CN106635199B - Reduce the additive of alcohol-based fuel pollutant emission - Google Patents

Reduce the additive of alcohol-based fuel pollutant emission Download PDF

Info

Publication number
CN106635199B
CN106635199B CN201611255481.6A CN201611255481A CN106635199B CN 106635199 B CN106635199 B CN 106635199B CN 201611255481 A CN201611255481 A CN 201611255481A CN 106635199 B CN106635199 B CN 106635199B
Authority
CN
China
Prior art keywords
alcohol
based fuel
additive
pollutant
fuel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201611255481.6A
Other languages
Chinese (zh)
Other versions
CN106635199A (en
Inventor
郭四虎
张迪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanxi Medical University
Original Assignee
Shanxi Medical University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanxi Medical University filed Critical Shanxi Medical University
Priority to CN201611255481.6A priority Critical patent/CN106635199B/en
Publication of CN106635199A publication Critical patent/CN106635199A/en
Application granted granted Critical
Publication of CN106635199B publication Critical patent/CN106635199B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/23—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2300/00—Mixture of two or more additives covered by the same group of C10L1/00 - C10L1/308
    • C10L2300/20—Mixture of two components

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The invention discloses a kind of additive for reducing stove and being discharged with alcohol-based fuel flue gas pollutant, it is made of the component of following mass percents：Diphenyl germanous chloride 19~31%, N (4 methoxy-benzyl) N methylamines 16~33%, cis 3 hexenol formic acid esters 15~26%, 3 nonene, 2 ketone 12~24%, 2 acetylamino benzyl carbinols 10~21%, dimethyl diselenide ether 9~19%.Additive of the present invention is added in alcohol-based fuel with 0.08~0.3wt%, can substantially reduce pollutant caused by alcohol-based fuel burning, in boiler combustion flue gas discharge of major pollutant averagely reduce a quarter or so.

Description

Reduce the additive of alcohol-based fuel pollutant emission
Technical field
The invention belongs to alcohol-based fuel to substitute furnace fuel technical field, is related to alcohol-based fuel additive, particularly relates to A kind of and additive that can reduce the pollutant emission that alcohol-based fuel burning produces.
Background technology
In China's using energy source structure, with serious pollution coal accounts for 70% or so of total energy consumption.Each class A fuel A boiler, Burn in the burners such as kiln, produce the pollution such as substantial amounts of flue dust, oxysulfide, particulate matter, carbon monoxide, hydrocarbon Thing.The enterprises and institutions such as thermal power generation, metallurgy, chemical industry, building materials and hospital, school and city dweller's heat supply etc. are all equipped with industry Boiler, kiln or life heating boiler, especially medium small boiler kiln, quantity is more, distribution is wide, burning condition is poor, and flue gas exists Low-altitude discharged, it is larger to some areas atmospheric pollution effect.For the problem of environmental pollution because of coal-burning boiler, kiln generation, subtract The use of few coal furnace, promotes and applies novel environment friendly clean fuel, will be highly beneficial for improving city atmospheric environment quality 's.
Alcohol-based fuel refers to the liquid fuel that alcohols (mainly methanol or crude glycol) is main modulation, is a kind of efficient, ring The clean energy resource of guarantor.
As China's economic development and the raising of people's living standard, society are increasing to the demand of clean energy resource, alcohol Base liquid fuel is increasingly becoming novel alternative fuel because of its clean environment firendly.
For alcohol-based fuel using methanol as primary raw material, raw material sources are wide, simple production process, technology maturation.China is " a richness The country of coal, oil starvation, few gas ", coal resources conversion alcohol-based fuel are adapted to China's actual conditions., will if this fuel is popularized Largely make up the shortage of China's oil resource, to improve the state of air pollution, readjust the energy structure, ensures the energy peace There is extremely important strategic importance entirely.
The content of the invention
The object of the present invention is to provide a kind of reduction stove additive of alcohol-based fuel pollutant emission, alcohol is added into In base fuel, pollutant caused by alcohol-based fuel burning can be substantially reduced.
The additive provided by the invention for reducing alcohol-based fuel pollutant emission is made of the component of following mass percents： Diphenyl germanous chloride 19~31%, N- (4- methoxy-benzyls)-N- methylamines 16~33%, cis -3- hexenols formic acid esters 15~ 26%th, 3- nonenes -2- ketone 12~24%, 2- acetylaminos benzyl carbinol 10~21%, dimethyl diselenide ether 9~19%.
The each component of above-mentioned mass percent is mixed, stirring at normal temperature is uniform, you can obtains reduction alcohol of the present invention The additive of base fuel contaminant discharge.
The additive additive amount in alcohol-based fuel of the present invention for reducing alcohol-based fuel pollutant emission for 0.08~ 0.3wt%, specifically used method are that the additive of the additive amount is first added in material benzenemethanol or crude glycol, are uniformly mixed, ultrasound After processing, other conventional additives with the effect such as homogeneous, stabilization, combustion-supporting, inhibition are added, modulates and alcohol-based fuel is made.
Wherein, the supersound process condition is at normal temperatures, with the ultrasonication 15 minutes of power 180W.
Alcohol-based fuel indices after the addition present composition are better than standard GB/T 16663-1996《Alcohol fluid Fluid fuel》And professional standard NY 311-1997《Alcohol civil fuel》It is required that.
Environmental Protection Department is to the Hebei province environmental protection Room《Asking for version-related problems is performed on alcohol-based fuel boiler Show》（Ji Huanke (2015) 178）Write a letter in reply --- ring letter [2015] 319《It is related that standard is performed on alcohol-based fuel boiler Problem is write a letter in reply》Point out：" in the foreign countries such as European Union, Germany boiler emission standard, methanol, ethanol, pitch, fuel oil are sorted out For liquid fuel class, unified standard limited value is performed, it is proposed that the boiler reference of alcohol-based fuel《Boiler Air Pollutant Emission mark It is accurate》（GB 13271-2014）The emission control of intermediate fuel oil boiler requires to perform.”
It is raw material that the present invention, which selects 12 kinds of crude glycols of separate sources in all parts of the country, and 48 have been modulated using additive of the present invention Each 1000 liters of alcohol-based fuel sample, burns on four normal pressure alcohol radical boilers, according to GB 13271-2014 respectively《Boiler air Pollutant emission standard》Boiler combustion discharge flue gas is detected.The results show pollutant emission averagely reduces a quarter Left and right, other pollutants are also below gas fired-boiler special emission limit in key area as defined in standard.
The additive preparation process of the present invention is simple, nontoxic, pollution-free without metal and other harmful substance compositions, keeps away Exempt to produce secondary pollution to environment, additive amount is smaller, has cleared away obstruction for the extensive industrialized implementation of alcohol-based fuel, has had Extensive promotional value.
Embodiment
Technical scheme is described in further detail below by way of specific embodiment, but the embodiment is not It is understood that to be limiting the scope of the invention, made on the basis of the embodiment non-of those skilled in the art The modifications and adaptations of matter, still fall within protection scope of the present invention.
Embodiment 1
Take diphenyl germanous chloride 19kg, N- (4- methoxy-benzyls)-N- methylamines 19kg, cis -3- hexenols formic acid esters 18kg, 3- nonene -2- ketone 17kg, 2- acetylamino benzyl carbinol 14.5kg and dimethyl diselenide ether 12.5kg are added to stirred tank In, stirred evenly under room temperature, obtain transparent, the limpid additive finished product for reducing the generation of alcohol-based fuel pollutant.
0.8kg the present embodiment additives are added in 990kg crude glycols, is uniformly mixed, uses U.S. BRANSON's under room temperature BMT-180 Ultrasound Instruments are handled 15 minutes, add other alcohol-based fuels conventional additives 9.2kg, and alcohol-based fuel is made.
Raw material based on selection 12 kinds of crude glycols in all parts of the country, modulates two groups of totally 24 alcohol-based fuel samples.Wherein first Group is not added with the blank control group of additive of the present invention to use 12 kinds of crude glycol raw materials respectively；Second group is to use 12 kinds respectively Crude glycol raw material, and with the addition of the sample group of the present embodiment additive.
Wherein, the 12 kinds of crude glycols used are respectively from Shanxi martial prowess chemical company, Yulin Chao Hua companies, Hebei are held De Yili coalifications company, Erdos Cheng Kai coalifications company, Shandong Zibo Yi Da chemical companies, Henan Jiaozhuo Sheng Hua companies, the Liao Dynasty Xin Zhi chemical companies of peaceful Huludao City, Lianyun Harbour Su Yuan chemical companies, Hubei Xiangyang hongda company and Ningbo Yi Likai industrial and trading companies Deng.
Each 1000 liters of sample, the testing results on four alcohol radical boilers, boiler are two 0.7MW and Liang Tai respectively 1.5MW normal-pressure hot-water boiler.Detection method is tested with reference to GB/T 16157《Particulate matter measure and gaseous state in Concentration in Fixed Pollutants Source The pollutant method of sampling》、HJ/T 373《Stationary source monitors QA and QC technical specification》、HJ/T 397 《Stationary source wasted nickel catalyst technical specification》、HJ/T 398《The measure Ringelman flue gas of fixed-contamination source emission flue gas blackness Blackness figure method》Deng discharge standard presses newest GB 13271-2014《Emission standard of air pollutants for boilers》Perform.
Testing result is as follows.
Embodiment 2
Take diphenyl germanous chloride 20kg, N- (4- methoxy-benzyls)-N- methylamines 16kg, cis -3- hexenols formic acid esters 18kg, 3- nonene -2- ketone 17.5kg, 2- acetylamino benzyl carbinol 14kg and dimethyl diselenide ether 14.5kg are added to stirred tank In, stirred evenly under room temperature, obtain transparent, the limpid additive finished product for reducing the generation of alcohol-based fuel pollutant.
1.0kg the present embodiment additives are added in 990kg crude glycols, is uniformly mixed, uses U.S. BRANSON's under room temperature BMT-180 Ultrasound Instruments are handled 15 minutes, add other alcohol-based fuels conventional additives 9.0kg, and alcohol-based fuel is made.
Tested according to 1 method of embodiment, testing result is as follows.
Embodiment 3
Take diphenyl germanous chloride 25kg, N- (4- methoxy-benzyls)-N- methylamines 16kg, cis -3- hexenols formic acid esters 15kg, 3- nonene -2- ketone 16kg, 2- acetylamino benzyl carbinol 12kg and dimethyl diselenide ether 16kg are added in stirred tank, often Stirred evenly under temperature, obtain transparent, the limpid additive finished product for reducing the generation of alcohol-based fuel pollutant.
1.5kg the present embodiment additives are added in 990kg crude glycols, is uniformly mixed, uses U.S. BRANSON's under room temperature BMT-180 Ultrasound Instruments are handled 15 minutes, add other alcohol-based fuels conventional additives 8.5kg, and alcohol-based fuel is made.
Tested according to 1 method of embodiment, testing result is as follows.
Embodiment 4
Take diphenyl germanous chloride 30kg, N- (4- methoxy-benzyls)-N- methylamines 19kg, cis -3- hexenols formic acid esters 17kg, 3- nonene -2- ketone 13kg, 2- acetylamino benzyl carbinol 11kg and dimethyl diselenide ether 10kg are added in stirred tank, often Stirred evenly under temperature, obtain transparent, the limpid additive finished product for reducing the generation of alcohol-based fuel pollutant.
2.0kg the present embodiment additives are added in 990kg crude glycols, is uniformly mixed, uses U.S. BRANSON's under room temperature BMT-180 Ultrasound Instruments are handled 15 minutes, add other alcohol-based fuels conventional additives 8.0kg, and alcohol-based fuel is made.
Tested according to 1 method of embodiment, testing result is as follows.
Embodiment 5
Take diphenyl germanous chloride 22kg, N- (4- methoxy-benzyls)-N- methylamines 20kg, cis -3- hexenols formic acid esters 16kg, 3- nonene -2- ketone 13kg, 2- acetylamino benzyl carbinol 19kg and dimethyl diselenide ether 10kg are added in stirred tank, often Stirred evenly under temperature, obtain transparent, the limpid additive finished product for reducing the generation of alcohol-based fuel pollutant.
2.5kg the present embodiment additives are added in 990kg crude glycols, is uniformly mixed, uses U.S. BRANSON's under room temperature BMT-180 Ultrasound Instruments are handled 15 minutes, add other alcohol-based fuels conventional additives 7.5kg, and alcohol-based fuel is made.
Tested according to 1 method of embodiment, testing result is as follows.
Embodiment 6
Take diphenyl germanous chloride 20kg, N- (4- methoxy-benzyls)-N- methylamines 16kg, cis -3- hexenols formic acid esters 17kg, 3- nonene -2- ketone 14kg, 2- acetylamino benzyl carbinol 17kg and dimethyl diselenide ether 16kg are added in stirred tank, often Stirred evenly under temperature, obtain transparent, the limpid additive finished product for reducing the generation of alcohol-based fuel pollutant.
3.0kg the present embodiment additives are added in 990kg crude glycols, is uniformly mixed, uses U.S. BRANSON's under room temperature BMT-180 Ultrasound Instruments are handled 15 minutes, add other alcohol-based fuels conventional additives 7.0kg, and alcohol-based fuel is made.
Tested according to 1 method of embodiment, testing result is as follows.
In above-described embodiment, sulfur dioxide, mercury and mercuric compounds do not detect, and flue gas blackness is less than 1 grade.Particulate matter and nitrogen oxygen Compound is far below GB 13271-2014《Emission standard of air pollutants for boilers》Middle key area gas fired-boiler 20mg/m3With 150mg/m3Limit value.

Claims (2)

1. reducing the additive of alcohol-based fuel pollutant emission, it is made of the component of following mass percents：Diphenyl dichloride Germanium 19~31%, N- (4- methoxy-benzyls)-N- methylamines 16~33%, cis -3- hexenols formic acid esters 15~26%, 3- nonenes -2- Ketone 12~24%, 2- acetylaminos benzyl carbinol 10~21%, dimethyl diselenide ether 9~19%.
2. the additive according to claim 1 for reducing alcohol-based fuel pollutant emission, it is characterized in that the additive exists Additive amount in alcohol-based fuel is 0.08~0.3wt%.
CN201611255481.6A 2016-12-30 2016-12-30 Reduce the additive of alcohol-based fuel pollutant emission Active CN106635199B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611255481.6A CN106635199B (en) 2016-12-30 2016-12-30 Reduce the additive of alcohol-based fuel pollutant emission

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611255481.6A CN106635199B (en) 2016-12-30 2016-12-30 Reduce the additive of alcohol-based fuel pollutant emission

Publications (2)

Publication Number Publication Date
CN106635199A CN106635199A (en) 2017-05-10
CN106635199B true CN106635199B (en) 2018-04-24

Family

ID=58837292

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611255481.6A Active CN106635199B (en) 2016-12-30 2016-12-30 Reduce the additive of alcohol-based fuel pollutant emission

Country Status (1)

Country Link
CN (1) CN106635199B (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003535967A (en) * 2000-06-20 2003-12-02 ザ ルブリゾル コーポレイション How to reduce pollutants from diesel engine exhaust
CN104449906A (en) * 2014-12-28 2015-03-25 山西华顿实业有限公司 Additive for reducing particle discharge of alcohol-based fuel
CN104449905A (en) * 2014-12-28 2015-03-25 山西华顿实业有限公司 Additive for reducing sulfur dioxide discharge of alcohol-based fuel
CN104479771A (en) * 2014-12-28 2015-04-01 山西华顿实业有限公司 Composition for inhibiting alcohol-based fuel for boilers from producing nitrogen oxides
CN104877719A (en) * 2015-04-30 2015-09-02 甘肃桑田清洁能源开发有限公司 Environment-friendly additive for alcohol-based fuel

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003535967A (en) * 2000-06-20 2003-12-02 ザ ルブリゾル コーポレイション How to reduce pollutants from diesel engine exhaust
CN104449906A (en) * 2014-12-28 2015-03-25 山西华顿实业有限公司 Additive for reducing particle discharge of alcohol-based fuel
CN104449905A (en) * 2014-12-28 2015-03-25 山西华顿实业有限公司 Additive for reducing sulfur dioxide discharge of alcohol-based fuel
CN104479771A (en) * 2014-12-28 2015-04-01 山西华顿实业有限公司 Composition for inhibiting alcohol-based fuel for boilers from producing nitrogen oxides
CN104449905B (en) * 2014-12-28 2016-05-11 山西华顿实业有限公司 Reduce the additive of alcohol-group fuel sulfur dioxide (SO2) emissions
CN104877719A (en) * 2015-04-30 2015-09-02 甘肃桑田清洁能源开发有限公司 Environment-friendly additive for alcohol-based fuel

Also Published As

Publication number Publication date
CN106635199A (en) 2017-05-10

Similar Documents

Publication Publication Date Title
CN105670715B (en) A kind of high-performance environment-friendly alcohol-based fuel and preparation method thereof
CN100510030C (en) Cleaning type combustion assistant for coal and oil
CN104615895B (en) The measuring method of coal dust and blast furnace gas multi-fuel fired boiler air leak rate of air preheater
CN108165326A (en) A kind of boiler methanol-based fuel
CN106635199B (en) Reduce the additive of alcohol-based fuel pollutant emission
CN104449906B (en) Reduce the granular material discharged additive of alcohol-group fuel
CN106957701B (en) Alcohol radical liquid fuel additive
CN103232868B (en) Novel environment-friendly high-energy alcohol-based industrial fuel and preparation method thereof
CN104479771B (en) Suppress the composition that boiler alcohol-group fuel nitrogen oxide generates
CN104877719B (en) Alcohol-group fuel environmental-protection additive
CN104449905B (en) Reduce the additive of alcohol-group fuel sulfur dioxide (SO2) emissions
CN101418244A (en) Alcohol-base liquid fuel
CN101486939B (en) Environment friendly coal-saving agent
CN104263431B (en) A kind of automobile fuel composition
CN101418242B (en) Energy-saving fuel oil and preparation method thereof
CN106947549A (en) A kind of high cleaning liquid boiler fuel
CN108384599B (en) Composite coal saving agent and application thereof
CN111763541A (en) High-calorific-value clean fuel for industrial boiler and preparation method thereof
CN104059700A (en) Efficient liquid fuel additive and liquid fuel with additive
CN113656758B (en) Method for calculating burn-up rate of one-dimensional flame furnace for mixed coal
CN110643406A (en) Preparation of coal-saving combustion improver
CN106118797B (en) A kind of coal-based alcohol ether fuel adjunct and its application based on chemical byproduct
CN203586217U (en) Dual-purpose burner of high temperature gas and fuel oil
CN102533357A (en) Methanol diesel fuel
CN113088348A (en) Industrial modified methanol fuel and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB03 Change of inventor or designer information

Inventor after: Guo Sihu

Inventor after: Zhang Di

Inventor before: Guo Sihu

CB03 Change of inventor or designer information
TA01 Transfer of patent application right

Effective date of registration: 20180308

Address after: 030001 Taiyuan New South Road, Shanxi, No. 56

Applicant after: Shanxi Medial University

Address before: The 036400 is Shanxi city of Xinzhou province Pianguan County Street No. 25

Applicant before: Guo Sihu

TA01 Transfer of patent application right
GR01 Patent grant
GR01 Patent grant