CN106554624A - A kind of high-temperature resistant nano silver heat-conducting silicone grease - Google Patents
A kind of high-temperature resistant nano silver heat-conducting silicone grease Download PDFInfo
- Publication number
- CN106554624A CN106554624A CN201610980258.1A CN201610980258A CN106554624A CN 106554624 A CN106554624 A CN 106554624A CN 201610980258 A CN201610980258 A CN 201610980258A CN 106554624 A CN106554624 A CN 106554624A
- Authority
- CN
- China
- Prior art keywords
- parts
- heat
- silicone grease
- conducting silicone
- temperature resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/28—Nitrogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/08—Materials not undergoing a change of physical state when used
- C09K5/14—Solid materials, e.g. powdery or granular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/28—Nitrogen-containing compounds
- C08K2003/282—Binary compounds of nitrogen with aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a kind of high-temperature resistant nano silver heat-conducting silicone grease, in terms of parts by weight, including following components:20 35 parts of silicone oil, 42 63 parts of aluminium nitride, 18 27 parts of aluminium oxide, 47 parts of nano-silver thread, 13 parts of iron octoate, 4 16 parts of flyash, 15 27 parts of dispersant.The heat-conducting silicone grease temperature tolerance is strong, can still keep stable under higher temperature conditionss.And heat-conducting effect is good, can the thermal conductivity on effectively faster devices surface go out.
Description
Technical field
The present invention relates to silicone grease field, more particularly to a kind of high-temperature resistant nano silver heat-conducting silicone grease.
Background technology
Heat-conducting silicone grease is a kind of common Heat Conduction Material, one kind of thermal interfacial material, can life-time service is also more than 200
Cream fat can be kept original-pack, and with good chemical stability, it is nontoxic, tasteless that corrosion is not resulted in base material.Heat-conducting silicone grease
The air gap between radiating contact surface can also be effectively eliminated, the heat of device can be dispersed.Additionally, having operation construction
Simply, later stage cleaning is easy and is easy to the advantage of plant maintenance.
Heat-conducting silicone grease be with silicone oil based on, conduction powder as filler and add function additive, then blended grinding plus
The product that work is prepared from.Wherein, what the base oil for heat-conducting silicone grease was commonly used has methyl phenyl silicone oil, methyl-silicone oil, fluorine chlorine
Hydrocarbon modified silicon oil or long-chain alkyl-silicone oil etc.;The heat conductivility of heat-conducting silicone grease can be improved by adding filler.Heat filling
Style be:Metal class, carbons or ceramic-like materials.
Now with the more and more higher of electricity needs in people's life, for transmission line capability there has also been higher requirement, because
This needs more stable power transmission and transformation line of more, function.Power transmission and transformation line can be still faced in running several asks greatly
Topic:The electric energy of conveying can produce substantial amounts of heat, need to shed in time;Circuit is exposed to be easily corroded out of doors, need to carry out anti-
Shield.Generally use currently for these problems and smear Hmp grease to solve, but most Hmp grease radiating effect
It is really poor, it is impossible to timely by the heat dissipation in circuit.The heat-conducting effect of heat-conducting silicone grease preferably, but is applied to defeated change
Remain a need for being improved its heat-resisting effect and sealing protected effect in electric line.
The content of the invention
It is an object of the invention to provide a kind of high-temperature resistant nano silver heat-conducting silicone grease, the heat-conducting silicone grease temperature tolerance is strong, higher
Temperature conditionss under can still keep stable.And heat-conducting effect is good, can the thermal conductivity on effectively faster devices surface go out.
For achieving the above object, the present invention is employed the following technical solutions:
A kind of high-temperature resistant nano silver heat-conducting silicone grease, in terms of parts by weight, including following components:
Silicone oil 20-35 parts, aluminium nitride 42-63 parts, aluminium oxide 18-27 parts, nano-silver thread 4-7 parts, iron octoate 1-3 parts, powder
Coal ash 4-16 parts, dispersant 15-27 parts.
Preferably, the silicone oil is one or more in methyl-silicone oil, fluorochlorohydrocarbon modified silicon oil or methyl phenyl silicone oil
Mixture.
Preferably, the mass ratio that feeds intake of the aluminium nitride and aluminium oxide is 7:3.
Preferably, the aluminium nitride is a kind of pale powder, and density is 3.2g/cm3;Particle mean size is 1-5 μm.
Preferably, the aluminium oxide is a kind of white powder, and density is 3.9g/cm3;Particle mean size is 1-5 μm.
Preferably, the nano-silver thread is a kind of pale powder, and density is 10.5g/cm3;Particle mean size is 1-5 μm.
Preferably, the dispersant is one or more in liquid paraffin, ethylene glycol or Tissuemat E.
The high-temperature resistant nano silver heat-conducting silicone grease, it is adaptable to the radiating and sealing of power transmission and transformation line.
The invention has the advantages that, using heat-conducting silicone grease using in power transmission and transformation line, effectively can increase
Heat conduction and anticorrosion effect in circuit, is conducive to extending the service life of power transmission and transformation line.The heat-conducting silicone grease uses aluminium nitride
Mix as filler in certain proportion with aluminium oxide, use cooperatively, have heat conductivity compared to any of which is used alone
The effect that can be improved.Coordinated using a small amount of nano-silver thread and flyash, be aluminum nitride-alumina compound cooperative cooperating,
So that the heat-conducting silicone grease has good heat conductivility.The heat-conducting silicone grease can keep cream under higher temperature conditionss simultaneously
Shape, sealing are good.
Specific embodiment
In order to be better understood from the present invention, below by embodiment, the present invention is further described, and embodiment is served only for solution
The present invention is released, any restriction will not be constituted to the present invention.
Embodiment 1
A kind of high-temperature resistant nano silver heat-conducting silicone grease, in terms of parts by weight, including following components:
20 parts of methyl-silicone oil, 63 parts of aluminium nitride, 27 parts of aluminium oxide, 4 parts of nano-silver thread, 1 part of iron octoate, 4 parts of flyash, second
15 parts of glycol.
The heat conductivity of the heat-conducting silicone grease is 1.7W/mk.
Embodiment 2
A kind of high-temperature resistant nano silver heat-conducting silicone grease, in terms of parts by weight, including following components:
25 parts of fluorochlorohydrocarbon modified silicon oil, 49 parts of aluminium nitride, 21 parts of aluminium oxide, 5 parts of nano-silver thread, 3 parts of iron octoate, flyash
15 parts, 27 parts of liquid paraffin.
The heat conductivity of the heat-conducting silicone grease is 2.0W/mk.
Embodiment 3
A kind of high-temperature resistant nano silver heat-conducting silicone grease, in terms of parts by weight, including following components:
30 parts of methyl phenyl silicone oil, 56 parts of aluminium nitride, 24 parts of aluminium oxide, 6 parts of nano-silver thread, 3 parts of iron octoate, flyash 6
Part, 18 parts of Tissuemat E.
The heat conductivity of the heat-conducting silicone grease is 2.0W/mk.
Embodiment 4
A kind of high-temperature resistant nano silver heat-conducting silicone grease, in terms of parts by weight, including following components:
35 parts of fluorochlorohydrocarbon modified silicon oil, 49 parts of aluminium nitride, 21 parts of aluminium oxide, 7 parts of nano-silver thread, 2 parts of iron octoate, flyash
12 parts, 20 parts of liquid paraffin.
The heat conductivity of the heat-conducting silicone grease is 1.7W/mk.
Embodiment 5
A kind of high-temperature resistant nano silver heat-conducting silicone grease, in terms of parts by weight, including following components:
30 parts of methyl phenyl silicone oil, 56 parts of aluminium nitride, 24 parts of aluminium oxide, 6 parts of nano-silver thread, 2 parts of iron octoate, flyash 16
Part, 25 parts of ethylene glycol.
The heat conductivity of the heat-conducting silicone grease is 2.0W/mk.
Claims (8)
1. a kind of high-temperature resistant nano silver heat-conducting silicone grease, it is characterised in that in terms of parts by weight, including following components:
Silicone oil 20-35 parts, aluminium nitride 42-63 parts, aluminium oxide 18-27 parts, nano-silver thread 4-7 parts, iron octoate 1-3 parts, flyash
4-16 parts, dispersant 15-27 parts.
2. high-temperature resistant nano according to claim 1 silver heat-conducting silicone grease, it is characterised in that:The silicone oil be methyl-silicone oil,
One or more mixture in fluorochlorohydrocarbon modified silicon oil or methyl phenyl silicone oil.
3. high-temperature resistant nano according to claim 1 silver heat-conducting silicone grease, it is characterised in that:The aluminium nitride and aluminium oxide
The mass ratio that feeds intake is 7:3.
4. high-temperature resistant nano according to claim 1 silver heat-conducting silicone grease, it is characterised in that:The aluminium nitride particle mean size is
1-5μm。
5. high-temperature resistant nano according to claim 1 silver heat-conducting silicone grease, it is characterised in that:The aluminium oxide particle mean size is
1-5μm。
6. high-temperature resistant nano according to claim 1 silver heat-conducting silicone grease, it is characterised in that:The nano-silver thread particle mean size
For 1-5 μm.
7. high-temperature resistant nano according to claim 1 silver heat-conducting silicone grease, it is characterised in that:The dispersant is liquid stone
One or more in wax, ethylene glycol or Tissuemat E.
8. the silver-colored heat-conducting silicone grease of the high-temperature resistant nano according to any one of claim 1-7, it is characterised in that:Suitable for defeated change
The radiating and sealing of electric line.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610980258.1A CN106554624A (en) | 2016-11-08 | 2016-11-08 | A kind of high-temperature resistant nano silver heat-conducting silicone grease |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610980258.1A CN106554624A (en) | 2016-11-08 | 2016-11-08 | A kind of high-temperature resistant nano silver heat-conducting silicone grease |
Publications (1)
Publication Number | Publication Date |
---|---|
CN106554624A true CN106554624A (en) | 2017-04-05 |
Family
ID=58444646
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610980258.1A Pending CN106554624A (en) | 2016-11-08 | 2016-11-08 | A kind of high-temperature resistant nano silver heat-conducting silicone grease |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106554624A (en) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102024505A (en) * | 2010-10-12 | 2011-04-20 | 北京国电富通科技发展有限责任公司 | Silicone oil electric force compound grease and preparation method thereof |
CN102181271A (en) * | 2011-01-24 | 2011-09-14 | 重庆大学 | Binary mixed nano heat-conducting silicone grease for heat dissipation of high-power LED (light-emitting diode) lamp and preparation method thereof |
CN102516930A (en) * | 2011-12-13 | 2012-06-27 | 烟台德邦科技有限公司 | High temperature curing monocomponent heat-conduction flame-retardation electronic pouring sealant and preparation method thereof |
CN102757645A (en) * | 2012-08-18 | 2012-10-31 | 邵成芬 | Thermal-conductive silicone grease with high thermal conductivity and high temperature resistance and preparation method thereof |
CN103214848A (en) * | 2013-04-28 | 2013-07-24 | 深圳市新亚新材料有限公司 | Phase change heat-conducting thermal silicone grease composition for central processing unit (CPU) radiating and preparation method thereof |
-
2016
- 2016-11-08 CN CN201610980258.1A patent/CN106554624A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102024505A (en) * | 2010-10-12 | 2011-04-20 | 北京国电富通科技发展有限责任公司 | Silicone oil electric force compound grease and preparation method thereof |
CN102181271A (en) * | 2011-01-24 | 2011-09-14 | 重庆大学 | Binary mixed nano heat-conducting silicone grease for heat dissipation of high-power LED (light-emitting diode) lamp and preparation method thereof |
CN102516930A (en) * | 2011-12-13 | 2012-06-27 | 烟台德邦科技有限公司 | High temperature curing monocomponent heat-conduction flame-retardation electronic pouring sealant and preparation method thereof |
CN102757645A (en) * | 2012-08-18 | 2012-10-31 | 邵成芬 | Thermal-conductive silicone grease with high thermal conductivity and high temperature resistance and preparation method thereof |
CN103214848A (en) * | 2013-04-28 | 2013-07-24 | 深圳市新亚新材料有限公司 | Phase change heat-conducting thermal silicone grease composition for central processing unit (CPU) radiating and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
庞文键等: "《LED 用低热阻硅脂的制备》", 《有机硅材料》 * |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP7043630B2 (en) | Graphene denaturing method, modified graphene and composition containing graphene | |
Hadi et al. | Novel of water with (CeO2-WC) and (SiC-WC) nanoparticles systems for energy storage and release applications | |
CN103497739B (en) | Heat-conducting cream and preparation method thereof | |
CN105219220A (en) | A kind of novel high heat conducting nano heat loss through radiation coating and preparation method thereof | |
CN108373592B (en) | Heat-conducting silicone grease composition, heat-conducting silicone grease and LED lighting device | |
CN103756325A (en) | Low-filling-capacity and high-heat-conductivity graphene/silicone grease composite material and preparation method thereof | |
CN105331108A (en) | High thermal conductive silicone grease and preparation method thereof | |
CN104497574A (en) | Multifunctional organic silicon thermal interface material | |
TWI553111B (en) | Thermal grease having low thermal resistance | |
JP2007070492A (en) | Heat conductive grease, adhesive and elastomer composition, and cooling device | |
CN105949903B (en) | A kind of high efficiency and heat radiation coating and its application process | |
CN104710792A (en) | Spherical core-shell structured Al2O3/AlN thermal-conducting powder and high-thermal-conductivity insulating silicone grease and preparation methods thereof | |
CN102464940B (en) | Corrosion-resistant anti-lock material for high and low-temperature fasteners and preparation method thereof | |
CN104531082A (en) | Novel nanoscale copper-aluminum-alloy particle heat-conduction fluid material | |
CN106554624A (en) | A kind of high-temperature resistant nano silver heat-conducting silicone grease | |
CN105400497A (en) | All-metal heat conducting paste and preparation method thereof | |
CN109912980A (en) | A kind of High thermal-conductive silicone grease and preparation method thereof | |
CN104672911A (en) | Preparation method of carbon nanotube doped weather-proof heat conductive silicone grease for LED | |
CN109456601B (en) | Anti-cracking computer heat-conducting silicone grease and preparation method thereof | |
CN2932237Y (en) | Semiconductor thermoelectricity cooled heat pump | |
CN115181555A (en) | Solid-solid phase change cooling liquid for data center and preparation method thereof | |
CN108515189A (en) | A kind of preparation method of graphene carbon/carbon-copper composite material | |
CN104479639A (en) | Novel nanometer-grade copper-lead alloy micro-particle heat conducting liquid material | |
CN107057558A (en) | A kind of environment-friendly type heat conductive silicone grease composition and its preparation method and application | |
CN104151836A (en) | Heat-conducting silicone grease and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170405 |