CN101402901A - Plaster shaped decontaminating agent of silicon dioxide with disinfection function and method of producing the same - Google Patents
Plaster shaped decontaminating agent of silicon dioxide with disinfection function and method of producing the same Download PDFInfo
- Publication number
- CN101402901A CN101402901A CNA2008102262910A CN200810226291A CN101402901A CN 101402901 A CN101402901 A CN 101402901A CN A2008102262910 A CNA2008102262910 A CN A2008102262910A CN 200810226291 A CN200810226291 A CN 200810226291A CN 101402901 A CN101402901 A CN 101402901A
- Authority
- CN
- China
- Prior art keywords
- acid
- liquid
- sodium
- parts
- stain remover
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention relates to a silicon dioxide paste eradicator with a disinfection function and a preparation method thereof. The invention is characterized in that replacement reaction is carried out on 10 to 20 portions of liquid dodecyl benzene sulfonic acid, 30 to 60 portions of liquid sodium silicate as well as 30 to 60 portions of water; then organic acid or inorganic acid is used for regulating the pH to be between 6.0 and 10.0 for obtaining a sticky and white mixture which comprises sodium dodecyl benzene sulfonate, deposited silicon dioxide particles and dissociative sodium silicate, and organic salt or inorganic salt; then the mixture is milled into the product of the silicon dioxide paste eradicator with the disinfection function by a colloid mill; liquid naphthenic acid, a disinfectant and carboxymethyl cellulose can also be added into the materials; the product has the advantages and effects of more effectively removing various oil stains and besmirches, neutral and alkalescent performances, being easily dissolved in water, less dosage, simple preparation method, being composed by one step and low production cost without damaging skins and fibers and containing alkali and sulphate.
Description
Technical field
The present invention relates to a kind of silicon-dioxide paste stain remover, belong to the stain remover field with sterilizing function.
The invention still further relates to the preparation method of this stain remover,
Background technology
Existing paste stain remover preparation method is complicated, raw material type is more, because alkali content and sulphate content height, the problem of hand and packing bag is often stabbed in easy crystallization in winter, and does not contain the frosted particle of silicon-dioxide, do not contain solvent, the ability of deoiling, and energy consumption height, price are expensive, the production cost height.Technology of the present invention adopts liquid Witco 1298 Soft Acid, liquid ring alkanoic acid and one step of liquid sodium silicate to finish neutralization reaction to this case raw material and prepares stain remover through the retrieval of Chinese patent information center, and Shang Weiyou openly reports.
Summary of the invention
Purpose of the present invention provides a kind of silicon-dioxide paste stain remover with sterilizing function in order to overcome the above-mentioned shortcoming that oneself has technology to exist with deficiency just, sterilizes and sterilizing function with having thereby can improve the decontamination ability of deoiling.
The present invention also provides the preparation method of this stain remover.
The objective of the invention is to realize by following technical proposal:
A kind of silicon-dioxide paste stain remover with sterilizing function is characterized in that its employing comprises the following weight proportion raw material through the replacement(metathesis)reaction one-step synthesis,
10～20 parts of liquid Witco 1298 Soft Acids
30～60 parts of liquid sodium silicates
30～60 parts in water,
Regulate pH value 6.0～10.0 with the pH value conditioning agent,
Described pH value conditioning agent is organic acid or mineral acid.
Also can add the liquid ring alkanoic acid in the described raw material and replace the liquid Witco 1298 Soft Acid, or the combination of liquid ring alkanoic acid and liquid Witco 1298 Soft Acid arbitrary proportion; Also can add 3～5 portions of ethylene glycol monoethyl ethers, 0.5～4.5 part of disinfection sanitizer, 0.5～2.0 part of carboxymethyl cellulose in the described raw material; Described disinfection sanitizer is a 4-chloro-3, one or more the combination wherein of 5-xylenol, 2,4-two chloro-3,5-xylenol or 2,4,4`-three chloro-2` dihydroxy diphenyl ethers.
The preparation method of stain remover, it is undertaken by following step:
Earlier 30～60 parts of liquid sodium silicates and 30～60 parts of water are added to stir in the agitator and add 10～20 parts of liquid Witco 1298 Soft Acids again and carry out replacement(metathesis)reaction, generate Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, after adding organic acid or mineral acid adjusting pH value to 6.0～10.0 again, obtain the mixture that contains Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, organic salt or inorganic salt of thickness white, grind with colloidal mill and make paste stain remover product.
Described preparation method also can be earlier adds 30～60 parts of liquid sodium silicates and 30～60 parts of water and stirs the composition that adds 10～20 parts of liquid ring alkanoic acids or liquid ring alkanoic acid and liquid Witco 1298 Soft Acid arbitrary proportion again in the agitator and carry out replacement(metathesis)reaction, generate the composition of sodium napthionate or sodium napthionate and Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, after adding organic acid or mineral acid adjusting pH value to 6.0～10.0 again, obtain the combination of sodium napthionate or the sodium napthionate and the Sodium dodecylbenzene sulfonate of thickness white, sedimentary silica dioxide granule and free water glass, the mixture of organic salt or inorganic salt is made paste stain remover product with the colloidal mill grinding.
Described preparation method also can be earlier adds 30～60 parts of liquid sodium silicates and 30～60 parts of water to stir in the agitator and adds 10～20 parts of liquid Witco 1298 Soft Acid line replacements reactions again, generate Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, after adding organic acid or mineral acid adjusting pH value to 6.0～10.0 again, obtain the Sodium dodecylbenzene sulfonate that contains of thickness white, sedimentary silica dioxide granule and free water glass, the mixture of organic salt or inorganic salt, add 3～5 portions of ethylene glycol monoethyl ethers more successively, 0.5 being thick back ,～4.5 parts of disinfection sanitizers and 0.5～2.0 part of carboxymethyl cellulose, stirring make silicon-dioxide paste stain remover product with sterilizing function with the colloidal mill grinding.
Described preparation method also can be earlier adds 30～60 parts of liquid sodium silicates and 30～60 parts of water and stirs the composition that adds 10～20 parts of liquid ring alkanoic acids or liquid ring alkanoic acid and liquid Witco 1298 Soft Acid arbitrary proportion again in the agitator and carry out replacement(metathesis)reaction, generate the composition of sodium napthionate or sodium napthionate and Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, after adding organic acid or mineral acid adjusting pH value to 6.0～10.0 again, obtain the combination of sodium napthionate or the sodium napthionate and the Sodium dodecylbenzene sulfonate of thickness white, sedimentary silica dioxide granule and free water glass, the mixture of organic salt or inorganic salt, add 3～5 portions of ethylene glycol monoethyl ethers more successively, 0.5 being thick back ,～4.5 parts of disinfection sanitizers and 0.5～2.0 part of carboxymethyl cellulose, stirring make silicon-dioxide paste stain remover product with sterilizing function with the colloidal mill grinding.
Described disinfection sanitizer is a 4-chloro-3, one or more the combination wherein of 5-xylenol, 2,4-two chloro-3,5-xylenol or 2,4,4`-three chloro-2` dihydroxy diphenyl ethers; But described organic acid citric acid, acetate, formic acid, oxalic acid or ethylenediamine tetraacetic acid (EDTA), mineral acid can be the mixing acid of phosphoric acid, hydrochloric acid or nitric acid or any one organic acid and mineral acid.
The liquid Witco 1298 Soft Acid that the present invention selects, it is an important monomer of producing Sodium dodecylbenzene sulfonate, normal Witco 1298 Soft Acid and the sodium hydroxide neutralization reaction of adopting produced Sodium dodecylbenzene sulfonate in the industrial production, the present invention carries out replacement(metathesis)reaction with liquid Witco 1298 Soft Acid and liquid sodium silicate, obtain the Sodium dodecylbenzene sulfonate that contains of thickness white, the mixture of sedimentary silica dioxide granule and free water glass, make silicon-dioxide paste stain remover product with the colloidal mill grinding, also liquid Witco 1298 Soft Acid and liquid ring alkanoic acid and liquid sodium silicate can be carried out replacement(metathesis)reaction, obtain the Sodium dodecylbenzene sulfonate that contains of thickness white, sodium napthionate, the mixture of sedimentary silica dioxide granule and free water glass, make silicon-dioxide paste stain remover product with the colloidal mill grinding, used naphthenic acid has another name called naphthenic acid, naphthoic acid, petroleum acid is the hydroxy derivatives of cycloalkanes hydroxyl.It is a kind of organic acid of separating from the petroleum products exquisiteness.Be used to make synthetic detergent, tensio-active agent, sterilant, sterilant, the precipitated silica particle is the soft abrasive material of oil removing, it can more effective removal remain in residual various greasy dirts and spot on metallic surface and the fabric face, thereby can improve soil removability, add the further replacement(metathesis)reaction of organic acid or mineral acid and mixture again and both removed got back washing assistant organic salt or inorganic salt of excessive alkali in the reaction, these two kinds of resultants have the effect of rib lotion again, finally obtain containing Sodium dodecylbenzene sulfonate, or Sodium dodecylbenzene sulfonate and sodium napthionate, the precipitated silica particle, the white aqueous solid mixture of organic salt sodium or inorganic salt, this stain remover is with tensio-active agent, stain remover, auxiliary agent, solvent organically combines one, do not produce any other material, and has a function of tensio-active agent, can make oily emulsification, and sedimentary silica dioxide granule, because its specific surface area is big, play and improve the ability effect of deoiling, its preparation method is simple, one-step synthesis, be that a kind of utmost point can be realized the product produced, this product is on probation by a plurality of users, the reaction consumption is few, the washing clean effect is good, especially the effect of deoiling is very obvious, and the adding of ethylene glycol monoethyl ether improves the ability of deoiling of stain remover and the speed of deoiling, the disinfection sanitizer that adopts is a 4-chloro-3, the 5-xylenol, 2,4-two chloro-3,5-xylenol or 2,4, a kind of or any two kinds combination of 4`-three chloro-2` dihydroxy diphenyl ethers, 4-chloro-3,5-xylenol, claim PCMX, molecular formula C abroad again
8H
9CI, it is a kind of antimildew and antibacterial agent of safe, efficient, wide spectrum, is widely used in the antiseptic-germicide of sanitary product, 2,4-two chloro-3,5-xylenol, trade(brand)name: DCMX or two chloro-m-cresols, molecular formula C
8H
8CI
2O, it also is a kind of safe antimildew and antibacterial agent, 2,4,4`-three chloro-2` dihydroxy diphenyl ethers, commodity triclosan by name or DP300, be praise highly in the world at present, efficiently, almost do not have a toxic disinfectant, be used for daily article for washing, carboxymethyl cellulose is stablizer, thickening material, can be made into the stain remover product of diverse fragrant flavour and different colours by the adding of essence and pigment.
Stain remover of the present invention adds nonionogenic tenside and softener again, can further improve foaming power, improves detersive power, improves the pliability of fiber.
With the stain remover of the inventive method preparation, as the manual dishwashing stain remover, head Jiangmen city Bureau of Technical Supervision is detected through Guangdong, and its result is:
Heavy metal 1mg/kg, (GB 1mg/kg)
Arsenic 0.01mg/kg (GB 0.05mg/kg)
Formaldehyde 0.01mg/kg (GB 0.1mg/kg)
Methyl alcohol 0.05mg/kg (GB 1mg/kg)
The result represents that this product reaches and is better than national standard.
Have following advantage and effect owing to take technique scheme to make the technology of the present invention and oneself have technology to compare:
(a) owing to contain the precipitated silica particle in the paste stain remover, has bigger specific surface area, it is the soft abrasive material of oil removing, can more effective removal remain in various greasy dirts and spot residual on metallic surface and the fabric face, thereby can improve soil removability, this product and commercially available washing powder, washing cream, liquid detergents compares, respectively to general greasy dirt, gear oil, chain oils is cleaned, and the result shows that this product washing speed is fast, can thoroughly clean up, and once finish, the product that oneself has can only be removed a part, can not thoroughly clean up, and repeatedly cleans and also leaves spot, illustrate that product of the present invention has the good decontamination effect of deoiling
(b) products obtained therefrom is neutral to weakly alkaline, not injured skin, do not destroy fiber, alkali-free, sulfur-bearing hydrochlorate not, the paste stain remover is soluble in water, consumption is few,
(c) preparation method is simple, and one-step synthesis has reduced production cost, three-waste free discharge again, and energy-conserving and environment-protective,
(d) raw material sources are wide, and kind is few.
Embodiment
Embodiment 1
Earlier 30kg liquid sodium silicate and 60kg water are added to stir in the agitator and add 10kg liquid Witco 1298 Soft Acid again and carry out replacement(metathesis)reaction, generate Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, after adding phosphoric acid regulating ph value to 6.0 again, obtain the mixture that contains Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, sodium phosphate of thickness white, grind with colloidal mill and make paste stain remover product.
Embodiment 2
Earlier 45kg liquid sodium silicate and 45kg water are added to stir in the agitator and add 15kg liquid Witco 1298 Soft Acid again and carry out replacement(metathesis)reaction, generate Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, after adding citric acid adjusting pH value to 8.0 again, obtain the mixture that contains Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, Citrate trianion of thickness white, grind with colloidal mill and make paste stain remover product.
Embodiment 3
Earlier 60kg liquid sodium silicate and 30kg water are added to stir in the agitator and add 20kg liquid Witco 1298 Soft Acid again and carry out replacement(metathesis)reaction, generate Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, after adding hydrochloric acid adjusting pH value to 10.0 again, obtain the mixture that contains Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, sodium-chlor of thickness white, grind with colloidal mill and make paste stain remover product.
Embodiment 4
Earlier 30kg liquid sodium silicate and 60kg water are added to stir in the agitator and add 18kg liquid ring alkanoic acid again and carry out replacement(metathesis)reaction, generate sodium napthionate, sedimentary silica dioxide granule and free water glass, after adding acetate adjusting pH value to 6.0 again, obtain the mixture that contains sodium napthionate, sedimentary silica dioxide granule and free water glass, sodium acetate of thickness white, add the 3kg ethylene glycol monoethyl ether again, stirring is thick back and makes paste stain remover product with the colloidal mill grinding.
Embodiment 5
Elder generation adds 10kg liquid Witco 1298 Soft Acid again with stirring in 45kg liquid sodium silicate and the 45kg water adding agitator and 10kg liquid ring alkanoic acid carries out replacement(metathesis)reaction, generate sodium napthionate, Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, after adding formic acid and hydrochloric acid adjusting pH value to 8.0 again, obtain the sodium napthionate that contains of thickness white, Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, the mixture of sodium formiate, add the 4kg ethylene glycol monoethyl ether again, stirring is thick back and makes paste stain remover product with the colloidal mill grinding.
Embodiment 6
Elder generation adds 8kg liquid Witco 1298 Soft Acid again with stirring in 30kg liquid sodium silicate and the 60kg water adding agitator and 2kg liquid ring alkanoic acid carries out replacement(metathesis)reaction, generate Sodium dodecylbenzene sulfonate, sodium napthionate, sedimentary silica dioxide granule and free water glass, after adding nitric acid and hydrochloric acid adjusting pH value to 10.0 again, obtain the Sodium dodecylbenzene sulfonate that contains of thickness white, sodium napthionate, sedimentary silica dioxide granule and free water glass, the mixture of SODIUMNITRATE, add the 5kg ethylene glycol monoethyl ether again, stirring is thick back and makes paste stain remover product with the colloidal mill grinding.
Embodiment 7
The mixture that contains Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, sodium phosphate of the thickness white that embodiment 1 is obtained, add 0.5kg4-chloro-3 more successively, 5-xylenol and 0.5kg carboxymethyl cellulose, stirring are thick back and make the silicon-dioxide paste stain remover product with sterilizing function with the colloidal mill grinding.
Embodiment 8
The mixture that contains Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, Citrate trianion of the thickness white that embodiment 2 is obtained, add 2.5kg 2 more successively, 4,4`-three chloro-2` dihydroxy diphenyl ethers and 1.0kg carboxymethyl cellulose, stirring are thick back and make the silicon-dioxide paste stain remover product with sterilizing function with the colloidal mill grinding.
Embodiment 9
The mixture that contains Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, sodium-chlor of the thickness white that embodiment 3 is obtained, add 2.0kg 4-chloro-3 more successively, 5-xylenol, 2.5kg 2,4-two chloro-3,5-xylenol and 2.0kg carboxymethyl cellulose, stirring are thick back and make the silicon-dioxide paste stain remover product with sterilizing function with the colloidal mill grinding.
Embodiment 10
The mixture that contains Sodium dodecylbenzene sulfonate, sodium napthionate, sedimentary silica dioxide granule and free water glass, sodium acetate of the thickness white that embodiment 4 is obtained, add 0.5kg4-chloro-3 more successively, 5-xylenol and 0.5kg carboxymethyl cellulose, stirring are thick back and make the silicon-dioxide paste stain remover product with sterilizing function with the colloidal mill grinding.
Embodiment 11
The mixture that contains Sodium dodecylbenzene sulfonate, sodium napthionate, sedimentary silica dioxide granule and free water glass, sodium formiate of the thickness white that embodiment 5 is obtained, add 2.5 kg 2 more successively, 4,4`-three chloro-2` dihydroxy diphenyl ethers and 1.0kg carboxymethyl cellulose, stirring are thick back and make the silicon-dioxide paste stain remover product that tool one has sterilizing function with the colloidal mill grinding.
Embodiment 12
The mixture that contains Sodium dodecylbenzene sulfonate, sodium napthionate, sedimentary silica dioxide granule and free water glass, SODIUMNITRATE of the thickness white that embodiment 6 is obtained, add 2.0kg 4-chloro-3 more successively, 5-xylenol and 2.5kg 2,4-two chloro-3,5-xylenol and 2.0kg carboxymethyl cellulose, stirring are thick back and make the silicon-dioxide paste stain remover product with sterilizing function with the colloidal mill grinding.
Claims (10)
1, a kind of silicon-dioxide paste stain remover with sterilizing function is characterized in that its employing comprises the following weight proportion raw material by the replacement(metathesis)reaction one-step synthesis,
10～20 parts of liquid Witco 1298 Soft Acids
30～60 parts of liquid sodium silicates
30～60 parts in water,
Regulate pH value 6.0～10.0 with the pH value conditioning agent,
Described pH value conditioning agent is organic acid or mineral acid.
2, stain remover according to claim 1 is characterized in that also can adding in the described raw material liquid ring alkanoic acid and replaces the liquid Witco 1298 Soft Acid, or the combination of liquid ring alkanoic acid and liquid Witco 1298 Soft Acid arbitrary proportion.
3, stain remover according to claim 1 and 2 is characterized in that also can adding in the described raw material 3～5 portions of ethylene glycol monoethyl ethers, 0.5～4.5 part of disinfection sanitizer, 0.5～2.0 part of carboxymethyl cellulose.
4, want 3 described stain removers according to right, it is characterized in that described disinfection sanitizer is a 4-chloro-3, one or more the combination wherein of 5-xylenol, 2,4-two chloro-3,5-xylenol or 2,4,4`-three chloro-2` dihydroxy diphenyl ethers.
5, the preparation method of stain remover according to claim 1 is characterized in that it is undertaken by following step:
Earlier 30～60 parts of liquid sodium silicates and 30～60 parts of water are added to stir in the agitator and add 10～20 parts of liquid Witco 1298 Soft Acids again and carry out replacement(metathesis)reaction, generate Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, after adding organic acid or mineral acid adjusting pH value to 6.0～10.0 again, obtain the mixture that contains Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, organic salt or inorganic salt of thickness white, grind with colloidal mill and make paste stain remover product.
6, want 5 described preparation methods according to right, it is characterized in that described preparation method also can be earlier adds 30～60 parts of liquid sodium silicates and 30～60 parts of water stirs the composition that adds 10～20 parts of liquid ring alkanoic acids or liquid ring alkanoic acid and liquid Witco 1298 Soft Acid arbitrary proportion again in the agitator and carries out replacement(metathesis)reaction, generate the composition of sodium napthionate or sodium napthionate and Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, after adding organic acid or mineral acid adjusting pH value to 6.0～10.0 again, obtain the combination of sodium napthionate or the sodium napthionate and the Sodium dodecylbenzene sulfonate of thickness white, sedimentary silica dioxide granule and free water glass, the mixture of organic salt or inorganic salt is made paste stain remover product with the colloidal mill grinding.
7, want 5 described preparation methods according to right, it is characterized in that described preparation method also can be earlier adds 30～60 parts of liquid sodium silicates and 30～60 parts of water to stir in the agitator adds 10～20 parts of liquid Witco 1298 Soft Acid line replacements reactions again, generate Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, after adding organic acid or mineral acid adjusting pH value to 6.0～10.0 again, obtain the Sodium dodecylbenzene sulfonate that contains of thickness white, sedimentary silica dioxide granule and free water glass, the mixture of organic salt or inorganic salt, add 3～5 portions of ethylene glycol monoethyl ethers more successively, 0.5 being thick back ,～4.5 parts of disinfection sanitizers and 0.5～2.0 part of carboxymethyl cellulose, stirring make silicon-dioxide paste stain remover product with sterilizing function with the colloidal mill grinding.
8, preparation method according to claim 5, it is characterized in that described preparation method also can be earlier adds 30～60 parts of liquid sodium silicates and 30～60 parts of water stirs the composition that adds 10～20 parts of liquid ring alkanoic acids or liquid ring alkanoic acid and liquid Witco 1298 Soft Acid arbitrary proportion again in the agitator and carries out replacement(metathesis)reaction, generate the composition of sodium napthionate or sodium napthionate and Sodium dodecylbenzene sulfonate, sedimentary silica dioxide granule and free water glass, after adding organic acid or mineral acid adjusting pH value to 6.0～10.0 again, obtain the combination of sodium napthionate or the sodium napthionate and the Sodium dodecylbenzene sulfonate of thickness white, sedimentary silica dioxide granule and free water glass, the mixture of organic salt or inorganic salt, add 3～5 portions of ethylene glycol monoethyl ethers more successively, 0.5 being thick back ,～4.5 parts of disinfection sanitizers and 0.5～2.0 part of carboxymethyl cellulose, stirring make silicon-dioxide paste stain remover product with sterilizing function with the colloidal mill grinding.
9,, it is characterized in that described disinfection sanitizer is a 4-chloro-3, one or more the combination wherein of 5-xylenol, 2,4-two chloro-3,5-xylenol or 2,4,4`-three chloro-2` dihydroxy diphenyl ethers according to claim 7 or 8 described preparation methods.
10, according to the described stain remover of claim 1～4, but it is characterized in that described organic acid citric acid, acetate, formic acid, oxalic acid or ethylenediamine tetraacetic acid (EDTA), mineral acid can be the mixing acid of phosphoric acid, hydrochloric acid or nitric acid or any one organic acid and mineral acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008102262910A CN101402901B (en) | 2008-11-12 | 2008-11-12 | Plaster shaped decontaminating agent of silicon dioxide with disinfection function and method of producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008102262910A CN101402901B (en) | 2008-11-12 | 2008-11-12 | Plaster shaped decontaminating agent of silicon dioxide with disinfection function and method of producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101402901A true CN101402901A (en) | 2009-04-08 |
| CN101402901B CN101402901B (en) | 2010-12-29 |
Family
ID=40537067
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008102262910A Expired - Fee Related CN101402901B (en) | 2008-11-12 | 2008-11-12 | Plaster shaped decontaminating agent of silicon dioxide with disinfection function and method of producing the same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101402901B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102899193A (en) * | 2012-10-31 | 2013-01-30 | 青岛美高集团有限公司 | Novel environmentally friendly efficient oil stain cleaning agent and preparation method thereof |
| CN103509656A (en) * | 2012-06-20 | 2014-01-15 | 上海和黄白猫有限公司 | Friction particle-containing liquid dish washing detergent |
| CN103509657A (en) * | 2013-10-17 | 2014-01-15 | 太仓康茂电子有限公司 | Component surface cleaning method |
| CN110862876A (en) * | 2019-11-06 | 2020-03-06 | 珠海格力电器股份有限公司 | Gel type detergent with high decontamination efficiency and preparation method thereof |
-
2008
- 2008-11-12 CN CN2008102262910A patent/CN101402901B/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103509656A (en) * | 2012-06-20 | 2014-01-15 | 上海和黄白猫有限公司 | Friction particle-containing liquid dish washing detergent |
| CN103509656B (en) * | 2012-06-20 | 2018-03-27 | 上海和黄白猫有限公司 | A kind of liquid dishwashing detergent containing friction particles |
| CN102899193A (en) * | 2012-10-31 | 2013-01-30 | 青岛美高集团有限公司 | Novel environmentally friendly efficient oil stain cleaning agent and preparation method thereof |
| CN102899193B (en) * | 2012-10-31 | 2015-01-14 | 青岛美高集团有限公司 | Novel environmentally friendly efficient oil stain cleaning agent and preparation method thereof |
| CN103509657A (en) * | 2013-10-17 | 2014-01-15 | 太仓康茂电子有限公司 | Component surface cleaning method |
| CN110862876A (en) * | 2019-11-06 | 2020-03-06 | 珠海格力电器股份有限公司 | Gel type detergent with high decontamination efficiency and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101402901B (en) | 2010-12-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US7196046B2 (en) | Hard surface cleaner comprising a suspension of alginate beads | |
| EP2102325B1 (en) | Aqueous highly acidic hard surface cleaning compositions | |
| US7186676B2 (en) | Hard surface cleaning compositions comprising alginate materials and xanthan gum | |
| EP1994129B1 (en) | Aqueous highly acidic hard surface cleaning compositions | |
| US7119055B2 (en) | Hard surface cleaners comprising a thickening gum mixture | |
| US7288512B2 (en) | Hard surface cleaning compositions comprising suspended alginate inclusions | |
| EP1597346B1 (en) | Hard surface cleaning compositions | |
| US20230295534A1 (en) | Galactarate based metal sequestration composition | |
| CN101402901B (en) | Plaster shaped decontaminating agent of silicon dioxide with disinfection function and method of producing the same | |
| CN101463293A (en) | Perfuming viscous type acidic closestool cleanser | |
| WO2006136774A1 (en) | Acidic hard surface cleaning composition comprising formic acid | |
| EP1597345B1 (en) | Hard surface cleaning compositions | |
| CA2712470A1 (en) | Light duty liquid cleaning compositions and methods of manufacture and use thereof | |
| WO2015171089A1 (en) | Use of oxidized humic acid its salts and derivatives in dishwashing compositions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20101229 Termination date: 20111112 |