CN1065149A - X-ray protection sheet material and production method thereof - Google Patents
X-ray protection sheet material and production method thereof Download PDFInfo
- Publication number
- CN1065149A CN1065149A CN 92106491 CN92106491A CN1065149A CN 1065149 A CN1065149 A CN 1065149A CN 92106491 CN92106491 CN 92106491 CN 92106491 A CN92106491 A CN 92106491A CN 1065149 A CN1065149 A CN 1065149A
- Authority
- CN
- China
- Prior art keywords
- screener
- protective plates
- described protective
- barium
- ray protection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 230000001681 protective effect Effects 0.000 claims abstract description 19
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 10
- YEXPOXQUZXUXJW-UHFFFAOYSA-N lead(II) oxide Inorganic materials [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 210000003608 fece Anatomy 0.000 claims abstract description 7
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 6
- 150000003839 salts Chemical class 0.000 claims abstract description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 5
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical class [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000004568 cement Substances 0.000 claims abstract description 5
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 5
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 claims abstract description 3
- 229910001626 barium chloride Inorganic materials 0.000 claims abstract description 3
- 239000011230 binding agent Substances 0.000 claims description 11
- 239000012779 reinforcing material Substances 0.000 claims description 7
- 159000000009 barium salts Chemical class 0.000 claims description 6
- 150000002611 lead compounds Chemical class 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 4
- 239000003365 glass fiber Substances 0.000 claims description 4
- 239000003292 glue Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000012530 fluid Substances 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 3
- 230000003068 static effect Effects 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 2
- WALYXZANOBBHCI-UHFFFAOYSA-K magnesium sodium trichloride hydrate Chemical compound O.[Cl-].[Na+].[Mg+2].[Cl-].[Cl-] WALYXZANOBBHCI-UHFFFAOYSA-K 0.000 claims description 2
- 229910052573 porcelain Inorganic materials 0.000 claims description 2
- 239000012744 reinforcing agent Substances 0.000 claims 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 abstract description 8
- 229910001629 magnesium chloride Inorganic materials 0.000 abstract description 4
- 238000000465 moulding Methods 0.000 abstract description 4
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 230000002265 prevention Effects 0.000 abstract description 2
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 abstract 1
- -1 massicot Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000004888 barrier function Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000013558 reference substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 231100000987 absorbed dose Toxicity 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
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- Curing Cements, Concrete, And Artificial Stone (AREA)
- Laminated Bodies (AREA)
Abstract
The invention provides a kind of x-ray protection sheet material, as inorganic bonding material, and make screener with inorganic salts such as massicot, vulcanized lead, barium sulphate, barium chloride and barium carbonates with high-alumina cement, magnesium oxide, magnesium chloride and sodium silicate etc.Earlier cementing agent is mixed in proportion with screener, a kind of semifluid dung of mixing one-tenth, molding moulding on template thereafter obtains protective plates through curing.This board quality is light, intensity is high, and is not yielding, and convenient formation also has the fire prevention antihunt action, and the X line is had good protective capacities, can widespread use on the x-ray protection device.
Description
The present invention is relevant with ray protection material, more specifically says so about the protective materials of X ray.
Along with the development of modern science, radiation has been widely applied to the every field of national economy as a kind of new technology.X ray is more and more general in the application aspect medical, for fear of the X line human body is brought harm, and the protection of doing the X line well is necessary.Traditional protective materials of X line is plumbous.Plumbous mechanical property is bad, and physical dimension is very unstable, and is yielding, sagging, not shockproof, so lead can not be constructed separately, the clamping materials for support must be arranged.Because plumbous ratio is great, use very inconveniently, and lead resource lacks the use cost height.
The object of the present invention is to provide that a kind of barrier propterty is good, in light weight, easy-formation, the low protective plates easy to use of cost.
Solution of the present invention is that the compound substance made with a kind of screener, cementing agent and reinforcing material is as protective plates.Here said cementing agent is a kind of inorganic binder, can certainly use the organic binder bond of unsaturated polyester resin and so on.Said screener is a kind of inorganic salts.The constituent of making this protective plates comprises (weight %): 55～70 inorganic salts screener, 25～40 inorganic binder and 3～4 reinforcing material.
Said in the present invention inorganic salts screener is that lead compound and barium salt are formed.Select for use leadization thing or barium salt to make screener separately and also can obtain protection effect, but preferred composition is still selected both potpourris for use, its preferred proportion is 1: 1.Here the lead compound of indication is to be selected from massicot and/or vulcanized lead, both can use wherein a kind of separately, also can be with both potpourris; Said barium salt then is a barium sulphate, one or more potpourris in barium chloride and the barium carbonate.
The inorganic binder that uses among the present invention is to comprise a kind of solid binder composition and a kind of liquid adhesive glue composition, and both ratios are 1: 1.Said solid binder composition is selected from high-alumina cement and magnesium oxide, and both can mix use, also can choose one of them independent use wantonly, but preferred ratio still is 1: 1 a potpourri.Said liquid adhesive glue composition is selected from a kind of magnesium chloride brine and liquid sodium silicate.Both equally also can select for use separately, but method for optimizing also is to use both potpourris, and both preferred proportions are 1: 1.The concentration of said magnesium chloride is 65～80%(weight %), the concentration of sodium silicate is 10～50%(weight %).
The used reinforcing material of the present invention then is selected from a kind of in flaxen fiber, porcelain fiber or the glass fibre.
The production method of x-ray protection sheet material of the present invention is: (a) drop into cementing agent and screener in proportion in stirring mixer, mix, continue to be stirred to semi-fluid condition with stirring machine, make the semifluid binding that contains screener; (b) molding moulding.First shop one deck semifluid dung on template is then spread one deck reinforcing material, is that 150～200 the even vibration air exhaust of bumper is to smooth surface with frequency.So alternately lay 3～5 layers and make mold base.(c) 25～35 ℃ of following static curing 48～72 hours.(d) the said protective plates of the present invention is so just made in the demoulding, shaping.The advantage of using this inorganic binder is not to be afraid of wet environment in process of production, and is low to the humidity requirement of former material, can omit raw material drying technology, and can reduce cost.
Further specify technological process of the present invention with a concrete instance more below.In stirring mixer, drop into 2.5 kilograms of high-alumina cements and 2.5 kilograms of magnesium oxide, add again after 16 kilograms in 4 kilograms in massicot, barium sulphate mixes, 2.5 kilograms of sodium silicate that add 40% concentration again, 2.5 kilograms in the magnesium chloride of 70% concentration, continue to mix to presenting semi-fluid condition, obtain 30 kilograms of semifluid dung.Then on template, spread the semifluid dung of 1-1.5 millimeters thick earlier, repave layer of glass, spread one deck dung again, when vibration air exhaust is to smooth surface thereafter, continue again alternately to spread 3～5 layers, consume about 1.2 kilograms of glass fibre.So make the mold base of about 8 millimeters thick of thickness, 25～35 ℃ of down static curing 48～72 hours, the demoulding, shaping obtain thickness and are 8 millimeters one square metre of protective shield.
For showing the protection effect of the present invention, done the mensuration of barrier propterty by Taishan Hospital to the X line.Method of testing is measured with instrumental method according to the argumentation that old professor jade worker writes " X line physics " book, represents the receptivity of material to the X line with lead equivalent.The meaning of lead equivalent is: with measured material the thickness of the lead of same absorbent ability is arranged.With F34-1 type Stabilipan is radiographic source, the dose rate that sees through with the measurement of NYL-III type roentgenomater.
Assay method: select tube voltage 100KVP, Measuring Time 10 seconds,, write down the dose rate that sees through of each standard lead flake of 0.2～2.5 millimeters thick with the integral absorbed dose of roentgenomater.Result such as table 1.
Table 1, standard lead flake dose rate is measured
| Lead flake thickness (millimeter) | 0.3 0.4 0.5 0.6 0.7 0.8 …… | ||||||
| Dose rate (human relations/minute) | 4.8 3.2 2.1 1.6 1.3 0.9 …… | ||||||
With dose rate (human relations/minute) is ordinate, and standard lead flake thickness (millimeter) is abscissa, draws out logarithmic curve chart (accompanying drawing 1).
With measuring different plates that the present invention makes the dose rate that sees through under the condition to the X line, check in the lead equivalent of sample by accompanying drawing 1, and with iron plate product in contrast, test result such as table 2.
Table 2 plate property of the present invention is measured
| Sample number | The present invention | Reference substance |
| 1 2 | ||
| Thickness (mm) dose rate (human relations/minute) lead equivalent (millimeter) proportion (g/cm 3) | 8 16 0.5 0.05 1.2 2.2 3.4 3.4 | 5 0.7 1.1 7.81 |
Test result shows that the proportion of sheet material of the present invention is lighter than reference substance, but more much better than iron to the shielding properties of X line, has reached requirement of shelter.
Advantage of the present invention is clearly, uses this sheet material to make protective materials, light weight, intensity height, and more stable than the physical dimension of lead, not yielding, convenient formation need not any gripping object, and has the fire prevention shockproof properties.Cheap, durable in use, use light, can widespread use on the x-ray protection device.
Further specify the present invention with several embodiment more below, be not confined to this several example formulations scopes certainly.
Embodiment 123
Form weight %
High-alumina cement 8.01 15.54
Magnesium oxide 8.01 16.0
50% sodium silicate 8.01 15.53
70% magnesium chloride 8.01 16.1
Massicot 12.83 32.05
Barium sulphate 51.28 32.0 65.22
Glass fibre 3.85 3.85 3.72
Performance
Proportion 3.4 4.6 3.3
Lead equivalent 1.0 1.3 0.9
Claims (10)
1, a kind of X-ray protection sheet material is made up of shielding material, cementing agent and reinforcing material, it is characterized in that containing inorganic binder and inorganic salts screener, and its constituent content is (weight %):
Inorganic salts screener 55-70
Inorganic binder 25-40
Reinforcing agent 3-4
2,, it is characterized in that said screener is made up of lead compound and/or barium salt according to the described protective plates of claim 1.
3,, it is characterized in that said lead compound is selected from massicot and/or vulcanized lead according to the described protective plates of claim 2.
4,, it is characterized in that said barium salt is one or more in barium sulphate, barium chloride and the barium carbonate according to the described protective plates of claim 2.
5,, it is characterized in that the ratio of lead compound and barium salt is 1: 1 in the said screener according to the described protective plates of claim 2.
6,, it is characterized in that said cementing agent is to comprise a kind of solid binder and a kind of liquid adhesive glue according to the described protective plates of claim 1.
7,, it is characterized in that said solid binder is selected from high-alumina cement and magnesium oxide according to the described protective plates of claim 6.
8,, it is characterized in that said liquid adhesive glue is selected from a kind of magnesium chloride brine and sodium silicate according to the described protective plates of claim 6.
9,, it is characterized in that said reinforcing material is selected from a kind of in flaxen fiber, porcelain fiber or the glass fibre according to the described protective plates of claim 1.
10, according to the production method of the described protective plates of claim 1: it is characterized in that:
(a) cementing agent and screener are mixed in proportion, be stirred to semi-fluid condition, make the semifluid dung that contains screener with stirring machine;
(b) on template, lay semifluid dung and reinforcing material, and vibration air exhaust is to smooth surface;
(c) 25～35 ℃ of following static curing 48～72 hours;
(d) demoulding, shaping.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92106491 CN1027017C (en) | 1992-05-03 | 1992-05-03 | X-ray protective plates and its producing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92106491 CN1027017C (en) | 1992-05-03 | 1992-05-03 | X-ray protective plates and its producing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1065149A true CN1065149A (en) | 1992-10-07 |
| CN1027017C CN1027017C (en) | 1994-12-14 |
Family
ID=4942160
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 92106491 Expired - Fee Related CN1027017C (en) | 1992-05-03 | 1992-05-03 | X-ray protective plates and its producing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1027017C (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008080282A1 (en) * | 2006-12-28 | 2008-07-10 | Shandong Wanjie High-Tech Co., Ltd | A protective concrete for weakening the intensity of proton radiation |
| CN102842350A (en) * | 2011-06-22 | 2012-12-26 | 梁瑶娟 | Barium-based fiber protection plate |
| CN102930908A (en) * | 2011-08-10 | 2013-02-13 | 刘学文 | Method for manufacturing lead-free plant fiber protecting plate |
| CN102945687A (en) * | 2012-08-21 | 2013-02-27 | 曾小荣 | Ionization ray shielding protection plate and manufacture method thereof |
| CN103243427A (en) * | 2013-01-13 | 2013-08-14 | 山东来利来毛纺有限公司 | Anti-electromagnetic-radiation antistatic fabric |
| CN103243438A (en) * | 2013-01-14 | 2013-08-14 | 山东来利来毛纺有限公司 | Anti-electromagnetic-radiation antistatic woolen blanket |
| CN103238942A (en) * | 2013-01-13 | 2013-08-14 | 山东来利来毛纺有限公司 | Anti-electromagnetic-radiation antistatic undergarment |
| CN103238959A (en) * | 2013-01-14 | 2013-08-14 | 山东来利来毛纺有限公司 | Anti-electromagnetic-radiation antistatic maternity dress |
| CN103243479A (en) * | 2013-01-14 | 2013-08-14 | 山东来利来毛纺有限公司 | Anti-electromagnetic-radiation and antistatic seat cushion |
| CN107342113A (en) * | 2017-07-21 | 2017-11-10 | 中国核动力研究设计院 | A kind of resistance to irradiation inorganic mask material of high temperature resistant |
| CN107919177A (en) * | 2017-10-20 | 2018-04-17 | 株洲合力电磁技术有限公司 | Radiation protection brick and preparation method thereof and radiation protection wall and its application |
| CN112331375A (en) * | 2020-11-23 | 2021-02-05 | 四川玄武岩纤维新材料研究院(创新中心) | Basalt and other fiber honeycomb fabric nuclear shielding composite material and preparation method and application thereof |
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| CN100533602C (en) * | 2007-09-06 | 2009-08-26 | 张兴茂 | Radial protection plate and its preparation method |
-
1992
- 1992-05-03 CN CN 92106491 patent/CN1027017C/en not_active Expired - Fee Related
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008080282A1 (en) * | 2006-12-28 | 2008-07-10 | Shandong Wanjie High-Tech Co., Ltd | A protective concrete for weakening the intensity of proton radiation |
| CN102842350A (en) * | 2011-06-22 | 2012-12-26 | 梁瑶娟 | Barium-based fiber protection plate |
| CN102930908A (en) * | 2011-08-10 | 2013-02-13 | 刘学文 | Method for manufacturing lead-free plant fiber protecting plate |
| CN102945687A (en) * | 2012-08-21 | 2013-02-27 | 曾小荣 | Ionization ray shielding protection plate and manufacture method thereof |
| CN103243427A (en) * | 2013-01-13 | 2013-08-14 | 山东来利来毛纺有限公司 | Anti-electromagnetic-radiation antistatic fabric |
| CN103243427B (en) * | 2013-01-13 | 2015-08-12 | 山东来利来生态纺织科技有限公司 | A kind of Anti-electromagneticantistatic antistatic fabric |
| CN103238942A (en) * | 2013-01-13 | 2013-08-14 | 山东来利来毛纺有限公司 | Anti-electromagnetic-radiation antistatic undergarment |
| CN103243479A (en) * | 2013-01-14 | 2013-08-14 | 山东来利来毛纺有限公司 | Anti-electromagnetic-radiation and antistatic seat cushion |
| CN103238959A (en) * | 2013-01-14 | 2013-08-14 | 山东来利来毛纺有限公司 | Anti-electromagnetic-radiation antistatic maternity dress |
| CN103243479B (en) * | 2013-01-14 | 2014-11-05 | 山东来利来毛纺有限公司 | Anti-electromagnetic-radiation and antistatic seat cushion |
| CN103238959B (en) * | 2013-01-14 | 2015-06-24 | 山东来利来生态纺织科技有限公司 | Anti-electromagnetic-radiation antistatic maternity dress |
| CN103243438A (en) * | 2013-01-14 | 2013-08-14 | 山东来利来毛纺有限公司 | Anti-electromagnetic-radiation antistatic woolen blanket |
| CN103243438B (en) * | 2013-01-14 | 2015-08-12 | 山东来利来生态纺织科技有限公司 | A kind of Anti-electromagneticantistatic antistatic woolen blanket |
| CN107342113A (en) * | 2017-07-21 | 2017-11-10 | 中国核动力研究设计院 | A kind of resistance to irradiation inorganic mask material of high temperature resistant |
| CN107919177A (en) * | 2017-10-20 | 2018-04-17 | 株洲合力电磁技术有限公司 | Radiation protection brick and preparation method thereof and radiation protection wall and its application |
| CN112331375A (en) * | 2020-11-23 | 2021-02-05 | 四川玄武岩纤维新材料研究院(创新中心) | Basalt and other fiber honeycomb fabric nuclear shielding composite material and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1027017C (en) | 1994-12-14 |
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Owner name: JINAN DEKANG RADIOLOGICAL PROTECTION AND DECORATE Free format text: FORMER OWNER: ZHAO CHENGCHEN Effective date: 20061201 |
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Effective date of registration: 20061201 Address after: 250300, Shandong City, Changqing province Ji'nan City South East Su Village Patentee after: Jinan Dekang Ray Protection Materials Co., Ltd. Address before: 250300 Chenguang glass mill, Ji'nan, Shandong, Changqing Patentee before: Zhao Chengchen |
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