CN106590777A - Methanol gasoline and preparation method thereof - Google Patents

Methanol gasoline and preparation method thereof Download PDF

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Publication number
CN106590777A
CN106590777A CN201611188601.5A CN201611188601A CN106590777A CN 106590777 A CN106590777 A CN 106590777A CN 201611188601 A CN201611188601 A CN 201611188601A CN 106590777 A CN106590777 A CN 106590777A
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CN
China
Prior art keywords
parts
methanol
mtbe
ether
methanol gasoline
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201611188601.5A
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Chinese (zh)
Inventor
贺艺
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Qinzhou Xinghuo Planning Office
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Qinzhou Xinghuo Planning Office
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Priority to CN201611188601.5A priority Critical patent/CN106590777A/en
Publication of CN106590777A publication Critical patent/CN106590777A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/04Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1608Well defined compounds, e.g. hexane, benzene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/185Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852Ethers; Acetals; Ketals; Orthoesters

Abstract

The invention discloses methanol gasoline and a preparation method thereof. The methanol gasoline is prepared from formula components in parts by mass as follows: 3-5 parts of light aromatics, 60-80 parts of base oil, 6-8 parts of methanol, 5-7 parts of MTBE, 10-12 parts of a solubilizer, 2-4 parts of a heat value improver, 4-8 parts of MTBE (methyl tertiary butyl ether), 4-6 parts of ethylene glycol monobutyl ether, 3-5 parts of dimethyl ether, 4-6 parts of desulfurized heavy alkyl, 6-8 parts of naphtha, and 5-15 parts of n-hexane. Consumption of petroleum resources is reduced, and atmosphere pollution by fuel is reduced; the methanol gasoline is not layered at low temperature, does not produce gas resistance and is good in low-temperature starting performance and water resistance. The preparation technology is simple, a synthesis reaction is rapid, the whole process only needs 30 min, industrial production equipment is simple, and implementation and popularization are facilitated greatly.

Description

A kind of methanol gasoline and preparation method thereof
Technical field
The present invention relates to gasoline field, in particular to a kind of methanol gasoline and preparation method thereof.
Background technology
Since nineteen seventies, methanol fuel for vehicles technology has at home and abroad started constantly research and development, has promoted, its Economy, the feature of environmental protection, cleaning have obtained the extensive approval of domestic and international derived energy chemical industry the advantages of renewable.Methanol fuel for vehicles Popularization and application, China's oil resource anxiety situation not only can be alleviated, and can effectively reduce the pollutant such as carbon dioxide Discharge, meet the fundamental state policy of China's energy-saving and emission-reduction.
The Chinese patent of Application No. 200610127695.5 discloses a kind of alcohol ether gasoline and its formula.The alcohol ether gasoline It is made up of methanol, gasoline, Petroleum, isobutanol, petrobenzene, petroleum ether and additive, its additive is by zinc peroxide, carbonic acid Dimethyl ester, vat yellow, DBPC 2,6 ditertiary butyl p cresol and nitric acid isooctyl are mixed by a certain percentage.
The content of the invention
The invention provides a kind of methanol gasoline and preparation method thereof, the consumption of present invention reduction petroleum resources, reduce The pollution that fuel oil brings to air;Its low temperature is not stratified, does not produce vapour lock, and low-temperature startup performance is good, and water-resistance is good.Its preparation Process is simple, synthetic reaction is rapid, and whole process is only needed 30 minutes, and industrialized production equipment is simple, is very beneficial for enforcement and pushes away Extensively.
For achieving the above object, the present invention provides following technical scheme:
A kind of methanol gasoline and preparation method thereof, is made up of following mass fraction formula components:Light aromatic hydrocarbons 3-5 part, basis Oily 60-80 parts, methanol 6-8 parts, MTBE 5-7 parts, cosolvent 10-12 parts, calorific value modifier 2-4 part, methyl tertiary butyl ether(MTBE) 4-8 Part, ethylene glycol monobutyl ether 4-6 parts, dimethyl ether 3-5 parts, desulfurization weight alkane 4-6 parts, Petroleum 6-8 parts, normal hexane 5-15 parts.
Further:It is made up of following mass fraction formula components:3 parts of light aromatic hydrocarbons, 60 parts of base oil, 6 parts of methanol, MTBE 5 Part, 10 parts of cosolvent, 2 parts of calorific value modifier, 4 parts of methyl tertiary butyl ether(MTBE), 4 parts of ethylene glycol monobutyl ether, 3 parts of dimethyl ether, desulfurization weight 4 parts of alkane, 6 parts of Petroleum, 5 parts of normal hexane.
Further:It is made up of following mass fraction formula components:4 parts of light aromatic hydrocarbons, 70 parts of base oil, 7 parts of methanol, MTBE 6 Part, 11 parts of cosolvent, 3 parts of calorific value modifier, 6 parts of methyl tertiary butyl ether(MTBE), 5 parts of ethylene glycol monobutyl ether, 4 parts of dimethyl ether, desulfurization weight 5 parts of alkane, 7 parts of Petroleum, 10 parts of normal hexane.
Further:It is made up of following mass fraction formula components:5 parts of light aromatic hydrocarbons, 80 parts of base oil, 8 parts of methanol, MTBE 7 Part, 12 parts of cosolvent, 4 parts of calorific value modifier, 8 parts of methyl tertiary butyl ether(MTBE), 6 parts of ethylene glycol monobutyl ether, 5 parts of dimethyl ether, desulfurization weight 6 parts of alkane, 8 parts of Petroleum, 15 parts of normal hexane.
Further:Preparation method comprises the steps:
Step one, by above-mentioned raw materials according to mass fraction proportioning, it is standby;
Step 2, by light aromatic hydrocarbons, base oil, methanol, MTBE, methyl tertiary butyl ether(MTBE), ethylene glycol monobutyl ether, dimethyl ether, de- Sulfur weight alkane, Petroleum, normal hexane, are squeezed into above-mentioned raw materials in blending tank using explosion-proof centrifugal pump, are stirred 30 minutes, and static 1 is little When;
Step 3, cosolvent and calorific value modifier mix homogeneously is added to get product methanol gasoline step 2 gained.
The invention has the beneficial effects as follows:
1st, the present invention reduces the consumption of petroleum resources, reduces the pollution that fuel oil brings to air;
2nd, its low temperature is not stratified, does not produce vapour lock, and low-temperature startup performance is good, and water-resistance is good;
3rd, its preparation process is simple, synthetic reaction is rapid, and whole process is only needed 30 minutes, and industrialized production equipment is simple, It is very beneficial for practice and extension.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all Belong to the scope of protection of the invention.
Embodiment one:
A kind of methanol gasoline is made up of following mass fraction formula components:Light aromatic hydrocarbons 3-5 part, base oil 60-80 parts, methanol 6-8 parts, MTBE 5-7 parts, cosolvent 10-12 parts, calorific value modifier 2-4 part, methyl tertiary butyl ether(MTBE) 4-8 parts, ethylene glycol monobutyl ether 4-6 parts, dimethyl ether 3-5 parts, desulfurization weight alkane 4-6 parts, Petroleum 6-8 parts, normal hexane 5-15 parts.
Embodiment two:
A kind of methanol gasoline is made up of following mass fraction formula components:3 parts of light aromatic hydrocarbons, 60 parts of base oil, 6 parts of methanol, 5 parts of MTBE, 10 parts of cosolvent, 2 parts of calorific value modifier, 4 parts of methyl tertiary butyl ether(MTBE), 4 parts of ethylene glycol monobutyl ether, 3 parts of dimethyl ether, 4 parts of desulfurization weight alkane, 6 parts of Petroleum, 5 parts of normal hexane.
Embodiment three:
A kind of methanol gasoline is made up of following mass fraction formula components:4 parts of light aromatic hydrocarbons, 70 parts of base oil, 7 parts of methanol, 6 parts of MTBE, 11 parts of cosolvent, 3 parts of calorific value modifier, 6 parts of methyl tertiary butyl ether(MTBE), 5 parts of ethylene glycol monobutyl ether, 4 parts of dimethyl ether, 5 parts of desulfurization weight alkane, 7 parts of Petroleum, 10 parts of normal hexane.
Example IV:
A kind of methanol gasoline is made up of following mass fraction formula components:5 parts of light aromatic hydrocarbons, 80 parts of base oil, 8 parts of methanol, 7 parts of MTBE, 12 parts of cosolvent, 4 parts of calorific value modifier, 8 parts of methyl tertiary butyl ether(MTBE), 6 parts of ethylene glycol monobutyl ether, 5 parts of dimethyl ether, 6 parts of desulfurization weight alkane, 8 parts of Petroleum, 15 parts of normal hexane.
Embodiment five:
A kind of preparation method of methanol gasoline comprises the steps:
Step one, by above-mentioned raw materials according to mass fraction proportioning, it is standby;
Step 2, by light aromatic hydrocarbons, base oil, methanol, MTBE, methyl tertiary butyl ether(MTBE), ethylene glycol monobutyl ether, dimethyl ether, de- Sulfur weight alkane, Petroleum, normal hexane, are squeezed into above-mentioned raw materials in blending tank using explosion-proof centrifugal pump, are stirred 30 minutes, and static 1 is little When;
Step 3, cosolvent and calorific value modifier mix homogeneously is added to get product methanol gasoline step 2 gained.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of description is only that for clarity those skilled in the art should Using description as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art Understandable other embodiment.

Claims (5)

1. a kind of methanol gasoline, it is characterised in that:It is made up of following mass fraction formula components:
Light aromatic hydrocarbons 3-5 part, base oil 60-80 parts, methanol 6-8 parts, MTBE 5-7 parts, cosolvent 10-12 parts, calorific value modifier 2- 4 parts, methyl tertiary butyl ether(MTBE) 4-8 parts, ethylene glycol monobutyl ether 4-6 parts, dimethyl ether 3-5 parts, desulfurization weight alkane 4-6 parts, Petroleum 6-8 Part, normal hexane 5-15 parts.
2. a kind of methanol gasoline according to claim 1, it is characterised in that:It is made up of following mass fraction formula components:
3 parts of light aromatic hydrocarbons, 60 parts of base oil, 6 parts of methanol, 5 parts of MTBE, 10 parts of cosolvent, 2 parts of calorific value modifier, methyl tertbutyl 4 parts of ether, 4 parts of ethylene glycol monobutyl ether, 3 parts of dimethyl ether, 4 parts of desulfurization weight alkane, 6 parts of Petroleum, 5 parts of normal hexane.
3. a kind of methanol gasoline according to claim 1, it is characterised in that:It is made up of following mass fraction formula components:
4 parts of light aromatic hydrocarbons, 70 parts of base oil, 7 parts of methanol, 6 parts of MTBE, 11 parts of cosolvent, 3 parts of calorific value modifier, methyl tertbutyl 6 parts of ether, 5 parts of ethylene glycol monobutyl ether, 4 parts of dimethyl ether, 5 parts of desulfurization weight alkane, 7 parts of Petroleum, 10 parts of normal hexane.
4. a kind of methanol gasoline according to claim 1, it is characterised in that:It is made up of following mass fraction formula components:
5 parts of light aromatic hydrocarbons, 80 parts of base oil, 8 parts of methanol, 7 parts of MTBE, 12 parts of cosolvent, 4 parts of calorific value modifier, methyl tertbutyl 8 parts of ether, 6 parts of ethylene glycol monobutyl ether, 5 parts of dimethyl ether, 6 parts of desulfurization weight alkane, 8 parts of Petroleum, 15 parts of normal hexane.
5. a kind of a kind of preparation method of methanol gasoline according to claim 1, it is characterised in that:Comprise the steps:
Step one, by above-mentioned raw materials according to mass fraction proportioning, it is standby;
Step 2, by light aromatic hydrocarbons, base oil, methanol, MTBE, methyl tertiary butyl ether(MTBE), ethylene glycol monobutyl ether, dimethyl ether, desulfurization weight Alkane, Petroleum, normal hexane, are squeezed into above-mentioned raw materials in blending tank using explosion-proof centrifugal pump, are stirred 30 minutes, static 1 hour;
Step 3, cosolvent and calorific value modifier mix homogeneously is added to get product methanol gasoline step 2 gained.
CN201611188601.5A 2016-12-20 2016-12-20 Methanol gasoline and preparation method thereof Pending CN106590777A (en)

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Application Number Priority Date Filing Date Title
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Publication Number Publication Date
CN106590777A true CN106590777A (en) 2017-04-26

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114891543A (en) * 2022-05-17 2022-08-12 兰州国信环境能源科技有限责任公司 Method for synthesizing methanol diesel oil

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5380346A (en) * 1992-06-12 1995-01-10 Fritz; James E. Fortified hydrocarbon and process for making and using the same
CN101538491A (en) * 2009-04-16 2009-09-23 陈斌 Alcohol ether gasoline used in new energy vehicles
CN101643673A (en) * 2009-09-08 2010-02-10 郭振山 Methanol gasoline
CN102925226A (en) * 2012-09-07 2013-02-13 江苏正泰医药化工有限公司 Synthetic gasoline
CN104263425A (en) * 2014-10-17 2015-01-07 广西丰泰能源防爆科技有限公司 Methanol composite gasoline and preparation method thereof
CN104946322A (en) * 2015-06-29 2015-09-30 青岛宇星智能科技开发有限公司 Nontoxic methanol gasoline additive
CN105273775A (en) * 2014-07-17 2016-01-27 朱景传 Methanol gasoline and preparation method thereof
CN106010680A (en) * 2016-06-23 2016-10-12 谢殷泽 Vehicle fuel

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5380346A (en) * 1992-06-12 1995-01-10 Fritz; James E. Fortified hydrocarbon and process for making and using the same
CN101538491A (en) * 2009-04-16 2009-09-23 陈斌 Alcohol ether gasoline used in new energy vehicles
CN101643673A (en) * 2009-09-08 2010-02-10 郭振山 Methanol gasoline
CN102925226A (en) * 2012-09-07 2013-02-13 江苏正泰医药化工有限公司 Synthetic gasoline
CN105273775A (en) * 2014-07-17 2016-01-27 朱景传 Methanol gasoline and preparation method thereof
CN104263425A (en) * 2014-10-17 2015-01-07 广西丰泰能源防爆科技有限公司 Methanol composite gasoline and preparation method thereof
CN104946322A (en) * 2015-06-29 2015-09-30 青岛宇星智能科技开发有限公司 Nontoxic methanol gasoline additive
CN106010680A (en) * 2016-06-23 2016-10-12 谢殷泽 Vehicle fuel

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114891543A (en) * 2022-05-17 2022-08-12 兰州国信环境能源科技有限责任公司 Method for synthesizing methanol diesel oil
CN114891543B (en) * 2022-05-17 2024-03-22 兰州国信环境能源科技有限责任公司 Method for synthesizing methanol diesel oil

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