CN115232571A - Novel environment-friendly adhesive sticker - Google Patents
Novel environment-friendly adhesive sticker Download PDFInfo
- Publication number
- CN115232571A CN115232571A CN202211001478.7A CN202211001478A CN115232571A CN 115232571 A CN115232571 A CN 115232571A CN 202211001478 A CN202211001478 A CN 202211001478A CN 115232571 A CN115232571 A CN 115232571A
- Authority
- CN
- China
- Prior art keywords
- parts
- water
- adhesive layer
- epoxy resin
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 28
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 23
- 239000012790 adhesive layer Substances 0.000 claims abstract description 18
- 239000003822 epoxy resin Substances 0.000 claims abstract description 16
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 16
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920000881 Modified starch Polymers 0.000 claims abstract description 7
- 239000004368 Modified starch Substances 0.000 claims abstract description 7
- 229920000954 Polyglycolide Polymers 0.000 claims abstract description 7
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 7
- 235000019426 modified starch Nutrition 0.000 claims abstract description 7
- 239000004633 polyglycolic acid Substances 0.000 claims abstract description 7
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 7
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims abstract description 7
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 7
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 7
- 239000013053 water resistant agent Substances 0.000 claims abstract description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- 229940077388 benzenesulfonate Drugs 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- -1 sodium alkyl benzene Chemical class 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 229920003023 plastic Polymers 0.000 abstract description 2
- 239000004033 plastic Substances 0.000 abstract description 2
- 239000010409 thin film Substances 0.000 abstract description 2
- 239000002023 wood Substances 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 15
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000004026 adhesive bonding Methods 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000010345 tape casting Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000004826 Synthetic adhesive Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/04—Starch derivatives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
- C09J129/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
- C09J167/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/324—Alkali metal phosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a novel environment-friendly adhesive sticker which comprises an adhesive layer, wherein the adhesive layer comprises the following components in parts by weight: 91-108 parts of water, 22-57 parts of modified starch, 20-40 parts of 15% polyvinyl formal, 20-40 parts of polyglycolic acid, 10-45 parts of dibutyl phthalate, 1-15 parts of modified epoxy resin, 1-8 parts of water-resistant agent, 0.2-4.5 parts of sodium hexametaphosphate and 0.2-4.5 parts of antibacterial agent. Compared with the prior art, the invention has the advantages that: the adhesive layer has the advantages of environment-friendly components, no harm to human bodies in the production process, strong cohesiveness, difficult shedding and excellent durability; the adhesive has good waterproofness, high temperature resistance and wide application range, is suitable for paper labels and is also suitable for wood and thin film plastic.
Description
Technical Field
The invention relates to the technical field of non-setting adhesive materials, in particular to a novel environment-friendly non-setting adhesive.
Background
The self-adhesive label material is a composite material which takes paper, film or special material as a plus material, the back surface is coated with adhesive, and silicon-coated protective paper is taken as base paper. The non-setting adhesive is originated in the last 30 th century, and has wide application in various industries because of the advantages of no need of brushing adhesive, paste, dipping water, pollution, labeling time saving and the like. The self-adhesive material mainly comprises a surface paper layer, an adhesive layer and a bottom paper layer. Wherein, the adhesive layer is an important component of the self-adhesive label. The non-setting adhesive material often has the phenomena of wrinkling, edge warping, falling off and the like, which are related to the performance quality of the adhesive layer.
The adhesive sticker materials are formed in different grades due to various coating technologies, the current development direction is to develop from the traditional roll coating and scraper coating to the high-pressure tape casting coating direction so as to ensure the uniform sensitivity of the coating to the maximum extent, avoid the generation of bubbles and pinholes and ensure the coating quality, the technology of the tape casting coating is not mature in China, and the traditional roll coating is mainly adopted in China.
The gluing (bonding, adhering, cementing, gluing) refers to a technique of connecting the surfaces of homogeneous or heterogeneous objects together by using an adhesive, and has the characteristics of continuous stress distribution, light weight, sealing, low temperature of most processes and the like. The glue joint is particularly suitable for connecting different materials, different thicknesses, ultrathin specifications and complex components. The glue joint has the fastest recent development and extremely wide application industry, and has great influence on the improvement of high-tech scientific and technical progress and the daily life of people. Therefore, it is very important to research, develop and produce various adhesives. The synthetic adhesive consists of a main agent and an auxiliary agent, wherein the main agent is also called as a main material, a base material or a bonding material; the auxiliary agent comprises curing agent, diluent, plasticizer, filler, coupling agent, initiator, thickener, anti-aging agent, polymerization inhibitor, stabilizer, complexing agent, emulsifier and the like, and can also comprise flame retardant, foaming agent, defoamer, colorant, mildewproof agent and the like according to requirements and purposes.
The traditional adhesive sticker material is difficult to degrade and recycle, and causes great pressure to the environment. With the global requirement on the environment becoming higher and higher, the environment-friendly adhesive sticker material has become a new product in the field of adhesive stickers at home and abroad. The adhesive layer of the biodegradable self-adhesive material becomes a key point and a focus of research due to the advantages of degradability, no pollution to the environment and the like, so that the improvement of the adhesive layer of the existing self-adhesive material is necessary.
Therefore, a new environmental-friendly adhesive sticker is urgently needed to be researched to solve the above-mentioned problems.
Disclosure of Invention
The invention aims to overcome the technical defects and provides a novel environment-friendly adhesive sticker which comprises an adhesive layer, wherein the adhesive layer comprises the following components in parts by weight: 91-108 parts of water, 22-57 parts of modified starch, 20-40 parts of 15% polyvinyl formal, 20-40 parts of polyglycolic acid, 10-45 parts of dibutyl phthalate, 1-15 parts of modified epoxy resin, 1-8 parts of water-resistant agent, 0.2-4.5 parts of sodium hexametaphosphate and 0.2-4.5 parts of antibacterial agent.
Further, the adhesive layer comprises the following components in parts by weight: 95-100 parts of water, 20-45 parts of modified starch, 25-35 parts of 15% polyvinyl formal, 25-35 parts of polyglycolic acid, 10-35 parts of dibutyl phthalate, 1-10 parts of modified epoxy resin, 1-6 parts of water-resistant agent, 2-4 parts of sodium hexametaphosphate and 1-3.5 parts of antibacterial agent.
Further, the preparation method of the modified epoxy resin comprises the following steps:
s1, adding 180mL of deionized water into a four-mouth bottle, adding 0.5mol of sodium alkyl benzene sulfonate and 0.2mol of potassium persulfate, introducing nitrogen to discharge air in the four-mouth bottle, and stirring for 50min to obtain a solution A;
s2, adding 0.6mol of epoxy resin and 0.2mol of vinyl acetate into the solution A in the S1, stirring for 2 hours, then heating to 80 ℃, reacting for 50min, and then cooling to 50 ℃ to obtain the modified epoxy resin.
Compared with the prior art, the invention has the advantages that:
1. the adhesive layer has the advantages of environment-friendly components, no harm to human bodies in the production process, strong cohesiveness, difficult falling and excellent durability;
2. the adhesive has good waterproofness, high temperature resistance and wide application range, is suitable for paper labels and is also suitable for wood and thin film plastic.
Detailed Description
The novel environment-friendly adhesive sticker comprises an adhesive layer, wherein the adhesive layer contains the following components in parts by weight: 91-108 parts of water, 22-57 parts of modified starch, 20-40 parts of 15% polyvinyl formal, 20-40 parts of polyglycolic acid, 10-45 parts of dibutyl phthalate, 1-15 parts of modified epoxy resin, 1-8 parts of water-resistant agent, 0.2-4.5 parts of sodium hexametaphosphate and 0.2-4.5 parts of antibacterial agent.
Further, the adhesive layer comprises the following components in parts by weight: 95-100 parts of water, 20-45 parts of modified starch, 25-35 parts of 15% polyvinyl formal, 25-35 parts of polyglycolic acid, 10-35 parts of dibutyl phthalate, 1-10 parts of modified epoxy resin, 1-6 parts of water-resistant agent, 2-4 parts of sodium hexametaphosphate and 1-3.5 parts of antibacterial agent.
Further, the preparation method of the modified epoxy resin comprises the following steps:
s1, adding 180mL of deionized water into a four-mouth bottle, adding 0.5mol of sodium alkyl benzene sulfonate and 0.2mol of potassium persulfate, introducing nitrogen to discharge air in the four-mouth bottle, and stirring for 50min to obtain a solution A;
s2, adding 0.6mol of epoxy resin and 0.2mol of vinyl acetate into the solution A in the S1, stirring for 2 hours, then heating to 80 ℃, reacting for 50min, and then cooling to 50 ℃ to obtain the modified epoxy resin.
The present invention and the embodiments thereof have been described above, and the description is not restrictive, and the embodiments shown in the detailed description are only a part of the embodiments of the present invention, not all embodiments, and the actual configuration is not limited thereto. In summary, those skilled in the art should appreciate that they can readily use the disclosed conception and specific embodiments as a basis for designing or modifying other structures for carrying out the same purposes of the present invention without departing from the spirit and scope of the invention as defined by the appended claims.
Claims (3)
1. The novel environment-friendly adhesive sticker comprises an adhesive layer and is characterized in that the adhesive layer contains the following components in parts by weight: 91-108 parts of water, 22-57 parts of modified starch, 20-40 parts of 15% polyvinyl formal, 20-40 parts of polyglycolic acid, 10-45 parts of dibutyl phthalate, 1-15 parts of modified epoxy resin, 1-8 parts of water-resistant agent, 0.2-4.5 parts of sodium hexametaphosphate and 0.2-4.5 parts of antibacterial agent.
2. The novel environment-friendly adhesive sticker as claimed in claim 1, wherein the adhesive layer comprises the following components in parts by weight: 95-100 parts of water, 20-45 parts of modified starch, 25-35 parts of 15% polyvinyl formal, 25-35 parts of polyglycolic acid, 10-35 parts of dibutyl phthalate, 1-10 parts of modified epoxy resin, 1-6 parts of water-resistant agent, 2-4 parts of sodium hexametaphosphate and 1-3.5 parts of antibacterial agent.
3. The novel environment-friendly adhesive sticker as claimed in claim 1, wherein the preparation method of the modified epoxy resin comprises the following steps:
s1, adding 180mL of deionized water into a four-mouth bottle, adding 0.5mol of sodium alkyl benzene sulfonate and 0.2mol of potassium persulfate, introducing nitrogen to discharge air in the four-mouth bottle, and stirring for 50min to obtain a solution A;
s2, adding 0.6mol of epoxy resin and 0.2mol of vinyl acetate into the solution A in the S1, stirring for 2 hours, then heating to 80 ℃, reacting for 50min, and then cooling to 50 ℃ to obtain the modified epoxy resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211001478.7A CN115232571A (en) | 2022-08-19 | 2022-08-19 | Novel environment-friendly adhesive sticker |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211001478.7A CN115232571A (en) | 2022-08-19 | 2022-08-19 | Novel environment-friendly adhesive sticker |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN115232571A true CN115232571A (en) | 2022-10-25 |
Family
ID=83680948
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202211001478.7A Pending CN115232571A (en) | 2022-08-19 | 2022-08-19 | Novel environment-friendly adhesive sticker |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115232571A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634686A (en) * | 2016-10-10 | 2017-05-10 | 上海金大塑胶有限公司 | Novel environment-friendly adhesive sticker material |
| CN108728022A (en) * | 2018-06-25 | 2018-11-02 | 安徽源美广告传媒有限公司 | A kind of adhesive sticker novel adhesive |
| US20210024786A1 (en) * | 2020-10-15 | 2021-01-28 | Hongsheng Technology (Beijing) Co., Ltd | Resin Modified Starch Adhesive And Preparation Method Thereof |
-
2022
- 2022-08-19 CN CN202211001478.7A patent/CN115232571A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634686A (en) * | 2016-10-10 | 2017-05-10 | 上海金大塑胶有限公司 | Novel environment-friendly adhesive sticker material |
| CN108728022A (en) * | 2018-06-25 | 2018-11-02 | 安徽源美广告传媒有限公司 | A kind of adhesive sticker novel adhesive |
| US20210024786A1 (en) * | 2020-10-15 | 2021-01-28 | Hongsheng Technology (Beijing) Co., Ltd | Resin Modified Starch Adhesive And Preparation Method Thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109575826B (en) | Easily-pulled removable double-sided adhesive tape with TPU (thermoplastic polyurethane) base material and preparation and use methods thereof | |
| CN108795307B (en) | Ultrathin double-sided adhesive tape and preparation method thereof | |
| CN113004494B (en) | Modified epoxy resin, preparation method and emulsion preparation method thereof, and application of waterproof coating | |
| CN108546540B (en) | Preparation method of ultraviolet curing transfer adhesive for glass substrate | |
| CN109810658B (en) | Easily-pulled removable adhesive tape with thermoplastic elastomer base material and preparation and use methods thereof | |
| CN110423334B (en) | Preparation method of total-organism-based vitrimer | |
| CN101481592A (en) | Anti-cracking adhesive for energy-saving lamp and preparation thereof | |
| CN108728022A (en) | A kind of adhesive sticker novel adhesive | |
| CN110184019B (en) | Polyurethane moisture-curing hot melt adhesive for edge sealing | |
| CN104531009A (en) | Offset print cold stamping dual-purpose adhesive and preparation method and usage method thereof | |
| CN115232571A (en) | Novel environment-friendly adhesive sticker | |
| CN103660653A (en) | Digital inkjet material made from water-borne pressure sensitive adhesive | |
| CN104327769A (en) | Mildew-proof water-resistant easy-to-alkali-washing performance-excellent environmentally-protective label adhesive and preparation method thereof | |
| CN102504740A (en) | Bonder for KT (Karat) board for advertisement | |
| CN102501502A (en) | KT (Karat) board for advertisement and preparation method thereof | |
| CN102101996A (en) | Pressure-sensitive adhesive used for cotton paper or non-woven fabrics and preparation method thereof | |
| CN110003807A (en) | A kind of water based emulsion xenogenesis graft materials and preparation method thereof and its application in soft pvc film pressure sensitive adhesive tape | |
| WO2010097024A1 (en) | Solid universal glue slurry and preparation method thereof | |
| CN111978918B (en) | Hot-melt pressure-sensitive adhesive for ultralow-temperature coated paper labeling and preparation method thereof | |
| CN109321177B (en) | Acrylate solid repositionable adhesive and preparation and coating methods thereof | |
| CN111253873A (en) | Processing technology of reusable heavy packaging adhesive tape | |
| CN110982456B (en) | Lead-sticking pencil glue and preparation method thereof | |
| CN114806444B (en) | Preparation process of advertisement car body paste | |
| CN115785859A (en) | Adhesive coating and method for paper and plastic | |
| CN114316832B (en) | Advertisement car body film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20221025 |