CN106614550A - Additive used for producing pesticide emulsion in water and preparation and application thereof - Google Patents

Additive used for producing pesticide emulsion in water and preparation and application thereof Download PDF

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Publication number
CN106614550A
CN106614550A CN201611233395.5A CN201611233395A CN106614550A CN 106614550 A CN106614550 A CN 106614550A CN 201611233395 A CN201611233395 A CN 201611233395A CN 106614550 A CN106614550 A CN 106614550A
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CN
China
Prior art keywords
aqueous emulsion
water
auxiliary agent
emulsion
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611233395.5A
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Chinese (zh)
Inventor
马斌武
王永生
韩仲强
申宝兵
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JIANGSU ZHONGSHANG CHEMICAL CO Ltd
Original Assignee
JIANGSU ZHONGSHANG CHEMICAL CO Ltd
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Application filed by JIANGSU ZHONGSHANG CHEMICAL CO Ltd filed Critical JIANGSU ZHONGSHANG CHEMICAL CO Ltd
Priority to CN201611233395.5A priority Critical patent/CN106614550A/en
Publication of CN106614550A publication Critical patent/CN106614550A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof

Abstract

The invention discloses an additive used for producing a pesticide emulsion in water. The additive is the mixture of three kinds of compounds, and the compounds comprise, by mass, 10-20% of castor oil polyoxyethylene ether, 30-40% of block polyether, and 10% of the supplement ethylene glycol. The invention further discloses an additive amount of the additive in the process in which highchlorobenzene,E.C. mother liquor is adopted to produce the emulsion in water and an application range of the highchlorobenzene,E.C. By using the additive to produce high-chlorine emulsion, the application range (3%-7%) of high chlorine in a preparation can be sharply improved, the preparation form is stable, and the preparation amount is low (the additive covers 8%-10% of the total amount of emulsion), the synergia is obvious, the particle size is superfine and the preparing method is simple. The invention further discloses the preparing method of producing the pesticide emulsion in water.

Description

A kind of auxiliary agent and its preparation and use for making pesticide emulsion in water
Technical field
The present invention relates to field of pesticide chemistry, and in particular to a kind of auxiliary agent and its preparation method for making pesticide emulsion in water and Purposes.
Background technology
Aqueous emulsion agent world code name EW, also referred to as emulsifiable concentrate, are by liquid or former with the liquid pesticidal that solvent is mixed to prepare The preparation that medicine is dispersed in water with the droplet of 0.5-1.5 microns, outward appearance is milky milk shape liquid.Aqueous emulsion is because using big The water of amount has saved natural resources as main solvent, is internationally recognized environment-friendly water-based agent type, and auxiliary agent low cost, production sets It is standby simple, it is one of main formulation of current Agrochemicals.
There are some technical barriers in aqueous emulsion product:1) stabilization time is stored short:The normal period of storage of agricultural chemicals is 2-3 Year, and the aqueous emulsion normal shelf time is 1 year or so;2) easily there is lamination:Can be with the thing of temperature, active compound and auxiliary agent Reason and the reason such as change, ultraviolet, time, water quality of chemistry and go out to manage breakdown of emulsion, be exactly that water is separated with solvent, formed and be layered;3) Easily there is deposited phenomenon:Because auxiliary agent and active compound such as decompose at the reason, and cause active compound to separate out from the middle of preparation, formation rice-shaped or Crystalline material and sink to bottom, greatly reduce the content of product drug effect and active ingredient;4) it is difficult solution pesticide synergistic to ask Topic:Due to being that, with water as main solvent, the formation of aqueous emulsion is a kind of dynamic stability principle, conventional builder is such as doubled Kill, vegetable oil, organosilicon, thiophene ketone etc., it is extremely unstable in the formulation, so, the normal formulation surface tension of aqueous emulsion with Almost, it is maximum problem that adhesion and penetration difference are aqueous emulsions, it is difficult to improve product drug effect for the surface tension of water;5) water Emulsion easily freezes in winter, and particularly northern China temperature is less than -15 DEG C, significantly limit the development of the formulation.
The content of the invention
In order to solve the above problems, the invention provides a kind of emulsion-in-water pesticide auxiliary agent and its application, should by addition Aqueous emulsion product stable dosage forms that auxiliary agent is obtained, synergy are notable, particle diameter is ultra-fine, and preparation method is simple.
Technical scheme is as follows:
A kind of auxiliary agent for making pesticide emulsion in water, the auxiliary agent is the mixture of three kinds of compounds:Including accounting for combination The castor oil polyoxyethylene ether of thing gross mass 10-20% and the block polyether of composition gross mass 30-40% is accounted for, ethylene glycol Supply 100%.
The auxiliary agent of above-mentioned aqueous emulsion, described castor oil polyoxyethylene ether is BY-125 castor oil polyoxyethylene ethers.
The auxiliary agent of above-mentioned aqueous emulsion, described block polyether is L64 block polyethers.
A kind of preparation method of the auxiliary agent of above-mentioned aqueous emulsion, it is weighed by the recipe ingredient of above-mentioned aqueous emulsion, and stirring is mixed Close uniform, obtain final product the auxiliary agent of described aqueous emulsion.
Application of the auxiliary agent of above-mentioned aqueous emulsion in effective cypermethrin benzene oil-water emulsions are prepared.Above-mentioned high chlorobenzene oil Aqueous emulsion, described effective cypermethrin benzene oil folding hundred is the 3%-7% of aqueous emulsion gross mass.
Above-mentioned aqueous emulsion, is characterized in that:The auxiliary agent of described aqueous emulsion is the 8%-10% of aqueous emulsion gross mass.
The aqueous emulsion product stable dosage forms that are obtained of auxiliary agent of the aqueous emulsion of the present invention, particle diameter are ultra-fine, and preparation method letter It is single.
Specific embodiment
The preferred embodiments of the present invention are illustrated below, it will be appreciated that preferred embodiment described herein is only used In the description and interpretation present invention, it is not intended to limit the present invention.
Unless otherwise stated, the percentage employed in the present invention is mass percent.
Embodiment 1:
Castor oil 93.3g is thrown in 1L reactors, catalyst KOH, 0.18g is added, after with nitrogen reactor is replaced, Dehydration is vacuumized, vacuum carries gas 2 hours after being warmed up to 110 DEG C, then led under 120~170 DEG C, 0.1~0.6MPa pressure conditions Enter 176 grams of EO (oxirane), after having entered EO, react aging 1.5hr, neutralized, absorption, dehydration, gas use leaf filter Filter, filtrate decompression is distilled, obtain product BY-125, number-average molecular weight 269.
Embodiment 2:
Ethylene glycol 62g is thrown in 1L reactors, catalyst KOH, 0.1g is added, after with nitrogen reactor is replaced, is taken out Vacuum dehydration, vacuum carries gas 2 hours after being warmed up to 110 DEG C, then is passed through under 120~170 DEG C, 0.1~0.6MPa pressure conditions 232 grams of PO (expoxy propane), 352 grams of EO (oxirane), after having entered EO, react aging 1.5hr, neutralized, absorption, dehydration, Gas, is filtered with leaf filter, and filtrate decompression is distilled, and obtains product L64, number-average molecular weight 646.
Effective cypermethrin benzene oil-water emulsions insecticide, by following mass percent into being grouped into:
The auxiliary agent 8%-10% of high chlorobenzene oil 3%-7%, the aqueous emulsion of the present invention., deionized water supply 100%.
The preparation of the auxiliary agent of the aqueous emulsion of embodiment 3.
Weigh:Castor oil polyoxyethylene ether BY-125 (Jiangsu Zhongshang Chemical Co., Ltd., similarly hereinafter) 10kg;
Block polyether L64 (Jiangsu Zhongshang Chemical Co., Ltd., similarly hereinafter) 40kg;
Ethylene glycol (Jinan Jing An Chemical Co., Ltd.s, similarly hereinafter) 50kg;
It is put in mixer and stirs, obtains final product the auxiliary agent of aqueous emulsion.
The preparation of the auxiliary agent of the aqueous emulsion of embodiment 4.
Weigh:Castor oil polyoxyethylene ether BY-125 20kg;
Block polyether L64 30kg;
Ethylene glycol 50kg;
It is put in mixer and stirs, obtains final product the auxiliary agent of aqueous emulsion.
The preparation of the auxiliary agent of the aqueous emulsion of embodiment 5.
Weigh:Castor oil polyoxyethylene ether BY-12515kg;
Block polyether L6425kg;
Ethylene glycol 50kg;
It is put in mixer and stirs, obtains final product the auxiliary agent of aqueous emulsion.
The effective cypermethrin benzene oil-water emulsions insecticide of embodiment 6.
High chlorobenzene oil is 5%, water and milk agent aid obtained in embodiment 3 is 10%., deionized water supply 100%.Make height Effect cypermethrin benzene oil-water emulsions insecticide.
As a result:Stable dosage forms, storage at normal temperature was up to more than 2 years;2nd, active ingredient 15 days, is put down without degraded, 52 DEG C ± 2 of heat storage Equal degradation rate 0.1%;- 10 DEG C of cold storage ± 2,15 days, does not freeze, and nodeless mesh, percent hydrolysis is 0.01%;Particle diameter≤3 μm.
The effective cypermethrin benzene oil-water emulsions insecticide of embodiment 7.
High chlorobenzene oil is 5%, water and milk agent aid obtained in embodiment 4 is 9%., deionized water supply 100%.Make height Effect cypermethrin benzene oil-water emulsions insecticide.
As a result:Stable dosage forms, storage at normal temperature was up to more than 2 years;Active ingredient without degraded, 52 DEG C ± 2 of heat storage, 15 days, averagely Degradation rate 0.14%;- 10 DEG C of cold storage ± 2,15 days, does not freeze, and nodeless mesh, percent hydrolysis is 0.03%;Particle diameter≤3.5 μm.
The effective cypermethrin benzene oil-water emulsions insecticide of embodiment 8.
High chlorobenzene oil is 5%, water and milk agent aid obtained in embodiment 5 is 8%., deionized water supply 100%.Make height Effect cypermethrin benzene oil-water emulsions insecticide.
As a result:Stable dosage forms, storage at normal temperature was up to more than 2 years;Active ingredient without degraded, 52 DEG C ± 2 of heat storage, 15 days, averagely Degradation rate 0.19%;- 10 DEG C of cold storage ± 2,15 days, does not freeze, and nodeless mesh, percent hydrolysis is 0.05%;Particle diameter≤4 μm.
The effective cypermethrin benzene oil-water emulsions insecticide of embodiment 9.
High chlorobenzene oil is 3%, water and milk agent aid obtained in embodiment 3 is 10%., deionized water supply 100%.Make height Effect cypermethrin benzene oil-water emulsions insecticide.
As a result:Stable dosage forms, storage at normal temperature was up to more than 2 years;Active ingredient without degraded, 52 DEG C ± 2 of heat storage, 15 days, averagely Degradation rate 0.11%;- 10 DEG C of cold storage ± 2,15 days, does not freeze, and nodeless mesh, percent hydrolysis is 0.03%;Particle diameter≤2.8 μm.
The effective cypermethrin benzene oil-water emulsions insecticide of embodiment 10.
High chlorobenzene oil is 7%, water and milk agent aid obtained in embodiment 3 is 10%., deionized water supply 100%.Make height Effect cypermethrin benzene oil-water emulsions insecticide.
As a result:Stable dosage forms, storage at normal temperature was up to more than 2 years;Active ingredient without degraded, 52 DEG C ± 2 of heat storage, 15 days, averagely Degradation rate 0.10%;- 10 DEG C of cold storage ± 2,15 days, does not freeze, and nodeless mesh, percent hydrolysis is 0.05%;Particle diameter≤3 μm.

Claims (7)

1. a kind of auxiliary agent for making pesticide emulsion in water, is characterized in that:The auxiliary agent is the mixture of three kinds of compounds:Including The castor oil polyoxyethylene ether for accounting for composition gross mass 10-20% and the block polyether for accounting for composition gross mass 30-40%, Ethylene glycol supplies 100%.
2. the auxiliary agent of aqueous emulsion according to claim 1, is characterized in that:Described castor oil polyoxyethylene ether is BY-125 Castor oil polyoxyethylene ether.
3. the auxiliary agent of aqueous emulsion according to claim 1, is characterized in that:Described block polyether is L64 block polyethers.
4. a kind of preparation method of the auxiliary agent of the aqueous emulsion described in claim 1, is characterized in that:It is the water as described in claim 1 The recipe ingredient of emulsion is weighed, and is uniformly mixed, and obtains final product the auxiliary agent of described aqueous emulsion.
5. application of the auxiliary agent of the aqueous emulsion described in claim 1 in high chlorobenzene oil-water emulsions are prepared.
6. high chlorobenzene oil-water emulsions according to claim 4, is characterized in that:Described high chlorobenzene oil is aqueous emulsion gross mass 3%-7%.
7. aqueous emulsion according to claim 4, is characterized in that:The auxiliary agent of described aqueous emulsion is aqueous emulsion gross mass 8%-10%.
CN201611233395.5A 2016-12-28 2016-12-28 Additive used for producing pesticide emulsion in water and preparation and application thereof Pending CN106614550A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611233395.5A CN106614550A (en) 2016-12-28 2016-12-28 Additive used for producing pesticide emulsion in water and preparation and application thereof

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Application Number Priority Date Filing Date Title
CN201611233395.5A CN106614550A (en) 2016-12-28 2016-12-28 Additive used for producing pesticide emulsion in water and preparation and application thereof

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Publication Number Publication Date
CN106614550A true CN106614550A (en) 2017-05-10

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1961674A (en) * 2005-11-07 2007-05-16 浙江新农化工有限公司 Water emulsion of hostathion and preparation method thereof
CN101700017A (en) * 2009-08-01 2010-05-05 深圳诺普信农化股份有限公司 Ethiprole emulsion in water and preparation method thereof
CN102885072A (en) * 2012-09-28 2013-01-23 王龙华 High-chlorine emulsion pesticide and production technology thereof
CN104413032A (en) * 2013-09-06 2015-03-18 浙江泰达作物科技有限公司 Ethoxysulfuron and fenoxaprop-p-ethyl compound emulsion in water and preparation method thereof
CN105165846A (en) * 2015-09-17 2015-12-23 上海万厚生物科技有限公司 BBIT water emulsion and preparation method thereof
CN106472490A (en) * 2016-09-26 2017-03-08 安徽省农业科学院植物保护与农产品质量安全研究所 A kind of hot mist machine functionalization auxiliary agent and its preparation and application

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1961674A (en) * 2005-11-07 2007-05-16 浙江新农化工有限公司 Water emulsion of hostathion and preparation method thereof
CN101700017A (en) * 2009-08-01 2010-05-05 深圳诺普信农化股份有限公司 Ethiprole emulsion in water and preparation method thereof
CN102885072A (en) * 2012-09-28 2013-01-23 王龙华 High-chlorine emulsion pesticide and production technology thereof
CN104413032A (en) * 2013-09-06 2015-03-18 浙江泰达作物科技有限公司 Ethoxysulfuron and fenoxaprop-p-ethyl compound emulsion in water and preparation method thereof
CN105165846A (en) * 2015-09-17 2015-12-23 上海万厚生物科技有限公司 BBIT water emulsion and preparation method thereof
CN106472490A (en) * 2016-09-26 2017-03-08 安徽省农业科学院植物保护与农产品质量安全研究所 A kind of hot mist machine functionalization auxiliary agent and its preparation and application

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Application publication date: 20170510