CN106519907B - 一种高弹体抗磨耐候导电防腐蚀舰船舵陶瓷涂料组合物 - Google Patents

一种高弹体抗磨耐候导电防腐蚀舰船舵陶瓷涂料组合物 Download PDF

Info

Publication number
CN106519907B
CN106519907B CN201611066511.9A CN201611066511A CN106519907B CN 106519907 B CN106519907 B CN 106519907B CN 201611066511 A CN201611066511 A CN 201611066511A CN 106519907 B CN106519907 B CN 106519907B
Authority
CN
China
Prior art keywords
agent
mesh
naval vessel
elastomer
wear
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201611066511.9A
Other languages
English (en)
Other versions
CN106519907A (zh
Inventor
黄福川
李康春
邓富康
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangxi University
Original Assignee
Guangxi University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangxi University filed Critical Guangxi University
Priority to CN201611066511.9A priority Critical patent/CN106519907B/zh
Publication of CN106519907A publication Critical patent/CN106519907A/zh
Application granted granted Critical
Publication of CN106519907B publication Critical patent/CN106519907B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1687—Use of special additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24—Electrically-conducting paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20—Diluents or solvents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种高弹体抗磨耐候导电防腐蚀舰船舵陶瓷涂料组合物，采用双酚F环氧树脂为基料，配合多种复合添加剂，包括：增韧剂、溶剂、导电剂、固化剂、助剂、流平剂、陶瓷粉填料，其中陶瓷粉填料含二氧化钛、氮化硅、氧化铈及棕钢玉。本发明的组合物具有单体价格低廉，合成与施工工艺简单，导电性能、附着强度、抗剪切性、撕裂性、抗冲击怏好，防腐蚀、抗盐水浸泡和生物附着物能力强。

Description

一种高弹体抗磨耐候导电防腐蚀舰船舵陶瓷涂料组合物
技术领域
本发明一种高弹体抗磨耐候导电防腐蚀舰船舵陶瓷涂料组合物属于船舶涂料领域。
背景技术
舵是舰船航行方向及稳定性的重要舰船设置，通常设置在舰船尾部及推进器后方。再其使用过程中由于长期浸泡在海水中，舵体会受到海水侵蚀和生物富聚。若是采用青铜质的材质舵。就会出现绿色的被氧化物，若采用钢质的舵，就会出现褐色或暗红色的被氧化物；此外当螺旋桨推进引起的高速水流冲刷并伴随空气作用，也会导致舵的机械损伤，产生点蚀和麻坑。而加工不良的舵在使用中，也会发生电化学腐蚀；另外，当舰船停靠码头泊位，接通陆上电源时，也产生杂散电流引起的腐蚀。从舰船使用寿命来分析，舵相对船体的大部分来说，更容易受到腐蚀。在涂料施工中采用双组分聚氨酯，底漆采用云母氧化铁底漆。
虽然舰船的舵在使用中发生腐蚀属于正常现象。但从统计资料可知舰船使用的舵的涂层在较短的使用时间(10～18个月)就可能发生严重脱落。经研究分析；导致涂层脱落的原因；从外因来说；有海水腐蚀、异物腐蚀、阴极腐蚀、空气泡腐蚀等综合原因影响；其中空气泡腐蚀危害较重；而内部原因则是；涂料选择和舵材料两个问题。
发明内容
本发明要解决的技术问题是提供一种高弹体抗磨耐候导电防腐蚀舰船舵陶瓷涂料组合物。
本发明采用如下技术方案解决上述技术问题：
一种高弹体抗磨耐候导电防腐蚀舰船舵陶瓷涂料组合物，采用双酚F环氧树脂为基料，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量
双酚F环氧树脂 30～35％
增韧剂 5～7％
溶剂 22～24％
导电剂 2.2～2.5％
固化剂 3～4％
助剂 0.8～1.2％
流平剂 2～3％
填料 23.5～35％
以上各组分的质量百分比总和为100％。
增韧剂是邻丙二甲酸丁酯。
溶剂是质量比50％的异丙醇和50％的丙二醚丁醚复合。
导电剂是石墨烯。
固化剂是改性聚酰胺Ancamide2353。
助剂是质量比60％的聚硅烷和40％的硅树脂复合。
流平剂是正戊基丙烯酯。
填料是陶瓷粉，所述质量百分比含量为23.5～35％的陶瓷粉含有以下质量百分比的各组分：5～7％的400目二氧化钛、9～11％的400目高铝钒土熟料、3～7％的400目氮化硅、5～7％的400目氧化铈和1.5～3％的325目棕刚玉。
本发明的显著优点在于：
本发明的组合物具有单体价格低廉，合成与施工工艺简单，导电性能、附着强度、抗剪切性、撕裂性、抗冲击怏好，防腐蚀、抗盐水浸泡和生物附着物能力强。
具体实施方式
实施例1：
将下列各组分按质量百分比调和而成：
以上各组分的质量百分比总和为100％。
实施例2：
将下列各组分按质量百分比调和而成：
以上各组分的质量百分比总和为100％。
实施例3：将下列各组分按质量百分比调和而成：
以上各组分的质量百分比总和为100％。
实施例1产品典型技术指标
实施例2产品典型技术指标
实施例3产品典型技术指标

Claims (1)

1.一种高弹体抗磨耐候导电防腐蚀舰船舵陶瓷涂料组合物，其特征在于：采用双酚F环氧树脂为基料，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量 双酚F环氧树脂 30～35% 增韧剂 5～7% 溶剂 22～24% 导电剂 2.2～2.5% 固化剂 3～4% 助剂 0.8～1.2% 流平剂 2～3% 填料 23.5～35%
以上各组分的质量百分比总和为100%；
导电剂是石墨烯；
固化剂是改性聚酰胺Ancamide2353；
助剂是质量比60%的聚硅烷和40%的硅树脂复合；
填料是陶瓷粉，所述质量百分比含量为23.5～35%的陶瓷粉含有以下质量百分比的各组分：5～7%的400目二氧化钛、9～11%的400目高铝钒土熟料、3～7%的400目氮化硅、5～7%的400目氧化铈和1.5～3%的325目棕刚玉。
CN201611066511.9A 2016-11-28 2016-11-28 一种高弹体抗磨耐候导电防腐蚀舰船舵陶瓷涂料组合物 Active CN106519907B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611066511.9A CN106519907B (zh) 2016-11-28 2016-11-28 一种高弹体抗磨耐候导电防腐蚀舰船舵陶瓷涂料组合物

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611066511.9A CN106519907B (zh) 2016-11-28 2016-11-28 一种高弹体抗磨耐候导电防腐蚀舰船舵陶瓷涂料组合物

Publications (2)

Publication Number Publication Date
CN106519907A CN106519907A (zh) 2017-03-22
CN106519907B true CN106519907B (zh) 2019-07-30

Family

ID=58357680

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611066511.9A Active CN106519907B (zh) 2016-11-28 2016-11-28 一种高弹体抗磨耐候导电防腐蚀舰船舵陶瓷涂料组合物

Country Status (1)

Country Link
CN (1) CN106519907B (zh)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107286761A (zh) * 2017-08-01 2017-10-24 合肥康之恒机械科技有限公司 一种用于工程机械的防腐涂料及其制备方法
CN109054585A (zh) * 2018-07-26 2018-12-21 广东鑫皇冠新材料有限公司 一种具有优良附着性能的纳米陶瓷涂料及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101457115A (zh) * 2007-12-12 2009-06-17 中国石油天然气集团公司 长输管道补口用无溶剂环氧涂料及制造方法
CN104371478A (zh) * 2014-12-10 2015-02-25 李永志 一种亲水性涂料的制备方法
CN104592858A (zh) * 2015-01-04 2015-05-06 林前锋 一种石墨烯导电涂料及其制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101457115A (zh) * 2007-12-12 2009-06-17 中国石油天然气集团公司 长输管道补口用无溶剂环氧涂料及制造方法
CN104371478A (zh) * 2014-12-10 2015-02-25 李永志 一种亲水性涂料的制备方法
CN104592858A (zh) * 2015-01-04 2015-05-06 林前锋 一种石墨烯导电涂料及其制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
双组分湿面混凝土防腐涂料的研制;傅佩芬;《中国涂料》;20080531;第23卷(第5期);第49页表1

Also Published As

Publication number Publication date
CN106519907A (zh) 2017-03-22

Similar Documents

Publication Publication Date Title
CN105440891B (zh) 一种防腐涂料及其制备方法
CN106519907B (zh) 一种高弹体抗磨耐候导电防腐蚀舰船舵陶瓷涂料组合物
KR101792406B1 (ko) 내식성이 우수한 도장용 강재
CN108997889A (zh) 一种海洋舰船用石墨烯重防腐底漆及其制备方法
CN106147539A (zh) 一种纳米耐海洋防腐底漆
CN102336256A (zh) 一种防止船舶螺旋桨腐蚀和海生物污损的方法
KR20150095582A (ko) 내식성이 우수한 도장 강재
CN109401526A (zh) 一种石墨烯防腐涂料及其制备方法
CN104177987A (zh) 一种耐阴极剥离防腐蚀环氧涂料及制造方法
CN105061723A (zh) 一种聚氨酯胶泥及其制备方法
CN104341967B (zh) 一种压载水舱防腐蚀涂料及制造方法
CN103589271A (zh) 船舶专用防锈漆
CN113292912A (zh) 一种海洋工程设备用重防腐水性涂料及其制备方法
CN111100529A (zh) 一种可以有效阻止海洋生物附着的船舶涂料及其制备方法
CN101885942B (zh) 一种憎水耐磨防腐蚀涂料及制造方法
CN104087164B (zh) 一种船舱盖涂料
CN106833274A (zh) 一种船用防海水腐蚀涂料及其制作方法
CN107868523B (zh) 船舶外船体保护涂层及其使用方法
CN104263162B (zh) 一种船体甲板用耐水涂料及其制备方法
CN103373019A (zh) 一种涂有耐腐蚀漆的复合甲板
CN115478243B (zh) 一种耐海洋环境腐蚀的高铝涂料及其喷涂方法
CN106519978A (zh) 一种环保型海洋防污涂料
CN103483975A (zh) 一种船舶油性沥青防锈漆
CN104559678A (zh) 一种海上平台用耐温差双组份改性环氧涂料
CN107739567A (zh) 防腐环氧富锌底漆及其制备方法及其制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant