CN106634377B - 一种适用于普通铝粉的水性闪光漆及其制备方法 - Google Patents
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Abstract
本发明公开了一种适用于普通铝粉的水性闪光漆及其制备方法,所述水性闪光漆为丙烯酸氨基烤漆,未经处理的铝粉可以直接添加在水性配方中,且储存稳定性良好,水性涂料由以下重量份的组份:铝粉,6‑10份;助溶剂B,5‑8份;清油,80‑90份;清油各组分及其重量份数为:水性羟基丙烯酸树脂,50‑55份;氨基树脂,8‑15份;N,N‑二甲基乙醇胺,0.3‑0.5份;水,10‑20;助溶剂A,5‑10份;基材润湿剂,0.1‑0.3份;流平剂,0.2‑0.5份;本发明制得的水性闪光漆适用于电动车、摩托车等领域,不仅满足环保要求,涂层性能不低于溶剂型涂料,且综合成本低于溶剂型涂料,实现水性涂料代替油性涂料的跨度。
Description
技术领域
本发明涉及化工、材料及环保领域,是关于一种适用于普通铝粉的水性闪光漆及其制备方法。该涂料涂可用于钢铁、铝材等金属表面,涂装成膜后起到很好的装饰效果。
背景技术
羟基丙烯酸氨基烤漆,广泛应用于溶剂型涂料及涂膜体系中,其产品及使用相对比较成熟。随着环保要求的提高,水性涂料及涂装逐渐走进大家的视线。对于实色漆体系而言,配方体系中,不含有锌粉,不会与水发生作用,储存稳定性佳,涂层性能好。而对于闪光漆体系而言,锌粉可与水发生作用,在水性配方中使用较为困难,目前,解决方案一般有两种途径:其一为:锌粉经过化学处理后应用在水性配方中,此方法主要是将锌粉用微胶囊或硅烷等进行包袱,然后再添加到水性配方中,以此避免锌粉直接与水接触,此方法所用化学处理后的锌粉价格较贵,比较适用于利润较高的汽车原厂漆体系中;其二为:配方体系中,使用大量的助溶剂,极少量的水,减少锌粉与水的接触面积,以此来确保锌粉漆一定时间的储存稳定性,此方法,VOC含量较高,且涂料有效期较短,较适用于较低端的,或者现配现用的涂装现场。
发明内容
为了克服上述现有技术的不足,本发明公开了一种适用于普通铝粉的水性闪光漆及其制备方法,所述水性闪光漆为丙烯酸氨基烤漆,未经处理的铝粉可以直接添加在水性配方中,且储存稳定性良好。
本发明是通过如下技术方案实现的,一种适用于普通铝粉的水性闪光漆,由以下各组分及其重量份数组成:铝粉,6-10份;助溶剂B,5-8份;清油,80-90份;
所述清油由以下各组分及其重量份数组成:水性羟基丙烯酸树脂,50-55份;氨基树脂,8-15份;N,N-二甲基乙醇胺,0.3-0.5份;水,10-20;助溶剂A,5-10份;基材润湿剂,0.1-0.3份;流平剂,0.2-0.5份;
其中,所述助溶剂A为正丁醇,乙醇和异丙醇的混合物,其按重量份数比为:正丁醇:乙醇:异丙醇为2:2:1;
所述助溶剂B为乙醇与正丁醚的混合物,其按重量份数比为:乙醇:正丁醚为3:2。
还可添加3-5份色浆。
所述水性羟基丙烯酸树脂,其羟值在110-160mgKOH/g,酸值在于20-50mgKOH/g,
进一步的,所述水性羟基丙烯酸树脂,羟值在120-140mgKOH/g,酸值在40-50mgKOH/g。
所述氨基树脂为甲醚化氨基树脂和丁醚化氨基树脂的混合物,其按重量份数比为:甲醚化氨基树脂:丁醚化氨基树脂=2:1。
所述清油pH值在9-11,且清油状态为澄清透明。
所述铝粉为普通、未经过化学处理的闪白银。
一种制备所述的水性闪光漆的方法,按如下步骤进行:
步骤1)清油的制备:首先将水性羟基丙烯酸树脂和氨基树脂加入涂料混合设备中低速搅拌均匀,逐渐加入N,N-二甲基乙醇胺至澄清为止,然后加入水,助溶剂A,基材润湿剂,流平剂;搅拌均匀后,即得到清油;
步骤2)水性闪光漆的制备:将铝粉用助溶剂B溶解,搅拌均匀,然后加入调好的清油中,搅拌均匀过滤后,即得到水性闪光漆。
一种制备所述的水性闪光漆的方法,按如下步骤进行:
步骤1)清油的制备:首先将水性羟基丙烯酸树脂和氨基树脂加入涂料混合设备中低速搅拌均匀,逐渐加入N,N-二甲基乙醇胺至澄清为止,然后加入水,助溶剂A,基材润湿剂,流平剂;搅拌均匀后,即得到清油;
步骤2)水性闪光漆的制备:将铝粉用助溶剂B溶解,搅拌均匀,然后加入调好的清油中,再加入磨好的色浆搅拌均匀过滤后,即得到水性闪光漆。
本发明有益技术效果:本发明提供的水性闪光漆适用于电动车、摩托车等领域,不仅满足环保要求,涂层性能不低于溶剂型涂料,且综合成本低于溶剂型涂料,实现水性涂料代替油性涂料的跨度,又有较好的储存稳定性,且可用普通铝粉,大大降低生产成本。
具体实施方式
下面结合实施例对本发明做进一步说明,本领域技术人员应该明白,实施例是对本发明具体实施所做的解释和说明,并不限制本发明要保护的范围。
实施例1
铝粉购买与上海恒展化工有限公司
一种适用于普通铝粉的水性闪光漆,由以下各组分及其重量份数组成:铝粉,8份;助溶剂B(乙醇,4.5份;正丁醚,3份);清油,80-90份;
所述清油由以下各组分及其重量份数组成:水性羟基丙烯酸树脂,50.15份;甲醚化氨基树脂(氰特325氨基树脂),6份;丁醚化氨基树脂(英力士MF980氨基树脂),3份;N,N-二甲基乙醇胺,0.4份;水,15份;助溶剂A(正丁醇,4份;乙醇,4份;异丙醇,2份;);基材润湿剂(基材润湿剂WET270),0.15份;流平剂(BYK-381流平剂),0.3份;
一种制备所述的水性闪光漆的方法,按如下步骤进行:
步骤1)清油的制备:首先将水性羟基丙烯酸树脂和氨基树脂(甲醚化氨基树脂和丁醚化氨基树脂的混合物)加入涂料混合设备中低速搅拌均匀,逐渐加入N,N-二甲基乙醇胺至澄清为止,然后加入水,助溶剂A(正丁醇,乙醇和异丙醇三者的混合物),基材润湿剂,流平剂;搅拌均匀后,即得到清油;
步骤2)水性闪光漆的制备:将铝粉用助溶剂B(乙醇和正丁醚两者的混合物);溶解,搅拌均匀,然后加入调好的清油中,搅拌均匀过滤后,即得到水性闪光漆。
本实施例制得的水性闪光漆,其涂层性能检测结果见表1。
实施例2
在实施例1中水性闪光漆的各组分及其重量份数基础上,添加3-5份色浆。一种制备所述的水性闪光漆的方法,按如下步骤进行:
步骤1)清油的制备:首先将水性羟基丙烯酸树脂和氨基树脂加入涂料混合设备中低速搅拌均匀,逐渐加入N,N-二甲基乙醇胺至澄清为止,然后加入水,助溶剂A,基材润湿剂,流平剂;搅拌均匀后,即得到清油;
步骤2)水性闪光漆的制备:将铝粉用助溶剂B溶解,搅拌均匀,然后加入调好的清油中,再加入磨好的色浆搅拌均匀过滤后,即得到水性闪光漆。
表1
Claims (8)
1.一种适用于普通铝粉的水性闪光漆,其特征在于:由以下各组分及其重量份数组成:铝粉,6-10份;助溶剂B,5-8份;清油,80-90份;
所述清油由以下各组分及其重量份数组成:水性羟基丙烯酸树脂,50-55份;氨基树脂,8-15份;N,N-二甲基乙醇胺,0.3-0.5份;水,10-20;助溶剂A,5-10份;基材润湿剂,0.1-0.3份;流平剂,0.2-0.5份;
其中,所述助溶剂A为正丁醇,乙醇和异丙醇的混合物,其按重量份数比为:正丁醇:乙醇:异丙醇为2:2:1;
所述助溶剂B为乙醇与正丁醚的混合物,其按重量份数比为:乙醇:正丁醚为3:2;
所述铝粉为普通、未经过化学处理的闪白银;
按如下步骤进行:
步骤1)清油的制备:首先将水性羟基丙烯酸树脂和氨基树脂加入涂料混合设备中低速搅拌均匀,逐渐加入N,N-二甲基乙醇胺至澄清为止,然后加入水,助溶剂A,基材润湿剂,流平剂;搅拌均匀后,即得到清油;
步骤2)水性闪光漆的制备:将铝粉用助溶剂B溶解,搅拌均匀,然后加入调好的清油中,搅拌均匀过滤后,即得到水性闪光漆。
2.根据权利要求1所述的水性闪光漆,其特征在于:还可添加3-5份色浆。
3.根据权利要求1所述的水性闪光漆,其特征在于:所述水性羟基丙烯酸树脂,其羟值在110-160mgKOH/g,酸值在于20-50mgKOH/g。
4.根据权利要求3所述的水性闪光漆,其特征在于:所述水性羟基丙烯酸树脂,羟值在120-140mgKOH/g,酸值在40-50mgKOH/g。
5.根据权利要求1所述的水性闪光漆,其特征在于:所述氨基树脂为甲醚化氨基树脂和丁醚化氨基树脂的混合物,其按重量份数比为:甲醚化氨基树脂:丁醚化氨基树脂=2:1。
6.根据权利要求1所述的水性闪光漆,其特征在于:所述清油pH值在9-11,且清油状态为澄清透明。
7.一种制备权利要求1、3-6任一项所述的水性闪光漆的方法,其特征在于:按如下步骤进行:
步骤1)清油的制备:首先将水性羟基丙烯酸树脂和氨基树脂加入涂料混合设备中低速搅拌均匀,逐渐加入N,N-二甲基乙醇胺至澄清为止,然后加入水,助溶剂A,基材润湿剂,流平剂;搅拌均匀后,即得到清油;
步骤2)水性闪光漆的制备:将铝粉用助溶剂B溶解,搅拌均匀,然后加入调好的清油中,搅拌均匀过滤后,即得到水性闪光漆。
8.一种制备权利要求2所述的水性闪光漆的方法,其特征在于:按如下步骤进行:
步骤1)清油的制备:首先将水性羟基丙烯酸树脂和氨基树脂加入涂料混合设备中低速搅拌均匀,逐渐加入N,N-二甲基乙醇胺至澄清为止,然后加入水,助溶剂A,基材润湿剂,流平剂;搅拌均匀后,即得到清油;
步骤2)水性闪光漆的制备:将铝粉用助溶剂B溶解,搅拌均匀,然后加入调好的清油中,再加入磨好的色浆搅拌均匀过滤后,即得到水性闪光漆。
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