CN106616917A - Method for preparing natural-flavor caramel by using red date processing wastes - Google Patents

Method for preparing natural-flavor caramel by using red date processing wastes Download PDF

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Publication number
CN106616917A
CN106616917A CN201611119815.7A CN201611119815A CN106616917A CN 106616917 A CN106616917 A CN 106616917A CN 201611119815 A CN201611119815 A CN 201611119815A CN 106616917 A CN106616917 A CN 106616917A
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China
Prior art keywords
caramel
red date
local flavor
date
red
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CN201611119815.7A
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Chinese (zh)
Inventor
何燕青
谢文明
胡忠南
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AIPU FOOD INDUSTRY Co Ltd SHANGHAI
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AIPU FOOD INDUSTRY Co Ltd SHANGHAI
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Priority to CN201611119815.7A priority Critical patent/CN106616917A/en
Publication of CN106616917A publication Critical patent/CN106616917A/en
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • Seasonings (AREA)

Abstract

The invention provides a method for preparing natural-flavor caramel by using red date processing wastes. The method is characterized by comprising the steps: carrying out pretreatment on date residues; putting the treated raw material in a reactor, meanwhile, adding an aqueous extracting medium into the reactor for aqueous extracting treatment, carrying out filtering so as to obtain an aqueous extract and filter residues, and storing the aqueous extract; carrying out enzymolysis treatment on the filter residue, and carrying out filtering, so as to obtain a date residue enzymolysis solution; adding the date residue extract or enzymolysis solution during the preparation of the caramel, thereby preparing the red-date-flavor caramel. According to the method, the natural red-date-flavor caramel and the red-date-flavor caramel with a coloring function are prepared through using the red date processing wastes, which are rich in source, extracting a concentrate with a red date flavor from the red date processing wastes by an extraction technology and a biological enzymolysis technology and using an advanced caramel production regulating and controlling technology. According to the method, the red date processing wastes are efficiently utilized, the flavor source is natural, and thus, the daily-increasing requirements of market and customers on healthy and natural diet are met.

Description

A kind of method that utilization red date processing waste prepares natural type local flavor caramel
Technical field
The present invention relates to a kind of preparation method of local flavor caramel, and in particular to prepared by a kind of recycling by scrap feed material The method of local flavor caramel.
Background technology
Caramel be by heating liquid glucose, make sugar that browning reaction to occur and prepare with special burnt odor smell and soft sweet The seasoning syrup of interest sense, has a wide range of applications in the industries such as baking, sweets, beverage, leisure food.The food of addition caramel Product such as Creme Brulee, caramel milk, Caramel Macchiato etc. are increasingly becoming the new lover in market, with consumer to local flavor and mouthfeel not Pursue disconnectedly, caramel syrup has been assigned different local flavors, such as red date local flavor, chocolate flavouring, fibert local flavor.In order that burnt Sugar itself carries a variety of local flavors, and adding various essence and flavoring agents becomes the differently flavoured master of most of producer's imparting caramel Means are wanted, with demand growth of the market to natural health, it is inevitable trend to prepare local flavor caramel by natural material.
China is red dates production and consumption big country, and with the fast development of modern food processing technology, red date is processed gradually Develop into an important industrial chain.In recent years such as date cake, red date drink, red date fillings product are commercially quietly emerging Rise, also contributed to the large enterprise that the country emerges many processing red dates.But the booming of red date processing industry result in greatly Amount jujube core and fructus corni are discarded, and the pressure of follow-up fixed-end forces are caused, while also making mass efficient composition in fructus corni, jujube core It is wasted.And in recent years, there is that research institution starts with the defect ware in red date process or fructus corni discarded object prepares red date Natural essence, red jujube polysaccharide and pigment etc., such as " fructus corni produces haematochrome technology " are (CN201310473971.3), " one kind is utilized The method that inferior jujube prepares Red jujube flavor and red jujube polysaccharide " (CN201310359528.3), " produce red date caramel colorant it is each because Element is checked colors the impact of rate " etc. research, but not yet have research that the system of local flavor caramel is carried out by using fructus corni, jujube core mixture at present It is standby.
The content of the invention
Problem to be solved by this invention is to provide a kind of utilization red date processing waste and prepares natural type local flavor caramel Method.
What the present invention was achieved through the following technical solutions:
A kind of method that utilization red date processing waste prepares natural type local flavor caramel, it is characterised in that concrete steps are such as Under:
Step 1):Jujube slag (fructus corni, jujube core mixture) is carried out into pre-treatment;
Jujube slag raw material sources in the Chinese different jujube paste processing factories for producing jujubes area, wherein red date species include Xinjiang date, Northern Shensi date, Shanxi date, Shandong date, Cangzhou Golden Chinese Date.Discarded object after preferably Cangzhou Golden Chinese Date of the invention processing As raw material.In pretreatment process preferably drying, breaking method, jujube slag is processed.
Step 2):Treated raw material is put in reactor, while adding water extraction medium to carry out water extraction process, mistake Filter, obtains Aqueous extracts and filter residue, stores Aqueous extracts;
Step 3):Filter residue is carried out into enzymolysis processing, jujube slag enzymolysis liquid is obtained after filtration;
Step 4):Add jujube slag extract or enzymolysis liquid in caramel preparation process, prepare red date local flavor caramel.
Preferably, the step 1) in pre-treatment method include washing, drying, crush and dry in any one or it is several The combination planted.
Preferably, described step 2) in water extraction to process stirred reactor used be the stainless steel reaction with heater The combination of one or more in device, enamel reactor and fiberglass reactor;Water extraction medium used be water, sodium carbonate liquor, The combination of one or more in sodium hydroxide solution;Water extraction solid content is 10~20% (w/w), and water extraction temperature is 80~100 DEG C, pH value is 4.0~8.0, and the water extraction time is 3~8 hours.
Preferably, the step 3) in enzyme preparation used by enzyme solution be pectase, cellulase, zytase, in Any one or a few combination in property protease, flavor protease, compound protease and fungal proteinase;Digesting pH value is 4.5~5.5, hydrolysis temperature is 45~55 DEG C, and enzymolysis time is 5~8 hours, and feed liquid is carried out 90 DEG C of enzymes 15 that go out by enzymolysis after terminating Minute, and filter.
Preferably, the step 4) in caramel preparation process temperature be 100~125 DEG C, pH value be 2.5~6.5, reaction Pressure is 0~0.1MPa, and the reaction time is 1~3 hour.
Preferably, described step 4) in the glycogen material of red date local flavor caramel reaction be that glucose, fructose mass content are Any one or a few combination in 30%~55% HFCS and sucrose.
It is highly preferred that the step 4) in the addition manner of jujube slag extract or jujube slag enzymolysis liquid be that initial stage and raw material are mixed Close, feed supplement and the one of which in addition or several combinations during the reaction later stage in course of reaction.
It is highly preferred that the step 4) in jujube slag extract or enzymolysis liquid be added batch-wise in caramel course of reaction, prepare Red date local flavor caramel with colouring function.
It is highly preferred that the reaction temperature for preparing the red date local flavor caramel with colouring function is 145~160 DEG C, pH It is worth for 2.5~6.5, reaction pressure is 0~0.7MPa, the reaction time is 5~8 hours.
The abundant red date processing waste of combining source of the present invention, is added by abstraction technique and biological enzymolysis technology from red date The concentrate with red date local flavor is extracted in work discarded object, with reference to advanced caramel production control technique, natural type red date is prepared Local flavor caramel and the red date local flavor caramel with colouring function.The invention has not only carried out efficient profit to the discarded object of red date processing With, and its local flavor source is natural, meets the pursuit to diet " healthy, natural " that market and consumer day by day increase.
Description of the drawings
Fig. 1 is the color contrast figure of caramel obtained in embodiment 1-5;
Fig. 2 is the flavour mark result of caramel obtained in embodiment 1-5.
Specific embodiment
To become apparent the present invention, hereby with preferred embodiment, and accompanying drawing is coordinated to be described in detail below.
Embodiment 1
Step 1:Jujube slag mixture 300g after dries pulverizing is added in 5L stainless steel stirred reactors, add water 2700g, Regulation system solid content 10%;
Step 2:PH being adjusted to 5.0, being extracted 5 hours under the conditions of 90 DEG C, extract is through sheet frame pressure with 30%NaOH solution After filter, obtain supernatant 2.4kg and store for future use;
Step 3:2.7kg HFCSs (fructose content 42%, solid content 70%) are weighed in reactor;
Step 4:Jujube pulp water extract 300g is added, pH to 4.5 is adjusted;
Step 5:121 DEG C are warming up to, pressure 0.1MPa reacts 1 hour, obtains the caramel syrup with red date local flavor, sugar Pulp color does not possess colouring function in light brown.
Embodiment 2
Step 1:The filter residue after filtering in example 1 is taken, its water content is measured for 51%;
Step 2:The wet filter residues of 600g are weighed, the 1656g that adds water is adjusted to system solid content 15%, pH value 4.8;
Step 3:Pectase (production of Shanghai Mazy companies) and cellulase are added with the 0.3% of siccative enzyme addition (production of Novo companies of Denmark) mixture (mixed proportion 1: 3), 50 DEG C digest 8 hours;
Step 4:After reaction terminates, be warming up to 90 DEG C, go out enzyme 15 minutes, filter supernatant 1.7kg is stored for future use, filter residue Store after drying;
Step 5:2.85kg HFCSs (fructose content 42%, solid content 70%) are weighed in reactor, jujube slag enzyme is added Solution liquid 150g, adjusts pH to 4.5;
Step 6:121 DEG C are warming up to, pressure 0.1MPa reacts 1 hour, obtains the caramel syrup with red date local flavor, sugar Pulp color is brown, does not possess colouring function.
Embodiment 3
Step 1:Jujube slag mixture 600g after dries pulverizing is added in 5L stainless steel stirred reactors, add water 2400g, Adjust solid content 20%;
Step 2:PH is adjusted to 5.0, extract 5 hours under the conditions of 90 DEG C with 30%NaOH solution;
Step 3:Extract obtains supernatant 1.7kg and stores for future use after plate compression;
Step 4:2.70kg glucose solutions (solid content 70%) are weighed in reactor, pH to 3.5 is adjusted;
Step 5:150 DEG C are warming up to, pressure 0.55MPa reacts 7 hours;
Step 6:After system is cooled to 100 DEG C, 450g jujube slag extracts are added by reactor material-feeding port;
Step 7:Under the conditions of 121 DEG C, pressure 0.1MPa, 1 hour is incubated, the sugar of the caramel with strong red date local flavor is obtained Slurry, syrup color is in dark brown, and color rate value is 0.025 after 1000 times of dilution, with certain colouring function.
Embodiment 4
Step 1:The filter residue obtained in embodiment 3 is carried out into moisture determination, measured value 55%;
Step 2:The wet filter residues of 1000g are weighed, the 2450g that adds water is adjusted to system solid content 15%, pH value 4.8;
Step 3:Add pectase (production of Shanghai Mazy companies) and cellulase (red with the 0.3% of siccative enzyme addition Wheat Novo companies produce) (ratio 1: 3), 50 DEG C digest 8 hours;
Step 4:After reaction terminates, be warming up to 90 DEG C, go out enzyme 15 minutes, filter supernatant 2kg is stored for future use;
Step 5:2.70kg glucose solutions (solid content 70%) are weighed in reactor, 150g jujube slag enzymolysis liquids are added, is adjusted Section pH to 3.5;
Step 6:150 DEG C of temperature, pressure 0.55MPa reacts 4.5 hours;100 DEG C are subsequently cooled to, are mended by reactor Material mouth adds 300g jujube pulp water extracts;
Step 7:1 hour is incubated in 121 DEG C, 0.1MPa, the caramel syrup with red date local flavor is obtained, syrup color is darkly Color, color rate value is 0.043 after 1000 times of dilution, with stronger colouring function.
Embodiment 5
Step 1:2.70kg HFCSs (fructose content 42%, solid content 70%) are weighed in reactor, 150g jujubes are added Slag enzymolysis liquid, adjusts pH to 3.5;
Step 2:150 DEG C are warming up to, pressure 0.55MPa reacts 4 hours;
Step 3:100 DEG C are subsequently cooled to, 450g jujube pulp water extracts are added by reactor material-feeding port;
Step 4:1 hour is incubated in 121 DEG C, 0.1MPa, the caramel syrup with red date local flavor is obtained, syrup color is darkly Color, color rate value is 0.052 after 1000 times of dilution, with stronger colouring function.
Respectively subjective appreciation is carried out to the red date local flavor caramel in 5 embodiments, caramel outward appearance is as shown in Figure 1.Adjuster Number 10 (5 male 5 female), local flavor and mouthfeel adopt descriptive analysis method, are divided into two grades of local flavor and mouthfeel, and local flavor aspect has 4 grades Scoring:The strong red date local flavors of 4-;The denseer red date local flavors of 3-;The slight red date local flavors of 2-;1- is without red date local flavor;Mouthfeel aspect has 5 grades Scoring:5- sweet tastes carry strong red-jujube flavor secretly;4- sweet tastes carry slight red-jujube flavor secretly;3- is only pleasantly sweet;2- only has red-jujube flavor;1- is bitter With red-jujube flavor;0- is bitter without red-jujube flavor, and appraisal result is as shown in Figure 2.
Can be drawn by Fig. 2:1. the red date local flavor caramel for being produced using red date processing waste is all embodied in the product Red date local flavor;2. judge in result, the caramel seasoning function of embodiment 2 is optimal;3. burnt in the red date local flavor with colouring function In sugar, the local flavor and mouthfeel of embodiment 4 is optimal, without obvious bitter taste.
The raw material of the red date local flavor caramel being related in this explanation is not limited only to the processing waste of Cangzhou Golden Chinese Date, also may be used Being the one or more combination of Xinjiang date, northern Shensi date, Shanxi date, Shandong date.The jujube slag being related in this explanation is carried The preparation method for taking liquid is not limited only to high temperature water extraction, or low temperature water extraction, high temperature alkaline extraction, low temperature alkaline extraction, height Warm acid-hydrolysis method, low temperature acid-hydrolysis method.Enzyme in the enzymolysis step being related in this explanation selects to be not limited only to pectase and fiber One or more in plain enzyme, or zytase, neutral proteinase, flavor protease, compound protease, fungal proteinase Combination.

Claims (9)

1. a kind of method that utilization red date processing waste prepares natural type local flavor caramel, it is characterised in that comprise the following steps that:
Step 1):Jujube slag is carried out into pre-treatment;
Step 2):Treated raw material is put in reactor, while adding water extraction medium to carry out water extraction process, filter, is obtained To Aqueous extracts and filter residue, Aqueous extracts are stored;
Step 3):Filter residue is carried out into enzymolysis processing, jujube slag enzymolysis liquid is obtained after filtration;
Step 4):Add jujube slag extract or enzymolysis liquid in caramel preparation process, prepare red date local flavor caramel.
2. the method for preparing natural type local flavor caramel using red date processing waste as claimed in claim 1, it is characterised in that The step 1) in pre-treatment method include washing, drying, crush and dry in any one or a few combination.
3. the method for preparing natural type local flavor caramel using red date processing waste as claimed in claim 1, it is characterised in that Described step 2) in water extraction process stirred reactor used be the stainless steel reactor with heater, enamel reactor and The combination of one or more in fiberglass reactor;Water extraction medium used is in water, sodium carbonate liquor, sodium hydroxide solution The combination of one or more;Water extraction solid content is 10~20%, and water extraction temperature is 80~100 DEG C, and pH value is 4.0~8.0, water extraction Time is 3~8 hours.
4. the method for preparing natural type local flavor caramel using red date processing waste as claimed in claim 1, it is characterised in that The step 3) in enzyme preparation used by enzyme solution be pectase, cellulase, zytase, neutral proteinase, local flavor egg Any one or a few combination in white enzyme, compound protease and fungal proteinase;Enzymolysis pH value is 4.5~5.5, enzymolysis temperature Spend for 45~55 DEG C, enzymolysis time is 5~8 hours, feed liquid is carried out 90 DEG C of enzymes 15 minutes of going out by enzymolysis after terminating, and is filtered.
5. the method for preparing natural type local flavor caramel using red date processing waste as claimed in claim 1, it is characterised in that The step 4) in caramel preparation process temperature be 100~125 DEG C, pH value be 2.5~6.5, reaction pressure be 0~ 0.1MPa, the reaction time is 1~3 hour.
6. the method that the utilization red date processing waste as described in claim 1 or 5 prepares natural type local flavor caramel, its feature exists In described step 4) in the reaction of red date local flavor caramel glycogen material be glucose, fructose mass content be 30%~55% Any one or a few combination in HFCS and sucrose.
7. the method for preparing natural type local flavor caramel using red date processing waste as claimed in claim 1, it is characterised in that The step 4) in jujube slag extract or jujube slag enzymolysis liquid addition manner mix with raw material for the initial stage, in course of reaction feed supplement and One of which in addition or several combinations during the reaction later stage.
8. the method for preparing natural type local flavor caramel using red date processing waste as claimed in claim 1, it is characterised in that The step 4) in jujube slag extract or enzymolysis liquid be added batch-wise in caramel course of reaction, prepare the red date with colouring function Local flavor caramel.
9. the method for preparing natural type local flavor caramel using red date processing waste as claimed in claim 8, it is characterised in that The reaction temperature for preparing the red date local flavor caramel with colouring function is 145~160 DEG C, and pH value is 2.5~6.5, reaction Pressure is 0~0.7MPa, and the reaction time is 5~8 hours.
CN201611119815.7A 2016-12-07 2016-12-07 Method for preparing natural-flavor caramel by using red date processing wastes Pending CN106616917A (en)

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CN107412275A (en) * 2017-05-11 2017-12-01 张新 The preparation method of a variety of biology enzyme micro mist fermentation preparations
CN109170792A (en) * 2018-09-04 2019-01-11 上海爱普食品工业有限公司 A method of natural type flavor caramel is prepared using tea extract
CN112088904A (en) * 2020-10-22 2020-12-18 丽水市农林科学研究院 Preparation method and application of paris polyphylla extractive solution
CN113209913A (en) * 2021-04-26 2021-08-06 上海爱普食品工业有限公司 Preparation method of caramel-colored hydrogel
CN116083657A (en) * 2022-12-05 2023-05-09 浙江华康药业股份有限公司 System and method for co-producing high-grade xylose and high-end caramel pigment by utilizing corncob

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107412275A (en) * 2017-05-11 2017-12-01 张新 The preparation method of a variety of biology enzyme micro mist fermentation preparations
CN109170792A (en) * 2018-09-04 2019-01-11 上海爱普食品工业有限公司 A method of natural type flavor caramel is prepared using tea extract
CN112088904A (en) * 2020-10-22 2020-12-18 丽水市农林科学研究院 Preparation method and application of paris polyphylla extractive solution
CN113209913A (en) * 2021-04-26 2021-08-06 上海爱普食品工业有限公司 Preparation method of caramel-colored hydrogel
CN116083657A (en) * 2022-12-05 2023-05-09 浙江华康药业股份有限公司 System and method for co-producing high-grade xylose and high-end caramel pigment by utilizing corncob

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