CN105165846A - BBIT water emulsion and preparation method thereof - Google Patents
BBIT water emulsion and preparation method thereof Download PDFInfo
- Publication number
- CN105165846A CN105165846A CN201510594745.XA CN201510594745A CN105165846A CN 105165846 A CN105165846 A CN 105165846A CN 201510594745 A CN201510594745 A CN 201510594745A CN 105165846 A CN105165846 A CN 105165846A
- Authority
- CN
- China
- Prior art keywords
- bbit
- aqueous emulsion
- ether
- emulsion
- add
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- LUYIHWDYPAZCNN-UHFFFAOYSA-N CCCCN1Sc(cccc2)c2C1=O Chemical compound CCCCN1Sc(cccc2)c2C1=O LUYIHWDYPAZCNN-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicinal Preparation (AREA)
- Colloid Chemistry (AREA)
Abstract
The invention discloses a BBIT water emulsion which comprises the following components in parts by weight: 10-40 percent of BBIT, 1-10 percent of an emulsion, 0.1-3 percent of a thickening agent, 1-5 percent of an anti-freezing agent and the balance of deionized water. The invention further discloses a preparation method of the BBIT water emulsion. The preparation method comprises the following steps: (1) adding the emulsion into the BBIT raw medicine to form an oil phase; (2) adding the thickening agent and a proper amount of deionized water to form a water phase; (3) adding the prepared oil phase into the water phase, and carrying out high-speed shearing emulsification to form stable O/W emulsion; (4) respectively adding the anti-freezing agent, adding the deionized water to 100ml, and uniformly stirring. The BBIT water emulsion prepared by the method is low in manufacturing cost, low in toxicity, unlikely to combust and high in environment compatibility.
Description
Technical field
The invention belongs to function Field of Fine Chemicals, specifically, is about a kind of BBIT aqueous emulsion and preparation method thereof.
Background technology
2-butyl-BIT (BBIT), its molecular structure is:
The sterling of BBIT is light yellow transparent liquid, boiling point is 170 ~ 175 DEG C, relative density 1.15 ~ 1.18, solvability (20 DEG C)≤1mg/L in water, heat endurance is greater than 300 DEG C, pH1 ~ pH13 hydrolysis-stable, has good UV resistant performance, can effectively killing fungus, bacterium, saccharomycete and part algae, use mainly as industrial bactericide at present.
At present in domestic and international selling market, BBIT preparation is mainly using a large amount of alcohols solvent as matrix, and this kind of organic solvent is inflammable and explosive, serious environment pollution, affects the VOC content of product simultaneously, also wastes a large amount of non-renewable resources.In recent years along with the increasingly stringent of environmental requirement, national requirements development environment friendly novel form, industrial bactericide formulation development to water baseization, ultramicronising, without dust and controlled release aspect development.Wherein water baseization is exactly one of Main way of industrial bactericide development.
Summary of the invention
The object of the present invention is to provide a kind of BBIT preparation using no or little organic solvent, Environmental Safety, provide its preparation method simultaneously.
For achieving the above object, the present invention is by the following technical solutions:
A kind of BBIT aqueous emulsion, comprises the formula of following mass percent:
Further, according to actual needs, described BBIT aqueous emulsion also comprises bleeding agent and/or defoamer.
According to the present invention, described emulsifier is dodecyl benzene sulfonate or castor oil/rilanit special and ethylene oxide mixture, castor oil polyoxyethylene base ether, glycerin polyoxyethylene ether fatty ester, aliphatic alcohol polyethenoxy base ether, aliphatic acid polyethenoxy ether phosphoric acid ester, fatty acid and ethylene oxide mixture, polyoxyethylene carboxylate, polyoxyethylene polyoxypropylene block polyether, polyoxyethylene sorbitan fatty acid ester, polyethylene glycol hard fatty acid ester, Castor Oil Phosphate Ester Salt, alkyl polyoxyethylene ether phosphoric acid ester, polyphosphazene polymer phosphoric acid ester/salt, at least one in fatty alcohol-polyoxyethylene ether phosphoric acid ester and salt thereof.
According to the present invention, described thickener is at least one in xanthans or cellulose ether and derivative thereof, polyvinyl alcohol, aluminium-magnesium silicate, gelatin, gum Arabic, bentonite, dextrin, polyvinylpyrrolidone PVP, white carbon.
Preferably, described thickener is at least one in xanthans or cellulose ether and derivative thereof.
According to the present invention, described antifreeze is at least one in ethylene glycol or propane diols, glycerine, polyethylene glycol, isopropyl alcohol, urea.
Preferably, described antifreeze is propane diols.
According to the present invention, described bleeding agent is at least one in organosilicon or aerosol-OT salt, fatty alcohol polyoxyalkyl ether, fatty alcohol-polyoxyethylene ether, fatty alcohol and ethylene oxide mixture, and described defoamer is the one in silicone based defoamer or lower alcohol system defoamer.
A preparation method for BBIT aqueous emulsion described in above-mentioned any one, the method is carried out according to the following steps:
(1) in the BBIT of 10g ~ 40g, add the emulsifier of 1g ~ 10g, form oil phase;
(2) thickener of 0.1 ~ 3g is joined in appropriate amount of deionized water, stir and form aqueous phase;
(3) being joined by the oil phase that step (1) prepares in the aqueous phase that step (2) configures and to open high speed shear emulsification, rotating speed is 3000 revs/min, forms stable O/W emulsion;
(4) after opening stirring, then add the antifreeze of 1 ~ 5g, add deionized water to 100ml, stir, be i.e. obtained BBIT aqueous emulsion.
According to the present invention, also can add defoamer in step (2), in step (4), add bleeding agent.
BBIT aqueous emulsion of the present invention and preparation method thereof, its beneficial effect is: the advantages such as its low cost of manufacture, toxicity are low, nonflammable, environmentally safe, are embodied in the following aspects:
(1) aqueous emulsion of the present invention hardly with an organic solvent, greatly reduces the VOC of product;
(2) without flash-point problem, do not burn and do not explode, produce storage and use safety;
(3) environmental pollution is little, to process operation and Environmental security;
(4) take water as matrix, aboundresources, safety when manufacturing and use, packaging, storage and convenient transportation, expense is low, thus reduces production cost;
(5) mildew-resistant better effects if after bleeding agent is added;
(6) the present invention is high speed homogenizing after oil phase mixes with the aqueous phase that emulsifier, thickener, stabilizing agent, antifreeze etc. form with BBIT, and be finally deployed into BBIT aqueous emulsion, the method technique is simple, is beneficial to suitability for industrialized production.
Embodiment
Below in conjunction with specific embodiment, BBIT aqueous emulsion of the present invention is described in further detail.Should be understood that following examples only for illustration of the present invention but not for limiting scope of the present invention.
The concentration used in following examples, as not dated especially, is mass percent concentration.
Embodiment 1:10%BBIT aqueous emulsion
The formula of the 10%BBIT aqueous emulsion of the present embodiment is in table 1.
The formula of table 110%BBIT aqueous emulsion
The preparation method of 10%BBIT aqueous emulsion: (1) adds the former medicine of BBIT, polyoxyethylene carboxylate, polyphosphazene polymer phosphoric acid ester/salt and glycerin polyoxyethylene ether fatty ester, forms oil phase; (2) add cellulose ether, aluminium-magnesium silicate, white carbon and appropriate amount of deionized water, form aqueous phase; (3) being joined by the oil phase of step (1) in the aqueous phase of step (2) and to open high speed shear emulsification, shear rate controls at 3000 revs/min; (4) add ethylene glycol, then add deionized water to 100ml, stir, mixing time 100 minutes.
Embodiment 2:15%BBIT aqueous emulsion
The formula of the 15%BBIT aqueous emulsion of the present embodiment is in table 2.
The formula of table 215%BBIT aqueous emulsion
The preparation method of 15%BBIT aqueous emulsion: (1) adds the former medicine of BBIT and dodecyl benzene sulfonate, forms oil phase; (2) add xanthans, lower alcohol and appropriate amount of deionized water, form aqueous phase; (3) being joined by the oil phase of step (1) in the aqueous phase of step (2) and to open high speed shear emulsification, shear rate controls at 3000 revs/min; (4) add isopropyl alcohol, then add deionized water to 100ml, stir, mixing time 100 minutes.
Embodiment 3:20%BBIT aqueous emulsion
The formula of the 20%BBIT aqueous emulsion of the present embodiment is in table 3.
The formula of table 320%BBIT aqueous emulsion
The preparation method of 20%BBIT aqueous emulsion: (1) adds the former medicine of BBIT, alkyl polyoxyethylene ether phosphoric acid ester, Castor Oil Phosphate Ester Salt, polyoxyethylene polyoxypropylene block polyether formation oil phase; (2) add xanthans and appropriate amount of deionized water, form aqueous phase; (3) being joined by the oil phase of step (1) in the aqueous phase of step (2) and to open high speed shear emulsification, shear rate controls at 3000 revs/min; (4) add propane diols and penetrating agent JFC, then add deionized water to 100ml, stir, mixing time 100 minutes.
Embodiment 4:30%BBIT aqueous emulsion
The formula of the 30%BBIT aqueous emulsion of the present embodiment is in table 4.
The formula of table 430%BBIT aqueous emulsion
The preparation method of 30%BBIT aqueous emulsion: (1) adds the former medicine of BBIT, fatty acid and ethylene oxide mixture, polyethylene glycol hard fatty acid ester, castor oil/rilanit special and ethylene oxide mixture and forms oil phase; (2) add gelatin, gum Arabic, silicone defoaming agent and appropriate amount of deionized water, form aqueous phase; (3) being joined by the oil phase of step (1) in the aqueous phase of step (2) and to open high speed shear emulsification, shear rate controls at 3000 revs/min; (4) add glycerine, bleeding agent OE-35, isopropyl alcohol, then add deionized water to 100ml, stir, mixing time 100 minutes.
Embodiment 5:35%BBIT aqueous emulsion
The Formulations Formula of the 35%BBIT aqueous emulsion of the present embodiment is in table 5.
The Formulations Formula of table 535%BBIT aqueous emulsion
The preparation method of 35%BBIT aqueous emulsion: (1) adds the former medicine of BBIT, castor oil polyoxyethylene base ether, fatty alcohol-polyoxyethylene ether phosphoric acid ester and salt thereof and forms oil phase; (2) add bentonite, dextrin, polyvinylpyrrolidone PVP and silicone defoaming agent and appropriate amount of deionized water, form aqueous phase; (3) being joined by the oil phase of step (1) in the aqueous phase of step (2) and to open high speed shear emulsification, shear rate controls at 3000 revs/min; (4) add urea, polyethylene glycol, propane diols, aerosol-OT salt and fatty alcohol polyoxyalkyl ether, then add deionized water to 100ml, stir, mixing time 100 minutes.
Embodiment 6:40%BBIT aqueous emulsion
The formula of the 40%BBIT aqueous emulsion of the present embodiment is in table 6.
The formula of table 640%BBIT aqueous emulsion
The preparation method of 40%BBIT aqueous emulsion: (1) adds the former medicine of BBIT, aliphatic acid polyethenoxy ether phosphoric acid ester, aliphatic alcohol polyethenoxy base ether, polyoxyethylene sorbitan fatty acid ester, forms oil phase; (2) add cellulose ether and derivative, polyvinyl alcohol, aluminium-magnesium silicate, lower alcohol defoamer and appropriate amount of deionized water, form aqueous phase; (3) being joined by the oil phase of step (1) in the aqueous phase of step (2) and to open high speed shear emulsification, shear rate controls at 3000 revs/min; (4) add glycerine, polyethylene glycol, aerosol-OT salt, fatty alcohol polyoxyalkyl ether, fatty alcohol and ethylene oxide mixture, then add deionized water to 100ml, stir, mixing time 100 minutes.
The product performance index of above six embodiments is in table 7:
The conventional performance index of table 7BBIT aqueous emulsion
Embodiment 7 thermal storage stability is tested
BBIT aqueous emulsion is stored 14d in (54 ± 2) DEG C insulating box, and before and after storage, use the content of efficient liquid phase chromatographic analysis active ingredient respectively, analytical error is ± 1%, the results are shown in Table 8.Visible BBIT aqueous emulsion thermal storage stability is good.
Table 8BBIT aqueous emulsion thermal storage stability result
Embodiment 8 antimold activity measures
The present embodiment for experimental subjects, tests the minimum inhibitory concentration of 10%BBIT, 20%BBIT, 30%BBIT aqueous emulsion and 10%BBIT, 20%BBIT, 30%BBIT solvent-borne type (commercially available) with aspergillus niger, paecilomyces varioti, penicillium funiculosum, Escherichia coli, staphylococcus aureus etc. respectively.
Test method is as follows:
1, the preparation of variable concentrations sample:
Accurately measure 10%BBIT, 20%BBIT, 30%BBIT aqueous emulsion and 10%BBIT, 20%BBIT, 30%BBIT solvent-borne type, adopting methyl alcohol to be mixed with volumetric concentration as solvent is respectively 0.5% (10%BBIT, 20%BBIT, 30%BBIT aqueous emulsion), 0.5% (solvent-borne type 10%BBIT, 20%BBIT, 30%BBIT), and then dilute successively with methyl alcohol using them as starting soln, thus obtain the sample solution of a series of variable concentrations.
The making of the agar plate 2, containing variable concentrations sample:
First draw 1 ml sample solution, be placed in the culture dish of having sterilized, then the medium of about 50 DEG C is cooled to after adding 19mL sterilization, medium and sample solution are fully mixed, leave standstill cooling (period methyl alcohol volatilization totally), simultaneously not contain the medium of sample solution as blank.
3, the inoculation of bacterium is tested:
Containing the fungi flat board of variable concentrations sample connecting fungi test bacterium, putting into 28 DEG C of incubators and cultivating after 4 ~ 5 days, taking out and observe.
Containing the Bacterial Plate of variable concentrations sample connecting bacterium test bacterium, putting into 37 DEG C of incubators and cultivating after 2 ~ 3 days, taking out and observe.
4, the determination of minimum inhibitory concentration:
The test bacterium observed on the flat board of some sample concentrations does not grow, and the test bacterium energy normal growth on the flat board of adjacent low concentration sample, then this concentration is the minimum inhibitory concentration of this sample to this test bacterium.10%BBIT, 20%BBIT, 30%BBIT aqueous emulsion and the minimum inhibitory concentration (MIC) of 10%BBIT, 20%BBIT, 30%BBIT solvent-borne type to experimental bacteria as shown in table 8.
Table 9 minimum inhibitory concentration (MIC)
Note: above bacterial strain is experimental strain.
As shown in Table 9,10%BBIT, 20%BBIT, 30%BBIT aqueous emulsion is substantially consistent to the minimum inhibitory concentration of above-mentioned test strain with 10%BBIT, 20%BBIT, 30%BBIT solvent-borne type respectively.
Claims (10)
1. a BBIT aqueous emulsion, is characterized in that, comprises the formula of following mass percent:
2. BBIT aqueous emulsion as claimed in claim 1, it is characterized in that, described BBIT aqueous emulsion also comprises bleeding agent or defoamer.
3. BBIT aqueous emulsion as claimed in claim 1, it is characterized in that, described emulsifier is dodecyl benzene sulfonate or castor oil/rilanit special and ethylene oxide mixture, castor oil polyoxyethylene base ether, glycerin polyoxyethylene ether fatty ester, aliphatic alcohol polyethenoxy base ether, aliphatic acid polyethenoxy ether phosphoric acid ester, fatty acid and ethylene oxide mixture, polyoxyethylene carboxylate, polyoxyethylene polyoxypropylene block polyether, polyoxyethylene sorbitan fatty acid ester, polyethylene glycol hard fatty acid ester, Castor Oil Phosphate Ester Salt, alkyl polyoxyethylene ether phosphoric acid ester, polyphosphazene polymer phosphoric acid ester/salt, at least one in fatty alcohol-polyoxyethylene ether phosphoric acid ester and salt thereof.
4. BBIT aqueous emulsion as claimed in claim 1, it is characterized in that, described thickener is at least one in xanthans or cellulose ether and derivative thereof, polyvinyl alcohol, aluminium-magnesium silicate, gelatin, gum Arabic, bentonite, dextrin, polyvinylpyrrolidone PVP, white carbon.
5. BBIT aqueous emulsion as claimed in claim 4, is characterized in that, described thickener is at least one in xanthans or cellulose ether and derivative thereof.
6. BBIT aqueous emulsion according to claim 1, is characterized in that, described antifreeze is at least one in ethylene glycol or propane diols, glycerine, polyethylene glycol, isopropyl alcohol, urea.
7. BBIT aqueous emulsion as claimed in claim 6, it is characterized in that, described antifreeze is propane diols.
8. BBIT aqueous emulsion as claimed in claim 2, it is characterized in that, described bleeding agent is at least one in organosilicon or aerosol-OT salt, fatty alcohol polyoxyalkyl ether, fatty alcohol-polyoxyethylene ether, fatty alcohol and ethylene oxide mixture, and described defoamer is the one in silicone based defoamer or lower alcohol system defoamer.
9. a preparation method for the BBIT aqueous emulsion as described in any one of claim 1-8, is characterized in that, the method is carried out according to the following steps:
(1) in the BBIT of 10g ~ 40g, add the emulsifier of 1g ~ 10g, form oil phase;
(2) thickener of 0.1 ~ 3g is joined in appropriate amount of deionized water, stir and form aqueous phase;
(3) oil phase that step (1) prepares to be joined in the aqueous phase that step (2) configures and to open high speed shear emulsification, forming stable O/W emulsion;
(4) after opening stirring, then add the antifreeze of 1 ~ 5g, add deionized water to 100ml, stir, be i.e. obtained BBIT aqueous emulsion.
10. the preparation method of BBIT aqueous emulsion as claimed in claim 9, is characterized in that, in step (2), add defoamer, in step (4), add bleeding agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510594745.XA CN105165846A (en) | 2015-09-17 | 2015-09-17 | BBIT water emulsion and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510594745.XA CN105165846A (en) | 2015-09-17 | 2015-09-17 | BBIT water emulsion and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105165846A true CN105165846A (en) | 2015-12-23 |
Family
ID=54888720
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510594745.XA Pending CN105165846A (en) | 2015-09-17 | 2015-09-17 | BBIT water emulsion and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105165846A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106614550A (en) * | 2016-12-28 | 2017-05-10 | 江苏钟山化工有限公司 | Additive used for producing pesticide emulsion in water and preparation and application thereof |
| CN110280051A (en) * | 2019-07-09 | 2019-09-27 | 四川省蜀爱新材料有限公司 | A kind of low silicon defoaming agent |
| CN110651784A (en) * | 2018-06-28 | 2020-01-07 | 江苏龙灯化学有限公司 | Preparation method of pesticide emulsion in water, emulsion in water prepared based on method and application of emulsion in water |
| CN110651782A (en) * | 2018-06-28 | 2020-01-07 | 江苏龙灯化学有限公司 | Pesticide aqueous emulsion and preparation method and application thereof |
| WO2021063250A1 (en) * | 2019-09-30 | 2021-04-08 | 佛山市舒洁环保科技有限公司 | Environmentally friendly pesticide emulsifier |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101528043A (en) * | 2006-09-08 | 2009-09-09 | 奥麒木材保护有限公司 | Isothiazolin-3-one-containing antimicrobial composition |
| CN102057898A (en) * | 2009-11-17 | 2011-05-18 | 联合国南通农药剂型开发中心 | Diazinon emulsion in water (EW) and preparation method thereof |
| CN102187864A (en) * | 2010-11-19 | 2011-09-21 | 南通联农农药制剂研究开发有限公司 | Pretilachlor aqueous emulsion and preparation method thereof |
| CN102771488A (en) * | 2012-07-31 | 2012-11-14 | 陕西上格之路生物科学有限公司 | Bactericidal composition containing isothiazolone |
| CN102986669A (en) * | 2012-12-31 | 2013-03-27 | 大连百傲化学股份有限公司 | Stable bactericide composition |
| CN103317566A (en) * | 2013-06-28 | 2013-09-25 | 北京林业大学 | Micro-emulsion-type wood and bamboo mould-proof agent, as well as preparation method and application thereof |
| JP2014019669A (en) * | 2012-07-19 | 2014-02-03 | Sumika Enviro-Science Co Ltd | Antimicrobial composition for aqueous composition containing reductant |
-
2015
- 2015-09-17 CN CN201510594745.XA patent/CN105165846A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101528043A (en) * | 2006-09-08 | 2009-09-09 | 奥麒木材保护有限公司 | Isothiazolin-3-one-containing antimicrobial composition |
| CN102057898A (en) * | 2009-11-17 | 2011-05-18 | 联合国南通农药剂型开发中心 | Diazinon emulsion in water (EW) and preparation method thereof |
| CN102187864A (en) * | 2010-11-19 | 2011-09-21 | 南通联农农药制剂研究开发有限公司 | Pretilachlor aqueous emulsion and preparation method thereof |
| JP2014019669A (en) * | 2012-07-19 | 2014-02-03 | Sumika Enviro-Science Co Ltd | Antimicrobial composition for aqueous composition containing reductant |
| CN102771488A (en) * | 2012-07-31 | 2012-11-14 | 陕西上格之路生物科学有限公司 | Bactericidal composition containing isothiazolone |
| CN102986669A (en) * | 2012-12-31 | 2013-03-27 | 大连百傲化学股份有限公司 | Stable bactericide composition |
| CN103317566A (en) * | 2013-06-28 | 2013-09-25 | 北京林业大学 | Micro-emulsion-type wood and bamboo mould-proof agent, as well as preparation method and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 方永勤 等: "N-甲基-1,2-苯并异噻唑啉-3-酮的合成研究", 《化学世界》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106614550A (en) * | 2016-12-28 | 2017-05-10 | 江苏钟山化工有限公司 | Additive used for producing pesticide emulsion in water and preparation and application thereof |
| CN110651784A (en) * | 2018-06-28 | 2020-01-07 | 江苏龙灯化学有限公司 | Preparation method of pesticide emulsion in water, emulsion in water prepared based on method and application of emulsion in water |
| CN110651782A (en) * | 2018-06-28 | 2020-01-07 | 江苏龙灯化学有限公司 | Pesticide aqueous emulsion and preparation method and application thereof |
| CN110280051A (en) * | 2019-07-09 | 2019-09-27 | 四川省蜀爱新材料有限公司 | A kind of low silicon defoaming agent |
| CN110280051B (en) * | 2019-07-09 | 2021-07-09 | 四川省蜀爱新材料有限公司 | Low-silicon defoaming agent |
| WO2021063250A1 (en) * | 2019-09-30 | 2021-04-08 | 佛山市舒洁环保科技有限公司 | Environmentally friendly pesticide emulsifier |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105165846A (en) | BBIT water emulsion and preparation method thereof | |
| CN106614584B (en) | A kind of compound peroxycarboxylic acid thimerosal and preparation method thereof | |
| CN101002559B (en) | Aqueous emulsion containing abamectin, and its preparing method | |
| CN105010314A (en) | Pesticide diluent and preparation method and applications thereof | |
| CN103518713B (en) | Synergist used in 5% avermectin emulsion in water | |
| CN111226996B (en) | Spraying auxiliary agent and application thereof | |
| CN103317566A (en) | Micro-emulsion-type wood and bamboo mould-proof agent, as well as preparation method and application thereof | |
| JP2009138028A (en) | Catechin-containing antioxidation and preservability improvement formulation excellent in storage stability and method for producing the same | |
| CN105557717A (en) | Florasulam suspension agent and preparation method thereof | |
| CN101002566A (en) | High performance aqueous emulsion of cypermethrin, and its preparing method | |
| CN104689771A (en) | Preparation method of oxyresveratrol microcapsules and products thereof | |
| JPWO2012086617A1 (en) | Stabilized liquid aqueous crop protection agent composition | |
| CN112340696B (en) | Hydrogen-rich antioxidant based on eutectic solvent, preparation method and application | |
| CN105145619B (en) | A kind of aqueous emulsion of synthetic pyrethroid insecticide and preparation method thereof | |
| CN102187864A (en) | Pretilachlor aqueous emulsion and preparation method thereof | |
| CN103583528B (en) | A kind of sterilized water suspending agent containing beta-schardinger dextrin-and preparation method thereof | |
| CN110583687A (en) | Glyphosate and triclopyr soluble solution | |
| CN113303333B (en) | Microemulsion herbicide of diquat and efficient haloxyfop and preparation method thereof | |
| CN101647436A (en) | Trifloxystrobin microemulsion and manufacturing method thereof | |
| CN102077836A (en) | Water-based liquid preparation for repelling mosquitoes after being electrically heated | |
| CN105432606A (en) | Composition containing benziothiazolinone and preparing method thereof | |
| CN113667113A (en) | Method for realizing slow release of spice by using waste oil | |
| CN105685025B (en) | For the auxiliary agent and preparation method of emamectin benzoate water baseization and application | |
| CN111925971A (en) | Environment-responsive bacillus emulsion and preparation method thereof | |
| CN101743953A (en) | Cyromazine suspending agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151223 |
|
| RJ01 | Rejection of invention patent application after publication |