CN106635199A - Additive for reducing discharge of alcohol-based fuel pollutants - Google Patents
Additive for reducing discharge of alcohol-based fuel pollutants Download PDFInfo
- Publication number
- CN106635199A CN106635199A CN201611255481.6A CN201611255481A CN106635199A CN 106635199 A CN106635199 A CN 106635199A CN 201611255481 A CN201611255481 A CN 201611255481A CN 106635199 A CN106635199 A CN 106635199A
- Authority
- CN
- China
- Prior art keywords
- alcohol
- based fuel
- additive
- percent
- fuel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 56
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 239000000654 additive Substances 0.000 title claims abstract description 37
- 230000000996 additive effect Effects 0.000 title claims abstract description 24
- 239000003344 environmental pollutant Substances 0.000 title claims abstract description 22
- 231100000719 pollutant Toxicity 0.000 title claims abstract description 22
- VLXBWPOEOIIREY-UHFFFAOYSA-N dimethyl diselenide Chemical compound C[Se][Se]C VLXBWPOEOIIREY-UHFFFAOYSA-N 0.000 claims abstract description 18
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 16
- 125000004217 4-methoxybenzyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1OC([H])([H])[H])C([H])([H])* 0.000 claims description 8
- 235000010290 biphenyl Nutrition 0.000 claims description 8
- 239000004305 biphenyl Substances 0.000 claims description 8
- YCBSHDKATAPNIA-UHFFFAOYSA-N non-3-ene Chemical compound CCCCCC=CCC YCBSHDKATAPNIA-UHFFFAOYSA-N 0.000 claims description 8
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 8
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 claims description 2
- -1 Diphenyl dichloride Germanium Chemical compound 0.000 claims 1
- USNPJOCIOSNHDE-UHFFFAOYSA-N n-[2-(2-hydroxyethyl)phenyl]acetamide Chemical compound CC(=O)NC1=CC=CC=C1CCO USNPJOCIOSNHDE-UHFFFAOYSA-N 0.000 abstract description 7
- 238000002485 combustion reaction Methods 0.000 abstract description 2
- 239000000779 smoke Substances 0.000 abstract 2
- AIJFPNKGGAPZFJ-UHFFFAOYSA-N 1-(4-methoxyphenyl)-n-methylmethanamine Chemical compound CNCC1=CC=C(OC)C=C1 AIJFPNKGGAPZFJ-UHFFFAOYSA-N 0.000 abstract 1
- XFXOLBNQYFRSLQ-UHFFFAOYSA-N 3-amino-2-naphthoic acid Chemical compound C1=CC=C2C=C(C(O)=O)C(N)=CC2=C1 XFXOLBNQYFRSLQ-UHFFFAOYSA-N 0.000 abstract 1
- PFPTYRFVUHDUIN-UHFFFAOYSA-N dichloro(diphenyl)germane Chemical compound C=1C=CC=CC=1[Ge](Cl)(Cl)C1=CC=CC=C1 PFPTYRFVUHDUIN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 150000002334 glycols Chemical class 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 7
- 125000006267 biphenyl group Chemical group 0.000 description 7
- 238000002604 ultrasonography Methods 0.000 description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000003546 flue gas Substances 0.000 description 5
- 239000003245 coal Substances 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 239000000809 air pollutant Substances 0.000 description 3
- 231100001243 air pollutant Toxicity 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000013618 particulate matter Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229960004217 benzyl alcohol Drugs 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003500 flue dust Substances 0.000 description 1
- 239000002816 fuel additive Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000010761 intermediate fuel oil Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- DOTMOQHOJINYBL-UHFFFAOYSA-N molecular nitrogen;molecular oxygen Chemical compound N#N.O=O DOTMOQHOJINYBL-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 230000037351 starvation Effects 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 238000002525 ultrasonication Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1857—Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/23—Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
- C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2300/00—Mixture of two or more additives covered by the same group of C10L1/00 - C10L1/308
- C10L2300/20—Mixture of two components
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
The invention discloses an additive for reducing discharge of smoke gas pollutants of alcohol-based fuel for a boiler. The additive is prepared from the following ingredients in percentage by mass: 19 to 31 percent of diphenylgermanium dichloride, 16 to 33 percent of N-(4-methoxybenzyl)-N-methylamine, 15 to 26 percent of cis-3-hexenyl formate, 12 to 24 percent of 3-nonene-2-ketone, 10 to 21 percent of 2-acetamidophenethyl alcohol and 9 to 19 percent of dimethyldiselenide. The additive provided by the invention is added in alcohol-based fuel in percentage of 0.08 to 0.3 weight percent; the pollutants generated when the alcohol-based fuel combusts can be obviously reduced; the main pollutant discharge in the boiler combustion smoke gas is averagely reduced by about 1/4.
Description
Technical field
The invention belongs to alcohol-based fuel substitutes furnace fuel technical field, it is related to alcohol-based fuel additive, particularly relates to
And a kind of additive that can reduce the pollutant emission that alcohol-based fuel burning is produced.
Background technology
In China's using energy source structure, with serious pollution coal accounts for 70% or so of total energy consumption.Each class A fuel A boiler,
Burn in the burners such as kiln, produce the pollution such as substantial amounts of flue dust, oxysulfide, particulate matter, carbon monoxide, hydrocarbon
Thing.The enterprises and institutions such as thermal power generation, metallurgy, chemical industry, building materials and hospital, school and city dweller's heat supply etc. are all equipped with industry
Boiler, kiln or life heating boiler, especially medium small boiler kiln, quantity is more, distribution is wide, burning condition is poor, and flue gas exists
Low-altitude discharged, it is larger to some areas atmospheric pollution effect.For the problem of environmental pollution produced because of coal-burning boiler, kiln, subtract
The use of few coal furnace, popularization and application novel environment friendly clean fuel will be highly beneficial for city atmospheric environment quality is improved
's.
Alcohol-based fuel refers to the liquid fuel with alcohols (mainly methyl alcohol or crude glycol) as main modulation, is a kind of efficient, ring
The clean energy resource of guarantor.
With China's economic development and the raising of people's living standard, social, alcohol increasing to the demand of clean energy resource
Base liquid fuel is increasingly becoming novel alternative fuel because of its clean environment firendly.
, with methyl alcohol as primary raw material, raw material sources are wide, simple production process, technology maturation for alcohol-based fuel.China is " a richness
The country of coal, oil starvation, few gas ", coal resources conversion alcohol-based fuel is adapted to China's actual conditions.If this fuel is popularized, will
The shortage of China's oil resource is made up to a great extent, to improving State of Air pollution, readjusting the energy structure, ensure that the energy is pacified
There is extremely important strategic importance entirely.
The content of the invention
It is an object of the invention to provide a kind of reduction stove additive of alcohol-based fuel pollutant emission, is added into alcohol
In base fuel, the pollutant produced when alcohol-based fuel burns can be substantially reduced.
The additive of the reduction alcohol-based fuel pollutant emission that the present invention is provided is made up of the component of following mass percents：
Diphenyl germanous chloride 19～31%, N- (4- methoxy-benzyls)-N- methylamines 16～33%, cis -3- hexenols formic acid esters 15～
26%th, 3- nonenes -2- ketone 12～24%, 2- acetylaminos benzyl carbinol 10～21%, dimethyl diselenide ether 9～19%.
The each component of above-mentioned mass percent is mixed, stirring at normal temperature is uniform, you can obtain reduction alcohol of the present invention
The additive of base fuel contaminant discharge.
Addition of the additive in alcohol-based fuel for reducing alcohol-based fuel pollutant emission of the present invention be 0.08～
0.3wt%, specifically used method is the additive that the addition is first added in material benzenemethanol or crude glycol, is well mixed, ultrasound
After process, other conventional additives with the effect such as homogeneous, stable, combustion-supporting, inhibition are added, modulation is obtained alcohol-based fuel.
Wherein, described ultrasonically treated condition is at normal temperatures, with the ultrasonication 15 minutes of power 180W.
Alcohol-based fuel indices after the addition present composition are better than standard GB/T 16663-1996《Alcohol fluid
Fluid fuel》And professional standard NY 311-1997《Alcohol civil fuel》Require.
Environmental Protection Department is to the Hebei province environmental protection Room《Asking for version-related problems is performed with regard to alcohol-based fuel boiler
Show》（Ji Huanke (2015) 178）Write a letter in reply --- ring letter [2015] 319《It is relevant standard to be performed with regard to alcohol-based fuel boiler
Problem is write a letter in reply》Point out：" in the foreign countries such as European Union, Germany boiler emission standard, methyl alcohol, ethanol, pitch, fuel oil are sorted out
For liquid fuel class, unified standard limited value is performed, it is proposed that the boiler reference of alcohol-based fuel《Boiler Air Pollutant Emission mark
It is accurate》（GB 13271-2014）The emission control of intermediate fuel oil boiler requires to perform.”
The present invention is raw material from 12 kinds of crude glycols of separate sources in all parts of the country, and using additive of the present invention 48 alcohol radicals have been modulated
Fuel sample is each 1000 liters, burns on four normal pressure alcohol radical boilers respectively, according to GB 13271-2014《Boiler atmosphere pollution
Thing discharge standard》Boiler combustion discharge flue gas is detected.As a result show that pollutant emission averagely reduces a quarter or so,
Other pollutants are also below the special emission limit of key area gas fired-boiler that standard specifies.
The additive preparation process is simple of the present invention, it is nontoxic, pollution-free without metal and other harmful substance compositions, keep away
Exempt to produce secondary pollution to environment, addition is less, is that the extensive industrialized implementation of alcohol-based fuel has cleared away obstruction, has
Extensive promotional value.
Specific embodiment
Technical scheme is described in further detail below by way of specific embodiment, but the embodiment is not
It is understood that to be limiting the scope of the invention, make on the basis of the embodiment non-of those skilled in the art
The modifications and adaptations of matter, still fall within protection scope of the present invention.
Embodiment 1
Take diphenyl germanous chloride 19kg, N- (4- methoxy-benzyls)-N- methylamine 19kg, cis -3- hexenols formic acid esters 18kg,
3- nonene -2- ketone 17kg, 2- acetylamino benzyl carbinol 14.5kg and dimethyl diselenide ether 12.5kg are added in stirred tank, normal temperature
Under stir, obtain transparent, limpid reducing the additive finished product that alcohol-based fuel pollutant is generated.
0.8kg the present embodiment additives are added in 990kg crude glycols, be well mixed, under normal temperature with U.S. BRANSON's
BMT-180 Ultrasound Instruments are processed 15 minutes, add other alcohol-based fuels conventional additives 9.2kg, and alcohol-based fuel is obtained.
Raw material based on 12 kinds of crude glycols in all parts of the country is chosen, two groups of totally 24 alcohol-based fuel samples are modulated.Wherein first
Group is not added with the blank control group of additive of the present invention to use 12 kinds of crude glycol raw materials respectively；Second group for respectively using 12 kinds
Crude glycol raw material, and with the addition of the sample group of the present embodiment additive.
Wherein, the 12 kinds of crude glycols for using are respectively from Shanxi martial prowess chemical company, Yulin Chao Hua companies, Hebei and hold
De Yili coalifications company, Erdos Cheng Kai coalification company, Shandong Zibo Yi Da chemical company, Henan Jiaozhuo Sheng Hua companies, the Liao Dynasty
Xin Zhi chemical companies of peaceful Huludao City, Lianyun Harbour Su Yuan chemical companies, Hubei Xiangyang company of HTC and Ningbo Yi Likai industrial and trading companies
Deng.
1000 liters of each sample, testing results on four alcohol radical boilers respectively, boiler is two 0.7MW and Liang Tai
1.5MW normal-pressure hot-water boiler.Test detection method is with reference to GB/T 16157《Particulate matter is determined and gaseous state in Concentration in Fixed Pollutants Source
The pollutant method of sampling》、HJ/T 373《Stationary source monitors QA and QC technical specification》、HJ/T 397
《Stationary source wasted nickel catalyst technical specification》、HJ/T 398《The measure Ringelman flue gas of fixed-contamination source emission flue gas blackness
Blackness figure method》Newest GB 13271-2014 are pressed Deng, discharge standard《Emission standard of air pollutants for boilers》Perform.
Testing result is as follows.
Embodiment 2
Take diphenyl germanous chloride 20kg, N- (4- methoxy-benzyls)-N- methylamine 16kg, cis -3- hexenols formic acid esters 18kg,
3- nonene -2- ketone 17.5kg, 2- acetylamino benzyl carbinol 14kg and dimethyl diselenide ether 14.5kg are added in stirred tank, normal temperature
Under stir, obtain transparent, limpid reducing the additive finished product that alcohol-based fuel pollutant is generated.
1.0kg the present embodiment additives are added in 990kg crude glycols, be well mixed, under normal temperature with U.S. BRANSON's
BMT-180 Ultrasound Instruments are processed 15 minutes, add other alcohol-based fuels conventional additives 9.0kg, and alcohol-based fuel is obtained.
Tested according to the method for embodiment 1, testing result is as follows.
Embodiment 3
Take diphenyl germanous chloride 25kg, N- (4- methoxy-benzyls)-N- methylamine 16kg, cis -3- hexenols formic acid esters 15kg,
3- nonene -2- ketone 16kg, 2- acetylamino benzyl carbinol 12kg and dimethyl diselenide ether 16kg are added in stirred tank, are stirred under normal temperature
Mix uniform, obtain transparent, the limpid additive finished product that alcohol-based fuel pollutant is generated that reduces.
1.5kg the present embodiment additives are added in 990kg crude glycols, be well mixed, under normal temperature with U.S. BRANSON's
BMT-180 Ultrasound Instruments are processed 15 minutes, add other alcohol-based fuels conventional additives 8.5kg, and alcohol-based fuel is obtained.
Tested according to the method for embodiment 1, testing result is as follows.
Embodiment 4
Take diphenyl germanous chloride 30kg, N- (4- methoxy-benzyls)-N- methylamine 19kg, cis -3- hexenols formic acid esters 17kg,
3- nonene -2- ketone 13kg, 2- acetylamino benzyl carbinol 11kg and dimethyl diselenide ether 10kg are added in stirred tank, are stirred under normal temperature
Mix uniform, obtain transparent, the limpid additive finished product that alcohol-based fuel pollutant is generated that reduces.
2.0kg the present embodiment additives are added in 990kg crude glycols, be well mixed, under normal temperature with U.S. BRANSON's
BMT-180 Ultrasound Instruments are processed 15 minutes, add other alcohol-based fuels conventional additives 8.0kg, and alcohol-based fuel is obtained.
Tested according to the method for embodiment 1, testing result is as follows.
Embodiment 5
Take diphenyl germanous chloride 22kg, N- (4- methoxy-benzyls)-N- methylamine 20kg, cis -3- hexenols formic acid esters 16kg,
3- nonene -2- ketone 13kg, 2- acetylamino benzyl carbinol 19kg and dimethyl diselenide ether 10kg are added in stirred tank, are stirred under normal temperature
Mix uniform, obtain transparent, the limpid additive finished product that alcohol-based fuel pollutant is generated that reduces.
2.5kg the present embodiment additives are added in 990kg crude glycols, be well mixed, under normal temperature with U.S. BRANSON's
BMT-180 Ultrasound Instruments are processed 15 minutes, add other alcohol-based fuels conventional additives 7.5kg, and alcohol-based fuel is obtained.
Tested according to the method for embodiment 1, testing result is as follows.
Embodiment 6
Take diphenyl germanous chloride 20kg, N- (4- methoxy-benzyls)-N- methylamine 16kg, cis -3- hexenols formic acid esters 17kg,
3- nonene -2- ketone 14kg, 2- acetylamino benzyl carbinol 17kg and dimethyl diselenide ether 16kg are added in stirred tank, are stirred under normal temperature
Mix uniform, obtain transparent, the limpid additive finished product that alcohol-based fuel pollutant is generated that reduces.
3.0kg the present embodiment additives are added in 990kg crude glycols, be well mixed, under normal temperature with U.S. BRANSON's
BMT-180 Ultrasound Instruments are processed 15 minutes, add other alcohol-based fuels conventional additives 7.0kg, and alcohol-based fuel is obtained.
Tested according to the method for embodiment 1, testing result is as follows.
In above-described embodiment, sulfur dioxide, mercury and mercuric compounds are not detected, and flue gas blackness is less than 1 grade.Particulate matter and nitrogen oxygen
Compound is far below GB 13271-2014《Emission standard of air pollutants for boilers》Middle key area gas fired-boiler 20mg/m3With
150mg/m3Limit value.
Claims (2)
1. the additive of alcohol-based fuel pollutant emission is reduced, is made up of the component of following mass percents：Diphenyl dichloride
Germanium 19～31%, N- (4- methoxy-benzyls)-N- methylamines 16～33%, cis -3- hexenols formic acid esters 15～26%, 3- nonene -2-
Ketone 12～24%, 2- acetylaminos benzyl carbinol 10～21%, dimethyl diselenide ether 9～19%.
2. the additive for reducing alcohol-based fuel pollutant emission according to claim 1, is characterized in that the additive exists
Addition in alcohol-based fuel is 0.08～0.3wt%.
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| JP2003535967A (en) * | 2000-06-20 | 2003-12-02 | ザ ルブリゾル コーポレイション | How to reduce pollutants from diesel engine exhaust |
| CN104449906A (en) * | 2014-12-28 | 2015-03-25 | 山西华顿实业有限公司 | Additive for reducing particle discharge of alcohol-based fuel |
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