CN106622281A - 一种有机配体改性甲醛净化催化剂的制备方法 - Google Patents
一种有机配体改性甲醛净化催化剂的制备方法 Download PDFInfo
- Publication number
- CN106622281A CN106622281A CN201610868453.5A CN201610868453A CN106622281A CN 106622281 A CN106622281 A CN 106622281A CN 201610868453 A CN201610868453 A CN 201610868453A CN 106622281 A CN106622281 A CN 106622281A
- Authority
- CN
- China
- Prior art keywords
- modified
- water
- catalyst
- titanium oxide
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 51
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical class O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 239000013110 organic ligand Substances 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 238000000746 purification Methods 0.000 title abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000000843 powder Substances 0.000 claims abstract description 32
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000000919 ceramic Substances 0.000 claims abstract description 16
- 150000003839 salts Chemical class 0.000 claims abstract description 9
- 229910052742 iron Inorganic materials 0.000 claims abstract description 7
- 229910052802 copper Inorganic materials 0.000 claims abstract description 6
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 6
- 229910052718 tin Inorganic materials 0.000 claims abstract description 6
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 18
- 239000007789 gas Substances 0.000 claims description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 15
- 239000002002 slurry Substances 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 238000004140 cleaning Methods 0.000 claims description 12
- NWAHZABTSDUXMJ-UHFFFAOYSA-N platinum(2+);dinitrate Chemical compound [Pt+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O NWAHZABTSDUXMJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- 230000009467 reduction Effects 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- 238000013019 agitation Methods 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 8
- 238000007493 shaping process Methods 0.000 claims description 8
- 229910021645 metal ion Inorganic materials 0.000 claims description 7
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 6
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 229910001593 boehmite Inorganic materials 0.000 claims description 5
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims description 5
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 238000000498 ball milling Methods 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 238000010926 purge Methods 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 239000012046 mixed solvent Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 7
- 239000000428 dust Substances 0.000 abstract description 6
- 230000009931 harmful effect Effects 0.000 abstract description 6
- 229920000609 methyl cellulose Polymers 0.000 abstract description 5
- 239000001923 methylcellulose Substances 0.000 abstract description 5
- 238000003421 catalytic decomposition reaction Methods 0.000 abstract description 2
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 2
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 abstract 1
- 230000035943 smell Effects 0.000 abstract 1
- 230000001954 sterilising effect Effects 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 6
- 238000001914 filtration Methods 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 6
- 230000000505 pernicious effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 238000004887 air purification Methods 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000007598 dipping method Methods 0.000 description 4
- 239000010931 gold Substances 0.000 description 4
- 229910052746 lanthanum Inorganic materials 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 239000010948 rhodium Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 2
- 239000007767 bonding agent Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 230000000249 desinfective effect Effects 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 241000256844 Apis mellifera Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 208000014085 Chronic respiratory disease Diseases 0.000 description 1
- 206010011224 Cough Diseases 0.000 description 1
- 206010014561 Emphysema Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 241001122767 Theaceae Species 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 206010047700 Vomiting Diseases 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 208000006673 asthma Diseases 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000000622 irritating effect Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- GEYXPJBPASPPLI-UHFFFAOYSA-N manganese(III) oxide Inorganic materials O=[Mn]O[Mn]=O GEYXPJBPASPPLI-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- -1 second Chemical compound 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/30—Particle separators, e.g. dust precipitators, using loose filtering material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/45—Gas separation or purification devices adapted for specific applications
- B01D2259/4508—Gas separation or purification devices adapted for specific applications for cleaning air in buildings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
本发明公开了一种有机配体改性甲醛净化催化剂的制备方法，将总含量为氧化钛重量1‑10%的La与Cu、Fe、Ni三种中至少一种与Sn、Mn两种中至少一种进行混合预混，再加水混合制成水溶性盐，再加入氧化钛粉料，经干燥高温焙烧制成改性催化剂载体，再加入到金属Pt有机溶液中，经干燥高温焙烧制成改性催化剂载体粉末，再加入拟薄水铝石和甲基纤维素、水制成改性浆料，将蜂窝孔陶瓷片浸渍在改性浆料中，干燥焙烧冷却还原，得到有机配体改性甲醛净化催化剂。本发明不仅能过滤粉尘、消除异味、杀菌消毒和吸附有害气体，还能完全催化分解甲醛有害气体，使吸附的有害气体不会形成二次污染，再是催化剂层不易脱落和开裂，使用寿命长。
Description
技术领域
本发明涉及室内空气净化技术，尤其是涉及一种有机配体改性净化空气分解甲醛的催化剂及其用催化剂制成的空气净化器。
背景技术
随着工业化进程的不断加快，室内空气污染日趋严重，使得室内空气净化也尤为关注。因此人们对居家环境的质量也有了更高的要求。目前对于室内空气净化大都采用滤网+活性炭滤网紫外线杀菌消毒+静电吸附滤网等方法来吸附粉尘、消除异味、杀菌消毒来净化空气。
随着人们生活水平的提高，居家装修已成为普遍性的时尚，但大量建筑材料和装潢材料又造成了室内空气的污染，这些材料中各种化学添加剂使用量也在不断增加，使得新装修房间内空气中挥发性气体浓度高于室外，甚至高于工业区。因此室内空气除有粉尘颗粒、微生物污染物外，还有化学添加剂产生的甲醛、甲苯、氨等挥发性气体等。其中挥发性气体主要甲醛。而甲醛是一种无色易溶的刺激性气体，当室内含量为 0.1 毫克/立方米时就有异味和不适感；0.5 毫克/立方米可刺激眼睛引起流泪；0.6 毫克/立方米时引起咽喉不适或疼痛；浓度再高可引起恶心、呕吐、咳嗽、胸闷、气喘甚至肺气肿；30 毫克/立方米时可当即导致死亡。长期接触低剂量甲醛还可引起慢性呼吸道疾病和致癌。
目前市场上的空气净化器的种类繁多、功能不尽相同，使用方法也不相同，空气净化器一般设置在室内地面上，也有将净化材料装入框内挂在墙壁上或用袋装式设置有分散设置在室内或移动的空气内。但仅工作原理来分，主要有以下两种：一种是被动吸附过滤式的空气净化器。被动式的空气净化，是用风机将空气抽入机器，通过内置的滤网、活性炭滤网、紫外线杀菌消毒+静电吸附滤网过滤空气，主要能够起到过滤粉尘、消除异味、杀菌消毒和吸附有害气体等作用，但它不能分解有害气体，容易使吸附的有害气体再次脱开形成二次污染；二种是主动式的空气净化器，它常采用银离子、负离子、低温等离子技术，虽然它摆脱了风机与滤网的限制，不是被动的等待室内空气被抽入净化器内进行过滤净化，之后再通过风机排出，而是有效、主动的向空气中释放净化灭菌因子，通过空气弥漫性的特点，到达室内的各个角落对空气进行无死角净化，但该类空气净化器最大的缺陷就是臭氧释放量超标。光触媒技术净化空气是一种以纳米级二氧化钛为代表的具有光催化功能的光半导体材料的新技术，它涂布于基材表面，在光线的作用下，产生催化降解功能，能降解空气中甲醛等有毒有害气体，但净化效率较低。
发明内容
针对上述现有技术中空气净化器所存的问题，本发明提供了一种既可过滤和吸附空气中粉尘颗粒、消除异味、杀菌消毒和吸附有害气体，又可有效分解有害气体，提高净化效率的有机配体改性甲醛净化催化剂的制备方法。
本发明所述有机配体改性甲醛净化催化剂的制备方法步骤是：
1、先用陶瓷原料及辅料经球磨、练泥、成型、烘干定型和高温焙烧制成蜂窝孔陶瓷片，
2、将氧化钛原料球磨粉碎成200目以上的粉料，
3、将总含量为氧化钛粉料重量1-10%的La与Cu、Fe、Ni三种中至少一种与Sn、Mn两种中至少一种进行混合预混，再加两倍氧化钛粉料重量的水混合制成相应的水溶性盐，
4、在搅拌条件下，在水溶性盐中加入步骤b的氧化钛粉料，再水浴蒸干，经100-120oC干燥后，再高温焙烧制成改性催化剂载体，
5、称取硝酸铂溶液，硝酸铂溶液中Pt含量为改性催化剂载体重量0.1-2%，将硝酸铂溶液加入到由甲醇、乙醇两种至少一种与甲醛、乙醛两种中至少一种与乙二醇丁醚组成的有机混合溶剂中，加水配成0.01mol/L金属Pt离子有机溶液，
6、在搅拌条件下，将改性催化剂载体加入金属Pt离子有机溶液中，用碳酸钠调节pH值为碱性，再水浴蒸干，经100-120oC干燥后，再高温焙烧制成改性催化剂载体粉末，
7、在改性催化剂载体粉末中加入其重量5-20%的拟薄水铝石和其重量0.5-2%的甲基纤维素及适量的水，充分球磨搅拌并调节成固含量为20-30%、pH值为酸性的改性浆料，
8、将上述蜂窝孔陶瓷片浸渍在改性浆料中，取出后吹扫孔道残余液，经100-120oC干燥后，再在200-600℃高温焙烧，冷却后将其置于还原炉中，通入体积比为10%氢气和90%氮气形成的混合气体，并加热至200℃保温还原，冷却后得到有机配体改性甲醛净化催化剂。
本发明在制备净化分解甲醛整体式催化剂时，一是以氧化钛催化剂层为载体，再在氧化钛中加入具有分散作用的La与Cu、Fe、Ni三种中至少一种与Sn、Mn两种中至少一种进行预混，使混合物能在氧化钛上形成单层分散，形成强的相互作用，从而提高氧化钛稳定性；二是通过加入La，提高了活性组分Pt的分散度，从而提高催化层的活性、选择性；三是制备过程中，引入有机溶剂为改性催化剂，利用有机溶剂与Pt的络合或者分散作用，改变浸渍液的表面张力，降低催化剂Pt纳米粒子的颗粒大小，提高活性中心的分散度，进而提高催化剂的活性，获得一种室温高效稳定处理甲烷的催化剂；五是在甲醛氧化分解过程中，单质Pt是活性中心，Cu、Fe、Ni能与活性组分Pt形成合金，减缓活性组分的氧化过程，SnO2和Mn2O3具有活泼的低温氧化物种，能促进甲醛的分解，提高催化剂层的活性；四是通过加入拟薄水铝石和甲基纤维素，拟薄水铝石与硝酸作用形成的铝溶胶，可以作为浆料的胶黏剂，加强催化剂与陶瓷载体之间的相互作用，提高催化剂浆料的上载量，降低涂层的脱落率，甲基纤维素作为表面活性剂，可以调高浆料的分散性，提高浆料的流动性，便于涂覆上载，同时亦能降低涂层的脱落率。
本发明通过在以氧化钛为基础的催化剂层中加入Pt活性组分与起分散和稳定作用的金属，使蜂窝孔陶瓷片的表面吸附、催化性能大大增强，在充分过滤粉尘、消除异味、杀菌消毒和吸附有害气体等作用的同时，能完全催化分解甲醛有害气体，使吸附的有害气体不会形成二次污染。再是催化剂层不易脱落和开裂，其使用寿命长。
本发明利用甲醇、乙醇、甲醛、乙醛、乙二醇丁醚能降低浸渍溶液的表面张力，从而改变毛细管作用力，使得进入氧化钛载体孔道结构中的Pt颗粒更细小，根据纳米粒子效应，Pt颗粒越小，暴露的活性中心越多，从而使得催化剂活性更高。同时甲醇、乙醇、甲醛、乙醛、乙二醇丁醚本身具有还原性，使得一部分PtO颗粒在的在焙烧过程中，直接还原成更为高效的Pt单质，而这一部分还原出来的Pt，能更为稳定的存在氧化钛的孔道结构中。碳酸钠溶液调节pH为碱性为了使进入载体孔道结构的Pt沉淀，防止在干燥过程中，部分Pt随溶剂挥发溢出。
本发明所述的有机配体改性甲醛净化催化剂包括蜂窝孔陶瓷片和浸渍涂覆在蜂窝孔表面上并由氧化钛、活性金属和起分散、稳定作用的金属或金氧化物组成的催化层通过高温焙烧制成。它可以用来制成箱式的空气净化器，也可以填充在框体中制成悬挂式净化器，还可以制成各种袋装空气净化器放置办公桌上、茶几上、沙发上以及汽车内的某个位置。
用本发明所述催化剂制成的空气净化器进行室内空气净化，经专业部门多次检测室内空气中甲醛含量均在0.08mg/m3以下。
具体实施方式
实施例1
本发明所述有机配体改性甲醛净化催化剂的制备方法步骤是：
1、先用40-50wt%的氧化铝（粉）、30-40wt%二氧化硅（粉）及10-30wt%的粘接剂、润滑剂和熔剂组成的辅料，加适量水经球磨、练泥、成型、烘干定型和高温焙烧制成蜂窝孔陶瓷片，蜂窝孔陶瓷片呈圆柱形，直径为25毫米，高度为12.5毫米，蜂窝孔目数为300目；
2、用氧化钛原料球磨粉碎成250目的氧化钛粉料；
3、将总含量为氧化钛粉料重量5%的La、Cu与Mn的粉末先预混，再加两倍氧化钛粉料重量的水混合制成相应的水溶性盐，La（镧）、Cu与Mn的重量比为4∶3∶3，
4、在搅拌条件下，在水溶性盐中加入步骤b的氧化钛粉料，再用80oC水浴蒸干，经120oC干燥12小时后，再在600oC高温焙烧4小时制成改性催化剂载体，
5、称取硝酸铂溶液，其中硝酸铂溶液中Pt含量为改性催化剂载体重量0.4%，将硝酸铂溶液加入到由重量比为4∶4∶2的甲醇、乙醛与乙二醇丁醚组成的有机溶混合剂中，加水配成0.01mol/L金属Pt离子有机溶液，
6、在搅拌条件下，将改性催化剂载体加入金属Pt离子有机溶液中，用0.1mol/L的碳酸钠溶液调节pH值为8，再用80oC水浴蒸干，经120oC干燥12小时后，再在200-600oC高温焙烧4小时制成改性催化剂载体粉末，
7、在改性催化剂载体粉末中加入其重量10%的拟薄水铝石和其重量1%的甲基纤维素和适量的水，充分球磨搅拌并调节成固含量为20-30%、pH值为4的酸性改性浆料，
8、将上述蜂窝孔陶瓷片浸渍在改性浆料中，浸渍5min后取出，吹扫孔道残余液，经100-120oC干燥后，再在200-600℃高温焙烧4小时，冷却后将其置于还原炉中，通入体积比为10%氢气和90%氮气形成的混合气体，并加热至200℃保温还原，冷却后得到有机配体改性甲醛净化催化剂。
所述金属Pt也可用Pd（钯）、Rh（铑）或金（Au）代用。所述适量的水表示将其调节为固含量为20-30%、pH值为4.5的酸性改性浆料时所用的水。
实施例2，
所述有机配体改性甲醛净化催化剂的制备方法步骤是：
1、先用40-50wt%的氧化铝（粉）、30-40wt%二氧化硅（粉）及10-30wt%的粘接剂、润滑剂和熔剂组成的辅料，加适量水经球磨、练泥、成型、烘干定型和高温焙烧制成蜂窝孔陶瓷片，蜂窝孔陶瓷片呈圆柱形，直径为25毫米，高度为12.5毫米，蜂窝孔目数为300目；
2、用氧化钛原料球磨粉碎成250目的氧化钛粉料；
3、将总含量为氧化钛粉料重量3-5%的La、Fe与Sn的粉末先预混，再加两倍氧化钛粉料重量的水混合制成相应的水溶性盐，La（镧）、Fe与Sn的重量比为4∶3∶3，
4、在搅拌条件下，在水溶性盐中加入步骤b的氧化钛粉料，再用80oC水浴蒸干，经120oC干燥12小时后，再在600oC高温焙烧4小时制成改性催化剂载体，
5、称取硝酸铂溶液，其中硝酸铂溶液中Pt含量为改性催化剂载体重量0.4%，将硝酸铂溶液加入到由重量比为5∶3∶3的乙醇、乙、甲醛与乙二醇丁醚组成的有机溶混合剂中，加水配成0.01mol/L金属Pt离子有机溶液，
6、在搅拌条件下，将改性催化剂载体加入金属Pt有机溶液中，用0.1mol/L的碳酸钠溶液调节pH值为8碱性，再用80oC水浴蒸干，经120oC干燥12小时后，再在200-600oC高温焙烧4小时制成改性催化剂载体粉末，
7、在改性催化剂载体粉末中加入其重量10%的拟薄水铝石和其重量1%的甲基纤维素和适量的水，充分球磨搅拌并调节成固含量为20-30%、pH值为4的酸性改性浆料，
8、将上述蜂窝孔陶瓷片浸渍在改性浆料中，浸渍5min后取出，吹扫孔道残余液，经100-120oC干燥后，再在200-600℃高温焙烧4小时，冷却后将其置于还原炉中，通入体积比为10%氢气和90%氮气形成的混合气体，并加热至200℃保温还原，冷却后得到有机配体改性甲醛净化催化剂。
所述金属Pt也可用Pd（钯）、Rh（铑）或金（Au）代用。所述适量的水表示将其调节为固含量为20-30%、pH值为4.5的酸性改性浆料时所用的水。
Claims (2)
1.一种有机配体改性甲醛净化催化剂的制备方法，其特征是：所述方法步骤是：
a、先用陶瓷原料及辅料经球磨、练泥、成型、烘干定型和高温焙烧制成蜂窝孔陶瓷片，
b、将氧化钛球磨粉碎成200目以上的粉料；
c、将总含量为氧化钛粉料重量1-10%的La与Cu、Fe、Ni三种中至少一种与Sn、Mn两种中至少一种进行混合预混，再加两倍氧化钛粉料重量的水混合制成相应的水溶性盐，
d、在搅拌条件下，在水溶性盐中加入步骤b的氧化钛粉料，再水浴蒸干，经100-120oC干燥后，再高温焙烧制成改性催化剂载体，
e、称取硝酸铂溶液，硝酸铂溶液中Pt含量为改性催化剂载体重量0.1-2%，将硝酸铂溶液加入到由甲醇、乙醇两种至少一种与甲醛、乙醛两种中至少一种与乙二醇丁醚组成的有机混合溶剂中，加水配成0.01mol/L金属Pt离子有机溶液，
f、在搅拌条件下，将改性催化剂载体加入金属Pt离子有机溶液中，用碳酸钠调节pH值为碱性，再水浴蒸干，经100-120oC干燥后，再高温焙烧制成改性催化剂载体粉末，
g、在改性催化剂载体粉末中加入其重量5-20%的拟薄水铝石和其重量0.5-2%的甲基纤维素及适量的水，充分球磨搅拌并调节成固含量为20-30%、pH值为酸性的改性浆料，
h、将上述蜂窝孔陶瓷片浸渍在改性浆料中，取出后吹扫孔道残余液，经100-120oC干燥后，再在200-600℃高温焙烧，冷却后将其置于还原炉中，通入体积比为10%氢气和90%氮气形成的混合气体，并加热至200℃保温还原，冷却后得到有机配体改性甲醛净化催化剂。
2.一种用权利要求1所述方法制成的催化剂制成的空气净化器，其特征是：所述空气净化器为箱式空气净化器，悬挂式净化器或空气净化袋。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610868453.5A CN106622281B (zh) | 2016-09-30 | 2016-09-30 | 一种有机配体改性甲醛净化催化剂的制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610868453.5A CN106622281B (zh) | 2016-09-30 | 2016-09-30 | 一种有机配体改性甲醛净化催化剂的制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106622281A true CN106622281A (zh) | 2017-05-10 |
| CN106622281B CN106622281B (zh) | 2018-11-20 |
Family
ID=58853471
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610868453.5A Active CN106622281B (zh) | 2016-09-30 | 2016-09-30 | 一种有机配体改性甲醛净化催化剂的制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106622281B (zh) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102247837A (zh) * | 2010-05-18 | 2011-11-23 | 上海牛翼新能源科技有限公司 | 消除微环境空气中甲醛的氧化钛负载型催化剂 |
| CN103691436A (zh) * | 2014-01-08 | 2014-04-02 | 兰州中科凯迪化工新技术有限公司 | 一种消除甲醛的低温型催化剂及制备方法 |
| CN104174395A (zh) * | 2014-08-04 | 2014-12-03 | 南昌大学 | 室温消除甲醛稀土改性负载型贵金属整体催化剂制备方法 |
| CN105289298A (zh) * | 2015-10-27 | 2016-02-03 | 展宗城 | 一种室温下消除甲醛的催化模块及其制备方法 |
| CN105561685A (zh) * | 2014-10-15 | 2016-05-11 | 康宁股份有限公司 | 蜂窝空气过滤器及其方法 |
-
2016
- 2016-09-30 CN CN201610868453.5A patent/CN106622281B/zh active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102247837A (zh) * | 2010-05-18 | 2011-11-23 | 上海牛翼新能源科技有限公司 | 消除微环境空气中甲醛的氧化钛负载型催化剂 |
| CN103691436A (zh) * | 2014-01-08 | 2014-04-02 | 兰州中科凯迪化工新技术有限公司 | 一种消除甲醛的低温型催化剂及制备方法 |
| CN104174395A (zh) * | 2014-08-04 | 2014-12-03 | 南昌大学 | 室温消除甲醛稀土改性负载型贵金属整体催化剂制备方法 |
| CN105561685A (zh) * | 2014-10-15 | 2016-05-11 | 康宁股份有限公司 | 蜂窝空气过滤器及其方法 |
| CN105289298A (zh) * | 2015-10-27 | 2016-02-03 | 展宗城 | 一种室温下消除甲醛的催化模块及其制备方法 |
Non-Patent Citations (1)
| Title |
|---|
| 司春波: "《实用电镀工手册》", 31 May 2007 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106622281B (zh) | 2018-11-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105289298B (zh) | 一种室温下消除甲醛的催化模块及其制备方法 | |
| US10188975B2 (en) | Honeycomb air filter and methods thereof | |
| CN107398272B (zh) | 一种甲醛室温催化用复合载体催化剂及其制备方法 | |
| CN107308983B (zh) | 室温除室内voc的催化剂及其制备方法 | |
| CN107876043B (zh) | 一种用于烟气净化的陶瓷催化滤芯及烟气一体化脱硫脱硝除尘方法 | |
| CN104772110B (zh) | 一种可见光响应型空气净化器光触媒滤网及其制备方法 | |
| CN103521174B (zh) | 一种室内空气净化材料及其制备方法 | |
| CN104338528A (zh) | 常温甲醛催化剂的制备 | |
| CN106381682B (zh) | 一种高吸附-光催化性能的纳米二氧化钛/活性炭纤维毡三维多孔材料及其制备方法 | |
| CN106732640B (zh) | 一种以改性海泡石为载体的臭氧分解催化剂网板的制备方法 | |
| CN102836712A (zh) | 一种室温完全去除室内空气中甲醛的催化剂 | |
| CN106582266A (zh) | 一种净化复合空气污染物的装置和方法 | |
| CN102838168A (zh) | 同时室温去除空气中臭氧和甲醛的介孔氧化锰纳米材料 | |
| CN104772109A (zh) | 一种携带层牢固的空气净化器化学触媒滤网及其制备方法 | |
| CN106475112B (zh) | 一种净化分解甲醛整体式催化剂的制备方法 | |
| CN107497442A (zh) | 一种制备高效稀土元素负载铜铝基催化剂的方法及其所制备的催化剂 | |
| CN105642333B (zh) | 一种多功能环境净化复合材料及其制备方法和应用 | |
| CN108435258A (zh) | 净化空气用半导体复合催化剂及其制备方法 | |
| CN115676896B (zh) | 一种非晶态锰氧化物复合材料及其制备方法和应用 | |
| CN102240549A (zh) | 一种高效抗湿室温去除甲醛的催化技术 | |
| CN107876050A (zh) | 一种有机废气净化催化剂及其制备方法 | |
| CN107262147B (zh) | 一种耐硫性催化燃烧催化剂及制备方法 | |
| CN109364892A (zh) | 一种用于烟气净化的高效吸附材料 | |
| CN110302830A (zh) | 高湿度环境下的VOCs净化用分子筛基催化剂及其制备方法与应用 | |
| CN116212853B (zh) | δ-MnO2催化材料及其制备方法和在可降解甲醛的滤网制备中的应用 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240220 Address after: Room 2101, Building 1, Yangfan Business Center, Liangzhu Street, Yuhang District, Hangzhou City, Zhejiang Province, 311121 Patentee after: Zhejiang Fengling Holding Group Co.,Ltd. Country or region after: China Address before: 337200 Luxi County Industrial Park, Pingxiang, Jiangxi Patentee before: JIANGXI BAOAN NEW MATERIAL TECH Co.,Ltd. Country or region before: China |