CN106590497A - Formaldehyde-free aqueous jointing agent and preparation method therefor - Google Patents
Formaldehyde-free aqueous jointing agent and preparation method therefor Download PDFInfo
- Publication number
- CN106590497A CN106590497A CN201611193520.4A CN201611193520A CN106590497A CN 106590497 A CN106590497 A CN 106590497A CN 201611193520 A CN201611193520 A CN 201611193520A CN 106590497 A CN106590497 A CN 106590497A
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- agent
- formaldehyde
- host
- free aqueous
- aqueous
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a formaldehyde-free aqueous jointing agent and a preparation method therefor. The formaldehyde-free aqueous jointing agent is prepared through mixing a main agent and a curing agent according to the mass ratio of (0.6 to 1.8): (0.8 to 1.6). According to the formaldehyde-free aqueous jointing agent, an aqueous bi-component macromolecular gluing technology is adopted, the product forms high-density reticular glue films at joints, and the glue films can be telescoped synchronous to sheet materials in case of climatic changes, so that the product has the characteristics that the sizing speed is high, the construction is easy, the sagging is difficult, the adhesive power is high, the cracking resistance is excellent, and the like. The formaldehyde-free aqueous jointing agent is applicable to the treatment on joints and easily-cracking parts of indoor and outdoor decorative materials and can play excellent roles in carrying out bonding and preventing cracking through injecting the product into gaps of the same or different materials such as wood, bricks and stones, gypsum boards, calcium silicate and cement wall faces.
Description
Technical field
The present invention relates to coating auxiliary material technical field, especially a kind of formaldehyde-free aqueous joint mixture, and preparation method thereof.
Background technology
Joint mixture is a kind of new coating product in connection ornament materials gap, with excellent crack resistance and bonding attachment
Power, pliability is good, strong covering power, corrosion-resistant, not sagging, impermeable color, easily construction.Joint mixture is applied to plasterboard, calcium silicate board with microporous, brick
The mutual bonding in the different finishing moulding material gaps such as stone, timber and metal.Existing joint mixture usually adopts oiliness epoxy
Resin is pacified as reactive diluent as host, oil-based solvent with strong pungent abnormal smells from the patient, harm human health and environment
Entirely.
The content of the invention
The present invention is directed to the deficiencies in the prior art, proposes a kind of formaldehyde-free aqueous joint mixture, cohesive force is strong, pliability is good,
Without oil-based solvent, without pungent abnormal smells from the patient, health environment-friendly.
In order to realize foregoing invention purpose, the present invention provides technical scheme below：A kind of formaldehyde-free aqueous joint mixture, by leading
Agent and firming agent in mass ratio 0.6～1.8:0.8～1.6 is mixed, and wherein host and firming agent are respectively by following weight parts
Component constitute：
Host：
Aqueous epoxy resins 15.00～40.00
Antifreezing agent 0.50～1.50
Dispersant 0.20～1.00
Wetting agent 0.10～0.50
Defoamer 0.10～0.50
Pulvis Talci 10.00～30.00
Quartz sand 5.00～15.00
Triple superphosphate 35.00～55.00
Attapulgite 0.00～1.00
Wood fibre 0.00～1.00
Deionized water 1.00～15.00；
Firming agent：
Aqueous epoxy curing agent 15.00～40.00
Antifreezing agent 0.00～1.50
Dispersant 0.20～1.00
Wetting agent 0.10～0.50
Defoamer 0.10～0.50
Pulvis Talci 20.00～40.00
Quartz sand 5.00～15.00
Triple superphosphate 25.00～35.00
Attapulgite 0.00～1.00
Wood fibre 0.00～1.00
Hydroxyethyl cellulose 0.00～0.60
Deionized water 1.00～15.00.
Further, the mass ratio 1 of host and firming agent: 1.
Further, the aqueous epoxy resins are the water-based emulsions of liquid epoxies.
Further, the aqueous epoxy curing agent is modified polyamide epoxy hardener.
A kind of preparation method of formaldehyde-free aqueous joint mixture as mentioned above, comprises the following steps：
(1), the preparation of host：Above-mentioned host each component is carried out into by weight operations described below：Aqueous epoxy resins, antifreezing agent, point
Powder, wetting agent and defoamer middling speed disperse 5-10 minutes to uniform, then add Pulvis Talci, quartz sand, triple superphosphate, attapulgite
Soil and wood fibre, high speed disperses 10-20 minutes to uniform, is finally slowly added to deionized water to adjust viscosity, stirs
；
(2), the preparation of firming agent：Above-mentioned firming agent each component is carried out into by weight operations described below：It is aqueous epoxy curing agent, anti-
Freezing agent, dispersant, wetting agent and defoamer middling speed disperses 5-10 minutes to uniform, then adds Pulvis Talci, quartz sand, weight
Calcium, attapulgite and wood fibre, high speed disperses 10-20 minutes to uniform, is finally slowly added to hydroxyethyl cellulose and goes
Ionized water stirs adjusting viscosity；
(3), by step (1) obtained host and step (2) obtained firming agent, mix in mass ratio, it is uniform after be formaldehydeless water
Property joint mixture.
Compared with prior art, the present invention has advantages below：Using aqueous dual-component macromolecule bonding technique, product exists
Seam crossing forms the netted glued membrane of high density, when climate change can with sheet material synchronization telescope, with sizing it is fast, easily construction,
Sagging, adhesive force are not likely to produce strong, the features such as crack resistence excellent performance.Suitable for interior/exterior decoration material joints and easy to crack
Position is processed, and this product is injected into the seam of the identical or different material such as timber, masonry, plasterboard, calcium silicates and cement wall surface
In gap, fabulous bonding anti-crack function can be played.Have the advantage that：
1st, aqueouss, without oil-based solvent, without pungent abnormal smells from the patient, formaldehydeless, health environment-friendly.
2nd, shape and soon, easily construct, be not likely to produce sagging, crack resistence excellent performance.
3rd, rough surface, easily polishing, adhesive force is strong.
Specific embodiment
Describe the present invention with reference to embodiment, the description of this part be only it is exemplary and explanatory, no
Reply protection scope of the present invention has any restriction effect.
A kind of formaldehyde-free aqueous joint mixture, it is characterised in that：By host and firming agent in mass ratio 0.6～1.8:0.8～
1.6 are mixed, and wherein host and firming agent are made up of respectively following components in parts by weight：
Host：
Aqueous epoxy resins 15.00～40.00
Antifreezing agent 0.50～1.50
Dispersant 0.20～1.00
Wetting agent 0.10～0.50
Defoamer 0.10～0.50
Pulvis Talci 10.00～30.00
Quartz sand 5.00～15.00
Triple superphosphate 35.00～55.00
Attapulgite 0.00～1.00
Wood fibre 0.00～1.00
Deionized water 1.00～15.00；
Firming agent：
Aqueous epoxy curing agent 15.00～40.00
Antifreezing agent 0.00～1.50
Dispersant 0.20～1.00
Wetting agent 0.10～0.50
Defoamer 0.10～0.50
Pulvis Talci 20.00～40.00
Quartz sand 5.00～15.00
Triple superphosphate 25.00～35.00
Attapulgite 0.00～1.00
Wood fibre 0.00～1.00
Hydroxyethyl cellulose 0.00～0.60
Deionized water 1.00～15.00.
Raw material in above-mentioned host and firming agent is having on the market sale.Wherein, aqueous epoxy resins are Breakup of Liquid Ring
The water-based emulsion of oxygen tree fat, aqueous epoxy curing agent is modified polyamide epoxy hardener.
The preparation method of above-mentioned formaldehyde-free aqueous joint mixture, comprises the following steps：
The making of host：By in the aqueous epoxy resins of above-mentioned host weight portion, antifreezing agent, dispersant, wetting agent and defoamer
Speed dispersion 5-10 minutes to uniform, then add the Pulvis Talci of above-mentioned host weight portion, quartz sand, triple superphosphate, attapulgite and
Wood fibre, high speed disperses 10-20 minutes to uniform, and the deionized water for being finally slowly added to above-mentioned host weight portion is viscous to adjust
Degree, stirs.
The making of firming agent：By aqueous epoxy curing agent, antifreezing agent, dispersant, the wetting agent of above-mentioned firming agent weight portion
Disperse 5-10 minutes to uniform with defoamer middling speed, then add Pulvis Talci, quartz sand, the weight of above-mentioned firming agent weight portion
Calcium, attapulgite and wood fibre, high speed disperses 10-20 minutes to uniform, is finally slowly added to above-mentioned firming agent weight portion
Hydroxyethyl cellulose and deionized water adjusting viscosity, stir.
Then quality proportioning is pressed again, will form formaldehyde-free aqueous joint mixture after host and firming agent mix homogeneously.
Embodiment 1
A kind of formaldehyde-free aqueous joint mixture, is mixed by host and firming agent, including：
Host, is made up of following components in parts by weight：
Aqueous epoxy resins 17.50
Antifreezing agent 1.00
Dispersant 0.50
Wetting agent 0.30
Defoamer 0.20
Pulvis Talci 20.00
Quartz sand 10.00
Triple superphosphate 43.00
Attapulgite 0.80
Wood fibre 0.70
Deionized water 6.00
Firming agent, is made up of following components in parts by weight：
Aqueous epoxy curing agent 16.00
Antifreezing agent 0.50
Dispersant 0.30
Wetting agent 0.30
Defoamer 0.20
Pulvis Talci 25.00
Quartz sand 12.00
Triple superphosphate 33.00
Attapulgite 0.80
Wood fibre 0.70
Hydroxyethyl cellulose 0.40
Deionized water 10.80
The mixed proportion of above-mentioned host and firming agent is：Host：Firming agent=1:1.
In the present embodiment, a kind of above-mentioned preparation method of formaldehyde-free aqueous joint mixture is comprised the following steps：
Host：The aqueous epoxy resins of above-mentioned host weight portion, antifreezing agent, dispersant, wetting agent and defoamer middling speed are disperseed into 5
Minute, to uniform, then adds Pulvis Talci, quartz sand, triple superphosphate, attapulgite and the wood fibre of above-mentioned host weight portion, in
At a high speed dispersion 20 minutes is to uniform, is finally slowly added to the deionized water of above-mentioned host weight portion to adjust viscosity, stirs i.e.
Can.
Firming agent：By the aqueous epoxy curing agent of above-mentioned firming agent weight portion, antifreezing agent, dispersant, wetting agent and froth breaking
Agent middling speed disperses 5 minutes to uniform, then adds Pulvis Talci, quartz sand, triple superphosphate, the attapulgite of above-mentioned firming agent weight portion
And wood fibre, high speed disperse 20 minutes to uniform, be finally slowly added to the hydroxyethyl cellulose of above-mentioned firming agent weight portion
Viscosity is adjusted with deionized water, is stirred.
Then 1 is pressed again:1 proportioning, will form formaldehyde-free aqueous joint mixture after host and firming agent mix homogeneously.
Embodiment 2
A kind of formaldehyde-free aqueous joint mixture, is mixed by host and firming agent, including：
Host, is made up of following components in parts by weight：
Aqueous epoxy resins 22.00
Antifreezing agent 1.20
Dispersant 0.60
Wetting agent 0.40
Defoamer 0.40
Pulvis Talci 12.00
Quartz sand 10.00
Triple superphosphate 41.00
Attapulgite 0.80
Wood fibre 0.70
Deionized water 10.90
Firming agent, is made up of following components in parts by weight：
Aqueous epoxy curing agent 20.50
Antifreezing agent 0.50
Dispersant 0.60
Wetting agent 0.40
Defoamer 0.30
Pulvis Talci 25.00
Quartz sand 12.00
Triple superphosphate 26.50
Attapulgite 0.70
Wood fibre 0.60
Hydroxyethyl cellulose 0.50
Deionized water 12.40
The mixed proportion of above-mentioned host and firming agent is：Host:Firming agent=0.6:1.6.
In the present embodiment, a kind of above-mentioned preparation method of formaldehyde-free aqueous joint mixture is comprised the following steps：
Host：By the dispersion of the aqueous epoxy resins of above-mentioned host weight portion, antifreezing agent, dispersant, wetting agent and defoamer middling speed
To uniform, Pulvis Talci, quartz sand, triple superphosphate, attapulgite and the wood fibre of above-mentioned host weight portion are then added within 10 minutes,
High speed disperses 10 minutes to uniform, is finally slowly added to the deionized water of above-mentioned host weight portion to adjust viscosity, stirs
.
Firming agent：By the aqueous epoxy curing agent of above-mentioned firming agent weight portion, antifreezing agent, dispersant, wetting agent and froth breaking
Agent middling speed disperses 10 minutes to uniform, then adds Pulvis Talci, quartz sand, triple superphosphate, the attapulgite of above-mentioned firming agent weight portion
Soil and wood fibre, high speed disperses 10 minutes to uniform, is finally slowly added to the hydroxy ethyl fiber of above-mentioned firming agent weight portion
Element and deionized water stir adjusting viscosity.
Then 0.6 is pressed again:1.6 proportionings, will form formaldehyde-free aqueous joint mixture after host and firming agent mix homogeneously.
Embodiment 3
A kind of formaldehyde-free aqueous joint mixture, is mixed by host and firming agent, including：
Host, is made up of following components in parts by weight：
Aqueous epoxy resins 32.00
Antifreezing agent 1.20
Dispersant 0.60
Wetting agent 0.40
Defoamer 0.30
Pulvis Talci 11.00
Quartz sand 10.00
Triple superphosphate 40.00
Attapulgite 0.80
Wood fibre 0.70
Deionized water 3.00
Firming agent, is made up of following components in parts by weight：
Aqueous epoxy curing agent 29.50
Antifreezing agent 0.50
Dispersant 0.60
Wetting agent 0.40
Defoamer 0.30
Pulvis Talci 25.00
Quartz sand 11.00
Triple superphosphate 25.50
Attapulgite 0.70
Wood fibre 0.60
Hydroxyethyl cellulose 0.20
Deionized water 5.70
The mixed proportion of above-mentioned host and firming agent is：Host:Firming agent=1.8:0.8.
In the present embodiment, a kind of above-mentioned preparation method of formaldehyde-free aqueous joint mixture is comprised the following steps：
Host：The aqueous epoxy resins of above-mentioned host weight portion, antifreezing agent, dispersant, wetting agent and defoamer middling speed are disperseed into 8
Minute, to uniform, then adds Pulvis Talci, quartz sand, triple superphosphate, attapulgite and the wood fibre of above-mentioned host weight portion, in
At a high speed dispersion 15 minutes is to uniform, is finally slowly added to the deionized water of above-mentioned host weight portion to adjust viscosity, stirs i.e.
Can.
Firming agent：By the aqueous epoxy curing agent of above-mentioned firming agent weight portion, antifreezing agent, dispersant, wetting agent and froth breaking
Agent middling speed disperses 7 minutes to uniform, then adds Pulvis Talci, quartz sand, triple superphosphate, the attapulgite of above-mentioned firming agent weight portion
And wood fibre, high speed disperse 16 minutes to uniform, be finally slowly added to the hydroxyethyl cellulose of above-mentioned firming agent weight portion
Viscosity is adjusted with deionized water, is stirred.
Then 1.8 are pressed again:0.8 proportioning, will form formaldehyde-free aqueous joint mixture after host and firming agent mix homogeneously.
In above-mentioned specific embodiment 1 to 3, the performance measurement of the formaldehyde-free aqueous joint mixture see the table below：
The above is only the preferred embodiment of the present invention, it is noted that for those skilled in the art come
Say, under the premise without departing from the principles of the invention, can also make some improvements and modifications, these improvements and modifications also should be regarded as
Protection scope of the present invention.
Claims (5)
1. a kind of formaldehyde-free aqueous joint mixture, it is characterised in that：By host and firming agent in mass ratio 0.6～1.8:0.8～1.6
It is mixed, wherein host and firming agent are made up of respectively following components in parts by weight：
Host：
Aqueous epoxy resins 15.00～40.00
Antifreezing agent 0.50～1.50
Dispersant 0.20～1.00
Wetting agent 0.10～0.50
Defoamer 0.10～0.50
Pulvis Talci 10.00～30.00
Quartz sand 5.00～15.00
Triple superphosphate 35.00～55.00
Attapulgite 0.00～1.00
Wood fibre 0.00～1.00
Deionized water 1.00～15.00；
Firming agent：
Aqueous epoxy curing agent 15.00～40.00
Antifreezing agent 0.00～1.50
Dispersant 0.20～1.00
Wetting agent 0.10～0.50
Defoamer 0.10～0.50
Pulvis Talci 20.00～40.00
Quartz sand 5.00～15.00
Triple superphosphate 25.00～35.00
Attapulgite 0.00～1.00
Wood fibre 0.00～1.00
Hydroxyethyl cellulose 0.00～0.60
Deionized water 1.00～15.00.
2. as claimed in claim 1 formaldehyde-free aqueous joint mixture, it is characterised in that：The mass ratio 1 of host and firming agent: 1.
3. as claimed in claim 1 formaldehyde-free aqueous joint mixture, it is characterised in that：The aqueous epoxy resins are Breakup of Liquid Ring oxygen trees
The water-based emulsion of fat.
4. as claimed in claim 1 formaldehyde-free aqueous joint mixture, it is characterised in that：The aqueous epoxy curing agent is modified polyamides
Amine epoxy curing agent.
5. a kind of preparation method of formaldehyde-free aqueous joint mixture as claimed in claim 1, comprises the following steps：
(1), the preparation of host：Above-mentioned host each component is carried out into by weight operations described below：Aqueous epoxy resins, antifreezing agent, point
Powder, wetting agent and defoamer middling speed disperse 5-10 minutes to uniform, then add Pulvis Talci, quartz sand, triple superphosphate, attapulgite
Soil and wood fibre, high speed disperses 10-20 minutes to uniform, is finally slowly added to deionized water to adjust viscosity, stirs
；
(2), the preparation of firming agent：Above-mentioned firming agent each component is carried out into by weight operations described below：It is aqueous epoxy curing agent, anti-
Freezing agent, dispersant, wetting agent and defoamer middling speed disperses 5-10 minutes to uniform, then adds Pulvis Talci, quartz sand, weight
Calcium, attapulgite and wood fibre, high speed disperses 10-20 minutes to uniform, is finally slowly added to hydroxyethyl cellulose and goes
Ionized water stirs adjusting viscosity；
(3), by step (1) obtained host and step (2) obtained firming agent, mix in mass ratio, it is uniform after be formaldehydeless water
Property joint mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611193520.4A CN106590497A (en) | 2016-12-21 | 2016-12-21 | Formaldehyde-free aqueous jointing agent and preparation method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611193520.4A CN106590497A (en) | 2016-12-21 | 2016-12-21 | Formaldehyde-free aqueous jointing agent and preparation method therefor |
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| Publication Number | Publication Date |
|---|---|
| CN106590497A true CN106590497A (en) | 2017-04-26 |
Family
ID=58602514
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|---|---|---|---|
| CN201611193520.4A Pending CN106590497A (en) | 2016-12-21 | 2016-12-21 | Formaldehyde-free aqueous jointing agent and preparation method therefor |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107502262A (en) * | 2017-09-26 | 2017-12-22 | 芜湖县双宝建材有限公司 | A kind of high adhesion force construction material glue |
| CN108441125A (en) * | 2018-03-05 | 2018-08-24 | 江兵 | A kind of multi-plywood processing high strong water resistant adhesive |
| CN108504251A (en) * | 2018-04-21 | 2018-09-07 | 湖南辰砾新材料有限公司 | A kind of corrosion-resistant water base tile adhesives of high viscosity and preparation method thereof |
| CN111849363A (en) * | 2020-07-24 | 2020-10-30 | 今程粘胶(惠州)有限公司 | Formula and process of green environment-friendly epoxy resin glue |
| CN114686147A (en) * | 2022-03-10 | 2022-07-01 | 华新水泥股份有限公司 | Bi-component water-based joint material |
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| US4199484A (en) * | 1977-10-06 | 1980-04-22 | Halliburton Company | Gelled water epoxy sand consolidation system |
| GR3033707T3 (en) * | 1993-02-08 | 2000-10-31 | Hoechst Ag | Curing agents for aqueous epoxy resin dispersions. |
| CN103409090A (en) * | 2013-06-05 | 2013-11-27 | 武汉市科达云石护理材料有限公司 | Epoxy caulk compound used in humid environment |
| CN103509507A (en) * | 2013-09-23 | 2014-01-15 | 三棵树涂料股份有限公司 | Environment-friendly epoxy seaming paste and preparation method thereof |
-
2016
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4199484A (en) * | 1977-10-06 | 1980-04-22 | Halliburton Company | Gelled water epoxy sand consolidation system |
| GR3033707T3 (en) * | 1993-02-08 | 2000-10-31 | Hoechst Ag | Curing agents for aqueous epoxy resin dispersions. |
| CN103409090A (en) * | 2013-06-05 | 2013-11-27 | 武汉市科达云石护理材料有限公司 | Epoxy caulk compound used in humid environment |
| CN103509507A (en) * | 2013-09-23 | 2014-01-15 | 三棵树涂料股份有限公司 | Environment-friendly epoxy seaming paste and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107502262A (en) * | 2017-09-26 | 2017-12-22 | 芜湖县双宝建材有限公司 | A kind of high adhesion force construction material glue |
| CN108441125A (en) * | 2018-03-05 | 2018-08-24 | 江兵 | A kind of multi-plywood processing high strong water resistant adhesive |
| CN108504251A (en) * | 2018-04-21 | 2018-09-07 | 湖南辰砾新材料有限公司 | A kind of corrosion-resistant water base tile adhesives of high viscosity and preparation method thereof |
| CN111849363A (en) * | 2020-07-24 | 2020-10-30 | 今程粘胶(惠州)有限公司 | Formula and process of green environment-friendly epoxy resin glue |
| CN114686147A (en) * | 2022-03-10 | 2022-07-01 | 华新水泥股份有限公司 | Bi-component water-based joint material |
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Application publication date: 20170426 |