CN106568520A - High temperature sensitive ceramic armored high-temperature thermocouple and manufacture method thereof - Google Patents

High temperature sensitive ceramic armored high-temperature thermocouple and manufacture method thereof Download PDF

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Publication number
CN106568520A
CN106568520A CN201610971660.3A CN201610971660A CN106568520A CN 106568520 A CN106568520 A CN 106568520A CN 201610971660 A CN201610971660 A CN 201610971660A CN 106568520 A CN106568520 A CN 106568520A
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China
Prior art keywords
thermocouple
ceramic
sleeve pipe
carbon fiber
terminal box
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CN201610971660.3A
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Inventor
甘常松
熊朝阳
黎正熙
李召
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Ningbo Jingfeng Measurement And Control Technology Co Ltd
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Ningbo Jingfeng Measurement And Control Technology Co Ltd
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Priority to CN201610971660.3A priority Critical patent/CN106568520A/en
Publication of CN106568520A publication Critical patent/CN106568520A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01KMEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
    • G01K7/00Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements
    • G01K7/02Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements using thermoelectric elements, e.g. thermocouples
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01KMEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
    • G01K1/00Details of thermometers not specially adapted for particular types of thermometer
    • G01K1/08Protective devices, e.g. casings

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Ceramic Products (AREA)

Abstract

The invention discloses a high temperature sensitive ceramic armored high-temperature thermocouple and a manufacture method thereof. The thermocouple is composed of a conjunction box, a cover casing, terminals, a protective bushing, a sealing strip, an insulating layer, a lead wire, a thermocouple wire and insulators; the protective bushing of a cylindrical hollow structure is made of alumina based high temperature ceramics, a carbon fiber basket is integrated in a ceramic body of the protective bushing, a central wire bundle of the carbon fiber basket extends out of the center of the bottom of the cylindrical hollow structure, a work end is connected with the exceeding end of the carbon fiber basket, and the center of an opening end is connected with the lead wire; the lead wire is formed by braiding silicon carbide based ceramic fibers; the sealing strip is made of a high-temperature adhesive HN-767A; an enclosed space formed by the protective bushing, the high temperature adhesive and the conjunction box is of a vacuum environment ranging from 1Pa to 10Pa; and the thermocouple wire is a nickel chromium silicon-nickel silicon thermocouple wire. The thermocouple of the invention can replace an expensive platinum rhodium thermocouple, the economic performance and the reliability are high, and the service life is long.

Description

High-temperature sensitive ceramic armouring pyrometer couple and its manufacture method
Technical field
The present invention relates to temperature sensor field, more particularly to a kind of high-temperature sensitive ceramic armouring pyrometer couple and its Manufacture method.
Background technology
For the Thermal-resistance tool Heat-Treatment of Steel such as heat resisting steel and high-speed steel (treatment temperature typically 1100 DEG C -1350 DEG C it Between) when, it is only capable of at present using platinum rhodium thermocouple (B idols, S occasionally R idols) as heat treatment thermometric idol, according to American army mark AMS The requirement of 2750E, needs altogether three thermocouples even as normalization, it is well known that platinum rhodium thermocouple price during high-temperature heat treatment Expensive (armouring platinum rhodium single of wholesale price of idol is minimum 1500 yuan, also only the S idols of rhodium-containing 10%), therefore be further increased Financial cost.More it is to be noted that in fact domestic platinum rhodium thermocouple routine is typically only capable of reaching 1200 DEG C using temperature, length Shi Chaowen will be substantially reduced using its service life and performance;And it is typically used as the even nickel chromium triangle silicon-nisiloys of N, although cheap, Durable, reliability is high, and theory uses temperature, but its at high temperature the characteristic of oxidizable failure be allowed to cannot be at conventional high temperature heat Used in reason, less than 1100 DEG C thermometrics are typically only used for.
In the Patents applied at home, also not by nickel chromium triangle silicon-nisiloy thermo wires for pyrometric patent money Material, in close patent document, patent《A kind of pyrometer couple》(application number:201610136518.7, publication date:2016-07- 20) a kind of structure of the pyrometer couple for being all ceramic protective sleeve pipe, is disclosed, but wherein there are 2 problems:1. platinum is still adopted Rhodium thermocouple, economy is bad;2. its protection outer tube adopts silicon carbide ceramics, although silicon carbide ceramics thermal conductivity is compared to other For ceramics very well, the characteristic that only its fragility is high, the difficult porosity of shaping is big makes its fragile, reliability when as protection sleeve pipe Difference, while tend to have molecule and invading, damaging its internal platinum rhodium precious metal structure, service life is short.
The content of the invention
To solve drawbacks described above present in prior art, the present invention is intended to provide a kind of alternative expensive platinum rhodium thermocouple Good economy performance, reliability high, the high-temperature sensitive ceramic armouring pyrometer couple of long service life and its manufacture method.
To achieve these goals, the present invention is employed the following technical solutions:A kind of high warm of high-temperature sensitive ceramic armouring Galvanic couple, by terminal box, the case that is fixed on terminal box edge, the binding post being fixed in terminal box, protection sleeve pipe, is arranged on guarantor Band between protecting pipe and terminal box, the insulating barrier for being fixed on protection internal surface of casing, lead, respectively with lead and wiring The thermocouple thermo wires of post connection, the insulator composition being interspersed on thermocouple thermo wires, wherein:The protection sleeve pipe adopts aluminum oxide Based high temperature ceramic is made, and protection sleeve pipe is hollow structure, and the hollow structure is cylindrical, protects the internal collection of ceramics of sleeve pipe Ceramic body is stretched out from the bottom center of cylindrical hollow structure into the centralized bunch for having carbon fiber basket, carbon fiber basket, The centralized bunch is lead;The band is manufactured using high-temp glue HN-767A, and the high-temp glue is by terminal box and protective case Gap between pipe is filled up completely with;The confined space that protection sleeve pipe, high-temp glue and terminal box are constituted is the vacuum ring of 1Pa~10Pa Border;Thermocouple thermo wires is the nicrosil nisil thermocouple thermo wires that conventional N is occasionally adopted.
The manufacture method of above-mentioned high-temperature sensitive ceramic armouring pyrometer couple, comprises the following steps:
1) preparation of raw material, equipment and frock
1. raw material:Prepare it is enough containing mass fraction for 8%-10% aluminate adhesives alumina-based ceramic powder, The nickel chromium triangle that enough carbon fibers, routinely technology are interted and are fixed with insulator and connected both positive and negative polarity thermo wires by intermediate connection point Silicon-Nickel-Silicom thermocouple thermo wires, the terminal box, high-temp glue HN-767A that are mounted with case and binding post;
2. equipment and frock;Prepare vacuum ceramic sintering furnace;Ceramic post sintering mould;Vacuum packaging equipment;Baking oven;
2) including the thermometric end shaping structures of protection sleeve pipe, carbon fiber basket and lead
1. ready alumina-based ceramic powder is fitted in ceramic post sintering mould, until by ceramic post sintering mold bottom Filling is full;
2. carbon fiber is woven into into basket, and the embedment of basket bottom is loaded with into the ceramic post sintering of alumina-based ceramic powder In mold bottom, length of embedment is basket outer away from ceramic post sintering die surface 0.4mm-0.7mm, then alumina base is made pottery in employing Porcelain powder is full by the filling of ceramic post sintering mould and flattens, be compacted, and retains the centralized bunch of carbon fiber basket from body of powder center Stretch out;
3. it is sintered in vacuum ceramic sintering furnace, 1800 DEG C -1850 DEG C of sintering temperature, heating rate room temperature -1000 DEG C stage heating rate is 10 DEG C/min-30 DEG C/min, 1000 DEG C of -1300 DEG C of stage heating rates are 8 DEG C/min-15 DEG C/ Min, 1300 DEG C to thermophase heating rate be 3 DEG C/min-5 DEG C/min, temperature retention time 4-6h to after temperature, insulation terminate after with The speed of not higher than 25 DEG C/min is come out of the stove after being cooled to not higher than 200 DEG C, the thermometric end structure of shaping needed for obtaining after the demoulding;
3) encapsulate
1. it is packaged in vacuum packaging equipment, keeps vacuum 1Pa~10Pa, brushes in protection sleeve pipe first exhausted Edge layer;Then lead is connected with both positive and negative polarity thermocouple thermo wires tie point that is interspersed and being fixed with insulator successively, by both positive and negative polarity Thermocouple thermo wires is connected respectively with two binding posts being fixed in terminal box;Again protection sleeve pipe and terminal box are adopted into high-temp glue HN-767A is fixed together and seals, that is, the thermocouple after being encapsulated;
4) stabilization processes
1. by step 3) thermocouple after the encapsulation that obtains is placed in baking oven, is heated to 200 DEG C -250 DEG C, insulation 30min-50min, i.e., final required acquisition high-temperature sensitive ceramic armouring pyrometer couple.
Compared with prior art, the present invention has advantages below:Using nicrosil nisil thermocouple thermo wires, drop significantly Low manufacturing cost;Using alumina-based ceramic manufacture protection sleeve pipe, compactness is good, shock resistance, high temperature resistant, be integrated with it Carbon fiber basket, carbon fiber can fundamentally overcome alumina-based ceramic to lead as the best material of existing known thermal conductivity Hot poor defect, the temperature sensitivity for making the present invention is greatly improved, using the carbon fiber of high heat conduction directly as heat carrier And lead, sensing carbon fiber temperature and by temperature conduction to lead, significant increase thermocouple makes integrally to the sensitiveness of temperature Reaction it is rapider, accurately, performance is more preferable;Worked under vacuum conditions completely using nicrosil nisil thermocouple thermo wires, Due to vacuum ranges 1Pa-10Pa, the vacuum both can ensure that thermo wires was not aoxidized at high temperature, again will not be due to vacuum Too high and cause composition to volatilize at high temperature, its invalid temperature (i.e. maximum operation (service) temperature) can be promoted to 1400 DEG C, and not have Other factorses cause it to fail, and reliability is high, overcomes nicrosil nisil thermocouple thermo wires and cannot be used for 1300 DEG C of high temperature above The technology prejudice measured when long;Sealed using high-temp glue HN-767A, on the one hand Volume Changes pole after the high temperature gum forming Little, air-tightness is good, adhesion is strong, and on the other hand the high-temp glue uses temperature up to 1700 DEG C, will not be old because using under high temperature Change or oxidation deactivation;Due to the heat-resisting, durable of present invention employing, anti-seismic structure and material, the service life of the present invention is made significantly Improve.
Description of the drawings
Fig. 1 is the structural representation of the present invention;
Fig. 2 is the top view of carbon fiber basket;
In figure:Case 1, binding post 2, terminal box 3, band 4, insulating barrier 5, insulator 6, thermocouple thermo wires 7, lead 8, Carbon fiber basket 9, protection sleeve pipe 10.
Specific embodiment
Embodiment 1:
A kind of high-temperature sensitive ceramic armouring pyrometer couple, by terminal box 3, be fixed on the edge of terminal box 3 case 1, It is the binding post 2 that is fixed in terminal box 3, protection sleeve pipe 10, the band 4 being arranged between protection sleeve pipe 10 and terminal box 3, solid It is scheduled on the protection insulating barrier 5 of the inner surface of sleeve pipe 10, lead 8, the thermocouple thermo wires 7 being connected with lead 8 and binding post 2 respectively, wears The insulator 6 being inserted on thermocouple thermo wires 7 is constituted, wherein:The protection sleeve pipe 10 is made using alumina base refractory ceramics, protects Protecting pipe 10 is hollow structure, and the hollow structure is cylindrical, and the ceramics for protecting sleeve pipe 10 are integrated with vivo carbon fibre web Basket 9, the centralized bunch of carbon fiber basket 9 stretches out ceramic body from the bottom center of cylindrical hollow structure, the central boundling Line is lead 8;The band 4 using high-temp glue HN-767A manufacture, the high-temp glue by terminal box 3 with protection sleeve pipe 10 it Between gap be filled up completely with;The confined space that protection sleeve pipe 10, high-temp glue and terminal box 3 are constituted is the vacuum ring of 1Pa~10Pa Border;Thermocouple thermo wires 7 is the nicrosil nisil thermocouple thermo wires 7 that routine N is occasionally adopted.
The manufacture method of above-mentioned high-temperature sensitive ceramic armouring pyrometer couple, comprises the following steps:
1) preparation of raw material, equipment and frock
1. raw material:Prepare enough containing the alumina-based ceramic powder, enough carbon that mass fraction is 8% aluminate adhesive Nickel chromium triangle silicon-nickel that fiber, routinely technology are interted and are fixed with insulator 6 and connected both positive and negative polarity thermo wires by intermediate connection point Silicon thermocouple thermo wires 7, the terminal box 3, high-temp glue HN-767A for being mounted with case 1 and binding post 2;
2. equipment and frock:Prepare vacuum ceramic sintering furnace;Ceramic post sintering mould;Vacuum packaging equipment;Baking oven;
2) including the thermometric end shaping structures of protection sleeve pipe 10, carbon fiber basket 9 and lead 8
1. ready alumina-based ceramic powder is fitted in ceramic post sintering mould, until by ceramic post sintering mold bottom Filling is full;
2. carbon fiber is woven into into basket, and the embedment of basket bottom is loaded with into the ceramic post sintering of alumina-based ceramic powder In mold bottom, length of embedment be basket outer away from ceramic post sintering die surface 0.7mm, then using by alumina-based ceramic powder Ceramic post sintering mould is filled full and flattened, be compacted, the centralized bunch for retaining carbon fiber basket 9 stretches out from body of powder center;
3. it is sintered in vacuum ceramic sintering furnace, 1800 DEG C of sintering temperature, -1000 DEG C of stage liters of heating rate room temperature Warm speed is 10 DEG C/min, and 1000 DEG C of -1300 DEG C of stage heating rates are 8 DEG C/min, and 1300 DEG C to thermophase heating rate For 3 DEG C/min, temperature retention time 4h to after temperature, it is incubated after being cooled to 200 DEG C with the speed of 25 DEG C/min after terminating and comes out of the stove, after the demoulding i.e. The thermometric end structure of shaping needed for obtaining;
3) encapsulate
1. it is packaged in vacuum packaging equipment, keeps vacuum 1Pa, brushes insulating barrier in protection sleeve pipe 10 first 5;Then lead 8 is connected with openend center successively, by lead 8 and both positive and negative polarity thermocouple that is interspersed and being fixed with insulator 6 The tie point of thermo wires 7 connects, is connected both positive and negative polarity thermocouple thermo wires 7 with two binding posts 2 being fixed in terminal box 3 respectively;Again Protection sleeve pipe 10 is fixed together using high-temp glue HN-767A and is sealed with terminal box 3, that is, the thermocouple after being encapsulated;
4) stabilization processes
1. by step 3) thermocouple after the encapsulation that obtains is placed in baking oven, is heated to 200 DEG C, is incubated 30min, i.e., most High-temperature sensitive ceramic armouring pyrometer couple is obtained needed for eventually.
Use temperature up to 1400 DEG C when the thermocouple produced by the present embodiment is most greatly enhanced, intensity is high, fragility is low, shock resistance By force, reliability height, long service life;With high temperature sensitivity and good resistance to elevated temperatures.
Embodiment 2:
The present embodiment structure is same as Example 1 with most of method and step, as follows at difference:
1) preparation of raw material, equipment and frock
1. raw material:Prepare it is enough containing the alumina-based ceramic powder that mass fraction is 10% aluminate adhesive, it is enough The nickel chromium triangle silicon that carbon fiber, routinely technology are interted and are fixed with insulator 6 and connected both positive and negative polarity thermo wires by intermediate connection point- Nickel-Silicom thermocouple thermo wires 7, the terminal box 3, high-temp glue HN-767A for being mounted with case 1 and binding post 2;
2. equipment and frock:Prepare vacuum ceramic sintering furnace;Ceramic post sintering mould;Vacuum packaging equipment;Baking oven;
2) including the thermometric end shaping structures of protection sleeve pipe 10, carbon fiber basket 9 and lead 8
1. ready alumina-based ceramic powder is fitted in ceramic post sintering mould, until by ceramic post sintering mold bottom Filling is full;
2. carbon fiber is woven into into basket, and the embedment of basket bottom is loaded with into the ceramic post sintering of alumina-based ceramic powder In mold bottom, length of embedment be basket outer away from ceramic post sintering die surface 0.4mm, then using by alumina-based ceramic powder Ceramic post sintering mould is filled full and flattened, be compacted, the centralized bunch for retaining carbon fiber basket 9 stretches out from body of powder center;
3. it is sintered in vacuum ceramic sintering furnace, 1850 DEG C of sintering temperature, -1000 DEG C of stage liters of heating rate room temperature Warm speed is 30 DEG C/min, and 1000 DEG C of -1300 DEG C of stage heating rates are 15 DEG C/min, and 1300 DEG C to thermophase heating rate For 5 DEG C/min, temperature retention time 6h to after temperature, it is incubated after being cooled to 180 DEG C with the speed of 20 DEG C/min after terminating and comes out of the stove, after the demoulding i.e. The thermometric end structure of shaping needed for obtaining;
3) encapsulate
1. it is packaged in vacuum packaging equipment, keeps vacuum 10Pa, brushes insulation in protection sleeve pipe 10 first Layer 5;Then lead 8 is connected with openend center successively, by lead 8 and both positive and negative polarity thermoelectricity that is interspersed and being fixed with insulator 6 The tie point of thermo wires 7 connects, is connected both positive and negative polarity thermocouple thermo wires 7 with two binding posts 2 being fixed in terminal box 3 respectively; Again protection sleeve pipe 10 is fixed together using high-temp glue HN-767A and is sealed with terminal box 3, that is, the thermoelectricity after being encapsulated It is even;
4) stabilization processes
1. by step 3) thermocouple after the encapsulation that obtains is placed in baking oven, is heated to 250 DEG C, is incubated 50min, i.e., most High-temperature sensitive ceramic armouring pyrometer couple is obtained needed for eventually.
By the present embodiment 2 produce thermocouple compared to embodiment 1 for, its maximum use high 30 DEG C or so of temperature, temperature Degree sensitiveness is also higher, but service life and reliability are relatively poor.
The foregoing description of the disclosed embodiments, only for enabling professional and technical personnel in the field to realize or using this Invention.Various modifications to these embodiments will be apparent for those skilled in the art, institute herein The General Principle of definition can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, The present invention is not intended to be limited to the embodiments shown herein, and is to fit to special with principles disclosed herein and novelty The consistent most wide scope of point.

Claims (2)

1. a kind of high-temperature sensitive ceramic armouring pyrometer couple, by terminal box (3), is fixed on the case at terminal box (3) edge (1) binding post (2) that, is fixed in terminal box (3), protection sleeve pipe (10), be arranged on protection sleeve pipe (10) and terminal box (3) it Between band (4), be fixed on the protection insulating barrier (5) of sleeve pipe (10) inner surface, lead (8), respectively with lead (8) and wiring The thermocouple thermo wires (7) of post (2) connection, insulator (6) composition being interspersed on thermocouple thermo wires (7), it is characterised in that;It is described Protection sleeve pipe (10) is made using alumina base refractory ceramics, and protection sleeve pipe (10) is hollow structure, and the hollow structure is circle Cylinder shape, the ceramics for protecting sleeve pipe (10) are integrated with vivo carbon fiber basket (9), the centralized bunch of carbon fiber basket (9) from Ceramic body stretches out in the bottom center of cylindrical hollow structure, and the centralized bunch is lead (8);The band (4) is adopted Manufactured with high-temp glue HN-767A, the high-temp glue is filled up completely with the gap between terminal box (3) and protection sleeve pipe (10);Protection The confined space that sleeve pipe (10), high-temp glue and terminal box (3) are constituted is the vacuum environment of 1Pa~10Pa;Thermocouple thermo wires (7) is The nicrosil nisil thermocouple thermo wires (7) that conventional N is occasionally adopted.
2. the manufacture method of high-temperature sensitive ceramic armouring pyrometer couple according to claim 1, it is characterised in that include Following steps:
1) preparation of raw material, equipment and frock
1. raw material:Prepare it is enough containing mass fraction for 8%-10% aluminate adhesives alumina-based ceramic powder, enough The nickel chromium triangle that carbon fiber, routinely technology are interted and be fixed with insulator (6) and connected both positive and negative polarity thermo wires by intermediate connection point Silicon-Nickel-Silicom thermocouple thermo wires (7), the terminal box (3), high-temp glue HN-767A that are mounted with case (1) and binding post (2);
2. equipment and frock:Prepare vacuum ceramic sintering furnace;Ceramic post sintering mould;Vacuum packaging equipment;Baking oven;
2) including the thermometric end shaping structures of protection sleeve pipe (10), carbon fiber basket (9) and lead (8)
1. ready alumina-based ceramic powder is fitted in ceramic post sintering mould, until ceramic post sintering mold bottom is filled It is full;
2. carbon fiber is woven into into basket, and the embedment of basket bottom is loaded with into the ceramic post sintering mould of alumina-based ceramic powder In bottom, length of embedment be basket outer away from ceramic post sintering die surface 0.4mm-0.7mm, then using by alumina-based ceramic powder End is full by the filling of ceramic post sintering mould and flattens, be compacted, and the centralized bunch for retaining carbon fiber basket (9) is stretched from body of powder center Go out;
3. it is sintered in vacuum ceramic sintering furnace, 1800 DEG C -1850 DEG C of sintering temperature, -1000 DEG C of ranks of heating rate room temperature Section heating rate is 10 DEG C/min-30 DEG C/min, and 1000 DEG C of -1300 DEG C of stage heating rates are 8 DEG C/min-15 DEG C/min, 1300 DEG C is 3 DEG C/min-5 DEG C/min to thermophase heating rate is arrived, and temperature retention time 4-6h to after temperature is incubated after terminating with not high Come out of the stove after the speed of 25 DEG C/min is cooled to not higher than 200 DEG C, the thermometric end structure of shaping needed for obtaining after the demoulding;
3) encapsulate
1. it is packaged in vacuum packaging equipment, keeps vacuum 1Pa~10Pa, brushes in protection sleeve pipe (10) first exhausted Edge layer (5);Then successively by lead (8) and both positive and negative polarity thermocouple thermo wires (7) tie point company that is interspersed and being fixed with insulator (6) Connect, be connected both positive and negative polarity thermocouple thermo wires (7) with two binding posts (2) being fixed in terminal box (3) respectively;Again by protective case Pipe (10) is fixed together using high-temp glue HN-767A and is sealed with terminal box (3), that is, the thermocouple after being encapsulated;
4) stabilization processes
1. by step 3) thermocouple after the encapsulation that obtains is placed in baking oven, is heated to 200 DEG C -250 DEG C, is incubated 30min- 50min, i.e., final required acquisition high-temperature sensitive ceramic armouring pyrometer couple.
CN201610971660.3A 2016-11-07 2016-11-07 High temperature sensitive ceramic armored high-temperature thermocouple and manufacture method thereof Pending CN106568520A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2699037C1 (en) * 2018-12-21 2019-09-03 Акционерное общество "Обнинское научно-производственное предприятие "Технология" им. А.Г. Ромашина" Method of increasing reliability of temperature sensor attachment to surface of ceramic materials
RU2710123C1 (en) * 2018-12-21 2019-12-24 Акционерное общество "Обнинское научно-производственное предприятие "Технология" им. А.Г. Ромашина" Method of mounting a thermoelectric temperature converter on the surface of ceramic materials
CN112475923A (en) * 2020-09-30 2021-03-12 北京中仪华世技术有限公司 Thermocouple, thermal resistance intelligent manufacturing and information integration production line

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2699037C1 (en) * 2018-12-21 2019-09-03 Акционерное общество "Обнинское научно-производственное предприятие "Технология" им. А.Г. Ромашина" Method of increasing reliability of temperature sensor attachment to surface of ceramic materials
RU2710123C1 (en) * 2018-12-21 2019-12-24 Акционерное общество "Обнинское научно-производственное предприятие "Технология" им. А.Г. Ромашина" Method of mounting a thermoelectric temperature converter on the surface of ceramic materials
CN112475923A (en) * 2020-09-30 2021-03-12 北京中仪华世技术有限公司 Thermocouple, thermal resistance intelligent manufacturing and information integration production line

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