CN106634213A - Environment-friendly thermal sublimation ink - Google Patents
Environment-friendly thermal sublimation ink Download PDFInfo
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- CN106634213A CN106634213A CN201610854460.XA CN201610854460A CN106634213A CN 106634213 A CN106634213 A CN 106634213A CN 201610854460 A CN201610854460 A CN 201610854460A CN 106634213 A CN106634213 A CN 106634213A
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- sublimation ink
- environment
- preservative
- heat sublimation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/328—Inkjet printing inks characterised by colouring agents characterised by dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses environment-friendly thermal sublimation ink. The ink is prepared from components as follows: 20-40 parts of disperse dye, 10-20 parts of a viscosity adjusting agent, 3-8 parts of a surfactant, 8-15 parts of sodium lignosulfonate, 1-6 parts of a fungicide, 1-5 parts of a preservative, 8-15 parts of carboxymethyl cellulose, 1-4 parts of inorganic oxide, 1-5 parts of a corrosion inhibitor, 3-8 parts of styrene-acrylic resin and 3-8 parts of polyvinyl alcohol. The preparation process is simple, the preparation process is environment-friendly and pollution-free, and the prepared thermal sublimation ink has quite good smoothness and stability, has effects of sterilization and corrosion resistance, and can prolong the storage time of inkjet products.
Description
Technical field
The present invention relates to heat sublimation ink preparing technical field, specially a kind of environment-friendly type heat sublimation ink.
Background technology
Heat sublimation ink (also known as thermal transfer ink) is exactly that, low energy, the disperse dyes of easily distillation are fabricated to digital printing
Ink, is printed upon on transfer paper, by heating, can be within the most short time by image making to exquisite porcelain, metal, very
In the materials such as silk, chemical fiber fabric, the market demand of individualized development and the requirement of environmental protection are especially suitable for.Heat sublimation ink is mostly
Prepared by the disperse dyes of weaving.Disperse dyes are due to the color and good weatherability of its saturation, so printing in weaving
Catch and have a wide range of applications, one of primary raw material of printing and dyeing industry is remained so far.Traditional fabrics printing and dyeing industry
There is serious problem of environmental pollution during using dispersion pigment dyeing, and be not suitable for the production of small lot.It is existing
Heat sublimation ink complicated process of preparation, and stability is poor, the rate of transform is low, strong influence production efficiency.
The content of the invention
It is an object of the invention to provide a kind of environment-friendly type heat sublimation ink, to solve above-mentioned background technology in propose ask
Topic.
For achieving the above object, the present invention provides following technical scheme：A kind of environment-friendly type heat sublimation ink, including dispersion dye
It is material 20-40 parts, viscosity-controlling agent 10-20 parts, surfactant 3-8 parts, sodium lignin sulfonate 8-15 parts, bactericide 1-6 parts, anti-
Rotten agent 1-5 parts, carboxymethylcellulose calcium 8-15 parts, inorganic oxide 1-4 parts, corrosion inhibiter 1-5 parts, styrene acrylic resin 3-8
Part and polyvinyl alcohol 3-8 parts.
Preferably, the preservative is made up of 30% Sodium Benzoate, 30% Potassium Benzoate, 40% sodium sorbate.
Preferably, the corrosion inhibiter is made up of water-soluble mercapto benzothiazole, TTA mixing.
Preferably, preferred composition proportion is：30 parts of disperse dyes, 15 parts of viscosity-controlling agent, 5 parts of surfactant, wood
12 parts of quality sodium sulfonate, 4 parts of bactericide, 3 parts of preservative, 12 parts of carboxymethylcellulose calcium, 3 parts of inorganic oxide, 3 parts of corrosion inhibiter,
5 parts of 5 parts of styrene acrylic resin and polyvinyl alcohol.
Preferably, its preparation method is comprised the following steps：
A, will disperse dyes, viscosity-controlling agent, surfactant, sodium lignin sulfonate mixing after be ground, during grinding
Between be 10h, obtain mixture A；
B, in mixture A add bactericide, preservative, carboxymethylcellulose calcium, inorganic oxide, corrosion inhibiter, styrene
Acrylic resin, polyvinyl alcohol, add in mixer after mixing and stir, and mixer rotating speed is 3000 revs/min, and mixing time is
25min, obtains mixture B；
C, by mixture B stand 2h after, use 0.3u membrane filtrations, that is, obtain heat sublimation ink.
Compared with prior art, the invention has the beneficial effects as follows：
(1) preparation process is simple of the present invention, preparation process is environment friendly and pollution-free, heat sublimation ink is obtained and has smoothness well
Property and stability, while having sterilized, antisepsis, the storage time of ink-jet products can be extended.
(2) styrene acrylic resin and polyvinyl alcohol are added with the present invention, it is possible to increase the levelability of ink, are prevented
Only shower nozzle is blocked in transfer process ink inside, improve transfer quality.
Specific embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment
Only a part of embodiment of the invention, rather than the embodiment of whole.Based on the embodiment in the present invention, the common skill in this area
The every other embodiment that art personnel are obtained under the premise of creative work is not made, belongs to the model of present invention protection
Enclose.
The present invention provides a kind of technical scheme：A kind of environment-friendly type heat sublimation ink, including disperse dyes 20-40 parts, viscosity
Conditioning agent 10-20 parts, surfactant 3-8 parts, sodium lignin sulfonate 8-15 parts, bactericide 1-6 parts, preservative 1-5 parts, carboxylic first
Base cellulose 8-15 parts, inorganic oxide 1-4 parts, corrosion inhibiter 1-5 parts, styrene acrylic resin 3-8 parts and polyvinyl alcohol
3-8 parts.
Embodiment one：
The composition proportion for adopting for：20 parts of disperse dyes, 10 parts of viscosity-controlling agent, 3 parts of surfactant, lignin sulfonic acid
8 parts of sodium, 1 part of bactericide, 1 part of preservative, 8 parts of carboxymethylcellulose calcium, 1 part of inorganic oxide, 1 part of corrosion inhibiter, styrene-acrylonitrile copolymer
3 parts of 3 parts of acid resin and polyvinyl alcohol.
In the present embodiment, preservative is made up of 30% Sodium Benzoate, 30% Potassium Benzoate, 40% sodium sorbate.
In the present embodiment, corrosion inhibiter is made up of water-soluble mercapto benzothiazole, TTA mixing.
The preparation method of the present embodiment is comprised the following steps：
A, will disperse dyes, viscosity-controlling agent, surfactant, sodium lignin sulfonate mixing after be ground, during grinding
Between be 10h, obtain mixture A；
B, in mixture A add bactericide, preservative, carboxymethylcellulose calcium, inorganic oxide, corrosion inhibiter, styrene
Acrylic resin, polyvinyl alcohol, add in mixer after mixing and stir, and mixer rotating speed is 3000 revs/min, and mixing time is
25min, obtains mixture B；
C, by mixture B stand 2h after, use 0.3u membrane filtrations, that is, obtain heat sublimation ink.
Embodiment two：
The composition proportion for adopting for：40 parts of disperse dyes, 20 parts of viscosity-controlling agent, 8 parts of surfactant, lignin sulfonic acid
15 parts of sodium, 6 parts of bactericide, 5 parts of preservative, 15 parts of carboxymethylcellulose calcium, 4 parts of inorganic oxide, 5 parts of corrosion inhibiter, styrene third
8 parts of 8 parts of olefin(e) acid resin and polyvinyl alcohol.
In the present embodiment, preservative is made up of 30% Sodium Benzoate, 30% Potassium Benzoate, 40% sodium sorbate.
In the present embodiment, corrosion inhibiter is made up of water-soluble mercapto benzothiazole, TTA mixing.
The preparation method of the present embodiment is comprised the following steps：
A, will disperse dyes, viscosity-controlling agent, surfactant, sodium lignin sulfonate mixing after be ground, during grinding
Between be 10h, obtain mixture A；
B, in mixture A add bactericide, preservative, carboxymethylcellulose calcium, inorganic oxide, corrosion inhibiter, styrene
Acrylic resin, polyvinyl alcohol, add in mixer after mixing and stir, and mixer rotating speed is 3000 revs/min, and mixing time is
25min, obtains mixture B；
C, by mixture B stand 2h after, use 0.3u membrane filtrations, that is, obtain heat sublimation ink.
Embodiment three：
The composition proportion for adopting for：25 parts of disperse dyes, 12 parts of viscosity-controlling agent, 4 parts of surfactant, lignin sulfonic acid
10 parts of sodium, 2 parts of bactericide, 2 parts of preservative, 9 parts of carboxymethylcellulose calcium, 2 parts of inorganic oxide, 2 parts of corrosion inhibiter, styrene-acrylonitrile copolymer
4 parts of 4 parts of acid resin and polyvinyl alcohol.
In the present embodiment, preservative is made up of 30% Sodium Benzoate, 30% Potassium Benzoate, 40% sodium sorbate.
In the present embodiment, corrosion inhibiter is made up of water-soluble mercapto benzothiazole, TTA mixing.
The preparation method of the present embodiment is comprised the following steps：
A, will disperse dyes, viscosity-controlling agent, surfactant, sodium lignin sulfonate mixing after be ground, during grinding
Between be 10h, obtain mixture A；
B, in mixture A add bactericide, preservative, carboxymethylcellulose calcium, inorganic oxide, corrosion inhibiter, styrene
Acrylic resin, polyvinyl alcohol, add in mixer after mixing and stir, and mixer rotating speed is 3000 revs/min, and mixing time is
25min, obtains mixture B；
C, by mixture B stand 2h after, use 0.3u membrane filtrations, that is, obtain heat sublimation ink.
Example IV：
The composition proportion for adopting for：35 parts of disperse dyes, 18 parts of viscosity-controlling agent, 7 parts of surfactant, lignin sulfonic acid
13 parts of sodium, 5 parts of bactericide, 4 parts of preservative, 13 parts of carboxymethylcellulose calcium, 3 parts of inorganic oxide, 4 parts of corrosion inhibiter, styrene third
7 parts of 7 parts of olefin(e) acid resin and polyvinyl alcohol.
In the present embodiment, preservative is made up of 30% Sodium Benzoate, 30% Potassium Benzoate, 40% sodium sorbate.
In the present embodiment, corrosion inhibiter is made up of water-soluble mercapto benzothiazole, TTA mixing.
The preparation method of the present embodiment is comprised the following steps：
A, will disperse dyes, viscosity-controlling agent, surfactant, sodium lignin sulfonate mixing after be ground, during grinding
Between be 10h, obtain mixture A；
B, in mixture A add bactericide, preservative, carboxymethylcellulose calcium, inorganic oxide, corrosion inhibiter, styrene
Acrylic resin, polyvinyl alcohol, add in mixer after mixing and stir, and mixer rotating speed is 3000 revs/min, and mixing time is
25min, obtains mixture B；
C, by mixture B stand 2h after, use 0.3u membrane filtrations, that is, obtain heat sublimation ink.
Embodiment five：
The composition proportion for adopting for：30 parts of disperse dyes, 15 parts of viscosity-controlling agent, 5 parts of surfactant, lignin sulfonic acid
12 parts of sodium, 4 parts of bactericide, 3 parts of preservative, 12 parts of carboxymethylcellulose calcium, 3 parts of inorganic oxide, 3 parts of corrosion inhibiter, styrene third
5 parts of 5 parts of olefin(e) acid resin and polyvinyl alcohol.
In the present embodiment, preservative is made up of 30% Sodium Benzoate, 30% Potassium Benzoate, 40% sodium sorbate.
In the present embodiment, corrosion inhibiter is made up of water-soluble mercapto benzothiazole, TTA mixing.
The preparation method of the present embodiment is comprised the following steps：
A, will disperse dyes, viscosity-controlling agent, surfactant, sodium lignin sulfonate mixing after be ground, during grinding
Between be 10h, obtain mixture A；
B, in mixture A add bactericide, preservative, carboxymethylcellulose calcium, inorganic oxide, corrosion inhibiter, styrene
Acrylic resin, polyvinyl alcohol, add in mixer after mixing and stir, and mixer rotating speed is 3000 revs/min, and mixing time is
25min, obtains mixture B；
C, by mixture B stand 2h after, use 0.3u membrane filtrations, that is, obtain heat sublimation ink.
Experimental example：
Common heat sublimation ink and various embodiments of the present invention are obtained into heat sublimation ink carries out viscosity and Tensiometry Test,
Obtain data such as following table：
| Viscosity (mpa.s) | Surface tension (mN/m) | |
| Common heat sublimation ink | 4.8 | 52 |
| Embodiment one | 2.5 | 23 |
| Embodiment two | 2.4 | 23 |
| Embodiment three | 2.2 | 21 |
| Example IV | 2.2 | 22 |
| Embodiment five | 1.8 | 19 |
From above table data, embodiment five obtains Dare heat sublimation ink can reach optimum efficiency.
Preparation process is simple of the present invention, preparation process is environment friendly and pollution-free, and prepared heat sublimation ink has good fluency
And stability, while having sterilized, antisepsis, the storage time of ink-jet products can be extended；Benzene second is added with the present invention
Alkene acrylic resin and polyvinyl alcohol, it is possible to increase the levelability of ink, prevent from blocking shower nozzle in transfer process ink inside, carry
High transfer quality.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding can carry out various changes, modification, replacement to these embodiments without departing from the principles and spirit of the present invention
And modification, the scope of the present invention be defined by the appended.
Claims (5)
1. a kind of environment-friendly type heat sublimation ink, it is characterised in that：Including disperse dyes 20-40 parts, viscosity-controlling agent 10-20 parts,
Surfactant 3-8 parts, sodium lignin sulfonate 8-15 parts, bactericide 1-6 parts, preservative 1-5 parts, carboxymethylcellulose calcium 8-15
Part, inorganic oxide 1-4 parts, corrosion inhibiter 1-5 parts, styrene acrylic resin 3-8 parts and polyvinyl alcohol 3-8 parts.
2. a kind of environment-friendly type heat sublimation ink according to claim 1, it is characterised in that：The preservative is by 30% benzene first
Sour sodium, 30% Potassium Benzoate, 40% sodium sorbate composition.
3. a kind of environment-friendly type heat sublimation ink according to claim 1, it is characterised in that：The corrosion inhibiter is by water-soluble mercapto
Base benzothiazole, TTA mixing composition.
4. a kind of environment-friendly type heat sublimation ink according to claim 1, it is characterised in that：Preferred composition proportion is：Point
30 parts of scattered dyestuff, 15 parts of viscosity-controlling agent, 5 parts of surfactant, 12 parts of sodium lignin sulfonate, 4 parts of bactericide, 3 parts of preservative,
5 parts of 12 parts of carboxymethylcellulose calcium, 3 parts of inorganic oxide, 3 parts of corrosion inhibiter, 5 parts of styrene acrylic resin and polyvinyl alcohol.
5. a kind of preparation method of the environment-friendly type heat sublimation ink described in claim 1 is realized, it is characterised in that：Its preparation method
Comprise the following steps：
A, will disperse dyes, viscosity-controlling agent, surfactant, sodium lignin sulfonate mixing after be ground, milling time is
10h, obtains mixture A；
B, in mixture A add bactericide, preservative, carboxymethylcellulose calcium, inorganic oxide, corrosion inhibiter, styrene-acrylonitrile copolymer
Acid resin, polyvinyl alcohol, add in mixer after mixing and stir, and mixer rotating speed is 3000 revs/min, and mixing time is 25min,
Obtain mixture B；
C, by mixture B stand 2h after, use 0.3u membrane filtrations, that is, obtain heat sublimation ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610854460.XA CN106634213A (en) | 2016-09-27 | 2016-09-27 | Environment-friendly thermal sublimation ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610854460.XA CN106634213A (en) | 2016-09-27 | 2016-09-27 | Environment-friendly thermal sublimation ink |
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| CN106634213A true CN106634213A (en) | 2017-05-10 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610854460.XA Pending CN106634213A (en) | 2016-09-27 | 2016-09-27 | Environment-friendly thermal sublimation ink |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107721193A (en) * | 2017-11-03 | 2018-02-23 | 太仓经济开发区坚毅工艺美术品工作室 | Heat sublimation ink, heat sublimation paint glass and preparation method thereof |
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|---|---|---|---|---|
| CN101623962A (en) * | 2009-08-10 | 2010-01-13 | 天津市赢事达办公用品厂 | Water-soluble heat sublimation colored bar and fabricating method thereof |
| CN101709177A (en) * | 2009-12-03 | 2010-05-19 | 上海英威喷墨科技有限公司 | Waterborne digital ink-jet printing sublimation ink and preparation method thereof |
| CN102585589A (en) * | 2012-03-07 | 2012-07-18 | 深圳市墨库图文技术有限公司 | Thermal sublimation ink as well as direct printing technology and equipment |
| CN103243575A (en) * | 2013-05-17 | 2013-08-14 | 杭州浙大海维特化工科技有限公司 | Digital inkjet thermal transfer printing water-based ink for textiles and preparation method of ink |
-
2016
- 2016-09-27 CN CN201610854460.XA patent/CN106634213A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101623962A (en) * | 2009-08-10 | 2010-01-13 | 天津市赢事达办公用品厂 | Water-soluble heat sublimation colored bar and fabricating method thereof |
| CN101709177A (en) * | 2009-12-03 | 2010-05-19 | 上海英威喷墨科技有限公司 | Waterborne digital ink-jet printing sublimation ink and preparation method thereof |
| CN102585589A (en) * | 2012-03-07 | 2012-07-18 | 深圳市墨库图文技术有限公司 | Thermal sublimation ink as well as direct printing technology and equipment |
| CN103243575A (en) * | 2013-05-17 | 2013-08-14 | 杭州浙大海维特化工科技有限公司 | Digital inkjet thermal transfer printing water-based ink for textiles and preparation method of ink |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107721193A (en) * | 2017-11-03 | 2018-02-23 | 太仓经济开发区坚毅工艺美术品工作室 | Heat sublimation ink, heat sublimation paint glass and preparation method thereof |
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Application publication date: 20170510 |
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