CN106636731B - High intensity height extends the processing technology of brass alloys band - Google Patents

High intensity height extends the processing technology of brass alloys band Download PDF

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Publication number
CN106636731B
CN106636731B CN201610933437.XA CN201610933437A CN106636731B CN 106636731 B CN106636731 B CN 106636731B CN 201610933437 A CN201610933437 A CN 201610933437A CN 106636731 B CN106636731 B CN 106636731B
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baffle
processing technology
brass alloys
high intensity
intensity height
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CN106636731A (en
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李泽
周胜
杜正平
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Jiangxi Kaian Intelligent Co ltd
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Jiangxi Kai'an Intelligent Ltd By Share Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/04Alloys based on copper with zinc as the next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/001Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
    • B22D11/004Copper alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/055Cooling the moulds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23PMETAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
    • B23P15/00Making specific metal objects by operations not covered by a single other subclass or a group in this subclass
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/08Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of copper or alloys based thereon

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Metal Rolling (AREA)

Abstract

The present invention relates to new material field shaping techniques, extend the processing technology of brass alloys band more particularly to high intensity height, it comprises the steps of, it is raw material to select copper, zinc, it is melted in smelting apparatus after raw material stoving, then two kinds of rare earth lanthanide series metals, manganese and iron are sequentially added, stirs, uses the charcoal toasted as coverture to ensure the vacuum state of aluminium alloy;It uses direct chill casting ingot method, casting machine to use oscillatory type cast, rolled using Hot Rolling Mill the aluminium alloy of generation, milling face is carried out to the band after hot rolling, is rolled using cold mill complex, give and finish rolling is carried out using recrystallization annealing again after finish rolling.Processing technology in the present invention obtains the equiax crystal of fine uniform, play the role of refined crystalline strengthening, improve the comprehensive performance of brass, brass alloys intensity produced by the invention is high, with good extension property, there is good application performance in manufacturing brass electronic component.

Description

High intensity height extends the processing technology of brass alloys band
Technical field
The present invention relates to new material field shaping techniques, extend adding for brass alloys band more particularly to high intensity height Work technique.
Background technology
The alloy that brass is made of copper and zinc.Brass band has good because its is in beautiful color, wear-resisting, anti-corrosion Plastic deformation ability and be widely used in the industries such as hardware, electronics telecommunication, possess vast market prospect.Existing market brass Connector demand is huge, and for client with the promotion of equipment, technique, the requirement to required brass performance is harsher, existing Brass processing technology can not meet requirement of the market to brass intensity and extension property.
Invention content
In order to solve above-mentioned the deficiencies in the prior art, the purpose of the present invention is to provide a kind of intensity height, extensibility are high The processing technology of brass alloys band.
The technical solution adopted by the present invention is:A kind of high intensity height extends the processing technology of brass alloys band, feature It is, comprises the steps of:
(1) select copper, zinc be raw material, melted in smelting apparatus after raw material stoving, smelting temperature be 850 DEG C- 1100 DEG C, then sequentially add two kinds of rare earth lanthanide series metals, manganese and iron, stir, use the charcoal that toasted as coverture with Ensure the vacuum state of aluminium alloy;
(2) direct chill casting ingot method, casting machine is used to use oscillatory type cast, cast the aluminium alloy that step (1) generates 1000 DEG C -1100 DEG C of temperature draws ingot speed degree 30-60mm/min, controls liquid level 30-50mm in crystallizer, crystallizer hydraulic pressure 0.1-0.8Mpa, crystallizer leaving water temperature are 30-40 DEG C;
(3) it is rolled using Hot Rolling Mill, control finishing temperature is 790 DEG C -810 DEG C, mill speed 1.5m/s- 5m/s;
(4) milling face is carried out to the band after hot rolling, milling face thickness is 0.2mm-0.5mm, is rolled using cold mill complex: 1. making and giving finish rolling again to roll using 60% or more working modulus;2. finish rolling is rolled using small working modulus, control below 20%;
(5) it is heat-treated:It gives and finish rolling is carried out using recrystallization annealing again after finish rolling, recrystallization annealing temperature is 500 DEG C -600 ℃;It is 270 DEG C -300 DEG C that finished product after finish rolling, which uses Low-temperature stress-relief annealing, Low-temperature stress-relief annealing temperature,.
Further, the mass percent of the alloying component is copper:60%-80%, rare earth lanthanide series metal:0- 0.3%, manganese:0-0.4%, iron:0-0.03%, inevitable impurity are less than or equal to 0.1%, and surplus is zinc.
Further, the rare earth lanthanide series metal is neodymium and lanthanum.
Further, the thickness of the charcoal is 80mm-100mm.
The crystallizer includes crystallizer ontology, and crystallizer ontology includes inner and outer wall, and the inner wall both ends are equipped with convex Platform, the boss make inner and outer wall form closed cooling duct, and the outer wall is equipped with inlet and outlet, it is described into It is connected to by cooling duct between the mouth of a river and water outlet, the inner wall outside is equipped with first baffle and along the second of inner wall surrounding Cooling duct is divided into several cooling subchannels, the cooling subchannel to be equipped with corresponding water inlet by baffle, the second baffle Mouthful.
Further, the second baffle includes the first radial baffle, the second radial baffle and the radial gear of connection first The connecting plate of plate and the second radial baffle, the described first radial baffle, the second radial baffle and connecting plate divide cooling duct Subchannel, first passage mouth that the cooling subchannel is equipped with by radial baffle, second are cooled down at upper, middle, and lower part Passway is connected to third channel mouth.
Further, the first passage mouth and third channel mouth are set to the side of first baffle, and second channel mouth is set to The other side, the first passage mouth are connected to third channel mouth, the first passage mouth, second channel mouth and third channel mouth point It is not connected with corresponding water inlet.
Further, radiating ribs are equipped in the cooling subchannel, between the radiating ribs and first baffle and second baffle It is equipped with gap.
Further, the water outlet is equipped with collection channel, and the cooling subchannel is connected to the collection channel.
Compared with prior art, the present invention have the advantage that for:Processing technology in the present invention obtains fine uniform Equiax crystal, play the role of refined crystalline strengthening, improve the comprehensive performance of brass, crystallizer cooling structure carries out subregion control, Strengthen central region intensity of cooling, while the connection of each cooling duct and setting radiating ribs, increases the contact area with water, improve The convection transfer rate of flow makes crystallizer crystallization rate be consistent, and to keep crystallization uniform, brass produced by the invention closes Golden intensity is high, has good extension property, has good application performance in manufacturing brass electronic component.
Description of the drawings
Fig. 1 is that a kind of high intensity height of the present invention extends the processing process figure of brass alloys band;
Fig. 2 is the structural schematic diagram of crystallizer of the present invention.
It illustrates:1- boss, 2- first passages mouth, 3- connecting plates, 4- third channels mouth, 5- first baffles, 6- second Passway, 7- radiating ribs, the radial baffles of 8- second, the radial baffles of 9- first.
Specific implementation mode
It elaborates below in conjunction with the accompanying drawings to the present invention.
As shown in Figure 1, the processing technology that the present invention produces the brass alloys band use of 0.1~0.2 × 400mm is as follows: One direct chill casting ingot of melting --- cold rolling group-heat treatment.
(1) select copper, zinc be raw material, melted in smelting apparatus after raw material stoving, smelting temperature be 850 DEG C- 1100 DEG C, fusion process, which first melts copper, to be completed, and then reduces temperature and zinc is added, and then sequentially adds two kinds of rare earth group of the lanthanides gold Belong to, manganese and iron, stirring, uses the charcoal toasted as coverture to ensure that the vacuum state of aluminium alloy, the thickness of charcoal be 80mm-100mm.The mass percent of the alloying component is copper:60%-80%, rare earth lanthanide series metal:0-0.3%, manganese:0- 0.4%, iron:0-0.03%, inevitable impurity are less than or equal to 0.1%, and surplus is zinc.Rare earth lanthanide series metal is neodymium and lanthanum. Harmful work that a small amount of rare earth lanthanide series metal can reduce impurity element to the processing performance of brass alloys is added in brass alloys With, while can reduce column crystal with crystal grain thinning, expanding the effect of isometric crystalline region, the effect of thinning microstructure.In brass alloys A small amount of manganese element, which is added, can form CuMn solid solution, and CuMn cellular solid solution remains Cu high-ductilities, high elongation, it is excellent cold plus Work performance etc. ensures that brass alloys have good cold-forming property to meet the plasticity of brass alloys in the application in brass, Prevent material embrittlement.Fe elements are used as nucleating agent in casting process, increase the quantity of forming core, hinder growing up for crystal grain, rise To the effect of crystal grain thinning, the comprehensive performance of material is improved, and ferro element is not dissolved part and is distributed in brass base so that star is flower-shaped On body, the fracture of cutting swarf can be promoted, improve the cutting ability of brass alloys.
(2) direct chill casting ingot method, casting machine is used to use oscillatory type cast, cast the aluminium alloy that step (1) generates 1000 DEG C -1100 DEG C of temperature draws ingot speed degree 30-60mm/min, controls liquid level 30-50mm in crystallizer, crystallizer hydraulic pressure 0.1-0.8Mpa, crystallizer leaving water temperature are 30-40 DEG C;Control mold liquid level height can effectively promote cooling effect, use Direct chill casting ingot method can be crystalline structure from bottom to top, ingot casting is full, and crystalline structure is finer and close, and ingredient is more uniform, fills Divide and meets following process requirement.
(3) it is rolled using Hot Rolling Mill, control finishing temperature is 790 DEG C -810 DEG C, mill speed 1.5m/s- 5m/s;Reduce casting flaw and improves the plasticity and extensibility of alloy to obtain the equiax crystal of fine uniform.
(4) brass alloys surface forms one layer of oxide after hot rolling, therefore carries out milling face to the band after hot rolling, and milling face is thick Degree is 0.2mm-0.5mm, is then rolled using cold mill complex:1. making and giving finish rolling again to roll using 60% or more cold working rate System;2. finish rolling is rolled using small working modulus, cold working rate controls below 20%;Make crystal grain fibre deformation, is conducive to recrystallize The Nucleation Mechanism of annealing.
(5) it is heat-treated:It gives and finish rolling is carried out using recrystallization annealing again after finish rolling, recrystallization annealing temperature is 500 DEG C -600 DEG C, be conducive to forming core, obtain tiny equiax crystal, play the role of refined crystalline strengthening.Finished product after finish rolling is moved back using low temperature destressing Fire, Low-temperature stress-relief annealing temperature are 270 DEG C -300 DEG C, in the case where not appreciably affecting Tensile strength, hardness, significantly Improve band plasticity.
Crystallizer that the present invention uses as shown in Fig. 2, crystallizer includes crystallizer ontology, crystallizer ontology include inner wall and Outer wall, the inner wall both ends are equipped with boss (1), and the boss (1) makes inner and outer wall form closed cooling duct, described outer Wall is equipped with inlet and outlet, is connected to by cooling duct between the inlet and outlet, in the inner wall outside Equipped with first baffle (5) and along the second baffle of inner wall surrounding, cooling duct is divided into several cooling sons by the second baffle Channel, the cooling subchannel are equipped with corresponding water inlet.It is divided into several cooling subchannels that can reach most cooling duct Big flow area, improves the cooling effect of crystallizer.
The second baffle includes the first radial baffle (9), the second radial baffle (8) and the radial baffle of connection first (9) and the connecting plate (3) of the second radial baffle (8), the described first radial baffle (9), the second radial baffle (8) and connecting plate (3) it is divided into upper, middle, and lower part to cool down subchannel cooling duct, top is formed by boss (1), the first radial baffle (9) Divide cooling subchannel, it is sub logical to form middle section cooling by the first radial baffle (9), the second radial baffle (8) and connecting plate (3) Road is formed lower part and is cooled down subchannel by the second radial baffle (8), boss (1).The upper, middle, and lower part cools down subchannel Corresponding first passage mouth (2), the second channel mouth (6) being equipped with by radial baffle is connected to third channel mouth (4) respectively.Institute It states first passage mouth (2) and third channel mouth (4) is set to the side of first baffle (5), second channel mouth (6) is set to the other side, The first passage mouth (2) is connected to third channel mouth (4), and the first passage mouth (2), second channel mouth (6) and third are logical Road junction (4) is connected with corresponding water inlet respectively.The water outlet is equipped with collection channel, and the cooling subchannel collects with this Channel is connected to.Outlet temperature is 30-40 DEG C, and the crystallization rate of brass is reasonable, effect is good, ensures slab quality.Three coolings Subchannel supplies different flow even different cooling media as required, and the cooling subchannel cooling flow of middle section is more than separately Outer two channels, realize the control of different zones, strengthen the intensity of cooling of central region, while the connected raising water of three subchannels The convection transfer rate of stream makes crystallizer crystallization rate be consistent, to make entire strand crystallization uniformly improve alloy strength And extension property.
Radiating ribs (7) are equipped in the cooling subchannel, the radiating ribs (7) and first baffle (5) are between second baffle It is equipped with gap.The contact area for increasing crystallizer and flow takes away more heats, while increasing the turbulivity of fluid Can, improve heat dissipation performance.
Processing technology of the present invention obtains the equiax crystal of fine uniform, plays the role of refined crystalline strengthening, improves the synthesis of brass Performance, crystallizer cooling structure carry out subregion control, strengthen central region intensity of cooling, while each cooling subchannel mutually interconnects Radiating ribs (7) are passed to and be arranged, increases the contact area with water, improves the convection transfer rate of flow, make crystallizer crystallization speed Degree is consistent, to make entire strand crystallization uniformly improve alloy strength and extension property.Brass tension produced by the invention Intensity is more than or equal to 580MPa, and extension property is more than or equal to 10%.
The above only expresses the preferred embodiment of the present invention, the description thereof is more specific and detailed, but can not be because This and be interpreted as the limitation to the scope of the claims of the present invention.It should be pointed out that for those of ordinary skill in the art, Under the premise of not departing from present inventive concept, several deformations can also be made, improves and substitutes, these belong to the protection of the present invention Range.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.

Claims (8)

1. a kind of high intensity height extends the processing technology of brass alloys band, which is characterized in that comprise the steps of:
(1) it is raw material to select copper, zinc, is melted in smelting apparatus after raw material stoving, and smelting temperature is 850 DEG C -1100 DEG C, two kinds of rare earth lanthanide series metals, manganese and iron are then sequentially added, stirs, uses the charcoal toasted as coverture to ensure The vacuum state of aluminium alloy;The mass percent of the alloying component of addition is copper:60%-80%, rare earth lanthanide series metal:0- 0.3%, manganese:0-0.4%, iron:0-0.03%, inevitable impurity are less than or equal to 0.1%, and surplus is zinc;
(2) direct chill casting ingot method, casting machine is used to use oscillatory type cast, pouring temperature the aluminium alloy that step (1) generates 1000 DEG C -1100 DEG C, ingot speed degree 30-60mm/min is drawn, controls liquid level 30-50mm, crystallizer hydraulic pressure 0.1- in crystallizer 0.8Mpa, crystallizer leaving water temperature are 30-40 DEG C;
(3) it is rolled using Hot Rolling Mill, control finishing temperature is 790 DEG C -810 DEG C, mill speed 1.5m/s-5m/s;
(4) milling face is carried out to the band after hot rolling, milling face thickness is 0.2mm-0.5mm, is rolled using cold mill complex:1. again It makes and gives finish rolling and use 60% or more working modulus;2. finish rolling is rolled using small working modulus, control below 20%;
(5) it is heat-treated:It gives and finish rolling is carried out using recrystallization annealing again after finish rolling, recrystallization annealing temperature is 500 DEG C -600 DEG C;Essence It is 270 DEG C -300 DEG C that finished product after rolling, which uses Low-temperature stress-relief annealing, Low-temperature stress-relief annealing temperature,.
2. a kind of high intensity height according to claim 1 extends the processing technology of brass alloys band, which is characterized in that institute It is neodymium and lanthanum to state rare earth lanthanide series metal.
3. a kind of high intensity height according to claim 1 extends the processing technology of brass alloys band, which is characterized in that institute The thickness for stating charcoal is 80mm-100mm.
4. a kind of high intensity height according to claim 1 extends the processing technology of brass alloys band, which is characterized in that institute It includes crystallizer ontology to state crystallizer, and crystallizer ontology includes inner and outer wall, and the inner wall both ends are equipped with boss, the boss Inner and outer wall is set to form closed cooling duct, the outer wall is equipped with inlet and outlet, the water inlet and water outlet It is connected to by cooling duct between mouthful, the inner wall outside is equipped with first baffle and the second baffle along inner wall surrounding, described Cooling duct is divided into several cooling subchannels, the cooling subchannel to be equipped with corresponding water inlet by second baffle.
5. a kind of high intensity height according to claim 4 extends the processing technology of brass alloys band, which is characterized in that institute State the company that second baffle includes the first radial baffle, the second radial baffle and the radial baffle of connection first and the second radial baffle Cooling duct is divided into upper, middle, and lower part to cool down by fishplate bar, the described first radial baffle, the second radial baffle and connecting plate Subchannel, first passage mouth, second channel mouth and the third channel mouth that the cooling subchannel is equipped with by radial baffle connect It is logical.
6. a kind of high intensity height according to claim 5 extends the processing technology of brass alloys band, which is characterized in that institute It states first passage mouth and third channel mouth is set to the side of first baffle, second channel mouth is set to the other side, the first passage Mouthful be connected to third channel mouth, the first passage mouth, second channel mouth and third channel mouth respectively with corresponding water inlet phase Even.
7. a kind of high intensity height according to claim 4 extends the processing technology of brass alloys band, which is characterized in that institute It states and is equipped with radiating ribs in cooling subchannel, gap is equipped between the radiating ribs and first baffle and second baffle.
8. a kind of high intensity height according to claim 4 extends the processing technology of brass alloys band, which is characterized in that institute It states water outlet and is equipped with collection channel, the cooling subchannel is connected to the collection channel.
CN201610933437.XA 2016-10-31 2016-10-31 High intensity height extends the processing technology of brass alloys band Active CN106636731B (en)

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Publication number Priority date Publication date Assignee Title
CN107119206A (en) * 2017-05-19 2017-09-01 海安县鹰球粉末冶金有限公司 A kind of high-strength powder metallurgical brass base shaft coupling
CN108405650B (en) * 2018-03-05 2020-05-19 清远楚江铜业有限公司 Processing technology of copper plate strip for moxibustion box
CN108531756A (en) * 2018-04-16 2018-09-14 东莞市德景五金钮扣有限公司 A kind of production technology improving brass material tensile strength and crystal grain refinement
CN110117735A (en) * 2019-05-07 2019-08-13 浙江天河铜业股份有限公司 A kind of low-cost high-strength copper strips and its manufacturing method
CN111378869B (en) * 2020-03-25 2021-06-01 宁波金田铜业(集团)股份有限公司 Fine-grain reinforced brass strip for connector and processing method thereof

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CN86101024A (en) * 1985-02-14 1986-09-17 奥林公司 Corrosion resistant copper-zinc alloy for heat exchanger tubes
US5140837A (en) * 1991-05-28 1992-08-25 Tippins Incorporated Process for rolling soft metals
CN102719696A (en) * 2012-06-27 2012-10-10 宁波金田铜业(集团)股份有限公司 Elastic brass alloy and preparation method thereof
CN102978442A (en) * 2012-11-16 2013-03-20 海安县恒昌金属压延有限公司 Rare earth zinc copper titanium alloy and production method thereof
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CN86101024A (en) * 1985-02-14 1986-09-17 奥林公司 Corrosion resistant copper-zinc alloy for heat exchanger tubes
US5140837A (en) * 1991-05-28 1992-08-25 Tippins Incorporated Process for rolling soft metals
CN103173647A (en) * 2011-12-20 2013-06-26 北京有色金属与稀土应用研究所 Making method of elastic copper alloy sheet used for spectacle frame
CN102719696A (en) * 2012-06-27 2012-10-10 宁波金田铜业(集团)股份有限公司 Elastic brass alloy and preparation method thereof
CN102978442A (en) * 2012-11-16 2013-03-20 海安县恒昌金属压延有限公司 Rare earth zinc copper titanium alloy and production method thereof

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