CN106520367A - Preparation method of wolfberry reactant for cigarette - Google Patents
Preparation method of wolfberry reactant for cigarette Download PDFInfo
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- CN106520367A CN106520367A CN201610854655.4A CN201610854655A CN106520367A CN 106520367 A CN106520367 A CN 106520367A CN 201610854655 A CN201610854655 A CN 201610854655A CN 106520367 A CN106520367 A CN 106520367A
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- fructus lycii
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- 239000000376 reactant Substances 0.000 title claims abstract description 26
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 24
- 244000241838 Lycium barbarum Species 0.000 title claims abstract description 20
- 235000015459 Lycium barbarum Nutrition 0.000 title claims abstract description 20
- 235000015468 Lycium chinense Nutrition 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims abstract description 30
- 239000000284 extract Substances 0.000 claims abstract description 24
- 238000004108 freeze drying Methods 0.000 claims abstract description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000000605 extraction Methods 0.000 claims abstract description 11
- 238000001914 filtration Methods 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims description 19
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 16
- 235000013399 edible fruits Nutrition 0.000 claims description 15
- 235000017784 Mespilus germanica Nutrition 0.000 claims description 14
- 244000182216 Mimusops elengi Species 0.000 claims description 14
- 235000000560 Mimusops elengi Nutrition 0.000 claims description 14
- 235000007837 Vangueria infausta Nutrition 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 11
- 239000000706 filtrate Substances 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- 229910021529 ammonia Inorganic materials 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 6
- 238000010298 pulverizing process Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 5
- 238000002203 pretreatment Methods 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 230000008719 thickening Effects 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 241000207199 Citrus Species 0.000 claims description 2
- 244000126002 Ziziphus vulgaris Species 0.000 claims description 2
- 235000020971 citrus fruits Nutrition 0.000 claims description 2
- 235000012907 honey Nutrition 0.000 claims description 2
- 238000012792 lyophilization process Methods 0.000 claims description 2
- 238000012360 testing method Methods 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 7
- 239000003205 fragrance Substances 0.000 abstract description 7
- 239000000779 smoke Substances 0.000 abstract description 4
- 239000000796 flavoring agent Substances 0.000 abstract description 3
- 235000019634 flavors Nutrition 0.000 abstract description 3
- 235000009508 confectionery Nutrition 0.000 abstract 1
- 230000000638 stimulation Effects 0.000 abstract 1
- 235000019605 sweet taste sensations Nutrition 0.000 abstract 1
- 235000001014 amino acid Nutrition 0.000 description 6
- 150000001413 amino acids Chemical class 0.000 description 6
- 235000000346 sugar Nutrition 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 230000001476 alcoholic effect Effects 0.000 description 3
- 239000003546 flue gas Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 244000061176 Nicotiana tabacum Species 0.000 description 2
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000008518 lycium barbarum polysaccharide Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- DWNBOPVKNPVNQG-LURJTMIESA-N (2s)-4-hydroxy-2-(propylamino)butanoic acid Chemical compound CCCN[C@H](C(O)=O)CCO DWNBOPVKNPVNQG-LURJTMIESA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 235000002710 Ilex cornuta Nutrition 0.000 description 1
- 241001310146 Ilex cornuta Species 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 1
- ONIBWKKTOPOVIA-BYPYZUCNSA-N L-Proline Chemical compound OC(=O)[C@@H]1CCCN1 ONIBWKKTOPOVIA-BYPYZUCNSA-N 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 241001106041 Lycium Species 0.000 description 1
- 235000010326 Osmanthus heterophyllus Nutrition 0.000 description 1
- ONIBWKKTOPOVIA-UHFFFAOYSA-N Proline Natural products OC(=O)C1CCCN1 ONIBWKKTOPOVIA-UHFFFAOYSA-N 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000000259 anti-tumor effect Effects 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 230000036772 blood pressure Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001728 carbonyl compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000035613 defoliation Effects 0.000 description 1
- 235000011869 dried fruits Nutrition 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 238000000874 microwave-assisted extraction Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002772 monosaccharides Chemical class 0.000 description 1
- 235000008935 nutritious Nutrition 0.000 description 1
- 230000000144 pharmacologic effect Effects 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B3/00—Preparing tobacco in the factory
- A24B3/12—Steaming, curing, or flavouring tobacco
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0003—Compounds of unspecified constitution defined by the chemical reaction for their preparation
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Medicines Containing Plant Substances (AREA)
Abstract
The invention provides a preparation method of a wolfberry reactant for cigarette. The wolfberry reactant for cigarette is prepared by the following steps: freeze-drying wolfberry and then crushing, carrying out low-temperature extraction by adding 40-70% ethanol, filtering an extracting solution and carrying out low-temperature vacuum concentration, and finally carrying out a Maillard reaction. According to the invention, wolfberry can be extracted and concentrated at low temperature so as to maintain the original flavor of the extract to the maximum, and through the maillard reaction, aroma and fragrance of the extract are further enriched and smoke panel test effect of the extract in the cigarette is improved. In comparison with a common wolfberry extract, the prepared reactant has good compatibility with smoke, has rich fragrance, increases sweet taste, and can be applied to cigarette so as to increase sweet aroma, refine and soften smoke and reduce stimulation.
Description
Technical field
The invention belongs to essence spice for cigarette additive preparing technical field, and in particular to a kind of cigarette medlar reactant
Preparation method.
Background technology
Fructus Lycii is Solanaceae Lycium defoliation bush plant, is the important economic plant resources of China, and it is not only nutritious,
And there are multiple pharmacological effect and the physiological active functionses such as antitumor, anti-aging, lowering blood pressure and blood fat.Containing abundant carbon in Fructus Lycii
Hydrate, up to 39.5%, content of reducing sugar is also higher for its total sugar content, accounts for the 1/3 of dried fruit of lycium barbarum total amount；Except tool in Fructus Lycii
Have outside the lycium barbarum polysaccharide of physiological activity, also containing various monosaccharide such as glucose, Fructose.In addition, in Fructus Lycii containing ferrum, zinc,
The various trace elements such as calcium, lithium, selenium, germanium, and 18 kinds of aminoacid needed by human, wherein with aspartic acid, glutamic acid, third
The content of propylhomoserin and proline is higher, and free amino acid accounts for more than the 50% of total amino acid content, is conducive to absorption of human body.
In recent years, the research of Fructus Lycii is focused mostly in lycium barbarum polysaccharide, Fructus Lycii acid and Fructus Lycii total alkaloidss isoreactivity into
Divide and extracted, extracting method mainly has immersion method, ultrasonic method, microwave method and enzyme process etc., as technics comparing falls behind so that carry
Take yield and purity is relatively low, it is impossible to which its effective ingredient is made full use of, cause the serious waste of resource.And for Fructus Lycii is extracted
Thing is less as the research that spice is applied in Medicated cigarette.
Maillard reaction is a kind of non-enzymatic browning for being widely present in food industry, be carbonyl compound (recuding sugars) and
Reaction between amino-compound (amino acid and protein), so react also known as carbonyl ammonia.The technology is fragrant in meat flavoring and Nicotiana tabacum L.
There is extraordinary application in essence, the essence for being formed has the vivid effect of natural essence, have the work that blending technology is incomparable
With.As Fructus Lycii itself contains substantial amounts of aminoacid and reducing sugar composition, therefore, it is especially suitable for carrying out Maillard reaction.
The content of the invention
It is an object of the invention to provide a kind of preparation method of cigarette medlar reactant, the method combine leach at low temperature and
Maillard reaction technology is realizing the preparation to cigarette medlar reactant.
For achieving the above object, the technical scheme of present invention offer is：A kind of preparation side of the cigarette medlar reactant
Method, it comprises the following steps：
(1) pre-treatment：The impurity in Fructus Lycii is removed, and Fructus Lycii is cleaned；
(2) pre-cooling and lyophilization：The Fructus Lycii pre-cooling that will be handled well in step (1), and be -30～-40 DEG C in temperature
Under the conditions of carry out vacuum lyophilization process 1～2h, vacuum keep 5～10Pa；
(3) crush：Fructus Lycii after lyophilization is crushed, degree of grinding is 80～100 mesh；
(4) leach at low temperature：Fructus Lycii powder after pulverization process is placed in thermostat water bath according to solid-to-liquid ratio 1:6～1:10
Ratio add the alcohol solvent that concentration is 40～70%, then extract 3～6h under conditions of 50～60 DEG C of temperature, and to carrying
Taking liquid carries out sucking filtration, collects filtrate；
(5) it is concentrated in vacuo：Cryogenic vacuum concentration is carried out to the filtrate after leach at low temperature in step (4), and thickening temperature is set
For 50～60 DEG C, cycles of concentration is 5～7 times, obtains wolfberry fruit extract；
(6) Maillard reaction：Wolfberry fruit extract in step (5) is placed in oil bath pan, and adds its weight 2%～5%
Ammonia (ammonia concn is 28%), 90～110 DEG C of keeping temperature, 120～150r/min of stir speed (S.S.), 2～3h of response time；
After Maillard reaction terminates, stopping is heated and is down to room temperature；
(7) allocate：To in step (6), reaction terminates and is reduced to addition reactant quality percentage ratio in the reactant of room temperature
For 3%～5% fruital Mel, Fructus Lycii maillard reaction thing after stirring, is.
The present invention preferably technical scheme：The precooling temperature before lyophilization is carried out in step (2) to Fructus Lycii for -20
～-25 DEG C, pre-coo time is 1～2h.
The present invention preferably technical scheme：The Fructus Lycii after leach at low temperature is extracted using buchner funnel in step (4)
Liquid is filtered.
Preferably, in step (4), the concentration of ethanol is 50%, and extraction temperature is 55 DEG C, extraction time 5h,
Solid-to-liquid ratio 1:8.
Preferably, the ammonia of its weight 3%, 100 DEG C of keeping temperature, stir speed (S.S.) is added in step (6)
For 130r/min, the response time is 2.5h.
Preferably：The fruital Mel in step (7) includes Fructus Litchi Mel, Citrus Mel, jujube flower honey.
In the present invention, involved concentration of alcohol, each means weight concentration, such as 50% ethanol, refers to every 100g ethanol waters
In solution, containing ethanol 50g.
It is an advantage of the current invention that：
1st, the present invention carries out freeze-drying process to Fructus Lycii, and the processing method is dried to raw material at low temperature, can
Preserve the original flavor characteristic of Fructus Lycii；Meanwhile, Fructus Lycii quality can be made to become fragile, it is easy to carry out next step crushing.
2nd, the present invention adopts pulverization process to Fructus Lycii, is conducive to more fully extracting the effective ingredient of Fructus Lycii.
3rd, the present invention adopts leach at low temperature to Fructus Lycii powder, and the method Extracting temperature is low, effective ingredient can be avoided to be heated
Destruction, so that ensure that the aroma quality of extract.
4th, the present invention carries out Maillard reaction to wolfberry fruit extract, further enriches its fragrance, fragrance so as to Neng Gougeng
Coordinate with Gas phase Smoke well, so as to improve the effect of smokeing panel test of Medicated cigarette；And the Maillard reaction in the present invention can be by means of Chinese holly
The abundant aminoacid of Qi itself and reducing sugar composition, without the need for additional amino and reducing sugar composition, make reactant at utmost keep
The unique flavor characteristic of Fructus Lycii, fragrance are more coordinated, and operate easier.
Specific embodiment
With reference to specific embodiment, the present invention is further illustrated.
Embodiment 1, a kind of preparation method of cigarette medlar reactant, it comprises the following steps：
(1) pre-treatment：The impurity in Fructus Lycii is removed, and Fructus Lycii is cleaned；
(2) lyophilization：The Fructus Lycii handled well in step (1) is carried out into freeze-drying process, wherein, precooling temperature for-
25 DEG C, pre-coo time is 1h；Vacuum lyophilization temperature is -40 DEG C, and time 1h, vacuum keep 5～10Pa；
(3) crush：Fructus Lycii after lyophilization is crushed, degree of grinding is 80 mesh；
(4) leach at low temperature：Fructus Lycii powder after pulverization process is placed in thermostat water bath, the second that concentration is 50% is added
Alcoholic solvent, carries out extracts active ingredients to which；50 DEG C of extraction temperature, extraction time 4h, solid-to-liquid ratio 1:7；
(5) filter：Sucking filtration is carried out to the fructus lycii extracted solution after leach at low temperature using buchner funnel, collects filtrate；
(6) it is concentrated in vacuo：Cryogenic vacuum concentration is carried out to the filtrate after leach at low temperature in step (5), and thickening temperature is set
For 50 DEG C, cycles of concentration is 5 times, obtains wolfberry fruit extract；
(7) Maillard reaction：Wolfberry fruit extract in step (6) is placed in oil bath pan, and adds the ammonia of its weight 3%
(concentration 28%), 90 DEG C of keeping temperature, stir speed (S.S.) 120r/min, response time 2h；
(8) cool down：After in step (7), Maillard reaction terminates, stopping is heated and is down to room temperature；
(9) allocate：The fruital Mel that its mass percent is 3% is added in the reactant in step (8), is stirred
Fructus Lycii maillard reaction thing is afterwards.
Embodiment 2, a kind of preparation method of cigarette medlar reactant, it comprises the following steps：
(1) pre-treatment：The impurity in Fructus Lycii is removed, and Fructus Lycii is cleaned；
(2) lyophilization：The Fructus Lycii handled well in step (1) is carried out into freeze-drying process, wherein, precooling temperature for-
23 DEG C, pre-coo time is 1.5h；Vacuum lyophilization temperature is -35 DEG C, and time 1.5h, vacuum keep 5～10Pa；
(3) crush：Fructus Lycii after lyophilization is crushed, degree of grinding is 90 mesh；
(4) leach at low temperature：Fructus Lycii powder after pulverization process is placed in thermostat water bath, the second that concentration is 60% is added
Alcoholic solvent, carries out extracts active ingredients to which；55 DEG C of extraction temperature, extraction time 5h, solid-to-liquid ratio 1:8；
(5) filter：Sucking filtration is carried out to the fructus lycii extracted solution after leach at low temperature using buchner funnel, collects filtrate；
(6) it is concentrated in vacuo：Cryogenic vacuum concentration is carried out to the filtrate after leach at low temperature in step (5), and thickening temperature is set
For 55 DEG C, cycles of concentration is 6 times, obtains wolfberry fruit extract；
(7) Maillard reaction：Wolfberry fruit extract in step (6) is placed in oil bath pan, and adds the ammonia of its weight 4%
(concentration 28%), 100 DEG C of keeping temperature, stir speed (S.S.) 130r/min, response time 2.5h；
(8) cool down：After in step (7), Maillard reaction terminates, stopping is heated and is down to room temperature；
(9) allocate：The fruital Mel that its mass percent is 4% is added in reactant in step (8), after stirring
As Fructus Lycii maillard reaction thing.
Embodiment 3, a kind of preparation method of cigarette medlar reactant, it comprises the following steps：
(1) pre-treatment：The impurity in Fructus Lycii is removed, and Fructus Lycii is cleaned；
(2) lyophilization：The Fructus Lycii handled well in step (1) is carried out into freeze-drying process, wherein, precooling temperature for-
20 DEG C, pre-coo time is 2h；Vacuum lyophilization temperature is -30 DEG C, and time 2h, vacuum keep 5～10Pa；
(3) crush：Fructus Lycii after lyophilization is crushed, degree of grinding is 100 mesh；
(4) leach at low temperature：Fructus Lycii powder after pulverization process is placed in thermostat water bath, the second that concentration is 70% is added
Alcoholic solvent, carries out extracts active ingredients to which；60 DEG C of extraction temperature, extraction time 6h, solid-to-liquid ratio 1:10；
(5) filter：Sucking filtration is carried out to the fructus lycii extracted solution after leach at low temperature using buchner funnel, collects filtrate；
(6) it is concentrated in vacuo：Cryogenic vacuum concentration is carried out to the filtrate after leach at low temperature in step (5), and thickening temperature is set
For 60 DEG C, cycles of concentration is 7 times, obtains wolfberry fruit extract；
(7) Maillard reaction：Wolfberry fruit extract in step (6) is placed in oil bath pan, and adds the ammonia of its weight 5%
(concentration 28%), 110 DEG C of keeping temperature, stir speed (S.S.) 150r/min, response time 3h；
(8) cool down：After in step (7), Maillard reaction terminates, stopping is heated and is down to room temperature；
(9) allocate：The fruital Mel that its mass percent is 5% is added in reactant in step (8), after stirring
As Fructus Lycii maillard reaction thing.
Fructus Lycii maillard reaction thing obtained in embodiment 1-3 is added separately to Medicated cigarette in 0.5 ‰ ratio by test example 1
In tobacco shred, while with common wolfberry fruit extract embodiment 1 and comparative example 2 as a comparison, wherein comparative example 1 be by
Fructus Lycii carries out microwave extraction, extracts what is be concentrated to give after filtering；Comparative example 2 is, by Fructus Lycii alcohol reflux, to extract
Obtain after liquid is filtered and after concentration, effect of specifically smokeing panel test is shown in Table 1.
The effect test of smokeing panel test of 1 embodiment of table and comparative example
Test finds that the Fructus Lycii maillard reaction thing prepared using the method for the present invention can significantly improve the fragrance of Medicated cigarette,
The zest of flue gas, good with flue gas harmony and fine and smooth soft flue gas is reduced, effect is substantially better than and is prepared using conventional method
Wolfberry fruit extract.And the synthesis of embodiment 2 smokes panel test effect slightly better than embodiment 1 and 3.
Test example 2, the composition of the Fructus Lycii maillard reaction thing in embodiment 2 is analyzed, its concrete component analyses knot
Fruit is shown in Table 2.
2 Fructus Lycii maillard reaction thing component analyses of table
Analyzed by makings, detect 35 kinds of volatile ingredients in embodiment 2 altogether, including various acids, ketone and esters
Deng material, composition quantity will be more than comparative example.Experiment results proved, can make the fragrance of Fructus Lycii richer through Maillard reaction
It is rich.
Claims (6)
1. a kind of preparation method of cigarette medlar reactant, it is characterised in that comprise the following steps：
(1) pre-treatment：The impurity in Fructus Lycii is removed, and Fructus Lycii is cleaned；
(2) pre-cooling and lyophilization：The Fructus Lycii pre-cooling that will be handled well in step (1), and carry out under conditions of -30～-40 DEG C
Vacuum lyophilization processes 1～2h, and vacuum keeps 5～10Pa；
(3) crush：Fructus Lycii after lyophilization is crushed, degree of grinding is 80～100 mesh；
(4) leach at low temperature：Fructus Lycii powder after pulverization process is placed in thermostat water bath according to solid-to-liquid ratio 1:6～1:10 ratio
Example adds the alcohol solvent that concentration is 40～70%, then extracts 3～6h under conditions of 50～60 DEG C of temperature, and to extracting solution
Sucking filtration is carried out, filtrate is collected；
(5) it is concentrated in vacuo：Cryogenic vacuum concentration is carried out to the filtrate after leach at low temperature in step (4), and it is 50 to arrange thickening temperature
～60 DEG C, cycles of concentration is 5～7 times, obtains wolfberry fruit extract；
(6) Maillard reaction：Wolfberry fruit extract in step (5) is placed in oil bath pan, and adds the ammonia of its weight 2%～5%
Water, 90～110 DEG C of keeping temperature, 120～150r/min of stir speed (S.S.), 2～3h of response time；After Maillard reaction terminates,
Stopping is heated and is down to room temperature；
(7) allocate：Terminating and be reduced to addition reactant quality percentage ratio in the reactant of room temperature to the middle reaction of step (6) is
3%～5% fruital Mel, is Fructus Lycii maillard reaction thing after stirring.
2. the preparation method of cigarette medlar reactant as claimed in claim 1, it is characterised in that：To Fructus Lycii in step (2)
The precooling temperature before lyophilization is carried out for -20～-25 DEG C, pre-coo time is 1～2h.
3. the preparation method of cigarette medlar reactant as described in the appended claim 1, it is characterised in that：Adopt in step (4)
Buchner funnel is filtered to the fructus lycii extracted solution after leach at low temperature.
4. the preparation method of cigarette medlar reactant as described in the appended claim 1, it is characterised in that：Ethanol in step (4)
Concentration be 50%, extraction temperature be 55 DEG C, extraction time 5h, solid-to-liquid ratio 1:8.
5. the preparation method of cigarette medlar reactant as described in the appended claim 1, it is characterised in that：Add in step (6)
The ammonia of its weight 3%, 100 DEG C of keeping temperature, stir speed (S.S.) are 130r/min, and the response time is 2.5h.
6. the preparation method of cigarette medlar reactant as described in the appended claim 1, it is characterised in that：The fruit in step (7)
Fragrant Mel includes Fructus Litchi Mel, Citrus Mel, jujube flower honey.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108424814A (en) * | 2018-03-20 | 2018-08-21 | 甘肃烟草工业有限责任公司 | A kind of preparation method of matrimony vine essence and the application in cigarette |
| CN109275952A (en) * | 2018-12-06 | 2019-01-29 | 武汉纺织大学 | A kind of preparation method of compound cigarette filter |
| CN109275953A (en) * | 2018-12-06 | 2019-01-29 | 武汉纺织大学 | A kind of preparation method of fiber base cigarette filter |
| CN111374345A (en) * | 2018-12-29 | 2020-07-07 | 贵州中烟工业有限责任公司 | Method for preparing Maillard reaction product by using medlar extract, Maillard reaction product and application |
| CN111808681A (en) * | 2020-07-20 | 2020-10-23 | 广西中烟工业有限责任公司 | Preparation method of lycium ruthenicum murr spice for cigarettes and application of lycium ruthenicum murr spice in cigarettes |
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| CN104830530A (en) * | 2015-04-27 | 2015-08-12 | 湖北中烟工业有限责任公司 | Preparation method of red date Maillard reactant for cigarettes |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108424814A (en) * | 2018-03-20 | 2018-08-21 | 甘肃烟草工业有限责任公司 | A kind of preparation method of matrimony vine essence and the application in cigarette |
| CN109275952A (en) * | 2018-12-06 | 2019-01-29 | 武汉纺织大学 | A kind of preparation method of compound cigarette filter |
| CN109275953A (en) * | 2018-12-06 | 2019-01-29 | 武汉纺织大学 | A kind of preparation method of fiber base cigarette filter |
| CN109275953B (en) * | 2018-12-06 | 2021-02-02 | 武汉纺织大学 | Preparation method of fiber-based cigarette filter |
| CN109275952B (en) * | 2018-12-06 | 2021-02-02 | 武汉纺织大学 | Preparation method of composite cigarette filter tip |
| CN111374345A (en) * | 2018-12-29 | 2020-07-07 | 贵州中烟工业有限责任公司 | Method for preparing Maillard reaction product by using medlar extract, Maillard reaction product and application |
| CN111808681A (en) * | 2020-07-20 | 2020-10-23 | 广西中烟工业有限责任公司 | Preparation method of lycium ruthenicum murr spice for cigarettes and application of lycium ruthenicum murr spice in cigarettes |
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