CN106589659A - Compression-resistant durable composite material for air hose - Google Patents
Compression-resistant durable composite material for air hose Download PDFInfo
- Publication number
- CN106589659A CN106589659A CN201610961367.9A CN201610961367A CN106589659A CN 106589659 A CN106589659 A CN 106589659A CN 201610961367 A CN201610961367 A CN 201610961367A CN 106589659 A CN106589659 A CN 106589659A
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- CN
- China
- Prior art keywords
- parts
- air hose
- composite material
- compression
- durable composite
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a compression-resistant durable composite material for an air hose. The material is prepared from, by weight, 140-150 parts of PVC, 40-55 parts of silicon rubber, 50-60 parts of polyurethane rubber, 12-15 parts of acrylic ester, 2-4 parts of molybdenum dithiocarbamate, 10-13 parts of polyethylene glycol, 1-3 parts of ethyl p-hydroxybenzoate, 3-5 parts of composite antioxidant, 5-12 parts of octyl tin mercaptide, 5-8 parts of cross-linking agent, 5-10 parts of pine tar, 15-20 parts of filling agent and 12-18 parts of hydroxy propyl cellulose. The compression-resistant durable composite material for the air hose is good in tensile strength, elongation at break and friction resistance, and also has good high and low temperature resistance and flex cracking resistance.
Description
Technical field
The invention belongs to polymeric material field, and in particular to a kind of air hose resistance to compression Durable composite material.
Technical background
Rubber hose, refers to wire braided hose, and which is typically by inner glue layer, layer of steel wire braiding layer and outer glue-line composition.
Suitable for delivering hydraulic fluid, such as alcohol, fuel oil, lubricating oil, emulsion etc..Mutually distinguish with hard tube,（Rubber）Flexible pipe maximum
It is characterized in that flexible.Compare civilian（Rubber）Flexible pipe, industrial operations environment is more complicated, more severe, equipment is wanted to delivery pipe
Ask also harsher, therefore industry（Rubber）Flexible pipe has from design, to choose production, transport or even the final storage of material
Strict codes and standards.Varied according to the design of the difference flexible pipe of applying working condition and performance requirement, industry（Rubber）It is soft
The optional scope of size of pipe is wider, and P-T region is vast, and chemical-resistance is higher.Industry（Rubber）Flexible pipe application is contained
Each commercial production is covered to manufacture and the field of circulation, has been the physics and electrochemical conditions for adapting to every profession and trade operation, generally industry（Rubber
Glue）Flexible pipe has very strict execution standard on the chemical raw material and technique of inside and outside colloid.Such as：Air hose is mainly used in
The aspects such as compressor, pneumatic means, mining, building.
PVC polrvinyl chloride, resistance to chemical attack, lightweight, anti-dyeing, anti-flatulence have the disadvantage easily aging.Main Ingredients and Appearance is
Polrvinyl chloride, bright in colour, corrosion-resistant, firm and durable, with preferable tension, comprcssive strength, heat resistance is projected, thermal deformation
Temperature is 100 DEG C, and chemical-resistance is excellent.But, not as other plastic tubes, excellent corrosion resistance, price is in all types of plastic for its flexibility
It is generally the least expensive in pipe but more crisp under low temperature.For this purpose, we set about from the formula of product, the formula design of rubber hose will be according to rubber
Influencing each other and cooperative effect between the compatibility of the performance of glue flexible pipe, structure, purposes, auxiliary agent and resin, each analog assistant, and
The characteristics of former, the forming factors of comprehensive each side, carry out the selection of resin model and various addition auxiliary agents.In order to meet
High request of the market to rubber hose, develops a kind of various performances preferably durable composite wood of air hose resistance to compression
Material.
The content of the invention
To achieve these goals, the invention provides a kind of air hose resistance to compression Durable composite material.
The purpose of the present invention is achieved through the following technical solutions：
A kind of air hose resistance to compression Durable composite material, is prepared by the raw materials in：PVC 140-150 parts, silicon rubber
Glue 40-55 parts, polyurethane rubber 50-60 parts, acrylate 12-15 parts, molybdenum dithiocarbamate 2-4 parts, Polyethylene Glycol 10-
13 parts, ethylparaben 1-3 parts, composite antioxidant 3-5 parts, octyl mercaptan stannum 5-12 parts, cross-linking agent 5-8 parts, pine it is burnt
Oily 5-10 parts, filler 15-20 parts, hydroxypropyl cellulose 12-18 parts.
It is 1 that the composite antioxidant is weight ratio：1 antioxidant 1010 and the compositionss of irgasfos 168.
The molecular weight of the Polyethylene Glycol is 10000～50000.
Described filler is ground calcium carbonate.
Described cross-linking agent is selected from triallyl cyanurate, divinylbenzene, dially phthalate and propylene
One or more in sour N-butyl.
Beneficial effect：Tensile strength of the air hose of the present invention with resistance to compression Durable composite material, good pulls apart elongation
Rate and rub resistance are good, also with good high-low temperature resistant and flex cracking resistance.
Specific embodiment
Embodiment 1
A kind of air hose resistance to compression Durable composite material, is prepared by the raw materials in：140 parts of PVC, silicone rubber 40
Part, 50 parts of polyurethane rubber, 12 parts of acrylate, 2 parts of molybdenum dithiocarbamate, 10 parts of Polyethylene Glycol, P-hydroxybenzoic acid
1 part of ethyl ester, 3 parts of composite antioxidant, 5 parts of octyl mercaptan stannum, 5 parts of cross-linking agent, 5 parts of pine tar, 15 parts of filler, hydroxy propyl cellulose
12 parts of element.
It is 1 that the composite antioxidant is weight ratio：1 antioxidant 1010 and the compositionss of irgasfos 168.
The molecular weight of the Polyethylene Glycol is 10000～50000.
Described filler is ground calcium carbonate.
Described cross-linking agent is selected from triallyl cyanurate, divinylbenzene, dially phthalate and propylene
One or more in sour N-butyl.
Embodiment 2
A kind of air hose resistance to compression Durable composite material, is prepared by the raw materials in：145 parts of PVC, silicone rubber 48
Part, 55 parts of polyurethane rubber, 13 parts of acrylate, 3 parts of molybdenum dithiocarbamate, 12 parts of Polyethylene Glycol, P-hydroxybenzoic acid
2 parts of ethyl ester, 4 parts of composite antioxidant, 8 parts of octyl mercaptan stannum, 7 parts of cross-linking agent, 8 parts of pine tar, 17 parts of filler, hydroxy propyl cellulose
15 parts of element.
It is 1 that the composite antioxidant is weight ratio：1 antioxidant 1010 and the compositionss of irgasfos 168.
The molecular weight of the Polyethylene Glycol is 10000～50000.
Described filler is ground calcium carbonate.
Described cross-linking agent is selected from triallyl cyanurate, divinylbenzene, dially phthalate and propylene
One or more in sour N-butyl.
Embodiment 3
A kind of air hose resistance to compression Durable composite material, is prepared by the raw materials in：150 parts of PVC, silicone rubber 55
Part, 60 parts of polyurethane rubber, 15 parts of acrylate, 4 parts of molybdenum dithiocarbamate, 13 parts of Polyethylene Glycol, P-hydroxybenzoic acid
3 parts of ethyl ester, 5 parts of composite antioxidant, 12 parts of octyl mercaptan stannum, 8 parts of cross-linking agent, 10 parts of pine tar, 20 parts of filler, hydroxypropyl are fine
18 parts of dimension element.
It is 1 that the composite antioxidant is weight ratio：1 antioxidant 1010 and the compositionss of irgasfos 168.
The molecular weight of the Polyethylene Glycol is 10000～50000.
Described filler is ground calcium carbonate.
Described cross-linking agent is selected from triallyl cyanurate, divinylbenzene, dially phthalate and propylene
One or more in sour N-butyl.
Sample is made by raw material in enforcement row formula carries out testing inspection, and the performance formula in above-described embodiment 1-3 is such as
Under：Tensile strength（Mpa）35.56、34.85、36.15；Elongation at break（%）422.12、418.56、407.69；Resistance to flexion Testudiniss
40,000 times are split without breach, without breach, without breach；Wear rate is 0.4%, 0.48%, 0.46%.
Claims (5)
1. a kind of air hose resistance to compression Durable composite material, it is characterised in that be prepared by the raw materials in：PVC
140-150 parts, silicone rubber 40-55 parts, polyurethane rubber 50-60 parts, acrylate 12-15 parts, molybdenum dithiocarbamate 2-4
Part, Polyethylene Glycol 10-13 parts, ethylparaben 1-3 parts, composite antioxidant 3-5 parts, octyl mercaptan stannum 5-12 parts, friendship
Connection agent 5-8 parts, pine tar 5-10 parts, filler 15-20 parts, hydroxypropyl cellulose 12-18 parts.
2. a kind of air hose resistance to compression Durable composite material according to claim 1, it is characterised in that：The compound antioxygen
It is 1 that agent is weight ratio：1 antioxidant 1010 and the compositionss of irgasfos 168.
3. a kind of air hose resistance to compression Durable composite material according to claim 1, it is characterised in that：The Polyethylene Glycol
Molecular weight be 10000～50000.
4. a kind of air hose resistance to compression Durable composite material according to claim 1, it is characterised in that：Described filler
For ground calcium carbonate.
5. a kind of air hose resistance to compression Durable composite material according to claim 1, it is characterised in that：Described cross-linking agent
It is the one kind or several in triallyl cyanurate, divinylbenzene, dially phthalate and n-butyl acrylate
Kind.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610961367.9A CN106589659A (en) | 2016-10-28 | 2016-10-28 | Compression-resistant durable composite material for air hose |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610961367.9A CN106589659A (en) | 2016-10-28 | 2016-10-28 | Compression-resistant durable composite material for air hose |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106589659A true CN106589659A (en) | 2017-04-26 |
Family
ID=58589645
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610961367.9A Pending CN106589659A (en) | 2016-10-28 | 2016-10-28 | Compression-resistant durable composite material for air hose |
Country Status (1)
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| CN (1) | CN106589659A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110317420A (en) * | 2019-06-25 | 2019-10-11 | 安徽英泰利科技有限公司 | A kind of anti-aging air flow meter connection rubber tube material and preparation method thereof |
| CN111893776A (en) * | 2020-08-10 | 2020-11-06 | 河北玉鑫工贸有限公司 | Processing method of polyvinyl chloride coated tarpaulin |
| CN116355328A (en) * | 2023-04-17 | 2023-06-30 | 浙江富华新材料科技有限公司 | Composition of heat-resistant and oxidation-resistant PVC particles and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11236480A (en) * | 1998-02-24 | 1999-08-31 | Shin Etsu Chem Co Ltd | Vinyl chloride-based resin composition |
| JP2004197036A (en) * | 2002-12-20 | 2004-07-15 | Denki Kagaku Kogyo Kk | Thermoplastic elastomer composition |
| CN104164012A (en) * | 2014-07-30 | 2014-11-26 | 青岛吉顺隆商贸有限公司 | High-strength PVC pipe material |
| CN104194203A (en) * | 2014-07-30 | 2014-12-10 | 青岛吉顺隆商贸有限公司 | PVC tube |
| CN105860341A (en) * | 2016-04-21 | 2016-08-17 | 安徽九华金润铜业有限公司 | Preparation method of polyvinyl chloride hose |
-
2016
- 2016-10-28 CN CN201610961367.9A patent/CN106589659A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11236480A (en) * | 1998-02-24 | 1999-08-31 | Shin Etsu Chem Co Ltd | Vinyl chloride-based resin composition |
| JP2004197036A (en) * | 2002-12-20 | 2004-07-15 | Denki Kagaku Kogyo Kk | Thermoplastic elastomer composition |
| CN104164012A (en) * | 2014-07-30 | 2014-11-26 | 青岛吉顺隆商贸有限公司 | High-strength PVC pipe material |
| CN104194203A (en) * | 2014-07-30 | 2014-12-10 | 青岛吉顺隆商贸有限公司 | PVC tube |
| CN105860341A (en) * | 2016-04-21 | 2016-08-17 | 安徽九华金润铜业有限公司 | Preparation method of polyvinyl chloride hose |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110317420A (en) * | 2019-06-25 | 2019-10-11 | 安徽英泰利科技有限公司 | A kind of anti-aging air flow meter connection rubber tube material and preparation method thereof |
| CN111893776A (en) * | 2020-08-10 | 2020-11-06 | 河北玉鑫工贸有限公司 | Processing method of polyvinyl chloride coated tarpaulin |
| CN116355328A (en) * | 2023-04-17 | 2023-06-30 | 浙江富华新材料科技有限公司 | Composition of heat-resistant and oxidation-resistant PVC particles and preparation method thereof |
| CN116355328B (en) * | 2023-04-17 | 2023-10-27 | 浙江富华新材料科技有限公司 | Composition of heat-resistant and oxidation-resistant PVC particles and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20170426 |