CN106519491A - Inner rubber material used for water delivery hose - Google Patents
Inner rubber material used for water delivery hose Download PDFInfo
- Publication number
- CN106519491A CN106519491A CN201610962923.4A CN201610962923A CN106519491A CN 106519491 A CN106519491 A CN 106519491A CN 201610962923 A CN201610962923 A CN 201610962923A CN 106519491 A CN106519491 A CN 106519491A
- Authority
- CN
- China
- Prior art keywords
- parts
- delivery hose
- glue material
- interior glue
- rubber material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/004—Additives being defined by their length
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
Abstract
The invention discloses an inner rubber material used for a water delivery hose. The inner rubber material is prepared from raw materials including, by weight, 140-150 parts of PVC, 80-85 parts of fluorinated silicone rubber, 20-30 parts of poly (butylenes terephthalate), 5-14 parts of an antioxidant, 4-8 parts of aluminum oxide, 3-5 parts of triphenyl phosphate, 13-15 parts of acrylic resin, 8-12 parts of thiocarbanilide, 12-17 parts of a reactive diluent, 30-40 parts of glass fiber, 5-9 parts of phthalic anhydride, 3-8 parts of a benzenesulfonic acid type catalyst, 1-5 parts of methyltin mercaptide and 1-4 parts of an aluminate coupling agent. The inner rubber material used for the water delivery hose is good in flexibility, resistant to distortion, good in bending performance, capable of bearing heavy loads and resistant to flex cracking.
Description
Technical field
The invention belongs to polymeric material field, and in particular to a kind of interior glue material of delivery hose.
Technical background
Rubber hose, refers to wire braided hose, and which is typically by inner glue layer, layer of steel wire braiding layer and outer glue-line composition.
Suitable for delivering hydraulic fluid, such as alcohol, fuel oil, lubricating oil, emulsion etc..Mutually distinguish with hard tube,（Rubber）Flexible pipe maximum
It is characterized in that flexible.Compare civilian（Rubber）Flexible pipe, industrial operations environment is more complicated, more severe, equipment is wanted to delivery pipe
Ask also harsher, therefore industry（Rubber）Flexible pipe has from design, to choose production, transport or even the final storage of material
Strict codes and standards.Varied according to the design of the difference flexible pipe of applying working condition and performance requirement, industry（Rubber）It is soft
The optional scope of size of pipe is wider, and P-T region is vast, and chemical-resistance is higher.Industry（Rubber）Flexible pipe application is contained
Each commercial production is covered to manufacture and the field of circulation, has been the physics and electrochemical conditions for adapting to every profession and trade operation, generally industry（Rubber
Glue）Flexible pipe has very strict execution standard on the chemical raw material of inside and outside colloid and technique.Such as：Delivery hose is mainly used in
The aspects such as the cleaning of irrigation, gardening, building, fire-fighting, equipment and tank car, agricultural fertilizer, feces, trade effluent draining.
PVC polrvinyl chloride, resistance to chemical attack, lightweight, anti-dyeing, anti-flatulence have the disadvantage easily aging.Main Ingredients and Appearance is
Polrvinyl chloride, bright in colour, corrosion-resistant, firm and durable, with preferable tension, comprcssive strength, heat resistance is projected, thermal deformation
Temperature is 100 DEG C, and chemical-resistance is excellent.But, not as other plastic tubes, excellent corrosion resistance, price is in all types of plastic for its flexibility
It is generally the least expensive in pipe but more crisp under low temperature.For this purpose, we set about from the formula of product, the formula design of rubber hose will be according to rubber
Influencing each other between the compatibility of the performance of glue flexible pipe, structure, purposes, auxiliary agent and resin, each analog assistant and cooperative effect, and
The characteristics of former, the forming factors of comprehensive each side, carry out the selection of resin model and various addition auxiliary agents.In order to meet
High request of the market to rubber hose, develops a kind of various performances preferably interior glue material of delivery hose.
The content of the invention
To achieve these goals, the invention provides a kind of interior glue material of delivery hose.
The purpose of the present invention is achieved through the following technical solutions：
A kind of interior glue material of delivery hose, is prepared by the raw materials in：PVC140-150 parts, fluorosioloxane rubber 80-85
Part, polybutylene terephthalate (PBT) 20-30 parts, antioxidant 5-14 parts, aluminium oxide 4-8 parts, triphenyl phosphite 3-5 parts,
Acrylic resin 13-15 parts, rhenocure CA 8-12 parts, reactive diluent 12-17 parts, glass fibre 30-40 parts, O-phthalic
Sour diformazan acid anhydride 5-9 parts, benzenesulfonic acid class catalyst 3-8 parts, methyl stannum 1-5 parts, aluminic acid vinegar coupling agent 1-4 parts.
The antioxidant be 2,6 ditertiary butyl p cresol or 2,4,6- tri-butyl-phenols.
The benzenesulfonic acid class catalyst is DBSA, cetyl benzenesulfonic acid or two kinds of mixture.
The diameter of the glass fibre is 1 ~ 10 micron, and fibre length is 10 ~ 100 microns.
The reactive diluent be molecular weight 30,000-5 ten thousand vinyl silicone oil.
Beneficial effect：The delivery hose of the present invention is good with hose lining material flexibility, and anti-twist, good bending property can be born
Heavier load and flex cracking resistance.
Specific embodiment
Embodiment 1
A kind of interior glue material of delivery hose, is prepared by the raw materials in：It is PVC140 parts, 80 parts of fluorosioloxane rubber, poly- right
20 parts of benzene dicarboxylic acid butanediol ester, 5 parts of antioxidant, 4 parts of aluminium oxide, 3 parts of triphenyl phosphite, 13 parts of acrylic resin, two
8 parts of phenylthiourea, 12 parts of reactive diluent, 30 parts of glass fibre, 5 parts of phthalic acid diformazan acid anhydride, benzenesulfonic acid class catalyst 3
Part, 1 part of methyl stannum, 1 part of aluminic acid vinegar coupling agent.
The antioxidant be 2,6 ditertiary butyl p cresol or 2,4,6- tri-butyl-phenols.
The benzenesulfonic acid class catalyst is DBSA, cetyl benzenesulfonic acid or two kinds of mixture.
The diameter of the glass fibre is 1 ~ 10 micron, and fibre length is 10 ~ 100 microns.
The reactive diluent be molecular weight 30,000-5 ten thousand vinyl silicone oil.
Embodiment 2
A kind of interior glue material of delivery hose, is prepared by the raw materials in：It is PVC150 parts, 85 parts of fluorosioloxane rubber, poly- right
30 parts of benzene dicarboxylic acid butanediol ester, 14 parts of antioxidant, 8 parts of aluminium oxide, 5 parts of triphenyl phosphite, 15 parts of acrylic resin, two
12 parts of phenylthiourea, 17 parts of reactive diluent, 40 parts of glass fibre, 9 parts of phthalic acid diformazan acid anhydride, benzenesulfonic acid class catalyst 8
Part, 5 parts of methyl stannum, 4 parts of aluminic acid vinegar coupling agent.
The antioxidant be 2,6 ditertiary butyl p cresol or 2,4,6- tri-butyl-phenols.
The benzenesulfonic acid class catalyst is DBSA, cetyl benzenesulfonic acid or two kinds of mixture.
The diameter of the glass fibre is 1 ~ 10 micron, and fibre length is 10 ~ 100 microns.
The reactive diluent be molecular weight 30,000-5 ten thousand vinyl silicone oil.
Embodiment 3
A kind of interior glue material of delivery hose, is prepared by the raw materials in：It is PVC145 parts, 83 parts of fluorosioloxane rubber, poly- right
25 parts of benzene dicarboxylic acid butanediol ester, 9 parts of antioxidant, 6 parts of aluminium oxide, 4 parts of triphenyl phosphite, 14 parts of acrylic resin, two
10 parts of phenylthiourea, 15 parts of reactive diluent, 35 parts of glass fibre, 7 parts of phthalic acid diformazan acid anhydride, benzenesulfonic acid class catalyst 6
Part, 3 parts of methyl stannum, 3 parts of aluminic acid vinegar coupling agent.
The antioxidant be 2,6 ditertiary butyl p cresol or 2,4,6- tri-butyl-phenols.
The benzenesulfonic acid class catalyst is DBSA, cetyl benzenesulfonic acid or two kinds of mixture.
The diameter of the glass fibre is 1 ~ 10 micron, and fibre length is 10 ~ 100 microns.
The reactive diluent be molecular weight 30,000-5 ten thousand vinyl silicone oil.
Sample is made by raw material in enforcement row formula carries out testing inspection, and the performance formula in above-described embodiment 1-3 is such as
Under：Tensile strength（Mpa）15.45、14.57、13.08；Elongation at break（%）380.8、398.56、410.69；Lower temperature resistance-
40 DEG C of * 5h are without fracture, without fracture, without fracture；Flex cracking resistance 40,000 times is without breach, without breach, without breach.
Claims (5)
1. the interior glue material of a kind of delivery hose, it is characterised in that be prepared by the raw materials in：PVC140-150 parts,
Fluorosioloxane rubber 80-85 parts, polybutylene terephthalate (PBT) 20-30 parts, antioxidant 5-14 parts, aluminium oxide 4-8 parts, phosphorous acid
Triphenylmethyl methacrylate 3-5 parts, acrylic resin 13-15 parts, rhenocure CA 8-12 parts, reactive diluent 12-17 parts, glass fibre 30-
40 parts, phthalic acid diformazan acid anhydride 5-9 parts, benzenesulfonic acid class catalyst 3-8 parts, methyl stannum 1-5 parts, aluminic acid vinegar coupling agent 1-4 parts.
2. the interior glue material of a kind of delivery hose according to claim 1, it is characterised in that：The antioxidant is 2,6- bis-
Butylated Hydroxytoluene or 2,4,6- tri-butyl-phenols.
3. the interior glue material of a kind of delivery hose according to claim 1, it is characterised in that：The benzenesulfonic acid class catalyst is
DBSA, cetyl benzenesulfonic acid or two kinds of mixture.
4. the interior glue material of a kind of delivery hose according to claim 1, it is characterised in that：The diameter of the glass fibre is
1 ~ 10 micron, fibre length is 10 ~ 100 microns.
5. the interior glue material of a kind of delivery hose according to claim 1, it is characterised in that：The reactive diluent is molecule
Measure the vinyl silicone oil 30,000-5 ten thousand.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610962923.4A CN106519491A (en) | 2016-10-28 | 2016-10-28 | Inner rubber material used for water delivery hose |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610962923.4A CN106519491A (en) | 2016-10-28 | 2016-10-28 | Inner rubber material used for water delivery hose |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106519491A true CN106519491A (en) | 2017-03-22 |
Family
ID=58326314
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610962923.4A Pending CN106519491A (en) | 2016-10-28 | 2016-10-28 | Inner rubber material used for water delivery hose |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106519491A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103275434A (en) * | 2013-06-21 | 2013-09-04 | 苏州新区特氟龙塑料制品厂 | Water supply flexible pipe manufactured by polyvinyl chloride plastics |
| CN104356532A (en) * | 2014-10-22 | 2015-02-18 | 青岛东泰诚恩新材料科技发展有限公司 | Aging-resistant PVC hose formula |
| CN104672654A (en) * | 2013-11-30 | 2015-06-03 | 青岛海发利粮油机械有限公司 | Corrosion-resistance aging-resistance PVC hose |
| CN105906980A (en) * | 2016-06-12 | 2016-08-31 | 开平市宝来塑胶制品有限公司 | High pressure and wear resistance PVC hose material and preparation method thereof |
-
2016
- 2016-10-28 CN CN201610962923.4A patent/CN106519491A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103275434A (en) * | 2013-06-21 | 2013-09-04 | 苏州新区特氟龙塑料制品厂 | Water supply flexible pipe manufactured by polyvinyl chloride plastics |
| CN104672654A (en) * | 2013-11-30 | 2015-06-03 | 青岛海发利粮油机械有限公司 | Corrosion-resistance aging-resistance PVC hose |
| CN104356532A (en) * | 2014-10-22 | 2015-02-18 | 青岛东泰诚恩新材料科技发展有限公司 | Aging-resistant PVC hose formula |
| CN105906980A (en) * | 2016-06-12 | 2016-08-31 | 开平市宝来塑胶制品有限公司 | High pressure and wear resistance PVC hose material and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| 周殿明: "《塑料成型技术》", 31 July 2014 * |
| 李伟光: "《中国优质化工产品大辞典》", 31 December 1991 * |
| 电线电缆手册编委会组编: "《电线电缆手册第2册》", 30 April 2014 * |
| 纪士寅等: "《石油化工实验名词术语》", 31 December 1999 * |
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| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170322 |