains in that good effect.
Twice in baking process, the excellent character of silk broadcloth itself can be kept, relatively low on whiteness influence, whiteness is maintained at more than 90%.
Embodiment
, below will be in the embodiment of the present invention to make the purpose, technical scheme and advantage of the embodiment of the present invention clearer
Technical scheme be clearly and completely described, it is clear that described embodiment is part of the embodiment of the present invention, rather than
Whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making creative work premise
Lower obtained every other embodiment, belongs to the scope of protection of the invention.
A kind of preparation method of anti-bacteria real silk silk fabric, comprises the steps：1. silk broadcloth is immersed to antiseptic I, 5-20
To be taken out after minute, wash through deionization after drying, then bakee, the baking time is 3-4min, and stoving temperature is 110-120 DEG C,
Obtain pre-processing silk broadcloth；2. 1. pretreatment silk broadcloth that step obtains is entered in antiseptic II, 5-20 takes after minute
Go out, washed after drying through deionization, then bakeed, the baking time is 3-4min, and stoving temperature is 110-120 DEG C, obtains crude product
Silk broadcloth；3. being washed again by deionized water after 2. crude product silk broadcloth that step obtains is soaped, then dry, obtain
Anti-bacteria real silk silk fabric；Antiseptic I is made up of the raw material of following weight parts：Chitin 5-15 parts, citric acid 3-8 parts, polyethylene glycol oxide
Trimethyl ammonium chloride 2-6 parts, the sodium 1-5 parts of metaphosphoric acid four, N- methylol stearamide 1-3 parts, 2- sulfanilamide (SN) quinoline uh quinoline 2-5 parts, angle
Shark alkane 1-3 parts, alcohol 20-30 parts；Antiseptic II is made up of the raw material of following weight parts：Chitosan quaternary ammonium salt 5-15 parts, ethene
Radical siloxane 3-6 parts, glauber salt 2-5 parts, monoethanolamine 2-5 parts, 2- amido -4- rosickyite base nitrobenzene 3-6 parts, lemon oil 4-6
Part, oleic alcohol polyoxyethylene（15）Ether 2-5 parts, alcohol 20-30 parts.The present invention is soaked respectively by two kinds of antiseptics, and silk broadcloth is entered
Row arranges, and the various raw materials synergy in antiseptic, effectively improves the antibacterial effect of silk broadcloth, also, pass through at the present invention
Silk broadcloth after reason is after repeatedly washing（Antibiotic rate remains able to reach more than 95% after 100 washings）, antibacterial effect is still
So keep good effect.Twice in baking process, the excellent character of silk broadcloth itself can be kept, it is relatively low on whiteness influence,
Whiteness is maintained at more than 90%.
Antiseptic I is made up of the raw material of the parts by weight of following embodiments：
Embodiment 1：5 parts of chitin, 5.5 parts of citric acid, 6 parts of polyethylene glycol oxide trimethyl ammonium chloride, the sodium 1 of metaphosphoric acid four
Part, 2 parts of N- methylols stearamide, 5 parts of 2- sulfanilamide (SN) quinoline uh quinoline, 1 part of saualane, 25 parts of alcohol.
Embodiment 2：10 parts of chitin, 8 parts of citric acid, 2 parts of polyethylene glycol oxide trimethyl ammonium chloride, 3 parts of four sodium of metaphosphoric acid,
3 parts of N- methylols stearamide, 2 parts of 2- sulfanilamide (SN) quinoline uh quinoline, 2 parts of saualane, 30 parts of alcohol.
Embodiment 3：15 parts of chitin, 3 parts of citric acid, 4 parts of polyethylene glycol oxide trimethyl ammonium chloride, 5 parts of four sodium of metaphosphoric acid,
1 part of N- methylols stearamide, 3.5 parts of 2- sulfanilamide (SN) quinoline uh quinoline, 3 parts of saualane, 20 parts of alcohol.
Described antiseptic II is made up of the raw material of following weight parts：
Embodiment 1：5 parts of chitosan quaternary ammonium salt, 4.5 parts of vinylsiloxane, 5 parts of glauber salt, 2 parts of monoethanolamine, 2- amine
4.5 parts of base -4- rosickyite bases nitrobenzene, 6 parts of lemon oil, oleic alcohol polyoxyethylene（15）2 parts of ether, 25 parts of alcohol.
Embodiment 2：10 parts of chitosan quaternary ammonium salt, 6 parts of vinylsiloxane, 2 parts of glauber salt, 3.5 parts of monoethanolamine, 2- amine
6 parts of base -4- rosickyite bases nitrobenzene, 4 parts of lemon oil, oleic alcohol polyoxyethylene（15）3.5 parts of ether, 30 parts of alcohol.
Embodiment 3：15 parts of chitosan quaternary ammonium salt, 3 parts of vinylsiloxane, 3.5 parts of glauber salt, 5 parts of monoethanolamine, 2- amine
3 parts of base -4- rosickyite bases nitrobenzene, 5 parts of lemon oil, oleic alcohol polyoxyethylene（15）5 parts of ether, 20 parts of alcohol.
The preparation method of described antiseptic I comprises the steps：The all components of antiseptic I are added in mixer, mixed
Conjunction stirs into slurries, by slurries by vacuum filter, produces.
The preparation method of described antiseptic II comprises the steps：The all components of antiseptic II are added in mixer,
Slurries are mixed into, by slurries by vacuum filter, are produced.
The antibacterial effect of the present invention is contrasted below by specific experiment.
The present invention is taken to prepare silk broadcloth：Trial target one is used in antiseptic I to be implemented in embodiment 1 and antiseptic II
Example 1 is prepared；Trial target two is prepared using embodiment 2 in embodiment 2 in antiseptic I and antiseptic II；Trial target
Two are prepared using embodiment 3 in embodiment 3 in antiseptic I and antiseptic II.
Trial target is washed by washing experimental machine, sample is put into the solution of 5g/L containing detergent (bath raio 1: 50)
In, 10min is washed in 40 DEG C, is then rinsed well with clear water, dries, washs certain number repeatedly, finally in 80 DEG C of drying, is divided
The 0th time, 20 times, 40 times, 60 times, 80 times, 100 measurement antibiotic rates not in washing.
The metering system of antibiotic rate is tested using " shake flask test ", and experimental strain is staphylococcus aureus ATCC6538.
Antibiotic fabric and sample bacterium are added in the flask for filling buffer solution, with oscillator in 25 DEG C of speed with 320-340r/min
After vibrating 1h, the front and rear viable count of vibration is calculated respectively, antibiotic rate is calculated as follows.
Antibiotic rate=(A-B)/A × 100%
A in formula --- the viable count before vibration；B --- the viable count after vibration.
The experimental results are shown inthe following table：
| Washing times | 0 | 20 | 40 | 60 | 80 | 100 |
| The antibiotic rate of trial target one（%） | 99.5 | 98.6 | 97.3 | 96.8 | 96.3 | 96.2 |
| The antibiotic rate of trial target two（%） | 98.9 | 98.6 | 98.1 | 97.5 | 96.2 | 95.4 |
| The antibiotic rate of trial target three（%） | 99.6 | 98.8 | 97.3 | 96.9 | 96.6 | 96.2 |
Finally it should be noted that：The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although
The present invention is described in detail with reference to the foregoing embodiments, it will be understood by those within the art that：It still may be used
To be modified to the technical scheme described in foregoing embodiments, or equivalent substitution is carried out to which part technical characteristic；
And these modification or replace, do not make appropriate technical solution essence depart from various embodiments of the present invention technical scheme spirit and
Scope.
Claims (10)
- A kind of 1. preparation method of anti-bacteria real silk silk fabric, it is characterised in that：Comprise the steps：1. silk broadcloth is immersed to antiseptic In I, 5-20 takes out after minute, is washed after drying through deionization, then bakees, and the baking time is 3-4min, and stoving temperature is 110-120 DEG C, obtain pre-processing silk broadcloth；2. 1. pretreatment silk broadcloth that step obtains is entered in antiseptic II, 5-20 To be taken out after minute, wash through deionization after drying, then bakee, the baking time is 3-4min, and stoving temperature is 110-120 DEG C, Obtain crude product silk broadcloth；3. being washed again by deionized water after 2. crude product silk broadcloth that step obtains is soaped, then dry It is dry, obtain anti-bacteria real silk silk fabric；Antiseptic I is made up of the raw material of following weight parts：Chitin 5-15 parts, citric acid 3-8 parts, polyoxy Change ethene trimethyl ammonium chloride 2-6 parts, the sodium 1-5 parts of metaphosphoric acid four, N- methylol stearamide 1-3 parts, 2- sulfanilamide (SN) quinoline uh quinoline 2-5 Part, saualane 1-3 parts, alcohol 20-30 parts；Antiseptic II is made up of the raw material of following weight parts：Chitosan quaternary ammonium salt 5-15 parts, Vinylsiloxane 3-6 parts, glauber salt 2-5 parts, monoethanolamine 2-5 parts, 2- amido -4- rosickyite base nitrobenzene 3-6 parts, lemon oil 4-6 parts, oleic alcohol polyoxyethylene（15）Ether 2-5 parts, alcohol 20-30 parts.
- A kind of 2. preparation method of anti-bacteria real silk silk fabric according to claim 1, it is characterised in that：Described antiseptic I by The raw material composition of following weight parts：5 parts of chitin, 5.5 parts of citric acid, 6 parts of polyethylene glycol oxide trimethyl ammonium chloride, metaphosphoric acid four 1 part of sodium, 2 parts of N- methylols stearamide, 5 parts of 2- sulfanilamide (SN) quinoline uh quinoline, 1 part of saualane, 25 parts of alcohol.
- A kind of 3. preparation method of anti-bacteria real silk silk fabric according to claim 1, it is characterised in that：Described antiseptic I by The raw material composition of following weight parts：10 parts of chitin, 8 parts of citric acid, 2 parts of polyethylene glycol oxide trimethyl ammonium chloride, metaphosphoric acid four 3 parts of sodium, 3 parts of N- methylols stearamide, 2 parts of 2- sulfanilamide (SN) quinoline uh quinoline, 2 parts of saualane, 30 parts of alcohol.
- A kind of 4. preparation method of anti-bacteria real silk silk fabric according to claim 1, it is characterised in that：Described antiseptic I by The raw material composition of following weight parts：15 parts of chitin, 3 parts of citric acid, 4 parts of polyethylene glycol oxide trimethyl ammonium chloride, metaphosphoric acid four 5 parts of sodium, 1 part of N- methylols stearamide, 3.5 parts of 2- sulfanilamide (SN) quinoline uh quinoline, 3 parts of saualane, 20 parts of alcohol.
- A kind of 5. preparation method of anti-bacteria real silk silk fabric according to claim 1, it is characterised in that：Described antiseptic II by The raw material composition of following weight parts：5 parts of chitosan quaternary ammonium salt, 4.5 parts of vinylsiloxane, 5 parts of glauber salt, 2 parts of monoethanolamine, 4.5 parts of 2- amido -4- rosickyite bases nitrobenzene, 6 parts of lemon oil, oleic alcohol polyoxyethylene（15）2 parts of ether, 25 parts of alcohol.
- A kind of 6. preparation method of anti-bacteria real silk silk fabric according to claim 1, it is characterised in that：Described antiseptic II by The raw material composition of following weight parts：10 parts of chitosan quaternary ammonium salt, 6 parts of vinylsiloxane, 2 parts of glauber salt, monoethanolamine 3.5 Part, 6 parts of 2- amido -4- rosickyite bases nitrobenzene, 4 parts of lemon oil, oleic alcohol polyoxyethylene（15）3.5 parts of ether, 30 parts of alcohol.
- A kind of 7. preparation method of anti-bacteria real silk silk fabric according to claim 1, it is characterised in that：Described antiseptic II by The raw material composition of following weight parts：15 parts of chitosan quaternary ammonium salt, 3 parts of vinylsiloxane, 3.5 parts of glauber salt, monoethanolamine 5 Part, 3 parts of 2- amido -4- rosickyite bases nitrobenzene, 5 parts of lemon oil, oleic alcohol polyoxyethylene（15）5 parts of ether, 20 parts of alcohol.
- A kind of 8. preparation method of anti-bacteria real silk silk fabric according to claim 1, it is characterised in that：Described antiseptic I Preparation method comprises the steps：The all components of antiseptic I are added in mixer, slurries is mixed into, slurries is passed through Vacuum filter, produce.
- A kind of 9. preparation method of anti-bacteria real silk silk fabric according to claim 1, it is characterised in that：Described antiseptic II Preparation method comprises the steps：The all components of antiseptic II are added in mixer, slurries is mixed into, slurries is passed through Vacuum filter, produce.
- A kind of 10. anti-bacteria real silk silk fabric prepared using claim 1-9 any one method.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103334300A (en) * | 2013-07-04 | 2013-10-02 | 太原理工大学 | Antibacterial treatment method for natural silk fabric surface |
| CN103668973A (en) * | 2012-09-21 | 2014-03-26 | 青岛道合生物科技有限公司 | Soft antibacterial finishing agent special for textiles |
| CN103757893A (en) * | 2013-12-31 | 2014-04-30 | 吴江市七都镇庙港雅迪针织制衣厂 | Antimicrobial moldproof agent for silk fabrics |
| CN104594018A (en) * | 2015-01-08 | 2015-05-06 | 盐城工学院 | Finishing method for textile with ultraviolet-resisting and antibacterial functions |
| CN104746365A (en) * | 2015-04-02 | 2015-07-01 | 太仓市宝明化纤有限公司 | Salt-free dyeing process for natural silk fabric |
| CN105040485A (en) * | 2015-08-14 | 2015-11-11 | 太仓市诚乐化纤有限公司 | Environmental-friendly dyeing and finishing process of real silk fabric |
-
2016
- 2016-09-18 CN CN201610827883.2A patent/CN106637961B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103668973A (en) * | 2012-09-21 | 2014-03-26 | 青岛道合生物科技有限公司 | Soft antibacterial finishing agent special for textiles |
| CN103334300A (en) * | 2013-07-04 | 2013-10-02 | 太原理工大学 | Antibacterial treatment method for natural silk fabric surface |
| CN103757893A (en) * | 2013-12-31 | 2014-04-30 | 吴江市七都镇庙港雅迪针织制衣厂 | Antimicrobial moldproof agent for silk fabrics |
| CN104594018A (en) * | 2015-01-08 | 2015-05-06 | 盐城工学院 | Finishing method for textile with ultraviolet-resisting and antibacterial functions |
| CN104746365A (en) * | 2015-04-02 | 2015-07-01 | 太仓市宝明化纤有限公司 | Salt-free dyeing process for natural silk fabric |
| CN105040485A (en) * | 2015-08-14 | 2015-11-11 | 太仓市诚乐化纤有限公司 | Environmental-friendly dyeing and finishing process of real silk fabric |
Non-Patent Citations (1)
| Title |
|---|
| 壳聚糖季铵盐在桑蚕丝织物抗菌整理中的应用;张伟等;《纺织学报》;20101030;第31卷(第10期);70-74 * |
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