CN106633527A - 高强度仿木塑料环保装饰材料 - Google Patents

高强度仿木塑料环保装饰材料 Download PDF

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CN106633527A
CN106633527A CN201611227597.9A CN201611227597A CN106633527A CN 106633527 A CN106633527 A CN 106633527A CN 201611227597 A CN201611227597 A CN 201611227597A CN 106633527 A CN106633527 A CN 106633527A
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聂小华
杨杰
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Fengcheng Ming Feng Intelligent Environmental Protection Decorative Material Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102—Azo-compounds
    • C08J9/103—Azodicarbonamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00—Flat articles, e.g. films or sheets
    • B29L2007/002—Panels; Plates; Sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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Abstract

本发明提供一种强度仿木塑环保装饰材料及其制备方法，制得的PVC仿木塑料拉伸强度和弯曲强度高。产品耐酸碱、耐磨，可以广泛生产并不断代替现有材料。采用特制的滚花机在塑料板材表面高温压制出了一层木纹图案，使塑料地板具有了木材的外观和质感，美观适用。比重与木材相当，其柔性超过木材。

Description

高强度仿木塑料环保装饰材料
技术领域
本发明属于仿木塑料环保装饰材料，特别涉及高强度仿木塑料环保装饰材料。
背景技术
塑料仿木产品的材料选用韧性强、防老化进口PP,PE,PS塑胶聚合而成。塑料仿木产品具有对人体无害、无干裂变形、不发霉、无污染和经久耐用的特点，产品的硬度不比实木差，与实木质感一样，表面看上去有木纹与年轮。该产品适用于露天场所、亲水景观、户外栈道、别墅露台、景观装饰、护墙板、壁板、室外露天桌和长凳、围栏、铺板等，用途广泛，市场可观，是广大户外家具厂商的首选取代真藤的户外家具材料。
新兴的仿木塑料主要采用塑料填充共混技术,国内早就有PVC/红泥塑料板,PVC/CaCO3钙塑板,PVC/硫铁矿渣塑料装饰板,塑料/木纤维复合板等。国外,美国Mobil公司利用废塑料膜回收料与锯末掺混做挤出型材,其复合材料具有对紫外光稳定、耐湿、着色性良好、易于油漆、有木质感等特点,用于加工地板、公路护栏及柱子等。
发明内容
本发明的目的，在于提供一种强度仿木塑环保装饰材料及其制备方法，制得的PVC仿木塑料拉伸强度和弯曲强度高。
本发明的技术方案是:
一种高强度仿木塑环保装饰材料，由下述重量配比的原料组成：PVC 100-120份、白炭黑0.5-1.5份、碱式硫酸铜4-8份、PE蜡1-4份、碳酸钙5-10份、硬脂酸钙0.5-1份、硬脂酸锌为0.1-0.3份、AC发泡剂为0.2-0.6份、环氧大豆油5-10份、硬脂酸单甘油醋0.4-0.8份、偶联剂3-6份。
所述偶联剂采用钛酸酯偶联剂。
其制备方法为：
（1）将原料混合后置于双螺杆挤出机中，挤出成型为设定宽度和厚度并且两侧面带有凹槽的板材；
（2）将步骤（1）所得板材切割成设定的长度后，用砂光机进行表面磨砂处理，达到表面平整无光;
（3）用特制的滚花机在经过表面处理的板材表面高温压制出一层由多个凹槽和凹坑组成的木纹图案，压制的温度控制在150-200℃。
本发明由于采用了以上技术方案，具有以下的优点和特点:
1、冲击强度、弯曲强度、拉伸强度均较高，产品耐酸碱、耐磨，可以广泛生产并不断代替现有材料。
2、采用特制的滚花机在塑料板材表面高温压制出了一层木纹图案，使塑料地板具有了木材的外观和质感，美观适用。
3、比重与木材相当，其柔性超过木材。
具体实施例
实施例1：一种高强度仿木塑环保装饰材料，由下述重量配比的原料组成：PVC 100份、白炭黑0.5份、碱式硫酸铜4份、PE蜡1份、碳酸钙5份、硬脂酸钙0.5份、硬脂酸锌为0.1份、AC发泡剂为0.2份、环氧大豆油5份、硬脂酸单甘油醋0.4份、偶联剂3份。
所述偶联剂采用钛酸酯偶联剂。
其制备方法为：
（1）将原料混合后置于双螺杆挤出机中，挤出成型为设定宽度和厚度并且两侧面带有凹槽的板材；
（2）将步骤（1）所得板材切割成设定的长度后，用砂光机进行表面磨砂处理，达到表面平整无光;
（3）用特制的滚花机在经过表面处理的板材表面高温压制出一层由多个凹槽和凹坑组成的木纹图案，压制的温度控制在150℃。
实施例2：一种高强度仿木塑环保装饰材料，由下述重量配比的原料组成：PVC 120份、白炭黑 1.5份、碱式硫酸铜8份、PE蜡4份、碳酸钙10份、硬脂酸钙1份、硬脂酸锌为0.3份、AC发泡剂为0.6份、环氧大豆油10份、硬脂酸单甘油醋0.8份、偶联剂6份。
所述偶联剂采用钛酸酯偶联剂。
其制备方法为：
（1）将原料混合后置于双螺杆挤出机中，挤出成型为设定宽度和厚度并且两侧面带有凹槽的板材；
（2）将步骤（1）所得板材切割成设定的长度后，用砂光机进行表面磨砂处理，达到表面平整无光;
（3）用特制的滚花机在经过表面处理的板材表面高温压制出一层由多个凹槽和凹坑组成的木纹图案，压制的温度控制在200℃。
实施例3：一种高强度仿木塑环保装饰材料，由下述重量配比的原料组成：PVC 120份、白炭黑1.5份、碱式硫酸铜8份、PE蜡4份、碳酸钙6份、硬脂酸钙0.5份、硬脂酸锌为0.2份、AC发泡剂为0.4份、环氧大豆油9份、硬脂酸单甘油醋0.7份、偶联剂4份。
所述偶联剂采用钛酸酯偶联剂。
其制备方法为：
（1）将原料混合后置于双螺杆挤出机中，挤出成型为设定宽度和厚度并且两侧面带有凹槽的板材；
（2）将步骤（1）所得板材切割成设定的长度后，用砂光机进行表面磨砂处理，达到表面平整无光;
（3）用特制的滚花机在经过表面处理的板材表面高温压制出一层由多个凹槽和凹坑组成的木纹图案，压制的温度控制在150℃。
实施例4：一种高强度仿木塑环保装饰材料，由下述重量配比的原料组成：PVC 110份、白炭黑0.6份、碱式硫酸铜6份、PE蜡2份、碳酸钙10份、硬脂酸钙0.5份、硬脂酸锌为0.2份、AC发泡剂为0.2份、环氧大豆油5份、硬脂酸单甘油醋0.8份、偶联剂3份。
所述偶联剂采用钛酸酯偶联剂。
其制备方法为：
（1）将原料混合后置于双螺杆挤出机中，挤出成型为设定宽度和厚度并且两侧面带有凹槽的板材；
（2）将步骤（1）所得板材切割成设定的长度后，用砂光机进行表面磨砂处理，达到表面平整无光;
（3）用特制的滚花机在经过表面处理的板材表面高温压制出一层由多个凹槽和凹坑组成的木纹图案，压制的温度控制在160℃。
实施例5：一种高强度仿木塑环保装饰材料，由下述重量配比的原料组成：PVC 120份、白炭黑0.6份、碱式硫酸铜5份、PE蜡2份、碳酸钙8份、硬脂酸钙1份、硬脂酸锌为0.1份、AC发泡剂为0.2份、环氧大豆油10份、硬脂酸单甘油醋0.4份、偶联剂6份。
所述偶联剂采用钛酸酯偶联剂。
其制备方法为：
（1）将原料混合后置于双螺杆挤出机中，挤出成型为设定宽度和厚度并且两侧面带有凹槽的板材；
（2）将步骤（1）所得板材切割成设定的长度后，用砂光机进行表面磨砂处理，达到表面平整无光;
（3）用特制的滚花机在经过表面处理的板材表面高温压制出一层由多个凹槽和凹坑组成的木纹图案，压制的温度控制在180℃。

Claims (4)

1.一种高强度仿木塑环保装饰材料，其特征在于：由下述重量配比的原料组成：PVC100-120份、白炭黑0.5-1.5份、碱式硫酸铜4-8份、PE蜡1-4份、碳酸钙5-10份、硬脂酸钙0.5-1份、硬脂酸锌为0.1-0.3份、AC发泡剂为0.2-0.6份、环氧大豆油5-10份、硬脂酸单甘油醋0.4-0.8份、偶联剂3-6份。
2.如权利要求1所述的一种高强度仿木塑环保装饰材料，其特征在于：所述偶联剂采用钛酸酯偶联剂。
3.如权利要求1所述的一种高强度仿木塑环保装饰材料，其特征在于：其制备方法为：
（1）将原料混合后置于双螺杆挤出机中，挤出成型为设定宽度和厚度并且两侧面带有凹槽的板材；
（2）将步骤（1）所得板材切割成设定的长度后，用砂光机进行表面磨砂处理，达到表面平整无光;
（3）用特制的滚花机在经过表面处理的板材表面高温压制出一层由多个凹槽和凹坑组成的木纹图案，压制的温度控制在150-200℃。
4.如权利要求1所述的一种高强度仿木塑环保装饰材料，其特征在于：由下述重量配比的原料组成：PVC 100份、白炭黑0.5份、碱式硫酸铜4份、PE蜡1份、碳酸钙5份、硬脂酸钙0.5份、硬脂酸锌为0.1份、AC发泡剂为0.2份、环氧大豆油5份、硬脂酸单甘油醋0.4份、偶联剂3份。
CN201611227597.9A 2016-12-27 2016-12-27 高强度仿木塑料环保装饰材料 Pending CN106633527A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107163715A (zh) * 2017-07-20 2017-09-15 合肥安力电力工程有限公司 一种内墙用的阻燃装饰板及其制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107163715A (zh) * 2017-07-20 2017-09-15 合肥安力电力工程有限公司 一种内墙用的阻燃装饰板及其制备方法

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Application publication date: 20170510