CN106543802A - A kind of film printing water color ink and preparation method thereof - Google Patents

A kind of film printing water color ink and preparation method thereof Download PDF

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Publication number
CN106543802A
CN106543802A CN201611049605.5A CN201611049605A CN106543802A CN 106543802 A CN106543802 A CN 106543802A CN 201611049605 A CN201611049605 A CN 201611049605A CN 106543802 A CN106543802 A CN 106543802A
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China
Prior art keywords
parts
color ink
water color
film printing
raw material
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CN201611049605.5A
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Chinese (zh)
Inventor
黄桂云
许焱
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Anhui Tianle Plastic Co Ltd
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Anhui Tianle Plastic Co Ltd
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Priority to CN201611049605.5A priority Critical patent/CN106543802A/en
Publication of CN106543802A publication Critical patent/CN106543802A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a kind of film printing water color ink and preparation method thereof, is made up of the raw material of following weight portion:28 35 parts of acrylic resin, 10 20 parts of epoxy resin, 12 20 parts of pigment, 6 12 parts of wollastonite in powder, 27 parts of nano-bentonite, 49 parts of biocide mildewcide, 0.5 3 parts of epoxy soybean oil, 14 parts of polyurethane, 0.5 2 parts of surfactant, 0.5 2 parts of silane, 26 38 parts of deionized water;The water color ink of the present invention, can improve the wearability and resistance to blocking of ink by adding wollastonite in powder;The biocide mildewcide of addition is prepared with Chinese medicine ingredients, and safety and environmental protection is harmless to health;The ink performance of the present invention is stable, and with good glossiness and dispersibility, rate of drying is fast;During use, ink do not fall off, not fall the effect of ink, and printing effect is lasting.

Description

A kind of film printing water color ink and preparation method thereof
Technical field
The present invention relates to printing-ink, and in particular to a kind of film printing water color ink and preparation method thereof.
Background technology
At present, plastic sheeting miscellaneous is widely used in printing and packaging industry.These thin film print in many cases There is writings and image, in order that printing quality meets use requirement, need have certain understanding to the preparation of printing-ink.It is common Printing-ink be divided into solvent type ink, water color ink and light-curable ink three types.With global environmental pollution and life Life, concern for the environment and the development of the mankind are increasingly paid close attention in the aggravation of state environmental disruption degree, people, improve production and using green Color product.Water color ink is widely used in printing and packaging industry.
The uniform slurry like material that water color ink is mainly made up of coloring agent and binder, with not firing, it is not quick-fried, nontoxic, The characteristic such as have no irritating odor.The effect of coloring agent is that image function is provided on base material, and gives latex film light resistance and light Pool.But at present, generally in dispersibility, glossiness, water-resistance, performance is not enough for water color ink, and hardening time is long, reduces use Efficiency, increased cost.Therefore, it is necessary to existing printing-ink is improved, it is many with low cost, function so as to produce Unitization, high temperature resistant, the printing-ink of wear-resisting, good environmental protection.
The content of the invention
It is an object of the invention to provide a kind of film printing water color ink, stable performance, antibacterial and mouldproof, with good light Damp degree and wearability.
In order to realize the purpose of the present invention, adopt the following technical scheme that:
A kind of film printing water color ink, is made up of the raw material of following weight portion:
Preferably, it is made up of the raw material of following weight portion:
Preferably, it is made up of the raw material of following weight portion:
Preferably, pigment is the one kind in phthalocyanine blue, titanium dioxide or permanent bordeaux.
Preferably, surfactant is sulfuric ester.
Further, the preparation method of biocide mildewcide is:By Herba Menthae 15-22 parts, Radix Sophorae Flavescentiss 12-20 parts, Flos Caryophylli 8-15 parts, Remonstrate with skin 6-12 parts, Flos Lonicerae 14-18 part of Radix Arnebiae (Radix Lithospermi) 10-15 parts, Rhizoma Coptidis 5-10 parts, Camphora 9-13 parts, hardship is added to 2-5 times of weight portion Water in, decoct 3 times, each 40-60min, filter, three filtrate is merged, cooling, concentration obtain final product biocide mildewcide.
Further, a kind of preparation method of film printing water color ink, comprises the following steps:
(1) each raw material of corresponding weight portion is weighed respectively;
(2) wollastonite in powder is placed in into roasting in Muffle furnace, sintering temperature is 650-800 DEG C, and roasting time is 45-70min, Cooling, ground 350 mesh standard sieve;
(3) wollastonite in powder after acrylic resin, epoxy resin and roasting is added in deionized water, Jing high-speed stirred Machine mixing and stirring, mixing speed are 80-120r/min, and heating-up temperature is 60-75 DEG C, obtains compound A;
(4) remaining raw material is added in the compound A that step (3) is obtained, is sufficiently stirred for up to preliminary dispersion, then ultrasound Ripple vibrates 20-30min, and compound B is obtained;
(5) compound B is ground on three-roller and is obtained final product.
Beneficial effects of the present invention:
The water color ink of the present invention, can improve the wearability and resistance to blocking of ink by adding wollastonite in powder;Addition Biocide mildewcide prepared with Chinese medicine ingredients, safety and environmental protection is harmless to health;The ink performance of the present invention is stable, tool There are good glossiness and dispersibility, rate of drying is fast;During use, ink do not fall off, not fall the effect of ink, and printing effect is held Long.
Specific embodiment
Below embodiments of the invention are elaborated, the present embodiment is carried out under premised on technical solution of the present invention Implement, give detailed embodiment and specific operating process, but protection scope of the present invention is not limited to following enforcements Example.
Embodiment 1
A kind of film printing water color ink, is made up of the raw material of following weight portion:28 parts of acrylic resin, epoxy resin 10 Part, 12 parts of pigment, 6 parts of wollastonite in powder, 2 parts of nano-bentonite, 4 parts of biocide mildewcide, 0.5 part of epoxy soybean oil, polyurethane 1 Part, 0.5 part of surfactant, 0.5 part of silane, 26 parts of deionized water;During wherein pigment is phthalocyanine blue, titanium dioxide or permanent bordeaux It is a kind of;Surfactant is sulfuric ester.
Wherein, the preparation method of biocide mildewcide is:By 15 parts of Herba Menthae, 12 parts of Radix Sophorae Flavescentiss, 8 parts of Flos Caryophylli, 10 parts of Radix Arnebiae (Radix Lithospermi), Rhizoma Coptidis 5 parts, 9 parts of Camphora, remonstrate with 6 parts of skin, 14 parts of Flos Lonicerae of hardship be added in the water of 2 times of weight portions, decoct 3 times, each 40min, filter, Three filtrate merging, cooling, concentrations are obtained final product into biocide mildewcide.
A kind of preparation method of film printing water color ink, comprises the following steps:
(1) each raw material of corresponding weight portion is weighed respectively;
(2) wollastonite in powder is placed in into roasting in Muffle furnace, sintering temperature is 650 DEG C, and roasting time is 50min, cooling is ground Honed 350 mesh standard sieve;
(3) wollastonite in powder after acrylic resin, epoxy resin and roasting is added in deionized water, Jing high-speed stirred Machine mixing and stirring, mixing speed are 80r/min, and heating-up temperature is 60 DEG C, obtains compound A;
(4) remaining raw material is added in the compound A that step (3) is obtained, is sufficiently stirred for up to preliminary dispersion, then ultrasound Ripple vibrates 20min, and compound B is obtained;
(5) compound B is ground on three-roller and is obtained final product.
Embodiment 2
A kind of film printing water color ink, is made up of the raw material of following weight portion:35 parts of acrylic resin, epoxy resin 20 Part, 20 parts of pigment, 12 parts of wollastonite in powder, 7 parts of nano-bentonite, 9 parts of biocide mildewcide, 3 parts of epoxy soybean oil, 4 parts of polyurethane, 2 parts of surfactant, 2 parts of silane, 38 parts of deionized water;Wherein pigment is the one kind in phthalocyanine blue, titanium dioxide or permanent bordeaux;Table Face activating agent is sulfuric ester.
Wherein, the preparation method of biocide mildewcide is:By 22 parts of Herba Menthae, 20 parts of Radix Sophorae Flavescentiss, 15 parts of Flos Caryophylli, 15 parts of Radix Arnebiae (Radix Lithospermi), Huang 10 parts of company, 13 parts of Camphora, bitter remonstrate with 12 parts of skin, 18 parts of Flos Lonicerae are added in the water of 3 times of weight portions, are decocted 3 times, each 50min, Filter, three filtrate merging, cooling, concentrations are obtained final product into biocide mildewcide.
A kind of preparation method of film printing water color ink, comprises the following steps:
(1) each raw material of corresponding weight portion is weighed respectively;
(2) wollastonite in powder is placed in into roasting in Muffle furnace, sintering temperature is 700 DEG C, and roasting time is 60min, cooling is ground Honed 350 mesh standard sieve;
(3) wollastonite in powder after acrylic resin, epoxy resin and roasting is added in deionized water, Jing high-speed stirred Machine mixing and stirring, mixing speed are 90r/min, and heating-up temperature is 65 DEG C, obtains compound A;
(4) remaining raw material is added in the compound A that step (3) is obtained, is sufficiently stirred for up to preliminary dispersion, then ultrasound Ripple vibrates 25min, and compound B is obtained;
(5) compound B is ground on three-roller and is obtained final product.
Embodiment 3
A kind of film printing water color ink, is made up of the raw material of following weight portion:30 parts of acrylic resin, epoxy resin 14 Part, 15 parts of pigment, 8 parts of wollastonite in powder, 4 parts of nano-bentonite, 5 parts of biocide mildewcide, 1 part of epoxy soybean oil, 2 parts of polyurethane, 1 part of surfactant, 1 part of silane, 32 parts of deionized water;Wherein pigment is the one kind in phthalocyanine blue, titanium dioxide or permanent bordeaux;Table Face activating agent is sulfuric ester.
Wherein, the preparation method of biocide mildewcide is:By 18 parts of Herba Menthae, 15 parts of Radix Sophorae Flavescentiss, 10 parts of Flos Caryophylli, 12 parts of Radix Arnebiae (Radix Lithospermi), Huang 8 parts of company, 10 parts of Camphora, bitter remonstrate with 8 parts of skin, 15 parts of Flos Lonicerae are added in the water of 3 times of weight portions, are decocted 3 times, each 55min, mistake Three filtrate merging, cooling, concentrations are obtained final product biocide mildewcide by filter.
A kind of preparation method of film printing water color ink, comprises the following steps:
(1) each raw material of corresponding weight portion is weighed respectively;
(2) wollastonite in powder is placed in into roasting in Muffle furnace, sintering temperature is 750 DEG C, and roasting time is 60min, cooling is ground Honed 350 mesh standard sieve;
(3) wollastonite in powder after acrylic resin, epoxy resin and roasting is added in deionized water, Jing high-speed stirred Machine mixing and stirring, mixing speed are 100r/min, and heating-up temperature is 70 DEG C, obtains compound A;
(4) remaining raw material is added in the compound A that step (3) is obtained, is sufficiently stirred for up to preliminary dispersion, then ultrasound Ripple vibrates 25min, and compound B is obtained;
(5) compound B is ground on three-roller and is obtained final product.
Embodiment 4
A kind of film printing water color ink, is made up of the raw material of following weight portion:32 parts of acrylic resin, epoxy resin 18 Part, 17 parts of pigment, 10 parts of wollastonite in powder, 5 parts of nano-bentonite, 7 parts of biocide mildewcide, 2 parts of epoxy soybean oil, 3 parts of polyurethane, 1.5 parts of surfactant, 1.5 parts of silane, 35 parts of deionized water;Wherein pigment is in phthalocyanine blue, titanium dioxide or permanent bordeaux Kind;Surfactant is sulfuric ester.
Wherein, the preparation method of biocide mildewcide is:By 20 parts of Herba Menthae, 18 parts of Radix Sophorae Flavescentiss, 12 parts of Flos Caryophylli, 12 parts of Radix Arnebiae (Radix Lithospermi), Huang 8 parts of company, 11 parts of Camphora, bitter remonstrate with 10 parts of skin, 16 parts of Flos Lonicerae are added in the water of 4 times of weight portions, are decocted 3 times, each 55min, Filter, three filtrate merging, cooling, concentrations are obtained final product into biocide mildewcide.
A kind of preparation method of film printing water color ink, comprises the following steps:
(1) each raw material of corresponding weight portion is weighed respectively;
(2) wollastonite in powder is placed in into roasting in Muffle furnace, sintering temperature is 750 DEG C, and roasting time is 65min, cooling is ground Honed 350 mesh standard sieve;
(3) wollastonite in powder after acrylic resin, epoxy resin and roasting is added in deionized water, Jing high-speed stirred Machine mixing and stirring, mixing speed are 115r/min, and heating-up temperature is 65 DEG C, obtains compound A;
(4) remaining raw material is added in the compound A that step (3) is obtained, is sufficiently stirred for up to preliminary dispersion, then ultrasound Ripple vibrates 30min, and compound B is obtained;
(5) compound B is ground on three-roller and is obtained final product.
Presently preferred embodiments of the present invention is the foregoing is only, not to limit the present invention, all essences in the present invention Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.

Claims (7)

1. a kind of film printing water color ink, it is characterised in that be made up of the raw material of following weight portion:
2. a kind of film printing water color ink according to claim 1, it is characterised in that by the raw material group of following weight portion Into:
3. a kind of film printing water color ink according to claim 1, it is characterised in that by the raw material group of following weight portion Into:
4. a kind of film printing water color ink according to claim 1, it is characterised in that pigment is phthalocyanine blue, titanium dioxide Or the one kind in permanent bordeaux.
5. a kind of film printing water color ink according to claim 1, it is characterised in that surfactant is sulfuric ester.
6. a kind of film printing water color ink according to claim 1, it is characterised in that the preparation method of biocide mildewcide For:By Herba Menthae 15-22 parts, Radix Sophorae Flavescentiss 12-20 parts, Flos Caryophylli 8-15 parts, Radix Arnebiae (Radix Lithospermi) 10-15 parts, Rhizoma Coptidis 5-10 parts, Camphora 9-13 parts, hardship Remonstrate with skin 6-12 parts, Flos Lonicerae 14-18 part is added in the water of 2-5 times of weight portion, is decocted 3 times, each 40-60min, is filtered, will Three filtrate merging, cooling, concentrations obtain final product biocide mildewcide.
7. a kind of preparation method of film printing water color ink, it is characterised in that comprise the following steps:
(1) each raw material of corresponding weight portion is weighed respectively;
(2) wollastonite in powder is placed in into roasting in Muffle furnace, sintering temperature is 650-800 DEG C, and roasting time is 45-70min, cold But, ground 350 mesh standard sieve;
(3) wollastonite in powder after acrylic resin, epoxy resin and roasting is added in deionized water, Jing homogenizers are mixed Conjunction stirs, and mixing speed is 80-120r/min, and heating-up temperature is 60-75 DEG C, obtains compound A;
(4) remaining raw material is added in the compound A that step (3) is obtained, is sufficiently stirred for until preliminary disperse, then ultrasound wave shakes Dynamic 20-30min, is obtained compound B;
(5) compound B is ground on three-roller and is obtained final product.
CN201611049605.5A 2016-11-24 2016-11-24 A kind of film printing water color ink and preparation method thereof Pending CN106543802A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107699043A (en) * 2017-10-16 2018-02-16 泰安市正泰激光印务有限公司 A kind of antibacterial water-based ink
CN108059870A (en) * 2017-12-26 2018-05-22 吕绍淼 A kind of antibiotic property offset ink and preparation method thereof
CN109382297A (en) * 2018-10-17 2019-02-26 苏州扬子江新型材料股份有限公司 Dirt-resistant stealth Coil Coating Products and preparation method thereof
CN109504174A (en) * 2018-11-30 2019-03-22 浙江荣丰纸业有限公司 A kind of cork paper changeable colour antibacterial ink and preparation method thereof
CN112063233A (en) * 2020-09-25 2020-12-11 广东福美新材料科技有限公司 Wear-resistant scratch-resistant printing ink for impregnated paper and preparation method thereof
CN115247018A (en) * 2022-08-02 2022-10-28 百草边大生物科技(青岛)有限公司 Preparation method of macrobiological functional agent containing sophora flavescens extract

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CN101792624A (en) * 2010-04-01 2010-08-04 北京今鼎新翰文化艺术有限公司 Traditional Chinese medicine decoction additive for water-based ink and preparation method thereof
CN102942821A (en) * 2012-10-30 2013-02-27 广东壮丽彩印股份有限公司 Nano-antibacterial gravure aqueous printing ink and preparation method thereof

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CN101792624A (en) * 2010-04-01 2010-08-04 北京今鼎新翰文化艺术有限公司 Traditional Chinese medicine decoction additive for water-based ink and preparation method thereof
CN102942821A (en) * 2012-10-30 2013-02-27 广东壮丽彩印股份有限公司 Nano-antibacterial gravure aqueous printing ink and preparation method thereof

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107699043A (en) * 2017-10-16 2018-02-16 泰安市正泰激光印务有限公司 A kind of antibacterial water-based ink
CN108059870A (en) * 2017-12-26 2018-05-22 吕绍淼 A kind of antibiotic property offset ink and preparation method thereof
CN109382297A (en) * 2018-10-17 2019-02-26 苏州扬子江新型材料股份有限公司 Dirt-resistant stealth Coil Coating Products and preparation method thereof
CN109504174A (en) * 2018-11-30 2019-03-22 浙江荣丰纸业有限公司 A kind of cork paper changeable colour antibacterial ink and preparation method thereof
CN112063233A (en) * 2020-09-25 2020-12-11 广东福美新材料科技有限公司 Wear-resistant scratch-resistant printing ink for impregnated paper and preparation method thereof
CN112063233B (en) * 2020-09-25 2023-01-24 广东福美新材料科技有限公司 Wear-resistant scratch-resistant printing ink for impregnated paper and preparation method thereof
CN115247018A (en) * 2022-08-02 2022-10-28 百草边大生物科技(青岛)有限公司 Preparation method of macrobiological functional agent containing sophora flavescens extract

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Application publication date: 20170329