CN106577694A - High efficiency broad-spectrum synergistic pesticide composition based on cycloxaprid and matrine - Google Patents
High efficiency broad-spectrum synergistic pesticide composition based on cycloxaprid and matrine Download PDFInfo
- Publication number
- CN106577694A CN106577694A CN201610924566.2A CN201610924566A CN106577694A CN 106577694 A CN106577694 A CN 106577694A CN 201610924566 A CN201610924566 A CN 201610924566A CN 106577694 A CN106577694 A CN 106577694A
- Authority
- CN
- China
- Prior art keywords
- cycloxaprid
- matrine
- agent
- pesticide composition
- efficiency broad
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a high efficiency broad-spectrum synergistic pesticide composition based on cycloxaprid and matrine. The high efficiency broad-spectrum synergistic pesticide composition includes cycloxaprid, matrine, tea saponin and an assistant, wherein cycloxaprid is hydrophilically-modified cycloxaprid. The high efficiency broad-spectrum synergistic pesticide composition can be water dispersible granules, wettable powder, suspending agent, missible oil, microemulsion, emulsion in water or microcapsule suspension, and is used for control of aphids, whiteflies, plant hoppers, leafhoppers, scale insects, thrips, stink bugs, gall midges, stem borers, spider mites, diamondback moth and noctuid pests. The high efficiency broad-spectrum synergistic pesticide composition adopts cycloxaprid and matrine as the pesticide raw materials, can control a variety of pests at the same time, also can reach a good control effect under a small dosage, has low toxicity to human body and the environment, is partially degradable, and is a green and environment-friendly pesticide.
Description
Technical field
The invention belongs to technical field of pesticide, and in particular to a kind of high-efficiency broad spectrum synergy based on cycloxaprid and matrine
Composition pesticide.
Background technology
Cycloxaprid is a kind of a kind of structure novelty anabasine insecticide by China's independent research, and it is with action target
For the nAChR ligands of insect, there is high-efficiency broad spectrum to act on sucking pest, it is safety low-poison to mammal.Epoxy
Nitro substituent in worm pyridine is cis-configuration, the insecticidal activity and effect matrix with the neonicotinoid insecticide of existing commercialization
Difference, when being conducive to delaying the resistance to medicine characteristic of insect, and the consumption of cycloxaprid to be less than 10 μm of ol/L, action target is still showed
For agonist character.Matrine is a kind of traditional Chinese medicine with heat-clearing and damp-drying drug effect, also has relatively broad in pesticide field
Application.Matrine has stomach toxicity and action of contace poison, can benumb the nerve center brought up again, and makes polypide protein coagulation, blocks gas
Hole, the effects such as have desinsection, sterilization to specific biological such as pine moth, Euproctis pseudoconspersa, cabbage caterpillar insect, and matrine has
Various chemical substances, the mechanism of action is complicated, and the resistance to the action of a drug is good, and other agricultural chemicals no interactions resistances, and can be rapid in the Nature
It is decomposed into carbon dioxide and water, very green, environmental protection.But, due to the particular organisms scope that cycloxaprid and matrine are directed to
Clearly, while specific aim is acted on, also prevention and control field is also subject to certain restrictions.Therefore, generally need in use and it
He is used cooperatively pesticide material, to improve the broad-spectrum antibacterial property of agricultural chemicals.
Tea Saponin also known as tea saponin, tea saponin, tea saponarin, Tea Saponin is the class in saponin, is knitted from Theaceae
A kind of glucoside compound that species or seed are extracted Jing after oil expression in product, basic structure includes aglucon, sugared body
And organic acid.Tea Saponin belongs to the mushroom class of five rings three, is a kind of nonionic surfactant of good performance, and Tea Saponin can be direct
Insecticide, bactericide and acaricide as biological pesticide etc., it is also possible to as a kind of natural environmental-protective type rather want synergist with it is many
Plant mixed pesticide to use, play a part of synergy.The synergy of matrine and Tea Saponin disclosed in Chinese patent CN 102484993B
Composition pesticide, said composition is used for agricultural and garden crop disease and insect prevents aspect, simultaneously simultaneous can control various while occurring
Insect, such as Homoptera, Lepidoptera, Thysanoptera, coleoptera, Diptera, cabbage caterpillar, diamondback moth, trialeurodes vaporariorum, planthopper, aphid,
Yellow rice borer, cigarette aphid etc., also have obvious preventive effect to rice sheath blight disease, pear scab, vegetable downy mildew etc. in addition.By above-mentioned existing
Technology understands that addition Tea Saponin can improve effect of the drug effect of matrine in matrine.
At present, it is cycloxaprid and matrine is actually rare as the pesticide research that primary raw material is compounded.The Shen of the present invention
Ask someone cycloxaprid and matrine as main pesticide material, Tea Saponin prepares a high-efficiency broad spectrum agricultural chemicals as synergist
Composition.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of high-efficiency broad spectrum synergy agriculture based on cycloxaprid and matrine
Drug composition, with cycloxaprid and matrine as main pesticide material in the high-efficiency broad spectrum synergetic pesticide composition, with Tea Saponin
As synergist, aid in forming water dispersible granules, wettable powder, suspending agent, missible oil, microemulsion, water and milk by other auxiliary agents
Agent or micro-capsule suspension, for it is anti-eliminate aphis, aleyrodid, plant hopper, leafhopper, scale insect, thrips, stinkbug, cecidomyiia, snout moth's larva, tetranychid,
Diamondback moth and noctuid insect.High-efficiency broad spectrum synergetic pesticide composition high-efficiency broad spectrum synergy environmental protection prepared by the present invention.
To solve above-mentioned technical problem, the technical scheme is that:
It is a kind of based on cycloxaprid and the high-efficiency broad spectrum synergetic pesticide composition of matrine, it is described based on cycloxaprid and hardship
The high-efficiency broad spectrum synergetic pesticide composition of ginseng alkali includes cycloxaprid, matrine, Tea Saponin and auxiliary agent, the cycloxaprid,
The mass ratio of matrine and Tea Saponin is 1:0.8-1.2:0.01-100, the cycloxaprid is the cycloxaprid of hydrophilic modifying,
The auxiliary agent is wetting agent, dispersant, carrier, disintegrant, adhesive, stabilizer, thickener, antifreezing agent, preservative, froth breaking
Several mixture in agent, emulsifying agent and solvent.
Used as the preferred of above-mentioned technical proposal, the mass ratio of the cycloxaprid, matrine and Tea Saponin is 1:0.8-
1.2:1-50。
Used as the preferred of above-mentioned technical proposal, the high-efficiency broad spectrum Synergistic fertilizer based on cycloxaprid and matrine is combined
Thing is water dispersible granules, wettable powder, suspending agent, missible oil, microemulsion, aqueous emulsion or micro-capsule suspension, and the moisture dissipates
The auxiliary agent of granula includes wetting agent, dispersant, carrier, disintegrant and adhesive, the auxiliary agent of the wettable powder be wetting agent,
Dispersant, stabilizer and carrier, the auxiliary agent of the suspending agent is wetting agent, dispersant, thickener, stabilizer, antifreezing agent, anti-corrosion
Agent, defoamer, the auxiliary agent of the missible oil is emulsifying agent and stabilizer, and the auxiliary agent of the microemulsion is emulsifying agent, stabilizer, antifreeze
Agent and preservative, the auxiliary agent of the aqueous emulsion is emulsifying agent, dispersant, antifreezing agent, preservative and thickener, the microcapsule suspension
The auxiliary agent of agent includes wetting agent, dispersant, thickener, stabilizer, antifreezing agent, preservative and defoamer.
As the preferred of above-mentioned technical proposal, the wetting agent be neopelex, dodecyl phenenyl sulfate,
The series of agriculture breast 2000, Span20, polysorbate60, alkylbenzene APEO, alkylaryl sulfonates, pull open powder, potassium oleate, amber
Sodium dioctyl sulfo, alkyl polyoxyethylene ether sodium sulfonate, sorbitol polyoxyethylene ether, agriculture breast 100, agriculture breast 600, sulphonyl amber
In hydrochlorate, APES, alkyl sulfate, fatty alcohol, spaonin powder, tea seed cake powder, diisooctyl succinic acid sodium sulfonate
One or more of mixture.
Used as the preferred of above-mentioned technical proposal, the dispersant is sodium lignin sulfonate, xylonic acid sulfoacid calcium, alkylnaphthalene sulphur
Hydrochlorate formaldehyde condensation products, pull open powder, ethoxylated dodecyl alcohol, dioctyl sodium sulphosuccinate, alkylphenol ethoxylate,
Polyoxyethylene polyoxypropylene base ether block copolymers, alkyl phenolic group alkylaryl sulfonates, polyoxyethylene groups phosphate, dibutyl
Sodium naphthalene sulfonate, alkylpolyoxyethylene phosphate, polycarboxylate sodium salt, polyaryl polyoxyethylene ether phosphate, oleic acid first
Base aminoethylsulfonic acid sodium, polycarboxylate sodium salt, alkylpolyoxyethylene phosphate, polyaryl phenol polyethenoxy ether phosphoric acid
The mixture of one or more in ester.
Used as the preferred of above-mentioned technical proposal, the carrier is potter's clay, attapulgite, kaolin, diatomite, lightweight carbonic acid
The mixture of one or more in calcium, mud coal, white carbon, montmorillonite.
Used as the preferred of above-mentioned technical proposal, the disintegrant is the chloride of urea, ammonium sulfate, sodium chloride, calcium and aluminium
In one or more of mixture, the adhesive be polyethylene glycol, polyvinyl alcohol, soybean lecithin, gelatin, cyclodextrin,
Starch, stabilizer is the mixture of one or more in alkyl phosphate and its alkoxide, polyvinyl alcohol, potassium phosphate, oozes
Thoroughly agent, bentonite, alkyl phosphate, aryl phosphate ester, phosphorous acid esters, polyalcohol, alkyl sulfonic ester and its substituted ammonium salt, take
The mixture of one or more in for epoxides.
Used as the preferred of above-mentioned technical proposal, the thickener is xanthans, heteroglycan, sodium carboxymethylcellulose, poly- second
The mixture of one or more in enol, gelatin, agar, soluble starch and its derivative, the antifreezing agent be ethylene glycol,
The mixture of one or more in propane diols, glycerine, sucrose, PEG400, polyvinylpyrrolidone, the anti-corrosion
Agent is sodium salicylate, Sodium Benzoate, formaldehyde, and the defoamer is that laurate, palm fibre put one or more in acid, sulfonamide mixed
Compound, the emulsifying agent be ethylene oxide-propylene oxide block copolymer, polyoxyethylene alkylphenyl ether, polyoxyethylene alkyl ether,
The mixing of one or more in alkyl benzene calcium sulfonate, oxirane-fat primary amine condensation product, polyoxyethylene sorbitol glycosides ester
Thing, the solvent is deionized water or ethanol.
Used as the preferred of above-mentioned technical proposal, the high-efficiency broad spectrum Synergistic fertilizer based on cycloxaprid and matrine is combined
Thing is used for control of insect.
Used as the preferred of above-mentioned technical proposal, the insect is aphid, aleyrodid, plant hopper, leafhopper, scale insect, thrips, Chinese toon
As, cecidomyiia, snout moth's larva, tetranychid, diamondback moth and noctuid.
Compared with prior art, the invention has the advantages that:
(1) the high-efficiency broad spectrum synergetic pesticide composition based on cycloxaprid and matrine prepared by the present invention is with cycloxaprid
It is main pesticide material with matrine, using Tea Saponin as synergist, cycloxaprid is different for object with matrine, and
Between the two without resistance, with synergy, and the presence of Tea Saponin can strengthen the wetting of liquid, disperse and open up
Ability, can reach preferable prevention effect, than cycloxaprid, matrine and epoxy in the case of the little consumption of agricultural chemicals
The prevention effect of the mixture of worm pyridine and matrine is all good, reduces the usage amount of agricultural chemicals, extends the resistance to the action of a drug of insect, and drops
The low body burden of environment and personnel, in addition cycloxaprid, matrine, Tea Saponin can degrade under certain environment
Entirely, noresidue, environmental pollution is little, promotes the ecological balance.
(2) containing various in the high-efficiency broad spectrum synergetic pesticide composition based on cycloxaprid and matrine prepared by the present invention
Auxiliary agent, aids in forming water dispersible granules, wettable powder, suspending agent, missible oil, microemulsion, aqueous emulsion or micro- by other auxiliary agents
Capsule suspension, can meet various use demands, suit measures to local conditions to select suitable formulation, make the aphid in various fields, aleyrodid,
Plant hopper, leafhopper, scale insect, thrips, stinkbug, cecidomyiia, snout moth's larva, tetranychid, diamondback moth and noctuid insect are prevented and treated well.
(3) the high-efficiency broad spectrum synergetic pesticide composition based on cycloxaprid and matrine prepared by the present invention is to can be to more
Plant insect to prevent and treat simultaneously, prevention effect is good, and consumption is low, high-efficiency broad spectrum, significantly, environmental protection, toxicity is low for synergistic effect.
Specific embodiment
Describe the present invention, the illustrative examples of the here present invention and explanation in detail below in conjunction with specific embodiment
It is for explaining the present invention but not as a limitation of the invention.
Embodiment 1:
Based on cycloxaprid and the component of the water dispersible granules of the high-efficiency broad spectrum synergetic pesticide composition of matrine, by weight
Percentages, including:Cycloxaprid 50%, matrine 20%, Tea Saponin 14%, neopelex wetting agent 2%, naphthalene
Sodium sulfonate formaldehyde condensation products dispersant 2%, lignin sulfonic acid dipersant 2%, urea disintegrant 2%, polyethylene glycol adhesive
2%th, white carbon black carrier 6%.
Preparation method is:Carrier, wetting agent, dispersant, disintegrant, builder and active compound are mixed by above-mentioned formula rate
Close, ultra-fine grinding mixes with the binder aqueous solution, plastic material is made in immersion kneader bonding, finally sends into material
Granulated in Squeezinggranulator, the high-efficiency broad spectrum Synergistic fertilizer group based on cycloxaprid and matrine is got by dry sieve
The water dispersible granules of compound.
Embodiment 2:
Based on cycloxaprid and the component of the wettable powder of the high-efficiency broad spectrum synergetic pesticide composition of matrine, by weight
Percentages, including:Cycloxaprid 20%, matrine 20%, Tea Saponin 20%, dodecyl sodium sulfate wetting agent 3%, naphthalene sulphur
Sour sodium formaldehyde condensation product dispersant 5%, potassium phosphate 2%, white carbon 10%, kaolin 10%.
Preparation method is:Active compound, builder, auxiliary agent and filling adsorption are well mixed, are crushed by airslide disintegrating mill,
Obtained based on the high-efficiency broad spectrum synergetic pesticide composition of cycloxaprid and matrine by adjusting operating pressure and stream pressure
Wettable powder.
Embodiment 3:
Based on cycloxaprid and the component of the suspending agent of the high-efficiency broad spectrum synergetic pesticide composition of matrine, by weight percentage
Than counting, including:Cycloxaprid 10%, matrine 10%, Tea Saponin 40%, dodecyl sodium sulfate wetting agent 1%, sodium naphthalene sulfonate
Formaldehyde condensation products dispersant 3%, xanthans thickener 0.1%, swelling soil stabilizer 5%, ethylene glycol antifreeze 4%, benzoic acid
Sodium preservative 0.1%, water complements to 100%.
Preparation method is:Active compound, builder, auxiliary agent and water are added in sand mill, frosted 3h is obtained based on epoxy insect
The suspending agent of the high-efficiency broad spectrum synergetic pesticide composition of pyridine and matrine.
Embodiment 4:
Based on cycloxaprid and the component of the missible oil of the high-efficiency broad spectrum synergetic pesticide composition of matrine, by weight percentage
Meter, including:Cycloxaprid 10%, matrine 10%, Tea Saponin 30%, dimethylbenzene 10%, pyrrolidones 5%, detergent alkylate
Sodium sulfonate 5%, By-15 emulsifying agents 4%, OP-20 emulsifying agents 2%, epoxy soybean oil stabilizer 5%, methyl oleate oil are complemented to
100%.
Preparation method:Active compound, builder, auxiliary agent and solvent are put in modulation kettle successively and is mixed, be based on
The missible oil of the high-efficiency broad spectrum synergetic pesticide composition of cycloxaprid and matrine.
Embodiment 5:
Based on cycloxaprid and the component of the microemulsion of the high-efficiency broad spectrum synergetic pesticide composition of matrine, by weight percentage
Than counting, including:Cycloxaprid 10%, matrine 10%, Tea Saponin 30%, dimethylbenzene 8%, n-butanol 5%, agriculture breast 2020 are emulsified
Agent 4%, EPE emulsifying agents 16%, glycerine 4%, water complement to 100%.
Preparation method:Water phase is made after builder, emulsifying agent and n-butanol are mixed with water, active compound is dissolved in into diformazan
In benzole soln, water phase is added, be uniformly mixing to obtain the high-efficiency broad spectrum synergetic pesticide composition based on cycloxaprid and matrine
Microemulsion.
Embodiment 6:
Based on cycloxaprid and the component of the aqueous emulsion of the high-efficiency broad spectrum synergetic pesticide composition of matrine, by weight percentage
Than counting, including:Cycloxaprid 5%, matrine 5%, Tea Saponin 50%, dimethylbenzene 10%, the emulsifying agent 4%, span- of agriculture breast 500
80 emulsifying agents 2%, the emulsifying agent 2% of agriculture breast 2201, glycerine 4%, water complement to 100%.
Preparation method:Builder, emulsifying agent and water are mixed and made into into water phase, active compound are dissolved in xylene solution,
Water phase is added, the aqueous emulsion of the high-efficiency broad spectrum synergetic pesticide composition based on cycloxaprid and matrine is uniformly mixing to obtain.
Embodiment 7:
Based on cycloxaprid and the component of the microcapsule suspending agent of the high-efficiency broad spectrum synergetic pesticide composition of matrine, by weight
Percentages, including:Cycloxaprid 2%, matrine 2%, Tea Saponin 50%, formalin 6.7%, melamine 3.3%, chlorine
Change ammonium 1%, penetrant t wetting agent 2%, naphthalenesulfonic acid-formaldehyde condensate dispersant 4%, xanthans thickener 0.1%, bentonite
Stabilizer 3%, ethylene glycol antifreeze 4%, Sodium Benzoate preservative 0.1%, Shui Shui complement to 100%.
Preparation method:Active compound, auxiliary agent and water are added in sand mill, 3h is processed, it is standby to obtain suspending agent, then weighs three
Under 70 DEG C of water bath conditions, stirring reaction production prepolymer is standby, and prepolymer is poured in suspending agent for poly cyanamid and formalin,
Stirring, adjusts pH value to 4.2, reacts 1.5h, adds 4% 25% ammonium chloride solution, then reacts 0.5h, adjusts pH value to 7.0,
Obtain the microcapsule suspending agent of the high-efficiency broad spectrum synergetic pesticide composition based on cycloxaprid and matrine.
Embodiment 8:Indoor virulence of the high-efficiency broad spectrum synergetic pesticide composition based on cycloxaprid and matrine to cotten aphid
Test
The high-efficiency broad spectrum synergetic pesticide composition for being based on cycloxaprid and matrine is determined to cotten aphid using band worm leaf dipping method
Toxicity action, by the rose of Sharon blade of cotten aphid be separately immersed in embodiment 1-7 preparation based on cycloxaprid and the height of matrine
10s in effect wide-spectrum synergy composition pesticide, dries naturally after taking-up, in being then placed in the culture dish for transferring filter paper by telegram, uses preservative film
Sealing, and it is ventilative to prick hole with pin.Blake bottle is placed in into temperature for 25 DEG C, periodicity of illumination is L:D=16:8, relative humidity is 60-
Raise in 70% incubator.24 as a child checked dead borer population, were calculated LC50, and the result of test is as follows:
Embodiment 9:
Field control effectiveness test
Reagent agent:Embodiment 1-7 based on cycloxaprid and the high-efficiency broad spectrum synergetic pesticide composition of matrine.
For studying thing:Cotton field, water and fertilizer condition is good, Bemisia tabaci occurs seriously.
Prevent and kill off object:Bemisia tabaci.
Test method:Reagent agent dilutes 1000 times, by area 667m2 water 45kg, carries out a cotton leaf positive and negative
Face even spraying, using 5 point samplings, per takes 10 cotton leafs, and 1 after medicine, 3,7,14d observe the anti-of each medicament
Effect, separately sets a blank district, not dispenser.
After testing, the high-efficiency broad spectrum synergetic pesticide composition based on cycloxaprid and matrine that prepared by embodiment 1-7
The result of preventive effect is as follows:
Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | |
1st day anti-efficiency (%) | 83.7 | 86.2 | 75.9 | 60.4 | 51.2 | 52.4 | 53.4 |
3rd day anti-efficiency (%) | 84.6 | 84.7 | 75.7 | 61.4 | 51.6 | 50.4 | 52.5 |
7th day anti-efficiency (%) | 85.2 | 85.6 | 76.0 | 63.5 | 52.0 | 50.5 | 51.2 |
14th day anti-efficiency (%) | 83.0 | 86.0 | 74.2 | 62.0 | 52.3 | 50.0 | 50.7 |
Embodiment 10:
Field control effectiveness test
Reagent agent:Embodiment 1-7 based on cycloxaprid and the high-efficiency broad spectrum synergetic pesticide composition of matrine.
For studying thing:Vineyard, water and fertilizer condition is good, grape leafhopper occurs seriously.
Prevent and kill off object:Leafhopper.
Test method:Reagent agent dilutes 1000 times, by area 667m2Water 45kg is used, a cotton leaf is carried out positive and negative
Face even spraying, using 5 point samplings, per takes 10 cotton leafs, and 1 after medicine, 3,7,14d observe the anti-of each medicament
Effect, separately sets a blank district, not dispenser.
After testing, the high-efficiency broad spectrum synergetic pesticide composition based on cycloxaprid and matrine that prepared by embodiment 1-7
The result of preventive effect is as follows:
Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | |
1st day anti-efficiency (%) | 91.3 | 88.4 | 75.2 | 62.4 | 53.4 | 50.2 | 49.8 |
3rd day anti-efficiency (%) | 93.6 | 91.2 | 70.3 | 63.4 | 55.6 | 51.7 | 50.2 |
7th day anti-efficiency (%) | 98.5 | 93.5 | 71.4 | 60.2 | 55.7 | 50.6 | 51.2 |
14th day anti-efficiency (%) | 90.2 | 90.2 | 72.5 | 61.5 | 54.2 | 51.2 | 50.7 |
As seen from the above table, in the high-efficiency broad spectrum synergetic pesticide composition based on cycloxaprid and matrine that prepared by the present invention
Good based on cycloxaprid and matrine Synergistic herbicidal effect, the synergy of Tea Saponin achieves noticeable achievement, and cycloxaprid and matrine contain
Amount and the higher agricultural chemicals of Tea Saponin are better to the prevention effect of insect.
The principle and its effect of above-described embodiment only illustrative present invention, it is of the invention not for limiting.It is any ripe
Know the personage of this technology all can carry out modifications and changes under the spirit and the scope without prejudice to the present invention to above-described embodiment.Cause
This, such as those of ordinary skill in the art is complete with institute under technological thought without departing from disclosed spirit
Into all equivalent modifications or change, should by the present invention claim be covered.
Claims (10)
1. a kind of based on cycloxaprid and the high-efficiency broad spectrum synergetic pesticide composition of matrine, it is characterised in that:It is described based on ring
The high-efficiency broad spectrum synergetic pesticide composition of the pyridine of oxygen worm and matrine includes cycloxaprid, matrine, Tea Saponin and auxiliary agent, described
The mass ratio of cycloxaprid, matrine and Tea Saponin is 1:0.8-1.2:0.01-100, the cycloxaprid is hydrophilic modifying
Cycloxaprid, the auxiliary agent is wetting agent, dispersant, carrier, disintegrant, adhesive, stabilizer, thickener, antifreezing agent, anti-corrosion
Several mixture in agent, defoamer, emulsifying agent and solvent.
2. according to claim 1 a kind of based on cycloxaprid and the high-efficiency broad spectrum synergetic pesticide composition of matrine, its
It is characterised by:The mass ratio of the cycloxaprid, matrine and Tea Saponin is 1:0.8-1.2:1-50.
3. according to claim 1 a kind of based on cycloxaprid and the high-efficiency broad spectrum synergetic pesticide composition of matrine, its
It is characterised by:The high-efficiency broad spectrum synergetic pesticide composition based on cycloxaprid and matrine is water dispersible granules, wettable
Pulvis, suspending agent, missible oil, microemulsion, aqueous emulsion or micro-capsule suspension, the auxiliary agent of the water dispersible granules include wetting agent,
Dispersant, carrier, disintegrant and adhesive, the auxiliary agent of the wettable powder is wetting agent, dispersant, stabilizer and carrier,
The auxiliary agent of the suspending agent be wetting agent, dispersant, thickener, stabilizer, antifreezing agent, preservative, defoamer, the missible oil
Auxiliary agent is emulsifying agent and stabilizer, and the auxiliary agent of the microemulsion is emulsifying agent, stabilizer, antifreezing agent and preservative, the water and milk
The auxiliary agent of agent is emulsifying agent, dispersant, antifreezing agent, preservative and thickener, the auxiliary agent of the microcapsule suspending agent include wetting agent,
Dispersant, thickener, stabilizer, antifreezing agent, preservative and defoamer.
4. according to claim 3 a kind of based on cycloxaprid and the high-efficiency broad spectrum synergetic pesticide composition of matrine, its
It is characterised by:The wetting agent is neopelex, dodecyl phenenyl sulfate, the series of agriculture breast 2000, Span20, tells
Temperature 60, alkylbenzene APEO, alkylaryl sulfonates, pull open powder, potassium oleate, dioctyl sodium sulfosuccinate, alkyl gather
Oxygen vinethene sodium sulfonate, sorbitol polyoxyethylene ether, agriculture breast 100, agriculture breast 600, sulphonyl succinate, alkylphenol-polyethenoxy
The mixing of one or more in ether, alkyl sulfate, fatty alcohol, spaonin powder, tea seed cake powder, diisooctyl succinic acid sodium sulfonate
Thing.
5. according to claim 3 a kind of based on cycloxaprid and the high-efficiency broad spectrum synergetic pesticide composition of matrine, its
It is characterised by:The dispersant be sodium lignin sulfonate, xylonic acid sulfoacid calcium, alkylnaphthalene sulfonate formaldehyde condensation products, pull open powder,
Ethoxylated dodecyl alcohol, dioctyl sodium sulphosuccinate, alkylphenol ethoxylate, polyoxyethylene polyoxypropylene base ether are embedding
Section copolymer, alkyl phenolic group alkylaryl sulfonates, polyoxyethylene groups phosphate, nekal, dodecyl polyoxy
Ethene ether phosphate, polycarboxylate sodium salt, polyaryl polyoxyethylene ether phosphate, oleic acid methylaminoethyl sodium sulfonate, poly- carboxylic
One or more in sodium salt, alkylpolyoxyethylene phosphate, polyarylphenol-polyoxyethylene ether phosphate it is mixed
Compound.
6. according to claim 3 a kind of based on cycloxaprid and the high-efficiency broad spectrum synergetic pesticide composition of matrine, its
It is characterised by:The carrier is potter's clay, attapulgite, kaolin, diatomite, precipitated calcium carbonate, mud coal, white carbon, montmorillonite
In one or more of mixture.
7. according to claim 3 a kind of based on cycloxaprid and the high-efficiency broad spectrum synergetic pesticide composition of matrine, its
It is characterised by:The disintegrant is the mixture of one or more in the chloride of urea, ammonium sulfate, sodium chloride, calcium and aluminium,
The adhesive is polyethylene glycol, polyvinyl alcohol, soybean lecithin, gelatin, cyclodextrin, starch, and stabilizer is alkyl phosphate
And its mixture of one or more in alkoxide, polyvinyl alcohol, potassium phosphate, bleeding agent, bentonite, alkyl phosphate,
One kind or many in aryl phosphate ester, phosphorous acid esters, polyalcohol, alkyl sulfonic ester and its substituted ammonium salt, substituted epoxide
The mixture planted.
8. according to claim 3 a kind of based on cycloxaprid and the high-efficiency broad spectrum synergetic pesticide composition of matrine, its
It is characterised by:The thickener is xanthans, heteroglycan, sodium carboxymethylcellulose, polyvinyl alcohol, gelatin, agar, soluble shallow lake
The mixture of one or more in powder and its derivative, the antifreezing agent is ethylene glycol, propane diols, glycerine, sucrose, poly- second
The mixture of one or more in glycol 400, polyvinylpyrrolidone, the preservative is sodium salicylate, Sodium Benzoate, first
Aldehyde, the defoamer is laurate, the brown mixture for putting one or more in acid, sulfonamide, and the emulsifying agent is epoxy second
Alkane-propylene oxide block copolymer, polyoxyethylene alkylphenyl ether, polyoxyethylene alkyl ether, alkyl benzene calcium sulfonate, oxirane-
The mixture of one or more in fat primary amine condensation product, polyoxyethylene sorbitol glycosides ester, the solvent is deionized water
Or ethanol.
9. according to claim 1 a kind of based on cycloxaprid and the high-efficiency broad spectrum synergetic pesticide composition of matrine, its
It is characterised by:The high-efficiency broad spectrum synergetic pesticide composition based on cycloxaprid and matrine is used for control of insect.
10. according to claim 9 a kind of based on cycloxaprid and the high-efficiency broad spectrum synergetic pesticide composition of matrine, its
It is characterised by:The insect is aphid, aleyrodid, plant hopper, leafhopper, scale insect, thrips, stinkbug, cecidomyiia, snout moth's larva, tetranychid, diamondback moth
And noctuid.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610924566.2A CN106577694A (en) | 2016-10-24 | 2016-10-24 | High efficiency broad-spectrum synergistic pesticide composition based on cycloxaprid and matrine |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610924566.2A CN106577694A (en) | 2016-10-24 | 2016-10-24 | High efficiency broad-spectrum synergistic pesticide composition based on cycloxaprid and matrine |
Publications (1)
Publication Number | Publication Date |
---|---|
CN106577694A true CN106577694A (en) | 2017-04-26 |
Family
ID=58556324
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610924566.2A Withdrawn CN106577694A (en) | 2016-10-24 | 2016-10-24 | High efficiency broad-spectrum synergistic pesticide composition based on cycloxaprid and matrine |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106577694A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107347903A (en) * | 2017-09-13 | 2017-11-17 | 佛山市瑞生通科技有限公司 | A kind of composition pesticide containing cycolxylidin and matrine |
CN109665789A (en) * | 2019-01-22 | 2019-04-23 | 广西大学 | A kind of glass fibre coral marine sand concrete and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101747320A (en) * | 2008-12-19 | 2010-06-23 | 华东理工大学 | Dialdehyde-built disinsection activity-having nitrogen or oxygen-containing heterocyclic compound and preparation method |
CN102197807A (en) * | 2011-03-31 | 2011-09-28 | 上海生农生化制品有限公司 | Cycloxaprid wettable powder and preparation method thereof |
CN102484993A (en) * | 2010-12-02 | 2012-06-06 | 华南农业大学 | Synergistic pesticide composition of matrine and tea saponin |
-
2016
- 2016-10-24 CN CN201610924566.2A patent/CN106577694A/en not_active Withdrawn
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101747320A (en) * | 2008-12-19 | 2010-06-23 | 华东理工大学 | Dialdehyde-built disinsection activity-having nitrogen or oxygen-containing heterocyclic compound and preparation method |
CN102484993A (en) * | 2010-12-02 | 2012-06-06 | 华南农业大学 | Synergistic pesticide composition of matrine and tea saponin |
CN102197807A (en) * | 2011-03-31 | 2011-09-28 | 上海生农生化制品有限公司 | Cycloxaprid wettable powder and preparation method thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107347903A (en) * | 2017-09-13 | 2017-11-17 | 佛山市瑞生通科技有限公司 | A kind of composition pesticide containing cycolxylidin and matrine |
CN109665789A (en) * | 2019-01-22 | 2019-04-23 | 广西大学 | A kind of glass fibre coral marine sand concrete and preparation method thereof |
CN109665789B (en) * | 2019-01-22 | 2021-03-30 | 广西大学 | Glass fiber coral sea sand concrete and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101595882B (en) | Pesticide composition containing methoxyl acrylic ester bactericide | |
CN101642117A (en) | Pesticidal composition with synergistic effect | |
CN101268779A (en) | Insecticidal composition containing chlorantraniliprole and monosultap | |
CN101642104A (en) | Sterilization composition containing fenoxanil | |
CN105010358A (en) | Bactericidal composition and application thereof | |
CN101658175A (en) | Pesticide composition and application thereof | |
CN105211075A (en) | Bactericidal composition and application thereof | |
CN106577694A (en) | High efficiency broad-spectrum synergistic pesticide composition based on cycloxaprid and matrine | |
CN102919251B (en) | Bactericidal composition containing benthiavalicarb isopropyl and captan | |
CN102246766A (en) | Insecticidal composition containing flonicamid and pymetrozine | |
CN102047915A (en) | Insecticidal composition containing thiacloprid amide | |
CN102754651A (en) | Acaricide and application thereof | |
CN102228056B (en) | Pesticide composition containing sulfur-fluorine oxime ether and part of organophosphorus pesticides | |
CN102228044B (en) | Insecticidal composition containing sufluoxime | |
CN105052997B (en) | A kind of composition pesticide and bactericide containing toxic fluoride phosphate and antimicrobial fungicides | |
CN102246778A (en) | Efficiency enhanced insecticidal composition, and application thereof | |
CN102210320A (en) | Sulfoxaflor-containing insecticidal composition | |
CN104996458A (en) | Pesticide composition and applications thereof | |
CN101617676A (en) | Pesticide compound | |
CN102972402B (en) | Kasugamycin-containing pesticide composition | |
CN102239875A (en) | Insecticidal composition containing 1-(3-fluoro-4-chlorphenyl)-2-methylthioethanone-O-(2-hydroxymethyl-3-methyl)aether and partial nicotine compounds | |
CN104957158B (en) | A kind of Herbicidal combinations of Han oxaziclomefones and benthiocarb | |
CN105104396B (en) | A kind of composition pesticide containing rosickyite azoles and amino-oligosaccharide | |
CN104430390A (en) | Amino-oligosaccharin and ethaboxam compounded agricultural fungicide | |
CN105076179B (en) | A kind of composition pesticide containing rosickyite azoles and iprodione |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170426 |
|
WW01 | Invention patent application withdrawn after publication |