CN106589714A - Acid and alkali-resistant protective shoe sole material - Google Patents
Acid and alkali-resistant protective shoe sole material Download PDFInfo
- Publication number
- CN106589714A CN106589714A CN201710068460.1A CN201710068460A CN106589714A CN 106589714 A CN106589714 A CN 106589714A CN 201710068460 A CN201710068460 A CN 201710068460A CN 106589714 A CN106589714 A CN 106589714A
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- China
- Prior art keywords
- parts
- component
- acid
- alkali
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- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides an acid and alkali-resistant protective shoe sole material, comprising a component A and a component B in a mass ratio of (7.2-8.6):1, wherein the component A is prepared from the following components in parts by weight: 77-94 parts of fluororubber, 5-18 parts of di-tert-butyl peroxide, 1-4 parts of N-tert-butyl-2-benzothiazole sulfenamide, 12-18 parts of 6-ethoxy-2,24-trimethyl-1,2-dihydroquinoline, 11-16 parts of semi-reinforcing furnace black, and 15-20 parts of heavy oil; and the component B is prepared from the following components in parts by weight: 10-18 parts of nano zinc oxide, 17-30 parts of antimony trioxide, 11-18 parts of zinc carbonate, 6-15 parts of stearic acid, 9-17 parts of salicylic acid, 9-12 parts of magnesium oxide, 30-40 parts of pottery clay, 5-10 parts of dibutyl ester, 10-17 parts of dioctyl ester, 12-19 parts of high styrene, and 3-5 parts of an active agent. The protective shoe sole material is simple in preparation process, low in cost, good in air permeability, light in mass, and good in performance.
Description
Technical field
The invention belongs to daily necessities field, more particularly to a kind of acid and alkali-resistance protective shoe bottom material and preparation method thereof.
Background technology
The species of material for sole of shoe is a lot, is generally divided into two kinds of natural class material for sole of shoe and synthesis class material for sole of shoe.Natural class
Material for sole of shoe includes natural bottom leather, bamboo and wood material etc., and synthesis class material for sole of shoe includes rubber, PU materials, PVC synthetic resin etc..
Protective shoe bottom industry is in the period of fast development, but due to its hydrolysis and acid-proof alkaline is poor and shadow
Ring it to use.Therefore, the decay resistance of protective shoe bottom material is studied, extends the life-span of protective shoe bottom material, to anti-
Shield footwear material for sole of shoe all has very important significance.Additionally, under the adverse circumstances such as industrial plant, protective shoe bottom is also easy to
It is aging.
The content of the invention
Technical problem：In order to solve the defect of prior art, the invention provides a kind of acid and alkali-resistance protective shoe bottom material.
Technical scheme：A kind of acid and alkali-resistance protective shoe bottom material that the present invention is provided, including mass ratio (7.2-8.6):1
Component A and component B；Wherein, the component A is made up of the component of following weight ratio：Fluorubber 77-94 parts, di-t-butyl peroxide
Compound 5-18 part, N tert butyl benzothiazole 2 sulfenamide 1-4 parts, 6- ethyoxyl -2,24- trimethyl -1,2- dihydroquinoline
12-18 parts, semi-reinforcing furnace black 11-16 parts, heavy oil 15-20 parts；The component B is made up of the component of following weight portion：Nano oxygen
Change zinc 10-18 parts, antimony oxide 17-30 parts, zinc carbonate 11-18 parts, stearic acid 6-15 part salicylic acid 9-17 parts, magnesium oxide 9-
12 parts, 30～40 parts of potter's clay, 5～10 parts of dibutyl ester, 10～17 parts of dioctyl ester, high-phenylethylene 12-19 parts, 3～5 parts of activating agent.
As improvement, including mass ratio 7.6:1 component A and component B；Wherein, the component A by following weight ratio group
Part is made：83 parts of fluorubber, 14 parts of di-tert-butyl peroxide, 3 parts of N tert butyl benzothiazole 2 sulfenamide, 6- ethoxies
14 parts of base -2,24- trimethyl -1,2- dihydroquinoline, 16 parts of semi-reinforcing furnace black, 18 parts of heavy oil；The component B is by following weight portion
Component make：16 parts of nano zine oxide, 21 parts of antimony oxide, 15 parts of zinc carbonate, 8 parts of stearic acid, 12 parts of salicylic acid, oxidation
11 parts of magnesium, 34 parts of potter's clay, 7 parts of dibutyl ester, 14 parts of dioctyl ester, 16 parts of high-phenylethylene, 4 parts of activating agent.
Present invention also offers a kind of preparation method of acid and alkali-resistance protective shoe bottom material, comprises the following steps：
(1) each component of component A is weighed in proportion, is mixed；The each component of component B is weighed in proportion, mixed；
(2) each component in 2/3 component A is added in autoclave, at 50-80 DEG C, reacts 0.5-1h；Add 1/3
Component A in each component add autoclave in, at 50-80 DEG C, continue react 3-4h；Room temperature is cooled to, performed polymer is obtained；
(3) by performed polymer and 1/3 component B mix homogeneously；In adding protective footwear sole casting machine batch can, 60- is warming up to
70 DEG C, constant temperature 5-10min；1/3 component B mix homogeneously is continuously added, 75-80 DEG C is warming up to, constant temperature 10-15min；It is cooled to
55-60 DEG C, continuously add remaining 1/3 component B, constant temperature 15-20min；
(4) by step (3) product on protective footwear die for shoe-sole coating release agent, dry up, pour into a mould, be incubated 10-12min, take off
Mould, obtains final product.
Beneficial effect：Protective shoe bottom material preparation process is simple, with low cost, good permeability, matter that the present invention is provided
Amount is light, performance is good.
Specific embodiment
Acid and alkali-resistance protective shoe bottom material of the present invention is further illustrated below.
Acid and alkali-resistance protective shoe bottom material, including mass ratio 7.6:1 component A and component B；Wherein, the component A by with
The component of lower weight ratio is made：83 parts of fluorubber, 14 parts of di-tert-butyl peroxide, the N- tert-butyl groups -2-[4-morpholinodithio time sulphonyl
3 parts of amine, 14 parts of 6- ethyoxyl -2,24- trimethyl -1,2- dihydroquinoline, 16 parts of semi-reinforcing furnace black, 18 parts of heavy oil；The component B
It is made up of the component of following weight portion：16 parts of nano zine oxide, 21 parts of antimony oxide, 15 parts of zinc carbonate, 8 parts of stearic acid, water
12 parts of poplar acid, 11 parts of magnesium oxide, 34 parts of potter's clay, 7 parts of dibutyl ester, 14 parts of dioctyl ester, 16 parts of high-phenylethylene, 4 parts of activating agent.
Present invention also offers a kind of preparation method of acid and alkali-resistance protective shoe bottom material, comprises the following steps：
(1) each component of component A is weighed in proportion, is mixed；The each component of component B is weighed in proportion, mixed；
(2) each component in 2/3 component A is added in autoclave, at 50-80 DEG C, reacts 0.5-1h；Add 1/3
Component A in each component add autoclave in, at 50-80 DEG C, continue react 3-4h；Room temperature is cooled to, performed polymer is obtained；
(3) by performed polymer and 1/3 component B mix homogeneously；In adding protective footwear sole casting machine batch can, 60- is warming up to
70 DEG C, constant temperature 5-10min；1/3 component B mix homogeneously is continuously added, 75-80 DEG C is warming up to, constant temperature 10-15min；It is cooled to
55-60 DEG C, continuously add remaining 1/3 component B, constant temperature 15-20min；
(4) by step (3) product on protective footwear die for shoe-sole coating release agent, dry up, pour into a mould, be incubated 10-12min, take off
Mould, obtains final product.
Claims (2)
1. a kind of acid and alkali-resistance protective shoe bottom material, it is characterised in that：Including mass ratio (7.2-8.6):1 component A and component
B；Wherein, the component A is made up of the component of following weight ratio：Fluorubber 77-94 parts, di-tert-butyl peroxide 5-18 parts,
N tert butyl benzothiazole 2 sulfenamide 1-4 parts, 6- ethyoxyl -2,24- trimethyl -1,2- dihydroquinoline 12-18 parts, half
RF reinforcing furnace black 11-16 parts, heavy oil 15-20 parts；The component B is made up of the component of following weight portion：Nano zine oxide 10-18
Part, antimony oxide 17-30 parts, zinc carbonate 11-18 parts, stearic acid 6-15 part salicylic acid 9-17 parts, magnesium oxide 9-12 parts, potter's clay
30～40 parts, 5～10 parts of dibutyl ester, 10～17 parts of dioctyl ester, high-phenylethylene 12-19 parts, 3～5 parts of activating agent.
2. a kind of acid and alkali-resistance protective shoe bottom material according to claim 1, it is characterised in that：Including mass ratio 7.6:1
Component A and component B；Wherein, the component A is made up of the component of following weight ratio：83 parts of fluorubber, di-tert-butyl peroxide
14 parts of thing, 3 parts of N tert butyl benzothiazole 2 sulfenamide, 14 parts of 6- ethyoxyl -2,24- trimethyl -1,2- dihydroquinoline,
16 parts of semi-reinforcing furnace black, 18 parts of heavy oil；The component B is made up of the component of following weight portion：16 parts of nano zine oxide, three oxidations
Two 21 parts of antimony, 15 parts of zinc carbonate, 8 parts of stearic acid, 12 parts of salicylic acid, 11 parts of magnesium oxide, 34 parts of potter's clay, 7 parts of dibutyl ester, dioctyl ester
14 parts, 16 parts of high-phenylethylene, 4 parts of activating agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710068460.1A CN106589714A (en) | 2017-02-08 | 2017-02-08 | Acid and alkali-resistant protective shoe sole material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710068460.1A CN106589714A (en) | 2017-02-08 | 2017-02-08 | Acid and alkali-resistant protective shoe sole material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106589714A true CN106589714A (en) | 2017-04-26 |
Family
ID=58586786
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710068460.1A Pending CN106589714A (en) | 2017-02-08 | 2017-02-08 | Acid and alkali-resistant protective shoe sole material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106589714A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109294017A (en) * | 2018-10-29 | 2019-02-01 | 南京航空航天大学溧水仿生产业研究院有限公司 | A kind of wear-resisting acid and alkali-resistance rubber material |
| CN109368247A (en) * | 2018-10-29 | 2019-02-22 | 南京航空航天大学溧水仿生产业研究院有限公司 | A kind of Medical Robot's grasping mechanism |
-
2017
- 2017-02-08 CN CN201710068460.1A patent/CN106589714A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109294017A (en) * | 2018-10-29 | 2019-02-01 | 南京航空航天大学溧水仿生产业研究院有限公司 | A kind of wear-resisting acid and alkali-resistance rubber material |
| CN109368247A (en) * | 2018-10-29 | 2019-02-22 | 南京航空航天大学溧水仿生产业研究院有限公司 | A kind of Medical Robot's grasping mechanism |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170426 |