CN106588377A - Farmland fertilizer for improving permeability of soil - Google Patents

Farmland fertilizer for improving permeability of soil Download PDF

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Publication number
CN106588377A
CN106588377A CN201611200360.1A CN201611200360A CN106588377A CN 106588377 A CN106588377 A CN 106588377A CN 201611200360 A CN201611200360 A CN 201611200360A CN 106588377 A CN106588377 A CN 106588377A
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CN
China
Prior art keywords
parts
prefabricated material
rhizoma dioscoreae
weight
washing
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CN201611200360.1A
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Chinese (zh)
Inventor
房兴林
周意林
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Anhui Kang Mu International Fertilizer Ltd By Share Ltd
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Anhui Kang Mu International Fertilizer Ltd By Share Ltd
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Priority to CN201611200360.1A priority Critical patent/CN106588377A/en
Publication of CN106588377A publication Critical patent/CN106588377A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/20Mixtures of one or more fertilisers with additives not having a specially fertilising activity for preventing the fertilisers being reduced to powder; Anti-dusting additives
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B1/00Superphosphates, i.e. fertilisers produced by reacting rock or bone phosphates with sulfuric or phosphoric acid in such amounts and concentrations as to yield solid products directly
    • C05B1/02Superphosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners

Abstract

The invention discloses a farmland fertilizer for improving the permeability of soil. The fertilizer comprises, by weight, 8-16 parts of potassium mineral powder, 25-45 parts of urea, 16-22 parts of a magnesium potassium sulfate fertilizer, 10-20 parts of phosphate rock powder, 4-6 parts of carboxymethylcellulose sodium, 4-10 parts of modified Chinese yam starch, 4-8 parts of yellow phosphorus furnace slag, 4-8 parts of cassava residues, 4-6 parts of manganese-containing calcium superphosphate, 2-4 parts of natural zeolite, 1-2 parts of manganese sulfate, 0.8-1.6 parts of borax, 0.003-0.006 parts of Bacillus subtilis, 0.002-0.005 parts of phytase, 0.02-0.05 parts of Bacillus licheniformis, 0.002-0.005 parts of metalloprotease, 12-20 parts of straw powder, 20-30 parts of animal manure, 6-10 parts of furfural residues, 20-25 parts of humus soil, 3-7 parts of shell powder, 3-6 parts of peanut shells, 4-8 parts of cottonseed meal and 25-45 parts of water.

Description

One kind can improved soil permeability farmland fertilizer
Technical field
The present invention relates to technical field of fertilizers, more particularly to one kind can improved soil permeability farmland fertilizer.
Background technology
Multinomial agricultural research points out, although chemical fertilizer is crops supplements enough nutrients, have ignored the benefit of organic matter Give, under conditions of sufficient organic matter is lacked, granule result is difficult to be formed the soil of Planting Crops, between soil particle Adhesive force weakens, and then lowers the water holding capacity of soil, when soil does not have enough moisture, even if fertilizer quality is high, is not easy to By nutrients release under favourable environmental condition, if long-term single administration chemical fertilizer, soil will give soil quality and environment band Carry out harmful effect.In addition, excessively apply chemical fertilizer also can environment be caused to have a strong impact on, when excessive chemical fertilizer is applied, do not have To be outflowed with water by the nutrient that soil absorbs, it is impossible to adapt to the requirement in the crops time of infertility.
The content of the invention
Based on background technology exist technical problem, the present invention propose one kind can improved soil permeability farmland fertilizer, Not only a large amount of mineral and trace element can be provided for farmland, it is ensured that farmland normal growth, and adhesive property is good, granule Good, mutual high adsorption capacity, heat stability are good, while fertilizer rate of release can be effectively adjusted, the rate of release of nutrient substance It is moderate, moreover it is possible to improve soil permeability.
One kind proposed by the present invention can improved soil permeability farmland fertilizer, its raw material includes by weight:Potassium breeze 8- 16 parts, carbamide 25-45 parts, potash magnesium sulphate fertilizer 16-22 parts, ground phosphate rock 10-20 parts, sodium carboxymethyl cellulose 4-6 parts, be modified Rhizoma Dioscoreae Starch 4-10 parts, yellow phosphorus furnace slag 4-8 parts, manioc waste 4-8 parts, the parts of 4-6 containing manganese superphosphate, natural zeolite 2-4 parts, manganese sulfate 1- 2 parts, Borax 0.8-1.6 parts, bacillus subtilises 0.003-0.006 parts, phytase 0.002-0.005 parts, Bacillus licheniformis 0.02-0.05 parts, metalloproteases 0.002-0.005 parts, powder of straw 12-20 part, feces of livestock and poultry 20-30 parts, alditol slag 6-10 Part, fertile soil 20-25 parts, conch meal 3-7 parts, Pericarppium arachidis hypogaeae 3-6 parts, cottonseed meal 4-8 parts, water 25-45 parts.
Preferably, potassium breeze, carbamide, potash magnesium sulphate fertilizer, ground phosphate rock, sodium carboxymethyl cellulose, the weight of modified Rhizoma Dioscoreae starch Amount is than being 10-14:30-40:18-20:12-18:4.5-5.5:6-8.
Preferably, bacillus subtilises, phytase, Bacillus licheniformis, the weight ratio of metalloproteases are 4-5:3-4: 30-40:3-4.
Preferably, its raw material includes by weight:Potassium breeze 10-14 part, carbamide 30-40 parts, potash magnesium sulphate fertilizer 18-20 Part, ground phosphate rock 12-18 parts, sodium carboxymethyl cellulose 4.5-5.5 parts, be modified Rhizoma Dioscoreae starch 6-8 parts, yellow phosphorus furnace slag 5-7 parts, Maninot esculenta crantz. Slag 5-7 parts, the parts of 4.5-5.5 containing manganese superphosphate, natural zeolite 2.5-3.5 parts, manganese sulfate 1.2-1.6 parts, Borax 1-1.4 parts, Bacillus subtilises 0.004-0.005 parts, phytase 0.003-0.004 parts, Bacillus licheniformis 0.03-0.04 parts, metal egg White enzyme 0.003-0.004 parts, powder of straw 14-18 part, feces of livestock and poultry 22-28 parts, alditol slag 7-9 part, fertile soil 22-24 parts, shellfish Shell powder 4-6 parts, Pericarppium arachidis hypogaeae 4-5 parts, cottonseed meal 5-7 parts, water 30-40 parts.
Preferably, the Rhizoma Dioscoreae starch that is modified is prepared using following technique:By Rhizoma Dioscoreae starch, acetic anhydride, glacial acetic acid mix homogeneously Obtain the first prefabricated material;Styrene, acrylic acid mix homogeneously are obtained into the second prefabricated material;Potassium peroxydisulfate is soluble in water, lead to nitrogen Air is removed, and adds the second prefabricated material, heated and stirred, centrifugation, washing, ultrasonic disperse toluene, positive heptan to be added in butanol solution Alkane is stirred, and centrifugation, washing obtain the 3rd prefabricated material;By glacial acetic acid, concentrated sulphuric acid mix homogeneously, first is added dropwise under stirring pre- In system material, Deca follow-up continuous stirring completely is sent under stirring in water, adds the 3rd prefabricated material, adjusts body with sodium hydroxide It is that pH value is neutrality, separates, washing, dry, pulverize and obtain modified Rhizoma Dioscoreae starch.
Preferably, the Rhizoma Dioscoreae starch that is modified is prepared using following technique:By weight by 25-35 part glacial acetic acid, 35-55 part vinegar Anhydride, 18-24 part Rhizoma Dioscoreae starch mix homogeneously obtain the first prefabricated material;By weight by 0.8-1.6 part acrylic acid, 6-12 part benzene Ethylene mix homogeneously obtains the second prefabricated material;By weight 0.05-0.1 part potassium peroxydisulfates are dissolved in 45-55 part water, logical nitrogen is removed Air is removed, adds 7-11 the second prefabricated material of part, heated and stirred, centrifugation to wash, ultrasonic disperse is 30- in 60-100 parts concentration In 35wt% butanol solutions, 5-8 part toluene, the stirring of 2-4 parts normal heptane are added, centrifugation, washing obtain the 3rd prefabricated material;By weight 25-35 part glacial acetic acid, 3-5 part concentrated sulphuric acid mix homogeneously are added dropwise under stirring in the first prefabricated material of 4-8 parts, Deca by part Continue stirring after completely, send under stirring in 140-180 part water, add the 3rd prefabricated material of 1.5-2.5 parts, use sodium hydroxide Regulation system pH value is neutrality, separates, washing, dry, pulverize and obtains modified Rhizoma Dioscoreae starch.
Preferably, the Rhizoma Dioscoreae starch that is modified is prepared using following technique:By weight by 25-35 part glacial acetic acid, 35-55 part vinegar Anhydride, 18-24 part Rhizoma Dioscoreae starch mix homogeneously obtain the first prefabricated material;By weight by 0.8-1.6 part acrylic acid, 6-12 part benzene Ethylene mix homogeneously obtains the second prefabricated material;By weight 0.05-0.1 part potassium peroxydisulfates are dissolved in 45-55 part water, logical nitrogen is removed Air is removed, 7-11 the second prefabricated material of part are added, 88-92 DEG C of stirring 25-35h is heated to, mixing speed is 300-500r/min, from The heart, washing, ultrasonic disperse add 5-8 part toluene, 2-4 part normal heptane in 60-100 parts concentration is 30-35wt% butanol solutions Stirring 35-55min, centrifugation, washing obtain the 3rd prefabricated material;By weight 25-35 part glacial acetic acid, 3-5 parts concentrated sulphuric acid are mixed Uniformly, it is added dropwise under stirring in the first prefabricated material of 4-8 parts, Deca follow-up continuous stirring 35-55min completely, under stirring Send in 140-180 part water, add the 3rd prefabricated material of 1.5-2.5 parts, be neutral with sodium hydroxide regulation system pH value, separate, Washing, 75-80 DEG C is dried 60-120min, and crushing obtains modified Rhizoma Dioscoreae starch.
The present invention is obtained using conventional fabrication process.
The present invention is using carbamide, ground phosphate rock, potash magnesium sulphate fertilizer, potassium breeze and modified Rhizoma Dioscoreae starch, sodium carboxymethyl cellulose Mating reaction, not only can provide growth necessary N P and K for farmland, and adhesive property is good, and granule is good, mutual energy of adsorption Power is strong, and heat stability is good;In 3rd prefabricated material of modified Rhizoma Dioscoreae starch, by rationally control reaction condition, the hole of thus obtained microsphere Deep moderate with aperture, specific surface area is big, can be adsorbed on other particle surfaces, and Rhizoma Dioscoreae starch is avette and ellipse, used as half Crystalline material, destroys the crystal structure of Rhizoma Dioscoreae starch after acetylation, as substitution value increases, degree of crystallinity is reduced, and is formed more Amorphous domain, the 3rd prefabricated material can active adsorption thereon, not only thermoplastic property is excellent, heat stability strengthen, specific surface Product is big, excellent adsorption so as to can preferably bear the operation of work in-process;Modified Rhizoma Dioscoreae starch is matched somebody with somebody with sodium carboxymethyl cellulose Close, adhesive property is moderate, the high adsorption capacity to raw material components, be not only convenient for granulation, and it is not broken, during hot weather Be unlikely to deform with loosely, further with manganese sulfate, Borax, containing manganese superphosphate, yellow phosphorus furnace slag, manioc waste, natural zeolite coordinate Effect, not only containing a large amount of mineral and trace element, it is ensured that farmland normal growth, while having certain slow release effect, and changes Property Rhizoma Dioscoreae starch coordinate, can effectively adjust fertilizer rate of release, the rate of release of nutrient substance is moderate;And modified Rhizoma Dioscoreae starch, Feces of livestock and poultry, powder of straw, fertile soil, alditol slag, conch meal, cottonseed meal, Pericarppium arachidis hypogaeae coordinate, and further improve soil permeability, On the basis of abundant organic matter is provided for field-grown, the growth for farmland provides good environment.
Specific embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
One kind proposed by the present invention can improved soil permeability farmland fertilizer, its raw material includes by weight:8 parts of potassium breeze, urine 45 parts of element, 16 parts of potash magnesium sulphate fertilizer, 20 parts of ground phosphate rock, 4 parts of sodium carboxymethyl cellulose, be modified 10 parts of Rhizoma Dioscoreae starch, yellow phosphorus furnace slag 4 Part, 8 parts of manioc waste, containing 4 parts of manganese superphosphate, 4 parts of natural zeolite, 1 part of manganese sulfate, 1.6 parts of Borax, bacillus subtilises 0.003 part, 0.005 part of phytase, 0.02 part of Bacillus licheniformis, 0.005 part of metalloproteases, 12 parts of powder of straw, animal dung Just 30 parts, 6 parts of alditol slag, 25 parts of fertile soil, 3 parts of conch meal, 6 parts of Pericarppium arachidis hypogaeae, 4 parts of cottonseed meal, 45 parts of water.
Embodiment 2
One kind proposed by the present invention can improved soil permeability farmland fertilizer, its raw material includes by weight:16 parts of potassium breeze, urine 25 parts of element, 22 parts of potash magnesium sulphate fertilizer, 10 parts of ground phosphate rock, 6 parts of sodium carboxymethyl cellulose, be modified 4 parts of Rhizoma Dioscoreae starch, yellow phosphorus furnace slag 8 Part, 4 parts of manioc waste, containing 6 parts of manganese superphosphate, 2 parts of natural zeolite, 2 parts of manganese sulfate, 0.8 part of Borax, bacillus subtilises 0.006 part, 0.002 part of phytase, 0.05 part of Bacillus licheniformis, 0.002 part of metalloproteases, 20 parts of powder of straw, animal dung Just 20 parts, 10 parts of alditol slag, 20 parts of fertile soil, 7 parts of conch meal, 3 parts of Pericarppium arachidis hypogaeae, 8 parts of cottonseed meal, 25 parts of water.
Modified Rhizoma Dioscoreae starch is prepared using following technique:Rhizoma Dioscoreae starch, acetic anhydride, glacial acetic acid mix homogeneously are obtained into first Prefabricated material;Styrene, acrylic acid mix homogeneously are obtained into the second prefabricated material;Potassium peroxydisulfate is soluble in water, lead to nitrogen and remove air, The second prefabricated material, heated and stirred, centrifugation, washing, ultrasonic disperse is added to add toluene, normal heptane stirring in butanol solution, from The heart, washing obtain the 3rd prefabricated material;Glacial acetic acid, concentrated sulphuric acid mix homogeneously are added dropwise in the first prefabricated material under stirring, are dripped Complete rear continuation stirring is added, is sent under stirring in water, is added the 3rd prefabricated material, in sodium hydroxide regulation system pH value being Property, separate, washing, dry, pulverize and obtain modified Rhizoma Dioscoreae starch.
Embodiment 3
One kind proposed by the present invention can improved soil permeability farmland fertilizer, its raw material includes by weight:10 parts of potassium breeze, urine 40 parts of element, 18 parts of potash magnesium sulphate fertilizer, 18 parts of ground phosphate rock, 4.5 parts of sodium carboxymethyl cellulose, be modified 8 parts of Rhizoma Dioscoreae starch, yellow phosphorus furnace slag 5 parts, 7 parts of manioc waste, containing 4.5 parts of manganese superphosphate, 3.5 parts of natural zeolite, 1.2 parts of manganese sulfate, 1.4 parts of Borax, hay spore 0.004 part of bacillus, 0.004 part of phytase, 0.03 part of Bacillus licheniformis, 0.004 part of metalloproteases, 14 parts of powder of straw, poultry 28 parts of poultry manure, 7 parts of alditol slag, 24 parts of fertile soil, 4 parts of conch meal, 5 parts of Pericarppium arachidis hypogaeae, 5 parts of cottonseed meal, 40 parts of water.
Modified Rhizoma Dioscoreae starch is prepared using following technique:By weight by 25 parts of glacial acetic acid, 55 portions of acetic anhydride, 18 portions of Rhizoma Dioscoreaes Starch mix homogeneously obtains the first prefabricated material;1.6 parts of acrylic acid, 6 parts of styrene mix homogeneously are obtained into second by weight pre- System material;By weight 0.1 part of potassium peroxydisulfate is dissolved in 45 parts of water, is led to nitrogen and is removed air, add 11 part of second prefabricated material, heating To 88 DEG C of stirring 35h, mixing speed is 300r/min, centrifugation, washing, and ultrasonic disperse is 30wt% butanol solutions in 100 parts of concentration In, add 8 parts of toluene, 2 parts of normal heptane to stir 55min, centrifugation, washing obtain the 3rd prefabricated material;By weight by 25 portions of ice vinegar Acid, 5 parts of concentrated sulphuric acid mix homogeneously, are added dropwise under stirring in 4 part of first prefabricated material, Deca follow-up continuous stirring 55min completely, Send under stirring in 140 parts of water, add 2.5 part of the 3rd prefabricated material, be neutral with sodium hydroxide regulation system pH value, divide From, washing, 75 DEG C are dried 120min, and crushing obtains modified Rhizoma Dioscoreae starch.
Embodiment 4
One kind proposed by the present invention can improved soil permeability farmland fertilizer, its raw material includes by weight:14 parts of potassium breeze, urine 30 parts of element, 20 parts of potash magnesium sulphate fertilizer, 12 parts of ground phosphate rock, 5.5 parts of sodium carboxymethyl cellulose, be modified 6 parts of Rhizoma Dioscoreae starch, yellow phosphorus furnace slag 7 parts, 5 parts of manioc waste, containing 5.5 parts of manganese superphosphate, 2.5 parts of natural zeolite, 1.6 parts of manganese sulfate, 1 part of Borax, bacillus subtilis 0.005 part of bacterium, 0.003 part of phytase, 0.04 part of Bacillus licheniformis, 0.003 part of metalloproteases, 18 parts of powder of straw, poultry 22 parts of feces, 9 parts of alditol slag, 22 parts of fertile soil, 6 parts of conch meal, 4 parts of Pericarppium arachidis hypogaeae, 7 parts of cottonseed meal, 30 parts of water.
Modified Rhizoma Dioscoreae starch is prepared using following technique:By weight by 35 parts of glacial acetic acid, 35 portions of acetic anhydride, 24 portions of Rhizoma Dioscoreaes Starch mix homogeneously obtains the first prefabricated material;0.8 part of acrylic acid, 12 parts of styrene mix homogeneously are obtained into second by weight pre- System material;By weight 0.05 part of potassium peroxydisulfate is dissolved in 55 parts of water, is led to nitrogen and is removed air, add 7 part of second prefabricated material, heating To 92 DEG C of stirring 25h, mixing speed is 500r/min, centrifugation, washing, and ultrasonic disperse is 35wt% butanol solutions in 60 parts of concentration In, add 5 parts of toluene, 4 parts of normal heptane to stir 35min, centrifugation, washing obtain the 3rd prefabricated material;By weight by 35 portions of ice vinegar Acid, 3 parts of concentrated sulphuric acid mix homogeneously, are added dropwise under stirring in 8 part of first prefabricated material, Deca follow-up continuous stirring 35min completely, Send under stirring in 180 parts of water, add 1.5 part of the 3rd prefabricated material, be neutral with sodium hydroxide regulation system pH value, divide From, washing, 80 DEG C are dried 60min, and crushing obtains modified Rhizoma Dioscoreae starch.
Embodiment 5
One kind proposed by the present invention can improved soil permeability farmland fertilizer, its raw material includes by weight:12 parts of potassium breeze, urine 35 parts of element, 19 parts of potash magnesium sulphate fertilizer, 15 parts of ground phosphate rock, 5 parts of sodium carboxymethyl cellulose, be modified 7 parts of Rhizoma Dioscoreae starch, yellow phosphorus furnace slag 6 Part, 6 parts of manioc waste, containing 5 parts of manganese superphosphate, 3 parts of natural zeolite, 1.4 parts of manganese sulfate, 1.2 parts of Borax, bacillus subtilises 0.0045 part, 0.0035 part of phytase, 0.035 part of Bacillus licheniformis, 0.0035 part of metalloproteases, 16 parts of powder of straw, poultry 25 parts of poultry manure, 8 parts of alditol slag, 23 parts of fertile soil, 5 parts of conch meal, 4.5 parts of Pericarppium arachidis hypogaeae, 6 parts of cottonseed meal, 35 parts of water.
Modified Rhizoma Dioscoreae starch is prepared using following technique:By weight by 30 parts of glacial acetic acid, 45 portions of acetic anhydride, 20 portions of Rhizoma Dioscoreaes Starch mix homogeneously obtains the first prefabricated material;1.2 parts of acrylic acid, 9 parts of styrene mix homogeneously are obtained into second by weight pre- System material;By weight 0.08 part of potassium peroxydisulfate is dissolved in 50 parts of water, is led to nitrogen and is removed air, add 9 part of second prefabricated material, heating Stirring, centrifugation, washing, ultrasonic disperse add 6 parts of toluene, 3 parts of normal heptane stirrings in 80 parts of concentration are 32wt% butanol solutions, Centrifugation, washing obtain the 3rd prefabricated material;By weight by 30 parts of glacial acetic acid, 4 parts of concentrated sulphuric acid mix homogeneously, Deca under stirring Enter in 6 part of first prefabricated material, Deca follow-up continuous stirring completely is sent under stirring in 160 parts of water, and 2 part the 3rd of addition is prefabricated Material, is neutral with sodium hydroxide regulation system pH value, separates, washing, dry, pulverize and obtain modified Rhizoma Dioscoreae starch.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its Inventive concept equivalent or change in addition, should all be included within the scope of the present invention.

Claims (7)

1. one kind can improved soil permeability farmland fertilizer, it is characterised in that its raw material includes by weight:Potassium breeze 8-16 Part, carbamide 25-45 parts, potash magnesium sulphate fertilizer 16-22 parts, ground phosphate rock 10-20 parts, sodium carboxymethyl cellulose 4-6 parts, the Rhizoma Dioscoreae that is modified are formed sediment Powder 4-10 parts, yellow phosphorus furnace slag 4-8 parts, manioc waste 4-8 parts, the parts of 4-6 containing manganese superphosphate, natural zeolite 2-4 parts, manganese sulfate 1-2 Part, Borax 0.8-1.6 parts, bacillus subtilises 0.003-0.006 parts, phytase 0.002-0.005 parts, Bacillus licheniformis 0.02-0.05 parts, metalloproteases 0.002-0.005 parts, powder of straw 12-20 part, feces of livestock and poultry 20-30 parts, alditol slag 6-10 Part, fertile soil 20-25 parts, conch meal 3-7 parts, Pericarppium arachidis hypogaeae 3-6 parts, cottonseed meal 4-8 parts, water 25-45 parts.
2. according to claim 1 can improved soil permeability farmland fertilizer, it is characterised in that potassium breeze, carbamide, potassium sulfate Fertiliser containing magnesium, ground phosphate rock, sodium carboxymethyl cellulose, the weight ratio of modified Rhizoma Dioscoreae starch are 10-14:30-40:18-20:12-18:4.5- 5.5:6-8.
3. according to claim 1 can improved soil permeability farmland fertilizer, it is characterised in that bacillus subtilises, phytic acid Enzyme, Bacillus licheniformis, the weight ratio of metalloproteases are 4-5:3-4:30-40:3-4.
4. according to claim 1 can improved soil permeability farmland fertilizer, it is characterised in that its raw material is wrapped by weight Include:Potassium breeze 10-14 part, carbamide 30-40 parts, potash magnesium sulphate fertilizer 18-20 parts, ground phosphate rock 12-18 parts, sodium carboxymethyl cellulose 4.5-5.5 parts, be modified Rhizoma Dioscoreae starch 6-8 parts, yellow phosphorus furnace slag 5-7 parts, manioc waste 5-7 parts, the parts of 4.5-5.5 containing manganese superphosphate, Natural zeolite 2.5-3.5 parts, manganese sulfate 1.2-1.6 parts, Borax 1-1.4 parts, bacillus subtilises 0.004-0.005 parts, phytic acid Enzyme 0.003-0.004 parts, Bacillus licheniformis 0.03-0.04 parts, metalloproteases 0.003-0.004 parts, powder of straw 14-18 Part, feces of livestock and poultry 22-28 parts, alditol slag 7-9 part, fertile soil 22-24 parts, conch meal 4-6 parts, Pericarppium arachidis hypogaeae 4-5 parts, cottonseed meal 5- 7 parts, water 30-40 parts.
5. according to claim 1 can improved soil permeability farmland fertilizer, it is characterised in that modified Rhizoma Dioscoreae starch is using such as It is prepared by lower technique:Rhizoma Dioscoreae starch, acetic anhydride, glacial acetic acid mix homogeneously are obtained into the first prefabricated material;Styrene, acrylic acid are mixed Second prefabricated material is obtained uniformly;Potassium peroxydisulfate is soluble in water, logical nitrogen removing air, the second prefabricated material of addition, heated and stirred, from The heart, washing, ultrasonic disperse add toluene, normal heptane stirring in butanol solution, and centrifugation, washing obtain the 3rd prefabricated material;By ice Acetic acid, concentrated sulphuric acid mix homogeneously, are added dropwise under stirring in the first prefabricated material, Deca follow-up continuous stirring completely, stirring In lower feeding water, the 3rd prefabricated material is added, be neutral with sodium hydroxide regulation system pH value, separate, washing dry, pulverize To modified Rhizoma Dioscoreae starch.
6. according to claim 5 can improved soil permeability farmland fertilizer, it is characterised in that modified Rhizoma Dioscoreae starch is using such as It is prepared by lower technique:By weight 25-35 part glacial acetic acid, 35-55 part acetic anhydride, 18-24 part Rhizoma Dioscoreae starch mix homogeneously are obtained First prefabricated material;0.8-1.6 part acrylic acid, 6-12 part styrene mix homogeneously are obtained into the second prefabricated material by weight;By weight Amount part is dissolved in 0.05-0.1 part potassium peroxydisulfates in 45-55 part water, leads to nitrogen and removes air, adds 7-11 the second prefabricated material of part, plus Thermal agitation, centrifugation, washing, ultrasonic disperse add 5-8 part toluene, 2-4 in 60-100 parts concentration is 30-35wt% butanol solutions Part normal heptane stirring, centrifugation, washing obtain the 3rd prefabricated material;By weight 25-35 part glacial acetic acid, 3-5 parts concentrated sulphuric acid are mixed Uniformly, it is added dropwise under stirring in the first prefabricated material of 4-8 parts, Deca follow-up continuous stirring completely sends into 140- under stirring In 180 parts of water, the 3rd prefabricated material of 1.5-2.5 parts is added, be neutral with sodium hydroxide regulation system pH value, separate, washing is done Dry, crushing obtains modified Rhizoma Dioscoreae starch.
7. according to claim 5 can improved soil permeability farmland fertilizer, it is characterised in that modified Rhizoma Dioscoreae starch is using such as It is prepared by lower technique:By weight 25-35 part glacial acetic acid, 35-55 part acetic anhydride, 18-24 part Rhizoma Dioscoreae starch mix homogeneously are obtained First prefabricated material;0.8-1.6 part acrylic acid, 6-12 part styrene mix homogeneously are obtained into the second prefabricated material by weight;By weight Amount part is dissolved in 0.05-0.1 part potassium peroxydisulfates in 45-55 part water, leads to nitrogen and removes air, adds 7-11 the second prefabricated material of part, plus To 88-92 DEG C of stirring 25-35h, mixing speed is 300-500r/min to heat, centrifugation, washing, and ultrasonic disperse is in 60-100 part concentration In 30-35wt% butanol solutions, to add 5-8 part toluene, 2-4 parts normal heptane stirring 35-55min, centrifugation, washing obtain the 3rd Prefabricated material;By weight by 25-35 part glacial acetic acid, 3-5 part concentrated sulphuric acid mix homogeneously, 4-8 parts first under stirring, are added dropwise to In prefabricated material, Deca follow-up continuous stirring 35-55min completely sends under stirring in 140-180 part water, adds 1.5-2.5 parts 3rd prefabricated material, is neutral with sodium hydroxide regulation system pH value, separates, washing, 75-80 DEG C is dried 60-120min, crushes To modified Rhizoma Dioscoreae starch.
CN201611200360.1A 2016-12-22 2016-12-22 Farmland fertilizer for improving permeability of soil Pending CN106588377A (en)

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CN107056499A (en) * 2017-06-06 2017-08-18 安徽云中生态农业开发有限公司 A kind of broccoli breeding method of environmental protection
CN109456132A (en) * 2018-12-30 2019-03-12 重庆天泽兴环境科技有限公司 The preparation method of novel organic mineral substance soil conditioner
WO2019069218A1 (en) 2017-10-04 2019-04-11 Mikroflor Sp. Z O.O., Sp.K. Granulated calcium fertilizer and method for preparing granulated calcium fertilizer
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CN112209778A (en) * 2020-09-26 2021-01-12 上海康恒环境修复有限公司 Novel slag soil conditioner and preparation method thereof

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CN104496712A (en) * 2015-01-16 2015-04-08 山东省农作物种质资源中心 Fertilizer special for green beans and kidney beans and preparation method and fertilizer application method thereof
CN104557208A (en) * 2015-01-16 2015-04-29 山东省农作物种质资源中心 Soybean special fertilizer as well as preparation method and fertilization method thereof
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CN112209778A (en) * 2020-09-26 2021-01-12 上海康恒环境修复有限公司 Novel slag soil conditioner and preparation method thereof

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Application publication date: 20170426