CN106633835A - PA (polyamide) masterbatch with anti-static and anti-aging functions - Google Patents
PA (polyamide) masterbatch with anti-static and anti-aging functions Download PDFInfo
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- CN106633835A CN106633835A CN201610909736.XA CN201610909736A CN106633835A CN 106633835 A CN106633835 A CN 106633835A CN 201610909736 A CN201610909736 A CN 201610909736A CN 106633835 A CN106633835 A CN 106633835A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses PA (polyamide) masterbatch with anti-static and anti-aging functions. The PA masterbatch is prepared from the following raw materials in parts by weight: 180-185 parts of PA6, 10-15 parts of HDPE (high-density polyethylene), 15-20 parts of an ethylene-vinyl acetate copolymer, 3-6 parts of polyethylene wax, 6-14 parts of coconut oil monoethanolamide, 3-7 parts of butyl benzyl phthalate, 3-5 parts of carbamide, 5-9 parts of silica, 5-12 parts of nano-molybdenum disulfide and 8-10 parts of lithium trifluoromethanesulfonate. The PA masterbatch with the anti-static and anti-aging functions has good anti-static and anti-aging performance, is low in processing cost and adopts a simple preparation process. When used in coloring of a PA product, the PA masterbatch has the advantages that the color stability is improved and the color difference is smaller, and the problems of instable color, larger color difference and the like of existing PA color masterbatch during coloring are solved.
Description
Technical field
The invention belongs to technical field of polymer materials, more particularly to a kind of PA color masterbatch with antistatic anti-aging function
Grain.
Background technology
With the raising of living standards of the people, people not only pay close attention to the performance of the product used in various lives, same to time
Its is attractive in appearance for benefit pursuit, and wishes that product of its purchase has good outward appearance.Because plastic products have abundant raw material source, valency
Lattice are cheap, nontoxic, be easy to processing and forming, higher rigidity and toughness, and mechanical strength is good, so being flooded with people's life now
Plastic products miscellaneous, and Masterbatch coloring is the coloring plastic method for most generally adopting now.Masterbatch is 20th century 60
A kind of plastics, the coloring new product of fiber of age exploitation, it is pigment super quantity to be uniformly attached in resin and is obtained
Polymer compound.With the progress of technology, in plastic processes, by adding Masterbatch, so as to play beautification, dress
Adorn, be easy to recognize, improve weatherability, improve mechanical property, improve the effect such as optical property.When being coloured using Masterbatch, pigment
Through pre-processing and it is dispersed in vector resin, the dispersive property and coloration efficiency of pigment is substantially increased, with operation
Simply, the advantages of with low cost, environmentally safe.
Polyamide（PA）It is that one kind uses extensive engineering plastic resin.It is to contain recurring amide radical on molecular backbone
The general name of the thermoplastic resin of group-[NHCO]-；Because unique low-gravity, high-tensile, wear-resisting, self lubricity are good, impact
Tenacity excellent, the attention for winning people with the hard and soft performance having both, in addition its simple processing, efficiency high, light specific gravity（Only
The 1/7 of metal）, various products can be processed into replace metal, be widely used in automobile and transportation.
At present, the variety of raw material such as the higher country of external PA Masterbatch technical merit, pigment, dispersant are complete, shape
Into seriation and specialized product structure.But domestic PA Masterbatch product structure is single, the former material item such as pigment, dispersant
Plant collocation complete, there is some difference to cause color and luster, and this is totally unfavorable for the coloring of product.When being coloured with Masterbatch,
Because carrier flow performance is poor, the problems such as easily there is flow liner, color and luster uneven, wayward aberration and single function.Therefore,
How to solve easily to be produced when PA Masterbatch is coloured the problems such as flow liner, color and luster be uneven, aberration is larger and shock resistance is deteriorated, be
The problem that PA need to be solved urgently when colouring.For this purpose, we set about from the formula of product, new Masterbatch is developed, there is provided a kind of PA
Masterbatch.
The content of the invention
It is an object of the invention to provide a kind of PA Masterbatch with antistatic anti-aging function.
To achieve these goals, the invention provides a kind of PA Masterbatch with antistatic anti-aging function, by with
The raw material of lower weight portion is obtained：PA6 180-185 parts, HDPE10-15 parts, ethylene-vinyl acetate copolymer 15-20 parts, poly- second
Xi Xi 3-6 parts, coconut monoethanolamide 6-14 parts, BBP(Butyl Benzyl Phthalate 3-7 parts, carbonyl diamide 3-5 parts, titanium dioxide
Silicon 5-9 parts, nano molybdenum disulfide 5-12 parts, trifluoromethyl sulfonic acid lithium 8-10 parts.
It also includes APES 2-4 parts.
It also includes dibasic lead phosphite 4-9 parts.
It also includes methacrylic resin 5-12 parts.
Beneficial effect：The PA Masterbatch with antistatic anti-aging function that the present invention is provided have it is good antistatic and
Anti ageing property, processing cost is low, preparation process is simple, when the coloring of PA products is applied to, improve with colour stability,
The less advantage of aberration, overcomes the problems such as color is unstable, aberration is larger when existing PA Masterbatch is coloured.
Specific embodiment
Embodiment 1
A kind of PA Masterbatch with antistatic anti-aging function that the present embodiment is provided, is obtained by the raw material of following weight portion：
180 parts of PA6, HDPE10 parts, 15 parts of ethylene-vinyl acetate copolymer, 3 parts of Ju Yi Xi Xi, 6 parts of coconut monoethanolamide,
3 parts of BBP(Butyl Benzyl Phthalate, 3 parts of carbonyl diamide, 5 parts of silica, 5 parts of nano molybdenum disulfide, trifluoromethyl sulfonic acid lithium 8
Part.
Embodiment 2
A kind of PA Masterbatch with antistatic anti-aging function that the present embodiment is provided, is obtained by the raw material of following weight portion：
185 parts of PA6, HDPE15 parts, 20 parts of ethylene-vinyl acetate copolymer, 6 parts of Ju Yi Xi Xi, coconut monoethanolamide 14
Part, 7 parts of BBP(Butyl Benzyl Phthalate, 5 parts of carbonyl diamide, 9 parts of silica, 12 parts of nano molybdenum disulfide, trifluoromethane sulfonic acid
10 parts of lithium, 4 parts of APES.
Embodiment 3
A kind of PA Masterbatch with antistatic anti-aging function that the present embodiment is provided, is obtained by the raw material of following weight portion：
180 parts of PA6, HDPE10 parts, 15 parts of ethylene-vinyl acetate copolymer, 3 parts of Ju Yi Xi Xi, 6 parts of coconut monoethanolamide,
3 parts of BBP(Butyl Benzyl Phthalate, 3 parts of carbonyl diamide, 5 parts of silica, 5 parts of nano molybdenum disulfide, trifluoromethyl sulfonic acid lithium 8
Part, 2 parts of APES, 4 parts of dibasic lead phosphite.
Embodiment 4
A kind of PA Masterbatch with antistatic anti-aging function that the present embodiment is provided, is obtained by the raw material of following weight portion：
185 parts of PA6, HDPE15 parts, 20 parts of ethylene-vinyl acetate copolymer, 6 parts of Ju Yi Xi Xi, coconut monoethanolamide 14
Part, 7 parts of BBP(Butyl Benzyl Phthalate, 5 parts of carbonyl diamide, 9 parts of silica, 12 parts of nano molybdenum disulfide, trifluoromethane sulfonic acid
10 parts of lithium, 4 parts of APES, 9 parts of dibasic lead phosphite, 12 parts of methacrylic resin.
The production technology that above-described embodiment 1-4 is used is conventional production process, and its step is：First weigh respectively by said ratio
In raw material input homogenizer, stirring mixing；Then the material being well mixed is added to into melting in double screw extruder, modeling
Change, extrude, granulate, obtain final product.
Claims (4)
1. a kind of PA Masterbatch with antistatic anti-aging function, it is characterised in that be made up of the raw material of following weight portion：PA6
180-185 parts, HDPE10-15 parts, ethylene-vinyl acetate copolymer 15-20 parts, Ju Yi Xi Xi 3-6 parts, cocinic acid monoethanol
Acid amides 6-14 parts, BBP(Butyl Benzyl Phthalate 3-7 parts, carbonyl diamide 3-5 parts, silica 5-9 parts, nano molybdenum disulfide 5-12
Part, trifluoromethyl sulfonic acid lithium 8-10 parts.
2. a kind of PA Masterbatch with antistatic anti-aging function according to claim 1, it is characterised in that：It is also wrapped
The parts of 2-4 containing APES.
3. a kind of PA Masterbatch with antistatic anti-aging function according to claim 2, it is characterised in that：It is also wrapped
The parts of 4-9 containing dibasic lead phosphite.
4. a kind of PA Masterbatch with antistatic anti-aging function according to claim 3, it is characterised in that：It is also wrapped
The parts of 5-12 containing methacrylic resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610909736.XA CN106633835A (en) | 2016-10-19 | 2016-10-19 | PA (polyamide) masterbatch with anti-static and anti-aging functions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610909736.XA CN106633835A (en) | 2016-10-19 | 2016-10-19 | PA (polyamide) masterbatch with anti-static and anti-aging functions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106633835A true CN106633835A (en) | 2017-05-10 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610909736.XA Pending CN106633835A (en) | 2016-10-19 | 2016-10-19 | PA (polyamide) masterbatch with anti-static and anti-aging functions |
Country Status (1)
| Country | Link |
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| CN (1) | CN106633835A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1110481A (en) * | 1993-06-07 | 1995-10-18 | 维塔利·伊里奇·克里施托波 | Process for obtaining antistatic polymer compounds |
| CN103131119A (en) * | 2013-01-31 | 2013-06-05 | 杜县南 | Color master batch and manufacturing method thereof |
| CN104744928A (en) * | 2015-03-14 | 2015-07-01 | 芜湖众力部件有限公司 | Low-wear plastic connecting piece |
-
2016
- 2016-10-19 CN CN201610909736.XA patent/CN106633835A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1110481A (en) * | 1993-06-07 | 1995-10-18 | 维塔利·伊里奇·克里施托波 | Process for obtaining antistatic polymer compounds |
| CN103131119A (en) * | 2013-01-31 | 2013-06-05 | 杜县南 | Color master batch and manufacturing method thereof |
| CN104744928A (en) * | 2015-03-14 | 2015-07-01 | 芜湖众力部件有限公司 | Low-wear plastic connecting piece |
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Application publication date: 20170510 |