CN106634686A - Novel environment-friendly adhesive sticker material - Google Patents
Novel environment-friendly adhesive sticker material Download PDFInfo
- Publication number
- CN106634686A CN106634686A CN201610882893.6A CN201610882893A CN106634686A CN 106634686 A CN106634686 A CN 106634686A CN 201610882893 A CN201610882893 A CN 201610882893A CN 106634686 A CN106634686 A CN 106634686A
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- Prior art keywords
- parts
- water
- novel environment
- acid
- adhesive material
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/04—Starch derivatives
- C09J103/10—Oxidised starch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
- C09J167/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to a novel environment-friendly adhesive sticker material. The material comprises an adhesive layer prepared from components in parts by weight as follows: 91-108 parts of water, 22-57 parts of modified starch, 20-40 parts of a lactic acid-glycolic acid copolymer, 20-40 parts of polyglycolic acid, 10-45 parts of polyhydroxyalkanoate, 1-15 parts of an alkaline matter, 1-8 parts of a water-proof agent, 0.2-4.5 parts of a crosslinking agent and 0.2-4.5 parts of an antibacterial agent. The novel environment-friendly adhesive sticker material has the effects of being high in bonding force, pollution-free and low in production cost.
Description
Technical field
The present invention relates to adhesive material technical field, more particularly to a kind of novel environment friendly adhesive material.
Background technology
Adhesive sticker originates from the thirties in last century, because it has without brush coating, without paste, without dipping in water, pollution-free, section
The advantages of saving the labeling time, is widely used in all trades and professions industry.Adhesive material mainly includes facial tissue layer, gluing
Oxidant layer and ground paper layer.Wherein, adhesive layer is the very important part of adhesive label.Adhesive material often have corrugation,
Alice, the phenomenon such as come off, and this is all relevant with the performance quality of adhesive layer.
Traditional adhesive material difficult degradation, difficult recovery, to environment immense pressure is caused.As the whole world is wanted to environment
More and more higher, environment-friendly type adhesive material is asked to become the emerging product in domestic and international adhesive material field.Biodegradable is not
The adhesive layer of dry glue material has the advantages that degradability, environmentally safe become the emphasis and focus of research, institute because of it
To be necessary to be improved the adhesive layer of existing adhesive material.
The content of the invention
It is an object of the invention to provide a kind of cohesive force is strong, the novel environment friendly of environmentally safe, low production cost is not done
Glue material.
To reach above-mentioned purpose, the invention provides a kind of novel environment friendly adhesive material, including adhesive layer, the glue
Adhensive layer contains the component of following weight portion：Water 91-108 parts, modified starch 22-57 parts, poly lactic coglycolic acid 20-
40 parts, polyglycolic acid 20-40 parts, polyhydroxyalkanoate 10-45 parts, alkaline matter 1-15 parts, water-proofing agent 1-8 parts, crosslinking
Agent 0.2-4.5 parts, antiseptic 0.2-4.5 parts.
Preferably, in novel environment friendly adhesive material of the present invention, the adhesive layer contains the component of following weight portion：Water
95-102 parts, modified starch 25-40 parts, poly lactic coglycolic acid 25-35 parts, polyglycolic acid 25-38 parts, poly- hydroxyl
Fatty acid ester 15-40 parts, alkaline matter 5-10 parts, water-proofing agent 3-7 parts, crosslinking agent 0.6-4 parts, antiseptic 0.2-4 parts.
It is highly preferred that the adhesive layer contains the component of following weight portion：98 parts of water, 30 parts of modified starch, lactic acid-hydroxyl
26 parts of acetic acid copolymer, 30 parts of polyglycolic acid, 35 parts of polyhydroxyalkanoate, 8 parts of alkaline matter, 6 parts of water-proofing agent, crosslinking
2 parts of agent, 0.2 part of antiseptic.
Preferably, in novel environment friendly adhesive material of the present invention, the modified starch is that sodium hypochlorite forms sediment to natural plants
What powder was obtained after being aoxidized.
Preferably, in novel environment friendly adhesive material of the present invention, the crosslinking agent is borax, sodium metaaluminate, potassium pyroantimonate
In one or two.
Preferably, in novel environment friendly adhesive material of the present invention, the antiseptic is shitosan, sorbic acid, polypyridine, poly-
One or two in thiazole.
The present invention is by poly lactic coglycolic acid, poly- hydroxyl second, polyhydroxyalkanoate degradable biological material should
For adhesive material field so that facestock can be completely achieved biodegradable with adhesive without the need for subsequent treatment；Using modified
Starch, can effectively strengthen cohesive force, adhesion strength and the water resistance of adhesive layer；Additionally, the present invention has preparation method
Simply, low production cost, the advantage of environmentally safe.
Specific embodiment
Novel environment friendly adhesive material of the present invention, including adhesive layer, wherein adhesive layer are located at the face of adhesive material
Between ply of paper and ground paper layer.
In specific embodiment 1, the adhesive layer contains the component of following weight portion：Water 91-108 parts, modified starch
22-57 parts, poly lactic coglycolic acid 20-40 parts, polyglycolic acid 20-40 parts, polyhydroxyalkanoate 10-45 parts, alkali
Property material 1-15 parts, water-proofing agent 1-8 parts, crosslinking agent 0.2-4.5 parts, antiseptic 0.2-4.5 parts.
In specific embodiment 2, the adhesive layer contains the component of following weight portion：Water 95-102 parts, modified starch
25-40 parts, poly lactic coglycolic acid 25-35 parts, polyglycolic acid 25-38 parts, polyhydroxyalkanoate 15-40 parts, alkali
Property material 5-10 parts, water-proofing agent 3-7 parts, crosslinking agent 0.6-4 parts, antiseptic 0.2-4 parts.
In specific embodiment 3, the adhesive layer contains the component of following weight portion：98 parts of water, 30 parts of modified starch,
26 parts of poly lactic coglycolic acid, 30 parts of polyglycolic acid, 35 parts of polyhydroxyalkanoate, 8 parts of alkaline matter, water-proofing agent 6
Part, 2 parts of crosslinking agent, 0.2 part of antiseptic.
In comparing embodiment, the adhesive layer contains the component of following weight portion：Water 91-108 parts, modified starch 22-
57 parts, polyhydroxyalkanoate 10-45 parts, alkaline matter 1-15 parts, water-proofing agent 1-8 parts, crosslinking agent 0.2-4.5 parts, antiseptic
0.2-4.5 parts.
The modified starch is obtained after sodium hypochlorite is aoxidized to natural plant starch.The crosslinking agent is boron
One or two in sand, sodium metaaluminate, potassium pyroantimonate.The antiseptic is in shitosan, sorbic acid, polypyridine, polythiazole
One or two.
The degradation rate of the adhesive layer of above-mentioned specific embodiment 1-3, adhesion, can load force, the experiment number of extensibility
It is as follows according to contrasting：
The preparation method of novel environment friendly adhesive material label of the present invention：
Embodiment 1
Weigh water 91g, modified starch 22g, poly lactic coglycolic acid 20g, polyglycolic acid 10g, poly- hydroxy aliphatic
Acid esters 10g, alkaline matter 1g, water-proofing agent 1g, boric acid 0.2g, shitosan 0.2g.Modified starch is soluble in water, stir 30min
After add alkaline matter, continue to stir 20min, add poly lactic coglycolic acid, polyglycolic acid, poly-hydroxy fatty acid
Ester, continues to stir 25min, is eventually adding alkaline matter, water-proofing agent, boric acid and shitosan, continue to stir until sample it is uniform and
Tacky flowing, stands, and naturally cools to and saved backup after room temperature.
Embodiment 2
Weigh water 108g, modified starch 56g, poly lactic coglycolic acid 40g, polyglycolic acid 40g, poly- hydroxyl fat
Fat acid esters 45g, alkaline matter 10g, water-proofing agent 8g, sodium metaaluminate 4.5g, sorbic acid 4.5g.Modified starch is soluble in water, stir
Mix and add after 30min alkaline matter, continue to stir 20min, add poly lactic coglycolic acid, polyglycolic acid, poly- hydroxyl
Fatty acid ester, continues to stir 25min, is eventually adding alkaline matter, water-proofing agent, sodium metaaluminate and sorbic acid, continue to stir until
Sample is uniform and tacky flowing, stands, and naturally cools to and saved backup after room temperature.
Embodiment 3
Weigh water 98g, modified starch 30g, poly lactic coglycolic acid 26g, polyglycolic acid 30g, poly- hydroxy aliphatic
Acid esters 35g, alkaline matter 8g, water-proofing agent 6g, potassium pyroantimonate 2g, polypyridine 2g.Modified starch is soluble in water, stir 30min
After add alkaline matter, continue to stir 20min, add poly lactic coglycolic acid, polyglycolic acid, poly-hydroxy fatty acid
Ester, continues to stir 25min, is eventually adding alkaline matter, water-proofing agent, potassium pyroantimonate and polypyridine, continues to stir until sample is equal
Even and tacky flowing, stands, and naturally cools to and saved backup after room temperature.
Adopt the adhesive layer to prepare the method for novel environment friendly adhesive material label for：By adhesive obtained above
It is evenly coated on the facial tissue for having prepared, is subsequently placed in oven for drying, obtain coating the facestock of adhesive, adhesive will be coated
The pressing that facestock passes through rubber rollers and cylinder with base stock, you can obtain adhesive label.
Above-described is only some embodiments of the present invention.For the person of ordinary skill of the art, not
On the premise of departing from the invention design, some deformations and improvement can also be made, these belong to the protection model of the present invention
Enclose.
Claims (6)
1. a kind of novel environment friendly adhesive material, including adhesive layer, it is characterised in that the adhesive layer contains following weight
The component of part：Water 91-108 parts, modified starch 22-57 parts, poly lactic coglycolic acid 20-40 parts, polyglycolic acid 20-
40 parts, polyhydroxyalkanoate 10-45 parts, alkaline matter 1-15 parts, water-proofing agent 1-8 parts, crosslinking agent 0.2-4.5 parts, antiseptic
0.2-4.5 parts.
2. novel environment friendly adhesive material according to claim 1, it is characterised in that the adhesive layer contains following heavy
The component of amount part：Water 95-102 parts, modified starch 25-40 parts, poly lactic coglycolic acid 25-35 parts, polyglycolic acid
25-38 parts, polyhydroxyalkanoate 15-40 parts, alkaline matter 5-10 parts, water-proofing agent 3-7 parts, crosslinking agent 0.6-4 parts, antiseptic
0.2-4 parts.
3. novel environment friendly adhesive material according to claim 1, it is characterised in that the adhesive layer contains following heavy
The component of amount part：98 parts of water, 30 parts of modified starch, 26 parts of poly lactic coglycolic acid, 30 parts of polyglycolic acid, poly- hydroxyl
35 parts of fatty acid ester, 8 parts of alkaline matter, 6 parts of water-proofing agent, 2 parts of crosslinking agent, 0.2 part of antiseptic.
4. the novel environment friendly adhesive material according to any one of claim 1-3, it is characterised in that the modified starch
It is to obtain after sodium hypochlorite is aoxidized to natural plant starch.
5. the novel environment friendly adhesive material according to any one of claim 1-3, it is characterised in that the crosslinking agent is
One or two in borax, sodium metaaluminate, potassium pyroantimonate.
6. the novel environment friendly adhesive material according to any one of claim 1-3, it is characterised in that the antiseptic is
One or two in shitosan, sorbic acid, polypyridine, polythiazole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610882893.6A CN106634686A (en) | 2016-10-10 | 2016-10-10 | Novel environment-friendly adhesive sticker material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610882893.6A CN106634686A (en) | 2016-10-10 | 2016-10-10 | Novel environment-friendly adhesive sticker material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106634686A true CN106634686A (en) | 2017-05-10 |
Family
ID=58855042
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610882893.6A Pending CN106634686A (en) | 2016-10-10 | 2016-10-10 | Novel environment-friendly adhesive sticker material |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107418492A (en) * | 2017-06-12 | 2017-12-01 | 北京工商大学 | A kind of biodegradable adhesive and its production and use |
| CN108192534A (en) * | 2017-12-29 | 2018-06-22 | 上海金大塑胶有限公司 | A kind of novel Self-leveling adhesive material |
| CN109147548A (en) * | 2018-08-22 | 2019-01-04 | 海安金通新材料科技有限公司 | A kind of environmental protection adhesive label and preparation method thereof |
| CN110216961A (en) * | 2019-06-03 | 2019-09-10 | 睿泊(中国)环保科技有限公司 | A kind of environment friendly composite material and preparation method thereof that metal, plastics classification can be recycled |
| CN110253997A (en) * | 2019-06-03 | 2019-09-20 | 睿泊(中国)环保科技有限公司 | It is a kind of classify recycle the environment friendly composite material and preparation method thereof of metal, plastics, paper |
| CN110341275A (en) * | 2019-06-03 | 2019-10-18 | 睿泊(中国)环保科技有限公司 | A kind of environment friendly composite material and preparation method thereof for the recycling that basis material can be classified |
| CN111139001A (en) * | 2019-12-20 | 2020-05-12 | 株洲工大彩色印刷有限公司 | Antibacterial starch adhesive and preparation method thereof |
| CN112226191A (en) * | 2020-08-24 | 2021-01-15 | 江苏美境新材料有限公司 | Biodegradable adhesive and preparation method thereof |
| CN113881106A (en) * | 2021-11-17 | 2022-01-04 | 广州市欣竹不干胶材料有限公司 | Environment-friendly degradable self-adhesive paper and preparation method thereof |
| CN115232571A (en) * | 2022-08-19 | 2022-10-25 | 珠海腾佳印务有限公司 | Novel environment-friendly adhesive sticker |
| CN115322722A (en) * | 2022-08-22 | 2022-11-11 | 珠海腾佳印务有限公司 | Environment-friendly degradable self-adhesive paper and preparation method thereof |
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| CN101538454A (en) * | 2008-03-18 | 2009-09-23 | 天津国韵生物材料有限公司 | Adhesive and preparation method thereof |
| CN102867459A (en) * | 2011-11-07 | 2013-01-09 | 中国印刷科学技术研究所 | Biodegradable adhesive sticker label |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107418492B (en) * | 2017-06-12 | 2020-07-28 | 北京工商大学 | Biodegradable adhesive and preparation method and application thereof |
| CN107418492A (en) * | 2017-06-12 | 2017-12-01 | 北京工商大学 | A kind of biodegradable adhesive and its production and use |
| CN108192534A (en) * | 2017-12-29 | 2018-06-22 | 上海金大塑胶有限公司 | A kind of novel Self-leveling adhesive material |
| CN109147548A (en) * | 2018-08-22 | 2019-01-04 | 海安金通新材料科技有限公司 | A kind of environmental protection adhesive label and preparation method thereof |
| CN110253997B (en) * | 2019-06-03 | 2021-08-10 | 睿泊(中国)环保科技有限公司 | Environment-friendly composite material capable of recycling metal, plastic and paper in classified manner and preparation method thereof |
| CN110341275A (en) * | 2019-06-03 | 2019-10-18 | 睿泊(中国)环保科技有限公司 | A kind of environment friendly composite material and preparation method thereof for the recycling that basis material can be classified |
| CN110253997A (en) * | 2019-06-03 | 2019-09-20 | 睿泊(中国)环保科技有限公司 | It is a kind of classify recycle the environment friendly composite material and preparation method thereof of metal, plastics, paper |
| CN110341275B (en) * | 2019-06-03 | 2021-08-10 | 睿泊(中国)环保科技有限公司 | Environment-friendly composite material capable of classifying and recycling matrix materials and preparation method thereof |
| CN110216961B (en) * | 2019-06-03 | 2021-08-10 | 睿泊(中国)环保科技有限公司 | Environment-friendly composite material capable of classifying and recycling metal and plastic and preparation method thereof |
| CN110216961A (en) * | 2019-06-03 | 2019-09-10 | 睿泊(中国)环保科技有限公司 | A kind of environment friendly composite material and preparation method thereof that metal, plastics classification can be recycled |
| CN111139001A (en) * | 2019-12-20 | 2020-05-12 | 株洲工大彩色印刷有限公司 | Antibacterial starch adhesive and preparation method thereof |
| CN111139001B (en) * | 2019-12-20 | 2021-05-14 | 株洲工大彩色印刷有限公司 | Antibacterial starch adhesive and preparation method thereof |
| CN112226191A (en) * | 2020-08-24 | 2021-01-15 | 江苏美境新材料有限公司 | Biodegradable adhesive and preparation method thereof |
| CN113881106A (en) * | 2021-11-17 | 2022-01-04 | 广州市欣竹不干胶材料有限公司 | Environment-friendly degradable self-adhesive paper and preparation method thereof |
| CN115232571A (en) * | 2022-08-19 | 2022-10-25 | 珠海腾佳印务有限公司 | Novel environment-friendly adhesive sticker |
| CN115322722A (en) * | 2022-08-22 | 2022-11-11 | 珠海腾佳印务有限公司 | Environment-friendly degradable self-adhesive paper and preparation method thereof |
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Application publication date: 20170510 |
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