CN106539712A - A kind of preparation method of modified model anhydrous hand cleaner agent - Google Patents
A kind of preparation method of modified model anhydrous hand cleaner agent Download PDFInfo
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- CN106539712A CN106539712A CN201510587987.6A CN201510587987A CN106539712A CN 106539712 A CN106539712 A CN 106539712A CN 201510587987 A CN201510587987 A CN 201510587987A CN 106539712 A CN106539712 A CN 106539712A
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Abstract
The invention discloses a kind of modified model anhydrous hand cleaner agent that can remove heavy oil stain.With weight ratio meter, the present invention is consisted of the following composition：Stearic acid（4.0%-16.0%）, triethanolamine（3.8%-10.0%）, paraffin（33.0%-79.0%）, deionized water（13.0%-38.0%）, essence（0.2%-3%）.The present invention can be washed in anhydrous conditions and be stained with grease, paint, tar, the handss of printing paint, and has functions that skin protection, moistens and sterilize, very easy to use；Raw material of the present invention is easy to get, process is simple, and rationally, strong detergency, using effect are good, and no side effectses, life-time service are safe and reliable for formula.
Description
Technical field
The present invention relates to a kind of preparation method of modified model anhydrous hand cleaner agent, more particularly to a kind of preparation method of the anhydrous hand cleaner agent that can remove heavy oil stain.
Background technology
Anhydrous hand cleaner agent is in anhydrous conditions, for washing a kind of New-type detergent for being stained with grease, paint, tar, printing paint handss, constantly to be rubbed with the hands by both hands with several grams of this product and wiped, wipe washing dirt with gauze or soft paper after a few minutes, just obtain the clean handss of a pair of.Anhydrous hand cleaner agent is different with the washing principle of current fancy soap used in everyday, detergent, liquid detergent.Fancy soap can not wash heavy oil stain；Detergent can only remove grease there is water condition to go down, but obvious to the side effect of skin, roughening with rear skin long；Liquid detergent is substantive with detergent, when simply forming commodity, liquid form is used.Fancy soap, detergent and liquid detergent are O/W type articless for washing, and anhydrous hand cleaner agent is then w/o type articles for washing.
Anhydrous hand cleaner agent is helped by Long carbon chain surfactant, oil-based solvent, alkaline auxiliary lotion, shaping material, powder washes material, essence and water and constitutes, and is that w/o type goes to wash the articles for washing of heavy oil stain.At present, external product has two kinds of forms, a kind of for semi-liquid-like, and a kind of is body of paste, and its composition material is close, and simply proportioning is different different with manner of packing.Anhydrous hand cleaner agent has the functions such as decontamination, expansion, emulsifying, infiltration, can by absorption oily pollutant on hand it is molten for wherein or by emulsifying suspend, allow grease to depart from contact with skin, so as to be wiped out.
Automobile driver repairs on highway, the grease that re-type and various field operation personnel are stain on hand is mainly：Waste lubricating oil, useless chilli oil, paint, tar, printing paint etc., these are heavy oil stain, oily matter of its main component for different molecular weight.These oily matters have very strong affinity with skin surface and adsorb on skin, and general soap can not be washed away, in addition also containing impurity such as metal dust, resins.The dirty general detergent of these heavy oil is not easily penetrated into, thus cleaning function is not just obvious.These greases are removed, anhydrous hand cleaner agent must just have the performances such as infiltration, swelling, emulsifying, moistening, decontamination.Using Long carbon chain surfactant（Several compoundings can be adopted）Can penetrate into clc layer, play effect of decontamination, emulsifying；There are saponification, decontamination using alkaline assistant；Essence then improves the taste of anhydrous hand cleaner agent, covers the abnormal smells from the patient of plastid；Sizing aids have functions that moistening, thickening.This few class material compounding is got up to form the w/o type anhydrous hand cleaner agent with performances such as infiltration, absorption, swelling, dispersion, emulsifyings.The appearance of anhydrous hand cleaner agent solves the worry that the full handss grease of driver is driven, while also improve work efficiency for them, and improves working condition.
Meanwhile, anhydrous hand cleaner agent also meets several requirements of detergent production：
（1）Strong detergency；
（2）Safety is good；
（3）Low production cost；
（4）In production process, environmental pollution is less.
Chinese patent literature CN101658473, CN104490714A and CN104173236A disclose the preparation method of some Chinese herbal medicine non-water hand cleansers, the compositions such as ethanol, plants essential oil, carbomer has been assembled in handwashing liquid mainly, using the sterilization of ethanol, using plants essential oil as carrier, using carbomer as thickening agent.
Chinese patent literature CN1895204A and CN100394910C disclose a kind of preparation method of antiseptic hand cleaning liquid with out water cleaning.The sterilization of ethanol is it makes use of, and using Carboxypolymethylene ultrez10 as thickening agent, the triclosan of 0.4%-0.5% is also added as a kind of sterilizing product.Triclosan is a kind of synthetic, with sterilizing function, but has generation chloroform when the chloropexia in triclosan with tap water（Carcinogen）It is potentially possible.In addition, excessively being possible to cause the Drug resistance of antibacterial using triclosan class antibacterial.
The preparation process of this kind of antiseptic hand cleaning liquid with out water cleaning is relatively complicated, complicated process of preparation, and focuses on sterilizing function, and being irritating to the skin property, detergency are weaker, and long-term storage is unstable, is susceptible to separate, and these handwashing liquid are not preferable handwashing liquid.
The content of the invention
It is an object of the invention to provide a kind of preparation method of the anhydrous hand cleaner agent that can wash heavy oil stain.
The preparation method of anhydrous hand cleaner agent of the present invention, it is characterised in that：Each component comprising Long carbon chain fatty acid, oiliness auxiliary agent, alkaline assistant, deionized water, essence is follow these steps to assemble：Long carbon chain fatty acid is dissolved in oil-based solvent, 70 DEG C are heated to, is stirred, form A liquid；Alkaline assistant is dissolved in into water, 80 DEG C are heated to, is stirred, form B liquid；B liquid is dividedly in some parts in A liquid, and is thermally formed mixed liquor while stirring, mix 10min；Lower the temperature under agitation, essence is finally added when temperature is down to 60 DEG C or so, then is down to room temperature, obtain final product product.
Preferably, with weight ratio meter, the present invention is consisted of the following composition：Stearic acid（4.0%-16.0%）, triethanolamine（3.8%-10.0%）, paraffin（33.0%-79.0%）, deionized water（13.0%-38.0%）, essence（0.2%-3.0%）.
Experimental process profile is by stearic acid（4.0%-16.0%）It is dissolved in oil-based solvent paraffin（33.0%-79.0%）In, heated and stirred forms A liquid；By triethanolamine（3.8%-10.0%）It is dissolved in water and forms B liquid（Heating）；Then B liquid is dividedly in some parts in A liquid, and is thermally formed mixed liquor while stirring, then lower the temperature under agitation, finally essence is added when temperature is down to 60 DEG C or so（0.2%-3.0%）, then room temperature is down to, obtain final product product.
It is highly preferred that the preferred version of the present invention is by stearic acid 6.7%, it is dissolved in 63.0% paraffin oil-based solvent, heated and stirred, forms A liquid；Triethanolamine 5.0% is dissolved in into 25.0% water and forms B liquid（Heating）；Then B liquid is dividedly in some parts in A liquid, and is thermally formed mixed liquor while stirring, then lowered the temperature under agitation, 0.3% essence is finally added when temperature is down to 60 DEG C or so, then is down to room temperature, obtain final product product.
During the present invention solves existing anhydrous hand cleaner agent, detergency is weaker, it is impossible to remove heavy oil stain, and long-term storage is unstable is susceptible to the problems such as separating.Strong detergency of the present invention, property are gentle, are not limited by water source, especially suitable in occasion that is anhydrous or being difficult to fetch water, carry and use very convenient, and simple process, simple to operate, greatly reduce production cost.
Specific embodiment
Below in conjunction with specific embodiment, the present invention will be further described.
Embodiment 1
By stearic acid 6.7%, it is dissolved in 63.0% paraffin oil-based solvent, heated and stirred, forms A liquid；Triethanolamine 5.0% is dissolved in into 25.0% water and forms B liquid（Heating）；Then B liquid is dividedly in some parts in A liquid, and is thermally formed mixed liquor while stirring, then lowered the temperature under agitation, 0.3% essence is finally added when temperature is down to 60 DEG C or so, then is down to room temperature, obtain final product product.Product Jing pH value is determined, measured value is 7.0；To product Jing viscosimetric analysis, measured value is 200pa.s；To product Jing stability tests, will 100g this product load glass reagent bottle in seal, be put in -8 DEG C of refrigerator after 8h, taking-up is put into rapidly 8h in 50 DEG C of baking oven, and after taking out cooling, product is not dry and cracked, not stratified, fragrance remains unchanged；Cleaning performance measure is carried out to the product, 25cm is marked on finger2The region of square, coats used oil, after with 0.5g, the anhydrous hand cleaner agent sample is applied in this region, constantly reciprocally wiped with handss, after 1 minute, wipe washing dirt with gauze, no black greasy dirt in this region.Detection performance indications, show that product is qualified above.
Embodiment 2
By stearic acid 16.0%, it is dissolved in 39.0% paraffin oil-based solvent, heated and stirred, forms A liquid；Triethanolamine 9.0% is dissolved in into 35.0% water and forms B liquid（Heating）；Then B liquid is dividedly in some parts in A liquid, and is thermally formed mixed liquor while stirring, then lowered the temperature under agitation, 1.0% essence is finally added when temperature is down to 60 DEG C or so, then is down to room temperature, obtain final product product.Product Jing pH value is determined, measured value is 7.5；To product Jing viscosimetric analysis, measured value is 280pa.s；To product Jing stability tests, will 100g this product load glass reagent bottle in seal, be put in -8 DEG C of refrigerator after 8h, taking-up is put into rapidly 8h in 50 DEG C of baking oven, and after taking out cooling, product is not dry and cracked, not stratified, fragrance remains unchanged；Cleaning performance measure is carried out to the product, 25cm is marked on finger2The region of square, coats used oil, after with 0.5g, the anhydrous hand cleaner agent sample is applied in this region, constantly reciprocally wiped with handss, after 1 minute, wipe washing dirt with gauze, no black greasy dirt in this region.Detection performance indications, show that product is qualified above.
Embodiment 3
By stearic acid 4.5%, it is dissolved in 70.0% paraffin oil-based solvent, heated and stirred, forms A liquid；Triethanolamine 4.0% is dissolved in into 20.0% water and forms B liquid（Heating）；Then B liquid is dividedly in some parts in A liquid, and is thermally formed mixed liquor while stirring, then lowered the temperature under agitation, 1.5% essence is finally added when temperature is down to 60 DEG C or so, then room temperature is down to, is obtained final product product.Product Jing pH value is determined, measured value is 6.5；To product Jing viscosimetric analysis, measured value is 250pa.s；To product Jing stability tests, will 100g this product load glass reagent bottle in seal, be put in -8 DEG C of refrigerator after 8h, taking-up is put into rapidly 8h in 50 DEG C of baking oven, and after taking out cooling, product is not dry and cracked, not stratified, fragrance remains unchanged；Cleaning performance measure is carried out to the product, 25cm is marked on finger2The region of square, coats used oil, after with 0.5g, the anhydrous hand cleaner agent sample is applied in this region, constantly reciprocally wiped with handss, after 1 minute, wipe washing dirt with gauze, no black greasy dirt in this region.Detection performance indications, show that product is qualified above.
Above-described embodiment is intended merely to the explanation present invention, and is not used as limitation of the invention, as long as in the essential scope of the present invention, the change, modification to above-described embodiment will all fall within the scope of the claims.
Claims (7)
1. a kind of preparation method of modified model anhydrous hand cleaner agent, it is characterised in that：Each component comprising Long carbon chain fatty acid, oiliness auxiliary agent, alkaline assistant, deionized water, essence is follow these steps to assemble：Long carbon chain fatty acid is dissolved in oil-based solvent, 70 DEG C are heated to, is stirred, form A liquid；Alkaline assistant is dissolved in into water, 80 DEG C are heated to, is stirred, form B liquid；B liquid is dividedly in some parts in A liquid, and is thermally formed mixed liquor while stirring, mix 10min；Lower the temperature under agitation, essence is finally added when temperature is down to 60 DEG C or so, then is down to room temperature, obtain final product product.
2. the preparation method of modified model anhydrous hand cleaner agent as claimed in claim 1, it is characterised in that Long carbon chain fatty acid is stearic acid, 4%-16% by weight.
3. the preparation method of modified model anhydrous hand cleaner agent as claimed in claim 1, it is characterised in that oiliness auxiliary agent is paraffin, 33%-79% by weight.
4. the preparation method of modified model anhydrous hand cleaner agent as claimed in claim 1, it is characterised in that alkaline assistant is triethanolamine, by weight 3.8%-10%.
5. the preparation method of modified model anhydrous hand cleaner agent as claimed in claim 1, it is characterised in that deionized water 13%-38% by weight.
6. the preparation method of modified model anhydrous hand cleaner agent as claimed in claim 1, it is characterised in that essence 0.2%-3% by weight.
7. as described in one of claim 1-6 the agent of modified model anhydrous hand cleaner preparation method, it is characterised in that by stearic acid 6.7%, be dissolved in 63.0% paraffin oil-based solvent, heated and stirred, formed A liquid；Triethanolamine 5.0% is dissolved in into 25% water and forms B liquid；Then B liquid is dividedly in some parts in A liquid, and is thermally formed mixed liquor while stirring, then lowered the temperature under agitation, 0.3% essence is finally added when temperature is down to 60 DEG C or so, then is down to room temperature, obtain final product product.
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| CN201510587987.6A CN106539712A (en) | 2015-09-16 | 2015-09-16 | A kind of preparation method of modified model anhydrous hand cleaner agent |
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| CN201510587987.6A CN106539712A (en) | 2015-09-16 | 2015-09-16 | A kind of preparation method of modified model anhydrous hand cleaner agent |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106166128A (en) * | 2016-08-16 | 2016-11-30 | 南通蛇类治疗研究所 | Exempt from water sterilizing abluent |
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| US4182686A (en) * | 1978-05-17 | 1980-01-08 | Sid Laks | Plastic wax cleaning and polishing composition and method of making same |
| CN1036225A (en) * | 1988-03-30 | 1989-10-11 | 王孟钟 | Nonaqueous lotion for hand |
| CN1051672A (en) * | 1989-11-15 | 1991-05-29 | 暨南稀土化工科技开发实业有限公司 | Exempt from the water washing frost |
| CN1061718A (en) * | 1990-11-21 | 1992-06-10 | 杨春山 | Multi-purpose washing and skin-protective cream |
| CN105476881A (en) * | 2014-09-17 | 2016-04-13 | 中国石油化工股份有限公司 | Water-free hand washing agent |
-
2015
- 2015-09-16 CN CN201510587987.6A patent/CN106539712A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4182686A (en) * | 1978-05-17 | 1980-01-08 | Sid Laks | Plastic wax cleaning and polishing composition and method of making same |
| CN1036225A (en) * | 1988-03-30 | 1989-10-11 | 王孟钟 | Nonaqueous lotion for hand |
| CN1051672A (en) * | 1989-11-15 | 1991-05-29 | 暨南稀土化工科技开发实业有限公司 | Exempt from the water washing frost |
| CN1061718A (en) * | 1990-11-21 | 1992-06-10 | 杨春山 | Multi-purpose washing and skin-protective cream |
| CN105476881A (en) * | 2014-09-17 | 2016-04-13 | 中国石油化工股份有限公司 | Water-free hand washing agent |
Non-Patent Citations (1)
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| 张桂秋: "《实用化工产品配方大全》", 31 July 1994, 江苏科学技术出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106166128A (en) * | 2016-08-16 | 2016-11-30 | 南通蛇类治疗研究所 | Exempt from water sterilizing abluent |
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Application publication date: 20170329 |