CN106517781A - Purple and golden glaze and preparation method thereof - Google Patents
Purple and golden glaze and preparation method thereof Download PDFInfo
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- CN106517781A CN106517781A CN201611016763.0A CN201611016763A CN106517781A CN 106517781 A CN106517781 A CN 106517781A CN 201611016763 A CN201611016763 A CN 201611016763A CN 106517781 A CN106517781 A CN 106517781A
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- glaze
- zijin
- oxide
- chlorite
- talcum
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Abstract
The invention provides purple and golden glaze. The purple and golden glaze is prepared from the following raw materials in percentage by weight: 20 to 50 percent of potassium feldspar, 5 to 15 percent of quartz, 1 to 5 percent of black mica, 10 to 20 percent of chlorite, 5 to 15 percent of calcite, 15 to 30 percent of talcum, 0.1 to 7 percent of sodium oxide, 0.2 to 3 percent of titanium oxide and 0.1 to 5 percent of copper oxide. The invention also relates to a preparation method of the purple and golden glaze. The purple and golden glaze provided by the invention has a purple and golden glaze surface and has a matt gloss or bright gloss effect, the glaze surface contains crystallization points, the glaze color is plain, elegant, noble and psychic, the purple and golden glaze is in golden gloss when being taken in hand, and a fondle admiringly feeling is obtained by people. In addition, the purple and golden glaze provided by the invention also has the effect of purifying tea performance, and the taste is more fragrant by using a purple and golden glaze porcelain cup to contain tea water.
Description
Technical field
The present invention relates to enamel field, and in particular to a kind of Zijin glaze and preparation method thereof.
Background technology
In the evolution of ceramic industry, the moulding of ceramics, glaze, decoration and drawing are always the complete of whole works
Body, and the allotment of glaze makes porcelain more dazzling brilliant, the porcelain embryo of same moulding often because of the difference of glaze, and to audience
Vision produce different impacts.
Zijin glaze is a kind of high temperature color glaze, and color is beautiful, and sight is strong, but as glaze formula is different, sintering procedure gas
Atmosphere, temperature control are inaccurate so that glaze color, gloss do not reach ideal effect.Jing test of many times of the present invention have developed one
New Zijin glaze glaze formula is planted, and strictly controls firing atmosphere and temperature so that the Zijin glaze glaze produced is in Zijin color
And there is sub- light gloss or light luster effect, glaze contains crystalline temperature, and its glaze colours is simple and tasteful, noble Ling Run, takes
There is gold lustre, allow people to have the sensation being so fond that will not let out of one's hand.
The content of the invention
For overcoming the problems referred to above not enough, present invention aim at providing a kind of new Zijin glaze glaze formula and making side
Method, Zijin glaze glaze obtained in the present invention is Zijin color and has sub- light gloss or light luster effect, and glaze contains crystalline temperature,
Its glaze colours is simple and tasteful, noble Ling Run, has taken gold lustre, allows people to have the sensation being so fond that will not let out of one's hand.
For achieving the above object, the invention provides a kind of Zijin glaze, is made up of the raw material of following percentage by weight：Potassium is long
Stone 20 ~ 50%, quartz 5 ~ 15%, biotite 1 ~ 5%, chlorite 10 ~ 20%, calcite 5 ~ 15%, Talcum 15 ~ 30%, sodium oxide 0.1 ~
7%, titanium oxide 0.2 ~ 3%, copper oxide 0.1 ~ 5%.
Zijin glaze of the present invention can be configured to sub- light Zijin color glaze or light Zijin color glaze by brewable material proportioning.
Wherein, sub- light Zijin color glaze is made up of the raw material of following percentage by weight：Potassium feldspar 20 ~ 35%, quartz 5 ~ 15% are black
Muscovitum 1 ~ 5%, chlorite 10 ~ 20%, calcite 5 ~ 15%, Talcum 15 ~ 20%, sodium oxide 0.1 ~ 3%, titanium oxide 0.2 ~ 1%, copper oxide
0.1~3%。
Above-mentioned sub- light Zijin color glaze is preferably made up of following percentage by weight raw material：Potassium feldspar 32%, quartz 12%, biotite
4%, chlorite 16%, calcite 13%, Talcum 18%, sodium oxide 2%, titanium oxide 1%, copper oxide 2%.
Light Zijin color glaze is made up of the raw material of following percentage by weight：Potassium feldspar 35 ~ 50%, quartz 5 ~ 15%, biotite 1
~ 5%, chlorite 10 ~ 20%, calcite 5 ~ 15%, Talcum 20 ~ 30%, sodium oxide 3 ~ 7%, titanium oxide 1 ~ 3%, copper oxide 3 ~ 5%.
Above-mentioned light Zijin color glaze is preferably made up of the raw material of following percentage by weight：Potassium feldspar 37%, quartz 8%, black clouds
Female 2%, chlorite 12%, calcite 8%, Talcum 23%, sodium oxide 4%, titanium oxide 2%, copper oxide 4%.
Present invention also offers the manufacture method of above-mentioned Zijin glaze, specifically includes following steps：
（1）Sieve after potassium feldspar, quartz, biotite, chlorite, calcite and Talcum are crushed respectively, specifically which is used respectively
100 ~ 200 sieves are crossed after rolling crusher machine；
（2）Potassium feldspar, quartz by stoichiometry by sodium oxide, titanium oxide, copper oxide and after sieving, biotite, chlorite, side
Xie Shi and Talcum are mixed；
（3）The raw material for mixing is put into into ball mill, by material:Water:Ball=1:0.5:1.5, wet ball grinding 10 ~ 15 hours；
（4）Glaze after ball milling is tuned into 50 ~ 80 Baume degrees glaze slips again Jing after 100 ~ 200 mesh sieves；
（5）Take molding idiosome to spray after the glaze slip is dried, Jing kilns burn manufactured goods, and kiln fire sintering procedure specifically includes following rank
Section：First oxidation stage, kiln temperature are raised to 980 DEG C from room temperature, and the heating-up time is 5 ~ 7 hours；Strong reduction phase, kiln temperature
1150 DEG C are raised to from 980 DEG C, 20 minutes is incubated when temperature is 1150 DEG C, and wherein, the heating-up time is 1 ~ 2 hour；Middle reduction phase,
Kiln temperature is raised to 1250 DEG C from 1150 DEG C, is incubated 10 minutes when temperature is 1250 DEG C, and wherein, the heating-up time is 0.5 ~ 1 hour；
Weak reduction phase, kiln temperature are raised to 1280 DEG C from 1250 DEG C, and the heating-up time is 20 ~ 40 minutes；Second oxidation stage, kiln interior temperature
Degree is raised to 1330 DEG C from 1280 DEG C, and the heating-up time is 30 ~ 50 minutes；Cooling down obtains final product product.Wherein, the shaping block after glaze spraying
Body is positioned on kiln furnitures carries out kiln baked wheaten cake system.
Raw material of the present invention is primarily served the purpose of：
Potassium feldspar：The glass phase creep resistance played under high temperature fused state by optimization Zijin glaze glaze is to improve product resistance
Shape ability, in Zijin glaze burns till, the melten glass of potassium feldspar can fill base substrate intergranular space, and can promote to melt other
Raw mineral materials, makes base substrate quality fine and close；Potassium feldspar also provides potassium element for Zijin glaze, and potassium element is in the form of potassium oxide
In Zijin glaze glaze, potassium oxide is the primary raw material to form Zijin glaze glaze, as solvent materials, can reduce the burning of Zijin glaze
Into temperature.
Quartz：Quartz provides silicon dioxide for Zijin glaze, silicon dioxide can improve in glaze Zijin glaze viscosity,
Mechanical strength, hardness, wearability, chemical resistance, reduce the coefficient of expansion of glaze.
Biotite：Melt temperature is low, the main connection for strengthening glaze, can more preferable improve product quality.Biotite is Zijin
Glaze provide aluminium element, aluminium element in the form of aluminium oxide in Zijin glaze glaze, aluminium oxide can make Zijin glaze have it is heat-resisting,
Anti-corrosion, wear-resisting performance.
Chlorite：Mainly as coloring agent, the color of Zijin glaze can be preferably embodied.Chlorite provides magnesium unit for Zijin glaze
Element and ferrum element, in Zijin glaze glaze in the form of magnesium oxide, magnesium oxide ensure that the uniformity on porcelain surface to magnesium elements,
The effect of electrical insulation can be played with high-k；Ferrum element is in the form of ferrous oxide and ferrum oxide in Zijin glaze
Glaze, ferrous oxide and ferrum oxide make glaze tone more enrich, more beautiful, and ferrous ion can be absorbed by the body to make
Hemopoietic Lactoferrin, can prevent iron deficiency anemia.
Calcite：Calcite provides calcium constituent for Zijin glaze, and calcium constituent is in the form of calcium oxide in Zijin glaze glaze
Face, calcium oxide mainly play solvent action in Zijin glaze, it is possible to increase the hardness of glaze, abrasion resistance, corrosion resistance and
Glossiness, reduces the high temperature viscosity of glaze；The intake of calcium constituent can promote the growth promoter of skeleton, while calcium constituent
Can dewatering and disinfecting, there is certain purification to water quality
Talcum：It is high temperature invariant color to be played a part of, and density strengthens, and good luster, surface are smooth, and main character is a kind of level
Soft raw mineral materials, Talcum provide magnesium elements for Zijin glaze.
Sodium oxide：It is a kind of fabulous raw material of easy fired, makes ceramic body realize easy fired, while makes ceramic body
In the high quartz content of unnecessary thermal coefficient of expansion reduce, shorten firing period, overcome deformation, expansion firing range, in addition by
The content of sodium makes the glass in ceramic body mutually increase, so sodium oxide can also reduce the property of water-bearing of ceramics, improves ceramic blank
The mechanical strength and enamel glossiness of body.
Titanium oxide：In Zijin glaze, add titanium oxide that glaze can be made more smooth, acid resistance strengthens, and improves glaze gloss
Degree.
Copper oxide:Copper oxide is added to certain component and Zijin glaze glaze can be caused to produce the effect of blacking up in Huang or black inner yellowing
Really, Zijin glaze glaze color can be adjusted.
The present invention has the beneficial effect that：The present invention have developed a kind of new Zijin glaze glaze formula through repetition test, and
By controlling firing atmosphere and temperature so that the Zijin glaze glaze produced is in Zijin color and has sub- light gloss or light gloss
Effect, glaze contain crystalline temperature, and its glaze colours is simple and tasteful, and noble Ling Run has taken gold lustre, allows people to be so fond that will not let out of one's hand
Sensation；The present invention can be configured to sub- light Zijin color glaze or light Zijin color glaze by brewable material proportioning；In addition, this experiment
Member has found that the Zijin glaze that the present invention makes also has the effect of alcoholization tea, takes advantage of dress tea with Zijin glaze porcelain cup, and mouthfeel is more aromatic.
Specific embodiment
With reference to embodiment, the present invention is described in detail.If it should be noted that not conflicting, the present invention is implemented
Each feature in example and embodiment can be combined with each other, within protection scope of the present invention.
Percentage by weight of the present invention can be the unit of weight well known in the art such as μ g, mg, g, kg, or
Its multiple, such as 1/10,1/100,10 times, 100 times etc..
Embodiment 1
（1）It is broken to sieve
Sieve after potassium feldspar, quartz, biotite, chlorite, calcite and Talcum are crushed respectively, can be crushed with edge runner mill respectively
Cross 100 ~ 200 mesh sieve afterwards to sieve；
（2）Raw material mixes
33 weight portions after taking the sodium oxide of 0.1 weight portion, the titanium oxide of 0.6 weight portion, the copper oxide of 2.3 weight portions and sieving
Potassium feldspar, the quartz of 12 weight portions, the biotite of 3 weight portions, the chlorite of 17 weight portions, the calcite of 14 weight portions and 18
The Talcum of weight portion is mixed；
（3）Wet ball grinding
By step（2）The raw material input ball mill for mixing, by material:Water:Ball=1:0.5:1.5, wet ball grinding 10 ~ 15 hours；
（4）Make glaze slip
Glaze after ball milling is tuned into 50 ~ 80 Baume degrees glaze slips again Jing after 100 ~ 200 mesh sieves；
（5）Glazing is fired
Molding idiosome being taken, the glaze slip being sprayed in idiosome, Jing kilns burn manufactured goods after being dried, kiln fire sintering procedure specifically includes following
Stage：First oxidation stage, kiln temperature are raised to 980 DEG C from room temperature, and the heating-up time is 5 ~ 7 hours；Strong reduction phase, kiln interior temperature
Degree is raised to 1150 DEG C from 980 DEG C, is incubated 20 minutes when temperature is 1150 DEG C, and wherein, the heating-up time is 1 ~ 2 hour；Middle reduction rank
Section, kiln temperature are raised to 1250 DEG C from 1150 DEG C, are incubated 10 minutes when temperature is 1250 DEG C, and wherein, the heating-up time is 0.5 ~ 1 little
When；Weak reduction phase, kiln temperature are raised to 1280 DEG C from 1250 DEG C, and the heating-up time is 20 ~ 40 minutes；Second oxidation stage, kiln
Interior temperature is raised to 1330 DEG C from 1280 DEG C, and the heating-up time is 30 ~ 50 minutes；Cooling down obtains final product product.
The Zijin glaze that the present embodiment is fired has sub- light Zijin color glaze face, and glaze contains crystalline temperature, increased Zijin glaze
Sight.
Embodiment 2
（1）It is broken to sieve
Sieve after potassium feldspar, quartz, biotite, chlorite, calcite and Talcum are crushed respectively, can be crushed with edge runner mill respectively
Cross 100 ~ 200 mesh sieve afterwards to sieve；
（2）Raw material mixes
The potassium of 32 weight portions after taking the sodium oxide of 2 weight portions, the titanium oxide of 1 weight portion, the copper oxide of 2 weight portions and sieving is long
Stone, the quartz of 12 weight portions, the biotite of 4 weight portions, the chlorite of 16 weight portions, the calcite of 13 weight portions and 18 weight portions
Talcum mixed；
（3）Wet ball grinding
By step（2）The raw material input ball mill for mixing, by material:Water:Ball=1:0.5:1.5, wet ball grinding 10 ~ 15 hours；
（4）Make glaze slip
Glaze after ball milling is tuned into 50 ~ 80 Baume degrees glaze slips again Jing after 100 ~ 200 mesh sieves；
（5）Glazing is fired
Molding idiosome being taken, the glaze slip being sprayed in idiosome, Jing kilns burn manufactured goods after being dried, kiln fire sintering procedure specifically includes following
Stage：First oxidation stage, kiln temperature are raised to 980 DEG C from room temperature, and the heating-up time is 5 ~ 7 hours；Strong reduction phase, kiln interior temperature
Degree is raised to 1150 DEG C from 980 DEG C, is incubated 20 minutes when temperature is 1150 DEG C, and wherein, the heating-up time is 1 ~ 2 hour；Middle reduction rank
Section, kiln temperature are raised to 1250 DEG C from 1150 DEG C, are incubated 10 minutes when temperature is 1250 DEG C, and wherein, the heating-up time is 0.5 ~ 1 little
When；Weak reduction phase, kiln temperature are raised to 1280 DEG C from 1250 DEG C, and the heating-up time is 20 ~ 40 minutes；Second oxidation stage, kiln
Interior temperature is raised to 1330 DEG C from 1280 DEG C, and the heating-up time is 30 ~ 50 minutes；Cooling down obtains final product product.
The Zijin glaze that the present embodiment is fired has sub- light Zijin color glaze face, and glaze contains crystalline temperature, increased Zijin glaze
Sight.
Embodiment 3
（1）It is broken to sieve
Sieve after potassium feldspar, quartz, biotite, chlorite, calcite and Talcum are crushed respectively, can be crushed with edge runner mill respectively
Cross 100 ~ 200 mesh sieve afterwards to sieve；
（2）Raw material mixes
The potassium of 36 weight portions after taking the sodium oxide of 7 weight portions, the titanium oxide of 2 weight portions, the copper oxide of 4 weight portions and sieving is long
Stone, the quartz of 6 weight portions, the biotite of 3 weight portions, the chlorite of 12 weight portions, the calcite of 8 weight portions and 22 weight portions
Talcum is mixed；
（3）Wet ball grinding
By step（2）The raw material input ball mill for mixing, by material:Water:Ball=1:0.5:1.5, wet ball grinding 10 ~ 15 hours；
（4）Make glaze slip
Glaze after ball milling is tuned into 50 ~ 80 Baume degrees glaze slips again Jing after 100 ~ 200 mesh sieves；
（5）Glazing is fired
Molding idiosome being taken, the glaze slip being sprayed in idiosome, Jing kilns burn manufactured goods after being dried, kiln fire sintering procedure specifically includes following
Stage：First oxidation stage, kiln temperature are raised to 980 DEG C from room temperature, and the heating-up time is 5 ~ 7 hours；Strong reduction phase, kiln interior temperature
Degree is raised to 1150 DEG C from 980 DEG C, is incubated 20 minutes when temperature is 1150 DEG C, and wherein, the heating-up time is 1 ~ 2 hour；Middle reduction rank
Section, kiln temperature are raised to 1250 DEG C from 1150 DEG C, are incubated 10 minutes when temperature is 1250 DEG C, and wherein, the heating-up time is 0.5 ~ 1 little
When；Weak reduction phase, kiln temperature are raised to 1280 DEG C from 1250 DEG C, and the heating-up time is 20 ~ 40 minutes；Second oxidation stage, kiln
Interior temperature is raised to 1330 DEG C from 1280 DEG C, and the heating-up time is 30 ~ 50 minutes；Cooling down obtains final product product.
The Zijin glaze that the present embodiment is fired has light Zijin color glaze face, and glaze contains crystalline temperature, increased Zijin glaze
Sight.
Embodiment 4
（1）It is broken to sieve
Sieve after potassium feldspar, quartz, biotite, chlorite, calcite and Talcum are crushed respectively, can be crushed with edge runner mill respectively
Cross 100 ~ 200 mesh sieve afterwards to sieve；
（2）Raw material mixes
The potassium of 37 weight portions after taking the sodium oxide of 4 weight portions, the titanium oxide of 2 weight portions, the copper oxide of 4 weight portions and sieving is long
Stone, the quartz of 8 weight portions, the biotite of 2 weight portions, the chlorite of 12 weight portions, the calcite of 8 weight portions and 23 weight portions
Talcum is mixed；
（3）Wet ball grinding
By step（2）The raw material input ball mill for mixing, by material:Water:Ball=1:0.5:1.5, wet ball grinding 10 ~ 15 hours；
（4）Make glaze slip
Glaze after ball milling is tuned into 50 ~ 80 Baume degrees glaze slips again Jing after 100 ~ 200 mesh sieves；
（5）Glazing is fired
Molding idiosome being taken, the glaze slip being sprayed in idiosome, Jing kilns burn manufactured goods after being dried, kiln fire sintering procedure specifically includes following
Stage：First oxidation stage, kiln temperature are raised to 980 DEG C from room temperature, and the heating-up time is 5 ~ 7 hours；Strong reduction phase, kiln interior temperature
Degree is raised to 1150 DEG C from 980 DEG C, is incubated 20 minutes when temperature is 1150 DEG C, and wherein, the heating-up time is 1 ~ 2 hour；Middle reduction rank
Section, kiln temperature are raised to 1250 DEG C from 1150 DEG C, are incubated 10 minutes when temperature is 1250 DEG C, and wherein, the heating-up time is 0.5 ~ 1 little
When；Weak reduction phase, kiln temperature are raised to 1280 DEG C from 1250 DEG C, and the heating-up time is 20 ~ 40 minutes；Second oxidation stage, kiln
Interior temperature is raised to 1330 DEG C from 1280 DEG C, and the heating-up time is 30 ~ 50 minutes；Cooling down obtains final product product.
The Zijin glaze that the present embodiment is fired has light Zijin color glaze face, and glaze contains crystalline temperature, increased Zijin glaze
Sight.
The present invention obtains a kind of Zijin glaze glaze formula through experiment repeatedly, embodiment 1,2,3,4 simply test in more
Preferred example, other embodiment are not just enumerated, every in the range of the Zijin glaze glaze formula that the present invention is provided, and
According to Zijin glaze manufacture method of the present invention, sub- light gloss or light luster effect can be produced in Zijin color and have
Zijin glaze glaze, meanwhile, glaze also contains crystalline temperature, increased the sight of Zijin glaze.Zijin glaze glaze obtained in of the invention
Color is simple and tasteful, noble Ling Run, has taken gold lustre, allows people to have the sensation being so fond that will not let out of one's hand.This laboratory technician has found this
The Zijin glaze of bright making also has the effect of alcoholization tea, takes advantage of dress tea with Zijin glaze porcelain cup, and mouthfeel is more aromatic.
In addition, the glossiness and color effects of this laboratory technician discovery Zijin glaze glaze percentage respectively with sodium oxide in raw material
Content accounting is relevant with the percentage composition accounting of copper oxide, is specifically described with reference to comparative example 1,2,3,4.
Comparative example 1
Only change the addition of sodium oxide as different from Example 1, its construction method is same as Example 1, by 0.1 weight portion
Sodium oxide make 0.05 part of weight portion into, account for the 0.05% of total raw material, the Zijin glaze glaze vitreous degree produced is relatively low, gloss effect
Fruit is not good.
Comparative example 2
Only change the addition of sodium oxide as different from Example 3, its construction method is same as Example 3, by 7 weight portions
Sodium oxide makes 10 parts of weight portions into, accounts for the 9.7% of total raw material, and height, glaze mobility are spent in the Zijin glaze glaze vitreous produced
It is high so that glaze bonding kiln furnitures, while glaze will not produce crystalline temperature.
Comparative example 3
Only change the addition of copper oxide as different from Example 1, its construction method is same as Example 1, by 2.3 weight portions
Copper oxide make 0.05 part of weight portion into, account for the 0.05% of total raw material, the Zijin glaze glaze produced be black, do not possess Zijin
Color.
Comparative example 4
Only change the addition of copper oxide as different from Example 3, its construction method is same as Example 3, by 4 weight portions
Copper oxide makes 8 parts of weight portions into, accounts for the 7.8% of total raw material, and the Zijin glaze glaze produced is redness, does not possess Zijin color.
Jing of the present invention is tested repeatedly and is learnt：
（1）The addition of sodium oxide for total raw material 0.1 ~ 7%（Weight）When, as the addition of sodium oxide increases, Zijin glaze glaze
The glossiness in face increases, and glaze is converted to light gloss, such as embodiment 1,2,3,4 from sub- light gloss；When the addition of sodium oxide
Less than total raw material 0.1% when, Zijin glaze glaze glossiness is relatively low, and luster effect is not good, such as comparative example 1；When the addition of sodium oxide
When amount is more than the 7% of total raw material, Zijin glaze glaze glossiness is high, possesses light gloss, but height is spent in Zijin glaze glaze vitreous,
Glaze mobility is big so that glaze bonding kiln furnitures, while glaze will not produce crystalline temperature, such as comparative example 2.
（2）When the addition of copper oxide is the 0.1 ~ 5% of total raw material, as the addition of copper oxide increases, Zijin glaze glaze
Color is Zijin color, such as embodiment 1,2,3,4 between black and redness；And work as the addition of copper oxide less than total raw material
When 0.1%, Zijin glaze glaze color is black, does not possess Zijin color, such as comparative example 3；And work as the addition of copper oxide more than total original
Material 5% when, Zijin glaze glaze for redness, do not possess Zijin color, such as comparative example 4.Copper oxide be glaze crystalline temperature it is main into
Point, chlorite can be coordinated to carry out the change of color to Zijin glaze.
Although above having used general explanation, specific embodiment and test, the present invention having been made to retouch in detail
State, but on the basis of the present invention, it can be made some modifications or improvements, this is apparent to those skilled in the art
's.Therefore, these modifications or improvements without departing from theon the basis of the spirit of the present invention, belong to claimed
Scope.
Claims (8)
1. a kind of Zijin glaze, it is characterised in that be made up of the raw material of following percentage by weight：Potassium feldspar 20 ~ 50%, quartzy 5 ~
15%, biotite 1 ~ 5%, chlorite 10 ~ 20%, calcite 5 ~ 15%, Talcum 15 ~ 30%, sodium oxide 0.1 ~ 7%, titanium oxide 0.2 ~ 3%,
Copper oxide 0.1 ~ 5%.
2. a kind of Zijin glaze according to claim 1, it is characterised in that be made up of the raw material of following percentage by weight：Potassium
Anhydrite 20 ~ 35%, quartz 5 ~ 15%, biotite 1 ~ 5%, chlorite 10 ~ 20%, calcite 5 ~ 15%, Talcum 15 ~ 20%, sodium oxide 0.1
~ 3%, titanium oxide 0.2 ~ 1%, copper oxide 0.1 ~ 3%.
3. a kind of Zijin glaze according to claim 2, it is characterised in that be made up of the raw material of following percentage by weight：Potassium
Anhydrite 32%, quartz 12%, biotite 4%, chlorite 16%, calcite 13%, Talcum 18%, sodium oxide 2%, titanium oxide 1%, copper oxide
2%。
4. a kind of Zijin glaze according to claim 1, it is characterised in that be made up of the raw material of following percentage by weight：Potassium
Anhydrite 35 ~ 50%, quartz 5 ~ 15%, biotite 1 ~ 5%, chlorite 10 ~ 20%, calcite 5 ~ 15%, Talcum 20 ~ 30%, sodium oxide 3 ~
7%, titanium oxide 1 ~ 3%, copper oxide 3 ~ 5%.
5. a kind of Zijin glaze according to claim 4, it is characterised in that be made up of the raw material of following percentage by weight：Potassium
Anhydrite 37%, quartz 8%, biotite 2%, chlorite 12%, calcite 8%, Talcum 23%, sodium oxide 4%, titanium oxide 2%, copper oxide
4%。
6. a kind of manufacture method of the Zijin glaze according to any one of claim 1-5, comprises the steps：
（1）Sieve after potassium feldspar, quartz, biotite, chlorite, calcite and Talcum are crushed respectively；
（2）Potassium feldspar, biotite by stoichiometry by sodium oxide, titanium oxide, copper oxide and after sieving, quartz, chlorite, side
Xie Shi and Talcum are mixed；
（3）The raw material for mixing is put into into ball mill, by material:Water:Ball=1:0.5:1.5, wet ball grinding 10 ~ 15 hours；
（4）Glaze after ball milling is tuned into 50 ~ 80 Baume degrees glaze slips again Jing after 100 ~ 200 mesh sieves；
（5）Take molding idiosome to spray after the glaze slip is dried, Jing kilns burn manufactured goods.
7. a kind of manufacture method of Zijin glaze according to claim 6, it is characterised in that the step（1）Specifically：Will
Potassium feldspar, quartz, biotite, chlorite, calcite and Talcum edge runner mill are crossed 100 ~ 200 mesh sieve after crushing respectively and are sieved.
8. a kind of manufacture method of Zijin glaze according to claim 6, it is characterised in that the step（5）Middle kiln is burnt
Process processed was specifically included with the next stage：First oxidation stage, kiln temperature are raised to 980 DEG C from room temperature, and the heating-up time is 5 ~ 7 little
When；Strong reduction phase, kiln temperature are raised to 1150 DEG C from 980 DEG C, are incubated 20 minutes, wherein, during intensification when temperature is 1150 DEG C
Between be 1 ~ 2 hour；Middle reduction phase, kiln temperature are raised to 1250 DEG C from 1150 DEG C, are incubated 10 minutes when temperature is 1250 DEG C, its
In, the heating-up time is 0.5 ~ 1 hour；Weak reduction phase, kiln temperature are raised to 1280 DEG C from 1250 DEG C, and the heating-up time is 20 ~ 40
Minute；Second oxidation stage, kiln temperature are raised to 1330 DEG C from 1280 DEG C, and the heating-up time is 30 ~ 50 minutes.
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| CN107244807A (en) * | 2017-05-18 | 2017-10-13 | 东北大学 | A kind of green speckled glaze of leaf and preparation method thereof |
| CN108585505A (en) * | 2018-06-01 | 2018-09-28 | 德化县如瓷生活文化有限公司 | A kind of persimmon red pottery glaze and preparation method thereof and glazing method |
| CN111635136A (en) * | 2020-07-13 | 2020-09-08 | 平江县阜山窑陶瓷文化艺术发展有限公司 | Green glaze capable of being sliced and preparation method thereof |
| CN112479589A (en) * | 2020-12-24 | 2021-03-12 | 湖州海程塑业有限公司 | Light pink glaze and preparation method thereof |
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