CN106986595A - A kind of extraordinary mortar for being used to make transparent cement product - Google Patents

A kind of extraordinary mortar for being used to make transparent cement product Download PDF

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Publication number
CN106986595A
CN106986595A CN201710294196.3A CN201710294196A CN106986595A CN 106986595 A CN106986595 A CN 106986595A CN 201710294196 A CN201710294196 A CN 201710294196A CN 106986595 A CN106986595 A CN 106986595A
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CN
China
Prior art keywords
water
mortar
transparent cement
cement product
liquid components
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710294196.3A
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Chinese (zh)
Inventor
王晓瑞
郑玉丽
高楠
张琢
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Shanghai Institute of Technology
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Shanghai Institute of Technology
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Filing date
Publication date
Application filed by Shanghai Institute of Technology filed Critical Shanghai Institute of Technology
Priority to CN201710294196.3A priority Critical patent/CN106986595A/en
Publication of CN106986595A publication Critical patent/CN106986595A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34Non-shrinking or non-cracking materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80Optical properties, e.g. transparency or reflexibility
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention provides a kind of extraordinary mortar for being used to make transparent cement product, it is made up of powder component and liquid component two parts, the parts by weight of powder component are:Binder materials 20 40, water-loss reducer 0.05 0.10, calcium sand 58 80, defoamer 0.08-0.20, water reducer 0.15-0.30, economization agent 1.0 2.0.The parts by weight of liquid components are:Aqueous epoxy resins 15 20, water 50 65, curing agent 20 30.The mixing ratio of powder component and liquid components is 1:0.2‑0.25.Present invention also offers the preparation method of above-mentioned extraordinary mortar.The present invention has fluidity good, product strength is high, the associativity of mortar and transparent plastic fiber is good, be conveniently used for template or manual method makes the advantage of transparent cement product, can be widely used for architectural decoration or indoor and outdoor transparent cement handicraft, works well.

Description

A kind of extraordinary mortar for being used to make transparent cement product
Technical field:
The invention belongs to materialogy field, it is related to a kind of mortar, specifically a kind of spy for being used to make transparent cement product Plant mortar.
Background technology:
Transparent cement is a kind of novel decorative structure material progressively risen in recent years, and this kind of material is possessing good external decoration work( In the case of energy, also with certain translucency, by reasonably applying, this kind of material can build unusual decoration effect Really, i.e., in the environment of being acted on without intense light source, the outward appearance similar with normal concrete, but situation about being acted in intense light source are possessed Under, possess the translucent effect of mystery.However, this kind of material in the case that special global facility thickness is larger, easily goes out when making Now cracking, contraction distortion, and not enough with transparent plastic or fibrous material compatibility, and the transparent plastic or fiber occurred easily with Mortar is separated, and causes transparent cement material to lose its globality so as to the problem of destruction.
The content of the invention:
For above-mentioned technical problem of the prior art, the invention provides a kind of special sand for being used to make transparent cement product Slurry, the described this extraordinary mortar for making transparent cement product will solve transparent cement of the prior art and easily open Split, contraction distortion and with transparent plastic or the not enough technical problem of fibrous material compatibility.
The invention provides a kind of extraordinary mortar for being used to make transparent cement product, by powder component and liquid components group Into,
Described powder component is made up of the raw material of following mass fraction:
Binder materials: 20-40
Water-loss reducer: 0.05-0.10
Calcium sand: 58-78
Defoamer:0.08-0.20
Water reducer:0.15-0.30
Economization agent: 1.0-2.0
Described liquid components are made up of the raw material of following mass fraction:
Aqueous epoxy resins:15-20
Water: 50-65
Curing agent: 20-30
Described powder component and the mass ratio of liquid components are 1:0.2-0.25.
Further, described binder materials is ordinary portland cement or alumina cement, and its strength grade is 42.5 or 52.5.
Further, described water-loss reducer is cellulose ether, and its range of viscosities is 400-800mPa S.
Further, described calcium sand is 10#-200# graded sand.
Further, described defoamer is organic silicon defoamer.
Further, described water reducer is polycarboxylate analog high efficiency water reducing agent.
Further, described economization agent is that poly- alkylol is birdsed of the same feather flock together compound.
Further, described curing agent is aqueous amine curing agent.
Present invention also offers a kind of above-mentioned preparation method of transparent cement product, comprise the following steps:
1)One the step of prepare powder component, weighs each raw material according to parts by weight, is then stirred with mortar mixer It is stand-by;
Described powder component is made up of the raw material of following mass fraction:
Binder materials: 20-40
Water-loss reducer: 0.05-0.10
Calcium sand: 58-78
Defoamer:0.08-0.20
Water reducer:0.15-0.30
Economization agent: 1.0-2.0
2)One the step of prepare liquid components, weighs each raw material according to parts by weight, is then stirred with homogenizer Stand-by, the charging sequence of liquid components is first stirs aqueous epoxy resins with curing agent, then by water in stirring It is lower add, until all liquid materials stir it is creamy;
Described liquid components are made up of the raw material of following mass fraction:
Aqueous epoxy resins:15-20
Water: 50-65
Curing agent: 20-30;
3)Powder component and liquid components are pressed 1:0.2-0.25 mass ratio is stirred stand-by using mortar mixer;
4)A diameter of 0.1-2mm transparent plastic fiber is arranged in a mould according to printing opacity requirement, then will be stirred Transparent cement mortar pour into mould, stand froth breaking, under conditions of 20 DEG C conserve one day be stripped, become transparent cement system Product.
The a kind of of the present invention is used to make under the extraordinary mortar material of transparent cement product and the collective effect of vitreous fibre, By template or make by hand, the cement products with light transmission can be obtained.
The present invention is compared with prior art, and its technological progress is significant.The present invention has fluidity good, product strength Height, the associativity of mortar and transparent plastic fiber is good, be conveniently used for template or manual method makes the advantage of transparent cement product, Architectural decoration or indoor and outdoor transparent cement handicraft are can be widely used for, is worked well.
Embodiment:
Embodiment 1:
The invention provides a kind of transparent cement product with extraordinary mortar, it is made up of powder component and liquid components:
The mass fraction of each raw material is as follows in powder component:
52.5 ordinary portland cements:30
400mPa S cellulose ethers:0.10
200# calcium sand:19
20-80# calcium sand:49.60
Defoamer:0.10
Water reducer:0.20
Economization agent:1.0
The mass fraction of each raw material is as follows in liquid components:
Aqueous epoxy resins:20
Water:54
Curing agent:26
The mass ratio of powder component and liquid components is 1:0.2, mixed printing opacity mud is with the fluidity of extraordinary mortar 140mm。
The extraordinary mortar and transparent optical fibers(Transparent optical fibers use 0.2mm diameters, and volume parts account for transparent cement cumulative volume 3%)It is fabricated to its performance parameter after transparent cement product as follows:
28d compression strength>=50MPa;
28d rupture strengths>=10MPa;
28d shrinkage values<=0.10mm/m.
A kind of preparation method of above-mentioned transparent cement product, comprises the following steps:
1)One the step of prepare powder component, weighs each raw material according to parts by weight, is then stirred with mortar mixer It is stand-by;
2)One the step of prepare liquid components, weighs each raw material according to parts by weight, is then stirred with homogenizer Stand-by, the charging sequence of liquid components is first stirs aqueous epoxy resins with curing agent, then by water in stirring It is lower add, until all liquid materials stir it is creamy;
3)Powder component and liquid components are pressed 1:0.2-0.25 mass ratio is stirred stand-by using mortar mixer;
4)A diameter of 0.1-2mm transparent plastic fiber is arranged in a mould according to printing opacity requirement, then will be stirred Transparent cement mortar pour into mould, stand froth breaking, under conditions of 20 DEG C conserve one day be stripped, become transparent cement system Product.
Embodiment 2:
The invention provides a kind of transparent cement product with extraordinary mortar, it is made up of powder component and liquid components:
The mass fraction of each raw material is as follows in powder component:
42.5 alumina cements:20
400mPa S cellulose ethers:0.05
10-30# calcium sand:21
20-160# calcium sand:58
Defoamer:0.10
Water reducer:0.15
Economization agent:2.0
The parts by weight of each raw material are as follows in liquid components:
Water-base epoxy:15
Water:60
Curing agent:25
The mass ratio of powder component and liquid components is:1:0.22, mixed printing opacity mud is with the fluidity of extraordinary mortar 130mm。
The extraordinary mortar and transparent optical fibers(Transparent optical fibers use 1.0mm diameters, and volume parts account for transparent cement cumulative volume 4%)It is fabricated to its performance parameter after transparent cement product as follows:(preparation method be the same as Example 1)
28d compression strength>=35MPa;
28d rupture strengths>=15MPa;
28d shrinkage values<=0.12mm/m.
Embodiment 3:
The invention provides a kind of transparent cement product with extraordinary mortar, it is made up of powder component and liquid components:
The mass fraction of each raw material is as follows in powder component:
42.5 ordinary portland cements:40
400mPa S cellulose ethers:0.10
200# calcium sand:15
20-80# calcium sand:42.60
Defoamer:0.10
Water reducer:0.20
Economization agent:2.0
The parts by weight of each raw material are as follows in liquid components:
Water-base epoxy:20
Water:54
Curing agent:26
The mass ratio of powder component and liquid components is:1:0.25, mixed printing opacity mud is with the fluidity of extraordinary mortar 150mm。
The extraordinary mortar and transparent optical fibers(Transparent optical fibers use 2.0mm diameters, and volume parts account for transparent cement cumulative volume 5%)It is fabricated to its performance parameter after transparent cement product as follows:(preparation method be the same as Example 1)
28d compression strength>=34MPa;
28d rupture strengths>=11MPa;
28d shrinkage values<=0.12mm/m.

Claims (9)

1. a kind of extraordinary mortar for being used to make transparent cement product, is made up of powder component and liquid components, it is characterised in that:
Described powder component is made up of the raw material of following mass fraction:
Binder materials: 20-40
Water-loss reducer: 0.05-0.10
Calcium sand: 58-78
Defoamer:0.08-0.20
Water reducer:0.15-0.30
Economization agent: 1.0-2.0
Described liquid components are made up of the raw material of following mass fraction:
Aqueous epoxy resins:15-20
Water: 50-65
Curing agent: 20-30;
Described powder component and the mass ratio of liquid components are 1:0.2-0.25.
2. a kind of extraordinary mortar for being used to make transparent cement product according to claim 1, it is characterised in that:Described Binder materials is ordinary portland cement or alumina cement, and its strength grade is 42.5 or 52.5.
3. a kind of extraordinary mortar for being used to make transparent cement product according to claim 1, it is characterised in that:Described Water-loss reducer is cellulose ether, and its range of viscosities is 400-800mPa S.
4. a kind of extraordinary mortar for being used to make transparent cement product according to claim 1, it is characterised in that:Described Calcium sand is 10#-200# graded sand.
5. a kind of extraordinary mortar for being used to make transparent cement product according to claim 1, it is characterised in that:Described Defoamer is organic silicon defoamer.
6. a kind of extraordinary mortar for being used to make transparent cement product according to claim 1, it is characterised in that:Described Water reducer is polycarboxylate analog high efficiency water reducing agent.
7. a kind of extraordinary mortar for being used to make transparent cement product according to claim 1, it is characterised in that:Described Economization agent is that poly- alkylol is birdsed of the same feather flock together compound.
8. a kind of extraordinary mortar for being used to make transparent cement product according to claim 1, it is characterised in that:Described Curing agent is aqueous amine curing agent.
9. a kind of preparation method of transparent cement product, it is characterised in that comprise the following steps:
1)One the step of prepare powder component, weighs each raw material according to parts by weight, is then stirred with mortar mixer It is stand-by;
Described powder component is made up of the raw material of following mass fraction:
Binder materials: 20-40
Water-loss reducer: 0.05-0.10
Calcium sand: 58-78
Defoamer:0.08-0.20
Water reducer:0.15-0.30
Economization agent: 1.0-2.0
2)One the step of prepare liquid components, weighs each raw material according to parts by weight, is then stirred with homogenizer Stand-by, the charging sequence of liquid components is first stirs aqueous epoxy resins with curing agent, then by water in stirring It is lower add, until all liquid materials stir it is creamy;
Described liquid components are made up of the raw material of following mass fraction:
Aqueous epoxy resins:15-20
Water: 50-65
Curing agent: 20-30;
3)Powder component and liquid components are pressed 1:0.2-0.25 mass ratio is stirred stand-by using mortar mixer;
4)A diameter of 0.1-2mm transparent plastic fiber is arranged in a mould according to printing opacity requirement, then will be stirred Transparent cement mortar pour into mould, stand froth breaking, under conditions of 20 DEG C conserve one day be stripped, become transparent cement system Product.
CN201710294196.3A 2017-04-28 2017-04-28 A kind of extraordinary mortar for being used to make transparent cement product Pending CN106986595A (en)

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CN201710294196.3A CN106986595A (en) 2017-04-28 2017-04-28 A kind of extraordinary mortar for being used to make transparent cement product

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109020347A (en) * 2018-09-29 2018-12-18 福建江夏学院 A kind of composite toughening perfusion mortar and preparation method thereof
CN109133799A (en) * 2018-09-27 2019-01-04 武汉普卫思建材科技有限公司 A kind of preparation method of shadow image concrete-containing building material
WO2020078294A1 (en) * 2018-10-17 2020-04-23 于长河 Multi-performance color-changeable light-transmission ornament

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1124642A (en) * 1964-06-18 1968-08-21 Tile Council Of America Improvements in ceramic products
FR1549150A (en) * 1966-12-30 1968-12-06
JPH11116315A (en) * 1997-10-15 1999-04-27 Takenaka Komuten Co Ltd Mortar composition, production of mortar composition, pc board produced by using the composition and production of the board
CN101309877A (en) * 2005-10-17 2008-11-19 透明混凝土有限责任公司 Formulation for obtaining a translucent concrete mixture
CN101830684A (en) * 2010-05-26 2010-09-15 江苏博特新材料有限公司 Super early strength polymer rapid-patching motar material
CN103003505A (en) * 2010-06-10 2013-03-27 意大利水泥股份公司 Composite panel based on cementitious mortar with properties of transparency
CN103085154A (en) * 2011-10-27 2013-05-08 比亚迪股份有限公司 Light-transmission concrete and method for manufacturing same
CN103570298A (en) * 2013-09-30 2014-02-12 郑州大学 High-strength polypropylene fiber polymer cement mortar and preparation method thereof
CN106587841A (en) * 2016-12-15 2017-04-26 上海阳森精细化工有限公司 High-ductility cement based composite material and preparation method thereof

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1124642A (en) * 1964-06-18 1968-08-21 Tile Council Of America Improvements in ceramic products
FR1549150A (en) * 1966-12-30 1968-12-06
JPH11116315A (en) * 1997-10-15 1999-04-27 Takenaka Komuten Co Ltd Mortar composition, production of mortar composition, pc board produced by using the composition and production of the board
CN101309877A (en) * 2005-10-17 2008-11-19 透明混凝土有限责任公司 Formulation for obtaining a translucent concrete mixture
CN101830684A (en) * 2010-05-26 2010-09-15 江苏博特新材料有限公司 Super early strength polymer rapid-patching motar material
CN103003505A (en) * 2010-06-10 2013-03-27 意大利水泥股份公司 Composite panel based on cementitious mortar with properties of transparency
CN103085154A (en) * 2011-10-27 2013-05-08 比亚迪股份有限公司 Light-transmission concrete and method for manufacturing same
CN103570298A (en) * 2013-09-30 2014-02-12 郑州大学 High-strength polypropylene fiber polymer cement mortar and preparation method thereof
CN106587841A (en) * 2016-12-15 2017-04-26 上海阳森精细化工有限公司 High-ductility cement based composite material and preparation method thereof

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Title
陈方斌: ""发光透光水泥基材料的制备与性能研究"", 《南昌大学硕士论文》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109133799A (en) * 2018-09-27 2019-01-04 武汉普卫思建材科技有限公司 A kind of preparation method of shadow image concrete-containing building material
CN109020347A (en) * 2018-09-29 2018-12-18 福建江夏学院 A kind of composite toughening perfusion mortar and preparation method thereof
WO2020078294A1 (en) * 2018-10-17 2020-04-23 于长河 Multi-performance color-changeable light-transmission ornament

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