CN106634868A - 一种含富勒醇的有机型发动机冷却液及其制备方法 - Google Patents
一种含富勒醇的有机型发动机冷却液及其制备方法 Download PDFInfo
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- CN106634868A CN106634868A CN201611149280.8A CN201611149280A CN106634868A CN 106634868 A CN106634868 A CN 106634868A CN 201611149280 A CN201611149280 A CN 201611149280A CN 106634868 A CN106634868 A CN 106634868A
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- fullerol
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- cooling liquid
- engine cooling
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- 239000002826 coolant Substances 0.000 title claims abstract description 38
- 239000007788 liquid Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 238000005260 corrosion Methods 0.000 claims abstract description 37
- 230000007797 corrosion Effects 0.000 claims abstract description 36
- 150000007524 organic acids Chemical class 0.000 claims abstract description 35
- 239000003112 inhibitor Substances 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000008367 deionised water Substances 0.000 claims abstract description 9
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 9
- 150000003851 azoles Chemical class 0.000 claims abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 33
- 239000000110 cooling liquid Substances 0.000 claims description 29
- 239000011259 mixed solution Substances 0.000 claims description 28
- 239000013530 defoamer Substances 0.000 claims description 25
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 24
- 239000000975 dye Substances 0.000 claims description 20
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 20
- 239000000243 solution Substances 0.000 claims description 18
- 150000001298 alcohols Chemical class 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
- 150000002763 monocarboxylic acids Chemical class 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 7
- 239000000047 product Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 150000001735 carboxylic acids Chemical class 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- MOFINMJRLYEONQ-UHFFFAOYSA-N [N].C=1C=CNC=1 Chemical class [N].C=1C=CNC=1 MOFINMJRLYEONQ-UHFFFAOYSA-N 0.000 claims 1
- 125000005605 benzo group Chemical group 0.000 claims 1
- 238000001802 infusion Methods 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 abstract description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 12
- 229910052751 metal Inorganic materials 0.000 abstract description 12
- 239000002184 metal Substances 0.000 abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 5
- 239000002518 antifoaming agent Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract description 3
- 229910000975 Carbon steel Inorganic materials 0.000 abstract description 2
- 229910001018 Cast iron Inorganic materials 0.000 abstract description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 2
- 239000010962 carbon steel Substances 0.000 abstract description 2
- 239000010949 copper Substances 0.000 abstract description 2
- 229910052802 copper Inorganic materials 0.000 abstract description 2
- 229910000928 Yellow copper Inorganic materials 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 abstract 1
- 238000005476 soldering Methods 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 19
- 239000012153 distilled water Substances 0.000 description 12
- 239000004411 aluminium Substances 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 8
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 8
- 229910052710 silicon Inorganic materials 0.000 description 8
- 239000010703 silicon Substances 0.000 description 8
- 239000012263 liquid product Substances 0.000 description 7
- 150000007513 acids Chemical class 0.000 description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
- 235000011037 adipic acid Nutrition 0.000 description 6
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical class CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 6
- 230000003628 erosive effect Effects 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229920000305 Nylon 6,10 Polymers 0.000 description 4
- 230000002421 anti-septic effect Effects 0.000 description 4
- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- 241000220317 Rosa Species 0.000 description 3
- 239000001361 adipic acid Substances 0.000 description 3
- 150000001279 adipic acids Chemical class 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 3
- 230000005764 inhibitory process Effects 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 2
- 241001062009 Indigofera Species 0.000 description 2
- -1 Propane diols Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N dimethylmethane Natural products CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229960002446 octanoic acid Drugs 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 239000001043 yellow dye Substances 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical class OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009396 hybridization Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003442 suberic acids Chemical class 0.000 description 1
- 230000009469 supplementation Effects 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/20—Antifreeze additives therefor, e.g. for radiator liquids
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
Description
Claims (10)
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CN201611149280.8A CN106634868B (zh) | 2016-11-27 | 2016-11-27 | 一种含富勒醇的有机型发动机冷却液及其制备方法 |
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CN201611149280.8A CN106634868B (zh) | 2016-11-27 | 2016-11-27 | 一种含富勒醇的有机型发动机冷却液及其制备方法 |
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CN106634868A true CN106634868A (zh) | 2017-05-10 |
CN106634868B CN106634868B (zh) | 2020-11-17 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108949118A (zh) * | 2018-08-16 | 2018-12-07 | 苏州火睿新材料科技有限公司 | 含羟基化富勒烯的无水冷却液及其制备方法 |
Citations (9)
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---|---|---|---|---|
CN101432403A (zh) * | 2006-04-28 | 2009-05-13 | 日产自动车株式会社 | 低摩擦润滑组件 |
CN101528887A (zh) * | 2006-09-01 | 2009-09-09 | 纳幕尔杜邦公司 | 氟烯烃用的环氧化物和氟化环氧化物稳定剂 |
CN101768428A (zh) * | 2008-12-31 | 2010-07-07 | 中国蓝星(集团)股份有限公司 | 一种发动机冷却液 |
CN101768429A (zh) * | 2010-01-26 | 2010-07-07 | 安徽江淮航天技术开发有限公司 | 有机环保型液态导热介质 |
CN103666403A (zh) * | 2013-12-02 | 2014-03-26 | 青岛康普顿科技股份有限公司 | 一种汽车发动机冷却液 |
CN103666404A (zh) * | 2013-12-26 | 2014-03-26 | 北京蓝星科技有限公司 | 一种全有机硬水稳定型发动机冷却液及其制作方法 |
CN104059618A (zh) * | 2014-04-29 | 2014-09-24 | 四川力森特环保科技有限公司 | 一种发动机用氧化石墨烯无水冷却液及其制备方法 |
CN104293311A (zh) * | 2013-07-20 | 2015-01-21 | 辽宁润迪精细化工有限公司 | 一种环保型冷却液 |
CN104479644A (zh) * | 2014-12-11 | 2015-04-01 | 山东大学 | 石墨烯型冷却介质及制备方法和应用 |
-
2016
- 2016-11-27 CN CN201611149280.8A patent/CN106634868B/zh active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101432403A (zh) * | 2006-04-28 | 2009-05-13 | 日产自动车株式会社 | 低摩擦润滑组件 |
CN101528887A (zh) * | 2006-09-01 | 2009-09-09 | 纳幕尔杜邦公司 | 氟烯烃用的环氧化物和氟化环氧化物稳定剂 |
CN101768428A (zh) * | 2008-12-31 | 2010-07-07 | 中国蓝星(集团)股份有限公司 | 一种发动机冷却液 |
CN101768429A (zh) * | 2010-01-26 | 2010-07-07 | 安徽江淮航天技术开发有限公司 | 有机环保型液态导热介质 |
CN104293311A (zh) * | 2013-07-20 | 2015-01-21 | 辽宁润迪精细化工有限公司 | 一种环保型冷却液 |
CN103666403A (zh) * | 2013-12-02 | 2014-03-26 | 青岛康普顿科技股份有限公司 | 一种汽车发动机冷却液 |
CN103666404A (zh) * | 2013-12-26 | 2014-03-26 | 北京蓝星科技有限公司 | 一种全有机硬水稳定型发动机冷却液及其制作方法 |
CN104059618A (zh) * | 2014-04-29 | 2014-09-24 | 四川力森特环保科技有限公司 | 一种发动机用氧化石墨烯无水冷却液及其制备方法 |
CN104479644A (zh) * | 2014-12-11 | 2015-04-01 | 山东大学 | 石墨烯型冷却介质及制备方法和应用 |
Non-Patent Citations (1)
Title |
---|
徐铭飞: "水溶性多羟基富勒烯及其衍生物的合成与性能研究", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108949118A (zh) * | 2018-08-16 | 2018-12-07 | 苏州火睿新材料科技有限公司 | 含羟基化富勒烯的无水冷却液及其制备方法 |
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Effective date of registration: 20171221 Address after: 266101 No. 18, Shenzhen Road, Laoshan District, Shandong, Qingdao Applicant after: Qingdao Copton Technology Co., Ltd. Applicant after: Qingdao University of Science & Technology Applicant after: Qingdao Compton Petrochemical Co., Ltd. Address before: 266101 No. 18, Shenzhen Road, Laoshan District, Shandong, Qingdao Applicant before: Qingdao Copton Technology Co., Ltd. Applicant before: Qingdao University of Science & Technology |
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