CN107082928A - A kind of high-strength toughness reinforcing high density PE Gas Pipes formula and preparation method thereof - Google Patents
A kind of high-strength toughness reinforcing high density PE Gas Pipes formula and preparation method thereof Download PDFInfo
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- CN107082928A CN107082928A CN201710306427.8A CN201710306427A CN107082928A CN 107082928 A CN107082928 A CN 107082928A CN 201710306427 A CN201710306427 A CN 201710306427A CN 107082928 A CN107082928 A CN 107082928A
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- parts
- high density
- gas pipes
- toughness reinforcing
- maleic anhydride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Abstract
It is formulated the present invention relates to a kind of high-strength toughness reinforcing high density PE Gas Pipes, the PE Gas Pipes formula is made up of the raw material of following parts by weight：100 parts of high density polyethylene (HDPE), 1 30 parts of inorganic filler, 1 10 parts of ethylene-vinylacetate grafting maleic anhydride copolymer, 0.2 3 parts of maleic anhydride, 0.1 0.5 parts of initiator.The high-strength toughness reinforcing high density PE Gas Pipes that the present invention is provided are made up of high density polyethylene (HDPE), inorganic filler, ethylene-vinylacetate grafting maleic anhydride copolymer, maleic anhydride, initiator, ethylene-vinylacetate grafting maleic anhydride copolymer can effectively facilitate the compatibility of inorganic filler and polyethylene, improve enhancing effect of the inorganic filler in system, the addition of maleic anhydride and initiator is favorably improved crosslinked action, further improves the intensity and toughness of tubing.
Description
Technical field
The invention belongs to combustion gas tubing field, especially a kind of high-strength toughness reinforcing high density PE Gas Pipes.
Background technology
PE, is polyethylene (Polyethyleneofraisedtemperatureresistance english abbreviation), typically
The application of PE tubing feedwater pipings is the temperature less than 40 DEG C, it is impossible to for delivery pipeline.PE tubing is a kind of knot
Brilliant degree is high, nonpolar thermoplastic resin.Ortho states HDPE milky appearance, in meagre section in a certain degree of translucent
Shape.PE has excellent resistance to most of characteristics lived with chemicals for industrial use.Some kinds of chemicals can produce chemical corruption
Erosion, such as corrosive oxidation agent (concentrated nitric acid), aromatic hydrocarbon (dimethylbenzene) and halogenated hydrocarbon (carbon tetrachloride).
At present, conventional PE Gas Pipes are mainly made of high density polyethylene (HDPE), but these pipeline compositions are reasonable not enough, are caused
Make intensity, rigidity, modulus of gas pipeline etc., all do not reach gratifying effect.
CN201510281792 has invented a kind of enhanced PE Gas Pipes of use clay nanocomposites, but this method institute
Organic coupling modifier is not carried out with clay nanocomposites, in actual applications, clay nanocomposites and PE matrix phases
Capacitive is short of, and causes enhancing effect limited, and the present invention is filled out using maleic anhydride grafted ethene-acetate ethylene copolymer as inorganic
The macromolecular coupling compatibility agent of material and PE matrixes, can effectively facilitate the compatibility of inorganic filler and base polyethylene, improve nothing
Enhancing effect of the machine filler in system, the addition of maleic anhydride and initiator is remarkably improved crosslinked action, further improves
The intensity and toughness of tubing.
The content of the invention
In view of the shortcomings of the prior art, in order to improve the intensity and toughness of conventional PE Gas Pipes, there is provided a kind of letter by the present invention
Single, rational high-strength toughness reinforcing high density PE Gas Pipes.
The present invention solves its technical problem and takes following technical scheme to realize：
A kind of high-strength toughness reinforcing high density PE Gas Pipes formula, the PE Gas Pipes are formulated the raw material group by following parts by weight
Into：100 parts of high density polyethylene (HDPE), 1-30 parts of inorganic filler, maleic anhydride grafted ethene -1-10 parts of acetate ethylene copolymer, horse
Come 0.1-0.5 parts of 0.2-3 parts of acid anhydrides, organic peroxide or azo-initiator.
The inorganic filler is selected from calcium carbonate, titanium dioxide, silica, silica flour, talcum powder, aluminum oxide, montmorillonite, height
One or more in the soil of ridge.
The inorganic filler is selected from organically-modified inorganic filler, especially through silane coupler, titanate coupling agent, aluminic acid
The treated inorganic filler of ester coupling agent, zirconium ester coupling agent, boric acid ester coupler.
Described initiator is selected from cumyl hydroperoxide, cumyl peroxide, benzoyl peroxide, benzoyl peroxide first
One or more in the acyl tert-butyl ester, methyl ethyl ketone peroxide, azodiisobutyronitrile, ABVN.
A kind of preparation method of high-strength toughness reinforcing high density PE Gas Pipes, comprises the following steps：
(1) mix：The raw material of above-mentioned parts by weight is well mixed and is put into kneading machine, is heated while stirring, temperature is maintained at
70-80 DEG C, after 10min, stop stirring, obtain tubing premix；
(2) granulate：Tubing premix is put into comminutor to be granulated, cooling obtains granular tubing batch mixing after drying；
(3) it is molded：Granular tubing batch mixing is put into extruder shaping, product is produced after traction, coiling, punching, cleaning.
Advantages and positive effects of the present invention are：
The high-strength toughness reinforcing high density PE Gas Pipes of the present invention are grafted second by high density polyethylene (HDPE), inorganic filler, maleic anhydride
Alkene-
Acetate ethylene copolymer, maleic anhydride, initiator composition, maleic anhydride grafted ethene-acetate ethylene copolymer can
With effective
Promote the compatibility of inorganic filler and polyethylene, improve enhancing effect of the inorganic filler in system, maleic anhydride
And initiation
The addition of agent is favorably improved crosslinked action, further improve tubing intensity and toughness, the Gas Pipe have with
Lower advantage：
1st, high-strength and high ductility, anti-stress cracking is good；2nd, wearability is good；3rd, pliability is good；4th, service life is long；With non-
Chang Youyi economic and social benefit.
Embodiment
The present invention, but following implementations can be further expressly understood by the specific embodiment of invention now given below
Example is not limitation of the invention.
Embodiment 1:
A kind of high-strength toughness reinforcing high density PE Gas Pipes, are made up of the raw material of following parts by weight：
100 parts of high density polyethylene (HDPE), 10 parts of precipitated calcium carbonate, 3 parts of maleic anhydride grafted ethene-acetate ethylene copolymer,
1 part of maleic anhydride, 0.3 part of azodiisobutyronitrile.
The preparation method of above-mentioned high-strength toughness reinforcing high density PE Gas Pipes, comprises the following steps：
(1) mix：The raw material of above-mentioned parts by weight is well mixed and is put into kneading machine, is heated while stirring, temperature is maintained at
70-80 DEG C, after 10min, stop stirring, obtain tubing premix；
(2) granulate：Tubing premix is put into comminutor to be granulated, cooling obtains granular tubing batch mixing after drying；
(3) it is molded：Granular tubing batch mixing is put into extruder shaping, product is produced after traction, coiling, punching, cleaning.
Embodiment 2:
A kind of high-strength toughness reinforcing high density PE Gas Pipes, are made up of the raw material of following parts by weight：
100 parts of high density polyethylene (HDPE), 15 parts of the precipitated calcium carbonate of silane coupled modification, 2 parts of titanium dioxide, maleic anhydride grafting
5 parts of ethylene-vinyl acetate copolymer, 1.5 parts of maleic anhydride, 0.4 part of benzoyl peroxide.
Preparation method be the same as Example 1.
Embodiment 3：
A kind of high-strength toughness reinforcing high density PE Gas Pipes, are made up of the raw material of following parts by weight：
100 parts of high density polyethylene (HDPE), 10 parts of the silicon dioxide powder of titanate esters coupling modifier, maleic anhydride grafted ethene-vinegar
Sour 4 parts of ethylene copolymer, 3 parts of maleic anhydride, 0.5 part of methyl ethyl ketone peroxide.
Preparation method be the same as Example 1.
Embodiment 4：
A kind of high-strength toughness reinforcing high density PE Gas Pipes, are made up of the raw material of following parts by weight：
100 parts of high density polyethylene (HDPE), 20 parts of the silica flour of borate coupling modifier, 10 parts of kaolin, maleic anhydride grafting
7 parts of ethylene-vinyl acetate copolymer, 2.5 parts of maleic anhydride, 0.4 part of ABVN.
Preparation method be the same as Example 1.
Embodiment 5：
A kind of high-strength toughness reinforcing high density PE Gas Pipes, are made up of the raw material of following parts by weight：
100 parts of high density polyethylene (HDPE), 15 parts of the montmorillonite of zirconate coupling modifier, 8 parts of kaolin, maleic anhydride grafting second
6 parts of alkene-acetate ethylene copolymer, 2 parts of maleic anhydride, 0.5 part of the benzoyl peroxide tert-butyl ester.
Preparation method be the same as Example 1.
Above-described embodiment batten test data is as follows：
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Bending modulus/MPa | 912 | 958 | 961 | 902 | 933 |
| Tensile strength/MPa | 25.6 | 26.8 | 27.2 | 25.9 | 26.6 |
| Elongation at break/% | 522 | 540 | 553 | 485 | 492 |
Above example is merely to illustrate technical scheme and unrestricted, and those skilled in the art should manage
Solution, technical scheme can be modified or equivalent substitution, without departing from technical solution of the present invention objective and
Scope, it all should cover among scope of the presently claimed invention.
Claims (5)
1. a kind of high-strength toughness reinforcing high density PE Gas Pipes formula, it is characterised in that：The PE Gas Pipes are formulated by following parts by weight
Raw material composition：100 parts of high density polyethylene (HDPE), 1-30 parts of inorganic filler, maleic anhydride grafted ethene-acetate ethylene copolymer 1-
10 parts, 0.2-3 parts of maleic anhydride, 0.1-0.5 parts of organic peroxide or azo-initiator.
2. a kind of high-strength toughness reinforcing high density PE Gas Pipes formula according to claim 1, it is characterised in that：It is described inorganic to fill out
Expect one kind or several in calcium carbonate, titanium dioxide, silica, silica flour, talcum powder, aluminum oxide, montmorillonite, kaolin
Kind.
3. a kind of high-strength toughness reinforcing high density PE Gas Pipes formula according to claim 1, it is characterised in that：It is described inorganic to fill out
Material is selected from organically-modified inorganic filler, through silane coupler, titanate coupling agent, aluminate coupling agent, zirconium ester coupling agent, boron
The inorganic filler that acid esters coupling agent treatment is crossed.
4. a kind of high-strength toughness reinforcing high density PE Gas Pipes formula according to claim 1, it is characterised in that：Described initiation
Agent is selected from cumyl hydroperoxide, cumyl peroxide, benzoyl peroxide, the benzoyl peroxide tert-butyl ester, peroxidating first
One or more in ethyl ketone, azodiisobutyronitrile, ABVN.
5. a kind of method for preparing high-strength toughness reinforcing high density PE Gas Pipes as claimed in claim 1, it is characterised in that：Including with
Lower step：
(1) mix：The raw material of above-mentioned parts by weight is well mixed and is put into kneading machine, is heated while stirring, temperature is maintained at 70-80
DEG C, after 10min, stop stirring, obtain tubing premix；
(2) granulate：Tubing premix is put into comminutor to be granulated, cooling obtains granular tubing batch mixing after drying；
(3) it is molded：Granular tubing batch mixing is put into extruder shaping, product is produced after traction, coiling, punching, cleaning.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710306427.8A CN107082928A (en) | 2017-05-04 | 2017-05-04 | A kind of high-strength toughness reinforcing high density PE Gas Pipes formula and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710306427.8A CN107082928A (en) | 2017-05-04 | 2017-05-04 | A kind of high-strength toughness reinforcing high density PE Gas Pipes formula and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107082928A true CN107082928A (en) | 2017-08-22 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710306427.8A Pending CN107082928A (en) | 2017-05-04 | 2017-05-04 | A kind of high-strength toughness reinforcing high density PE Gas Pipes formula and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110396235A (en) * | 2019-07-23 | 2019-11-01 | 深圳市沃尔核材股份有限公司 | Gas detecting tube supporting layer and preparation method thereof |
| CN110715118A (en) * | 2019-10-22 | 2020-01-21 | 湖北凯科塑业有限公司 | Antibacterial durable double-layer PE pipe and manufacturing method thereof |
| CN111647217A (en) * | 2020-07-02 | 2020-09-11 | 上海中塑管业有限公司 | Polyethylene pipe for fuel gas and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106609000A (en) * | 2015-10-23 | 2017-05-03 | 神华集团有限责任公司 | Polyethylene combination, preparation method thereof and modified crosslinked polyethylene |
-
2017
- 2017-05-04 CN CN201710306427.8A patent/CN107082928A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106609000A (en) * | 2015-10-23 | 2017-05-03 | 神华集团有限责任公司 | Polyethylene combination, preparation method thereof and modified crosslinked polyethylene |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110396235A (en) * | 2019-07-23 | 2019-11-01 | 深圳市沃尔核材股份有限公司 | Gas detecting tube supporting layer and preparation method thereof |
| CN110715118A (en) * | 2019-10-22 | 2020-01-21 | 湖北凯科塑业有限公司 | Antibacterial durable double-layer PE pipe and manufacturing method thereof |
| CN111647217A (en) * | 2020-07-02 | 2020-09-11 | 上海中塑管业有限公司 | Polyethylene pipe for fuel gas and preparation method thereof |
| CN111647217B (en) * | 2020-07-02 | 2022-11-29 | 上海中塑管业有限公司 | Polyethylene pipe for fuel gas and preparation method thereof |
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Application publication date: 20170822 |