CN106519821B - A kind of mould resistant and a kind of anti-mildew paint and preparation method thereof - Google Patents
A kind of mould resistant and a kind of anti-mildew paint and preparation method thereof Download PDFInfo
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- CN106519821B CN106519821B CN201610963322.5A CN201610963322A CN106519821B CN 106519821 B CN106519821 B CN 106519821B CN 201610963322 A CN201610963322 A CN 201610963322A CN 106519821 B CN106519821 B CN 106519821B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
- A01N37/04—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof polybasic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Wood Science & Technology (AREA)
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- Agronomy & Crop Science (AREA)
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- Dentistry (AREA)
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Abstract
The invention discloses a kind of mould resistants, are made of camphor and rudimentary organic acid, and camphor and rudimentary organic acid weight proportion are 1:(0.6~1.5).Rudimentary organic acid can generate synergistic effect with camphor, and then reinforce camphor antibacterial functions.It is found through experiments that, the anti-mildew paint that the mould resistant is added has excellent, lasting anti-mildew effect.The invention also discloses a kind of anti-mildew paints and preparation method thereof.Compared with the prior art, the invention has the following advantages: (1) present invention is prepared for can be used for the high-effective antimold of coating using suitable raw material,, with excellent fungicidal properties and flame retardant property, the coating being made from it has excellent, lasting anti-mold effect for it；(2) rationally, at low cost, compatibility is good between each component for coating composition disclosed by the invention, environmentally friendly, mould proof, fire-retardant, has excellent application value.
Description
Technical field
The present invention relates to paint field, in particular to a kind of mould resistant and a kind of anti-mildew paint and preparation method thereof.
Background technique
The coating used now as binder or is mostly mainly to form a film using high molecular materials such as water-soluble or aqueous emulsions
Object.Especially in summer, in the environment of certain temperature and humidity, very easily mouldy, blackening, fouling cannot use coating products.
In addition, mould can also make surface mildew greening or blackening after coating film forming, or even film is made to fall off, gives manufacturer and user
Bring economic loss.
It is, in general, that the main bacteria for causing coating mouldy have pseudomonas aeruginosa, Escherichia coli, beads micrococcus,
Streptococcus lactis, staphylococcus aureus, raw Flavobacterium in sea etc..The main mould for causing film mouldy has aspergillus niger, mould, root
It is mould etc..
Currently, the material main organic/inorganic substance mould proof for coating, such as nano-titanium dioxide, inorganic mantoquita；Organic matter,
Such as imidazolium compounds, quarternary ammonium salt compound.But the lasts of inorganic matter mould inhibitor are poor, and need that many is added
Auxiliary agent, processing cost are high；Degradation and decomposition can occur for organic matter mould inhibitor, and anti-mold effect is caused to decline, also will affect coating at
Film property.
Camphor, chemical name are thatch ketone-(2), are camphane class compounds, are divided into natural camphor and artificial camphor.
Natural camphor is the branch, dry, leaf and root of lauraceae plant camphor tree, is refined crystalline particulate obtained.Natural camphor
Have effects that orifice opening, qi stagnation removing, ward off that foul, desinsection is antipruritic, swelling and pain relieving, cures mainly scabies itch, injuries from falls as well, toothache etc.
Symptom.The main component of natural camphor is pure gum camphor (d-Camphora).
Artificial camphor is using turpentine oil as raw material, and through white powder crystal made of series of chemical, it is one
The inflammable terpenes ketone chemical combination of kind.Artificial camphor is generally gum camphor (d-Camphora) and levo-camphor (l-Camphora)
Mixture.
Camphor is widely used in the insect prevention of furniture and clothing and mothproof at present.
In research before, it is found by the applicant that camphor auxiliary agent as main component is added in coating, it can have excellent
The effect of formaldehyde in different removing indoor environment.Applicant has applied for Chinese patent 201410015147.8 according to this, and obtains
Patent for invention.In that patent, a kind of multifunctional coating auxiliary agent is disclosed, with the first in excellent removing indoor environment
The effect of aldehyde, including following components: camphor, solvent and catalyst, camphor are at least one in natural camphor or artificial camphor
Kind.The invention also discloses the oil paints containing the multifunctional coating auxiliary agent and multi-functional water-based coating and multifunctional water
The preparation method of property coating.Coating containing the multifunctional coating auxiliary agent, not only can be mothproof with mildew resistant moistureproof and insect prevention, Er Qietong
That crosses authoritative department verifies the formaldehyde that can effectively purify in indoor environment.
Also disclose that the multifunctional coating auxiliary agent has certain antibacterium and Anti-mildew capability in the above patent.But
This anti-microbial property is not too much prominent, it is difficult to apply in anti-mildew paint on a large scale.
On the basis of research achievement before, applicant has carried out further exploitation to the auxiliary agent of camphor.It uses
Many chemical substances and camphor cooperation are added in coating, to find optimal cooperation substance, so that it is generated with camphor and cooperate with work
With, and then reinforce camphor anti-mildew function.
Summary of the invention
It is an object of the present invention to provide a kind of mould resistants.It is a further object to provide a kind of paintings of anti-mildew
Material.A further object of the present invention is to provide the preparation method of the anti-mildew paint.
According to an aspect of the invention, there is provided a kind of mould resistant, is made of camphor and rudimentary organic acid, camphor with it is low
Grade organic acid weight proportion is 1:(0.6~1.5).Rudimentary organic acid can generate synergistic effect with camphor, and then it is anti-to reinforce camphor
Bacterium function.It is found through experiments that, the anti-mildew paint that the mould resistant is added has excellent, lasting anti-mildew effect.
In some embodiments, camphor is at least one of natural camphor or artificial camphor.
In some embodiments, rudimentary organic acid is monocarboxylic acid, dicarboxylic acids or tricarboxylic acid, rudimentary organic acid
Carbon chain lengths be C1~C4.
In some embodiments, rudimentary organic acid is formic acid, acetic acid, ethanedioic acid, propionic acid, malonic acid, butyric acid, isobutyric acid
Or at least one of succinic acid.
According to another aspect of the present invention, a kind of anti-mildew paint is provided, raw material includes: according to weight
Wherein, the mould resistant is above-mentioned mould resistant.
The anti-mildew paint anti-mildew excellent effect, and it is at low cost, and flame retardant property is good, colorless and odorless
In some embodiments, polymer emulsion is aqueous polyacrylamide yogurt liquid or aqueous cocounut oil resin emulsion, water
Property polyacrylate emulsion be one of allyl lotion, styrene-acrylic emulsion, pure-acrylic emulsion, acrylate and vinyl acetate emulsion or silicone acrylic emulsion or extremely
The mixture of few two kinds of compositions.
In some embodiments, filler is at least one of calcium carbonate, talcum powder or kaolin, and coalescing agent is
Alcohol ester 12, defoaming agent are the CF-246 of England Blackburn company.
In some embodiments, raw material includes: 12 parts of pure-acrylic emulsion according to parts by weight, and 25 parts of styrene-acrylic emulsion, naturally
1.5 parts of camphor, 2 parts of acetic acid, 23 parts of kaolin, 8 parts of calcium carbonate, 1.5 parts of coalescing agent, 0.6 part of defoaming agent, 2 parts of ethylene glycol, water
26.4 parts.
According to a further aspect of the invention, the preparation method of above-mentioned anti-mildew paint is provided, comprising the following steps:
1) it after, crushing camphor, is mixed with rudimentary organic acid, is heated to 45 DEG C, 100~200min of insulated and stirred, cooling
To room temperature, mould resistant is obtained；
2) filler of mould resistant and half, is put into ball mill mixing and ball milling 50-120min, is carried on mould resistant sufficiently
On filler；
3), polymer emulsion and water are mixed；Under the revolving speed of 400rpm~500rpm, 5~10min is stirred, is added
The filler and remaining filler for having loaded mould resistant, stir evenly, and mixture is made to be dispersed to 30 microns of fineness or less；
4) speed of agitator, is improved to 800rpm~1200rpm, controls temperature 60 C hereinafter, coalescing agent, defoaming agent is added
And ethylene glycol, continue to stir 30min；
5) it, filters and packages.
In some embodiments, during preparing mould resistant, the 5~8 of the weight for being equivalent to camphor are also added into
Water again.
Due to the above technical solutions, the present invention has the following advantages over the prior art:
(1) present invention is prepared for can be used for the high-effective antimold of coating using suitable raw material, with excellent mould proof
Performance and flame retardant property, the coating being made from it have excellent, lasting anti-mold effect；
(2) rationally, at low cost, compatibility is good between each component for coating composition disclosed by the invention, environmentally friendly, mould proof, fire-retardant,
With excellent application value.
Specific embodiment
The present invention is described in further detail below.
In each embodiment of the present invention, raw materials used is the common raw material of institute in the production of this field, can be obtained from market
It arrives, will not be had an impact without any particular/special requirement, and for production result；The equipment used in each process is all made of current
Conventional equipment used in production, has no special feature.
Embodiment 1 prepares anti-mildew paint A
1) it after, crushing 1.5kg natural camphor, is mixed with 2kg acetic acid, is heated to 45 DEG C, insulated and stirred 100~
200min is cooled to room temperature, and obtains mould resistant；
2) mould resistant and 15kg kaolin, are put into ball mill mixing and ball milling 50-120min, are carried on mould resistant sufficiently
On kaolin；
3), 12kg pure-acrylic emulsion, 25kg styrene-acrylic emulsion and 26.4kg water are mixed；In the revolving speed of 400rpm~500rpm
Under, 5~10min is stirred, the kaolin for having loaded mould resistant and 8kg kaolin, 8kg calcium carbonate is added, stirs evenly, make to mix
It closes object and is dispersed to 30 microns of fineness or less；
4), improve speed of agitator to 800rpm~1200rpm, control temperature 60 C hereinafter, be added 1.5kg alcohol ester 12,
0.6kgCF-246 and 2kg ethylene glycol continues to stir 30min；
5) 100kg anti-mildew paint A is obtained after, filtering.
Embodiment 2 prepares anti-mildew paint B
1) it after, crushing 1kg natural camphor, is mixed with 0.2kg acetic acid and 0.4kg succinic acid, is heated to 45 DEG C, heat preservation is stirred
100~200min is mixed, is cooled to room temperature, mould resistant is obtained；
2) mould resistant and 30kg kaolin, are put into ball mill mixing and ball milling 50-120min, are carried on mould resistant sufficiently
On kaolin；
3), 20kg allyl lotion, 20kg styrene-acrylic emulsion and 8kg silicone acrylic emulsion and 49kg water are mixed；400rpm~
Under the revolving speed of 500rpm, 5~10min is stirred, the kaolin for having loaded mould resistant and 6kg talcum powder, 20kg calcium carbonate are added,
It stirs evenly, mixture is made to be dispersed to 30 microns of fineness or less；
4), improve speed of agitator to 800rpm~1200rpm, control temperature 60 C hereinafter, be added 1.2kg alcohol ester 12,
1kgCF-246 and 3.2kg ethylene glycol continues to stir 30min；
5) 160kg anti-mildew paint is obtained after, filtering.
Embodiment 3 prepares anti-mildew paint C
1) after, 1kg natural camphor and 3kg artificial camphor are crushed, with 15kg10% aqueous formic acid, 3kg propionic acid and
The mixing of 1.5kg isobutyric acid, is heated to 45 DEG C, 100~200min of insulated and stirred is cooled to room temperature, obtains mould resistant；
2) mould resistant and 13kg kaolin, are put into ball mill mixing and ball milling 50-120min, are carried on mould resistant sufficiently
On kaolin；
3), by 12kg allyl lotion, 28kg silicone acrylic emulsion and the mixing of 6.5kg water；Under the revolving speed of 400rpm~500rpm,
5~10min is stirred, the kaolin for having loaded mould resistant and 12kg kaolin is added, stirs evenly, be dispersed to mixture carefully
30 microns of degree or less；
4), improve speed of agitator to 800rpm~1200rpm, control temperature 60 C hereinafter, be added 2kg alcohol ester 12,
0.8kgCF-246 and 2.2kg ethylene glycol continues to stir 30min；
5) 100kg anti-mildew paint C is obtained after, filtering.
The preparation comparison of embodiment 4 coating D
1) after, crushing 0.75kg natural camphor, it is put into ball mill mixing and ball milling 50-120min with 5kg kaolin, makes to resist
Mould dose is sufficiently carried on kaolin；
3), 6kg pure-acrylic emulsion, 12.5kg styrene-acrylic emulsion and 14.2kg water are mixed；In the revolving speed of 400rpm~500rpm
Under, 5~10min is stirred, the kaolin for having loaded mould resistant and 3.5kg kaolin, 4kg calcium carbonate is added, stirs evenly, make
Mixture is dispersed to 30 microns of fineness or less；
4), improve speed of agitator to 800rpm~1200rpm, control temperature 60 C hereinafter, be added 0.75kg alcohol ester 12,
0.3kgCF-246 and 1kg ethylene glycol continues to stir 30min；
5) 50kg comparison coating D is obtained after, filtering.
Performance test
The test of antibiotic rate is as follows: bacterium solution (Escherichia coli, black-koji mould) is spread evenly across the load for being coated with above-mentioned coating
On slide, bacterium solution is gently stained with swab stick after 1 day, 5 days, 15 days, 30 days, 60 days and is placed in physiological saline, vibrate, take 0.5ml
In culture dish, culture medium is added, is cultivated 24 hours in incubator, take out number clump count, antibiotic rate is calculated according to formula:
Antibiotic rate=(clump count after initial clump count-antibacterial)/initial clump count × 100%.
Antibiotic rate the results are shown in Table 1.
The antibiotic rate of 1 coating of table
Rudimentary organic acid can generate synergistic effect with camphor it can be seen from table, and then reinforce camphor antibacterial functions.It is logical
Experiment discovery is crossed, the anti-mildew paint that the mould resistant is added has excellent, lasting anti-mildew effect.
Above-described is only some embodiments of the present invention.For those of ordinary skill in the art, not
Under the premise of being detached from the invention design, various modifications and improvements can be made, these belong to protection model of the invention
It encloses.
Claims (8)
1. a kind of mould resistant, which is characterized in that the mould resistant is made of camphor and rudimentary organic acid, the camphor with it is described low
Grade organic acid weight proportion is 1:(0.6~1.5), the camphor is at least one of natural camphor or artificial camphor, institute
Stating rudimentary organic acid is monocarboxylic acid, dicarboxylic acids or tricarboxylic acid, and the carbon chain lengths of the rudimentary organic acid are C1~C4.
2. mould resistant according to claim 1, which is characterized in that the rudimentary organic acid be formic acid, acetic acid, ethanedioic acid,
At least one of propionic acid, malonic acid, butyric acid, isobutyric acid or succinic acid.
3. a kind of anti-mildew paint, which is characterized in that its raw material includes: according to weight
Wherein, the mould resistant is the described in any item mould resistants of claim 1 to 2.
4. anti-mildew paint according to claim 3, which is characterized in that the polymer emulsion is aqueous polyacrylamide yogurt liquid
Perhaps the aqueous cocounut oil resin emulsion aqueous polyacrylamide yogurt liquid is styrene-acrylic emulsion, pure-acrylic emulsion, acrylate and vinyl acetate emulsion or silicon third
The mixture of one of lotion or at least two compositions.
5. anti-mildew paint according to claim 4, which is characterized in that the filler is calcium carbonate, talcum powder or kaolinite
At least one of soil, the coalescing agent are alcohol ester 12, and the defoaming agent is the CF-246 of England Blackburn company.
6. anti-mildew paint according to claim 3, which is characterized in that its raw material includes: pure-acrylic emulsion 12 according to parts by weight
Part, 25 parts of styrene-acrylic emulsion, 1.5 parts of natural camphor, 2 parts of acetic acid, 23 parts of kaolin, 8 parts of calcium carbonate, 1.5 parts of coalescing agent, defoaming
0.6 part of agent, 2 parts of ethylene glycol, 26.4 parts of water.
7. a kind of preparation method of anti-mildew paint according to claim 3, which comprises the following steps:
1) it after, crushing the camphor, is mixed with the rudimentary organic acid, is heated to 45 DEG C, 100~200min of insulated and stirred,
It is cooled to room temperature, obtains the mould resistant；
2) filler of the mould resistant and half, is put into ball mill mixing and ball milling 50-120min, fills the mould resistant
Divide and is carried on the filler；
3), the polymer emulsion and water are mixed；Under the revolving speed of 400rpm~500rpm, 5~10min is stirred, is added
The filler and the remaining filler for having loaded the mould resistant, stir evenly, mixture are made to be dispersed to 30 microns of fineness
Below；
4) speed of agitator, is improved to 800rpm~1200rpm, controls temperature 60 C hereinafter, the coalescing agent is added, described disappears
Infusion and ethylene glycol continue to stir 30min；
5) it, filters and packages.
8. the preparation method of anti-mildew paint according to claim 7, which is characterized in that in the process for preparing the mould resistant
In, it is also added into 5~8 times of water of the weight for being equivalent to the camphor.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610963322.5A CN106519821B (en) | 2016-10-28 | 2016-10-28 | A kind of mould resistant and a kind of anti-mildew paint and preparation method thereof |
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| CN201610963322.5A CN106519821B (en) | 2016-10-28 | 2016-10-28 | A kind of mould resistant and a kind of anti-mildew paint and preparation method thereof |
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| CN106519821B true CN106519821B (en) | 2018-12-21 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030203991A1 (en) * | 2002-04-30 | 2003-10-30 | Hydromer, Inc. | Coating composition for multiple hydrophilic applications |
| CN101259149A (en) * | 2008-04-24 | 2008-09-10 | 张梅英 | Tinctura for treating beriberi |
| CN102771501A (en) * | 2011-05-13 | 2012-11-14 | 深圳国宝造币有限公司 | Composite mildewproof and antibacterial agent and its preparation method |
| CN103725082A (en) * | 2014-01-13 | 2014-04-16 | 中山市丽莎涂料有限公司 | Multifunctional coating additive, multifunctional coating and preparation method thereof |
-
2016
- 2016-10-28 CN CN201610963322.5A patent/CN106519821B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030203991A1 (en) * | 2002-04-30 | 2003-10-30 | Hydromer, Inc. | Coating composition for multiple hydrophilic applications |
| CN101259149A (en) * | 2008-04-24 | 2008-09-10 | 张梅英 | Tinctura for treating beriberi |
| CN102771501A (en) * | 2011-05-13 | 2012-11-14 | 深圳国宝造币有限公司 | Composite mildewproof and antibacterial agent and its preparation method |
| CN103725082A (en) * | 2014-01-13 | 2014-04-16 | 中山市丽莎涂料有限公司 | Multifunctional coating additive, multifunctional coating and preparation method thereof |
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