JPH0769706A - Adhesive inorganic material - Google Patents
Adhesive inorganic materialInfo
- Publication number
- JPH0769706A JPH0769706A JP5133706A JP13370693A JPH0769706A JP H0769706 A JPH0769706 A JP H0769706A JP 5133706 A JP5133706 A JP 5133706A JP 13370693 A JP13370693 A JP 13370693A JP H0769706 A JPH0769706 A JP H0769706A
- Authority
- JP
- Japan
- Prior art keywords
- inorganic material
- zeolite
- adhesive
- less
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
- C04B28/32—Magnesium oxychloride cements, e.g. Sorel cement
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00637—Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Carbon And Carbon Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】この発明は、接着性無機質材に関
するものである。さらに詳しくは、この発明は、無機質
材料とその構造物、あるいは、木材、発泡プラスチック
材、及び加工された金属類等の接着や表面コーティング
材等として有用な、軽量で、不燃耐風化性の接着性無機
質材に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an adhesive inorganic material. More specifically, the present invention is a lightweight, non-combustible, weathering-resistant adhesive useful as an adhesive or surface coating material for inorganic materials and their structures, or wood, foamed plastic materials, and processed metals. It relates to a porous inorganic material.
【０００２】[0002]
【従来の技術とその課題】従来より、接着性の無機質材
が、無機材料や木材、発泡プラスチック及び加工された
金属類等の接着に幅広く利用されている。この無機質材
は、大別すると３つに分類することができる。まず第一
には、コンクリート材料であって充填材としての効果を
有するポルトランドセメント系接着材がある。しかしな
がら、このポルトランドセメント系接着材は、薄層接着
材としてその接着作用がニートセメント糊の水和作用に
よる珪酸塩の結晶化によるものであるので、接着作用が
非常に小さく、さらに、それらの硬化収縮が大きいた
め、亀裂の発生により剥離されるという欠点がある。2. Description of the Related Art Conventionally, adhesive inorganic materials have been widely used for bonding inorganic materials, wood, foamed plastics and processed metals. This inorganic material can be roughly classified into three types. First of all, there is a Portland cement adhesive which is a concrete material and has an effect as a filler. However, since this Portland cement-based adhesive is a thin-layer adhesive whose adhesive action is due to crystallization of silicate by the hydration action of neat cement paste, the adhesive action is very small, and further, their curing Since there is a large shrinkage, there is a drawback that peeling occurs due to the occurrence of cracks.
【０００３】これらの欠点を改善するために、高分子エ
マルジョン等を添加し、その糊材効果を発揮させようと
しているが、実際上の問題はほとんど解決されていな
い。また、長期的には、炭酸化による風化作用で粉化
し、さらに、アルカリ反応により発華現象が起こるた
め、接着材としては、不十分な材料である。第二の種類
としては、金属酸化物微粉体の表面における、活性化に
よる硬化現象を利用したものがある。これらは、特殊な
用途、たとえば電融マグネシアの微粉末の発熱シールド
材等に使われているが、一般に高価で、金属酸化物とい
わゆる低融点ガラスとによる金属類の接着材等としても
用いられているが、加熱しなければならないので、特殊
な接着材として取扱われている。In order to improve these drawbacks, a polymer emulsion or the like is added to try to exert its sizing effect, but practical problems have hardly been solved. Further, in the long term, the material is insufficient as an adhesive because it is powdered by the weathering effect due to carbonation and further causes a halo phenomenon due to an alkali reaction. The second type is one that utilizes the curing phenomenon due to activation on the surface of the metal oxide fine powder. These are used for special purposes, for example, as a heat shielding material for fine powder of electro-fused magnesia, but are generally expensive and are also used as an adhesive for metals such as metal oxide and so-called low-melting glass. However, it is handled as a special adhesive because it must be heated.
【０００４】さらに第三の種類として、アルカリ土類金
属酸化物とそれらのオキシ塩による反応を利用した亜鉛
セメント、マグネシア−亜鉛系セメント、マグネシアセ
メント（ソーレルセメント）が知られている。このう
ち、マグネシア−亜鉛−燐酸系セメントは、歯料材料と
して、急硬性、接着性が大きな材料としてその特徴を発
揮しているが、単価コストが高く、瞬間硬化性のために
一般用としては利用できないという欠点がある。また、
マグネシアセメントは、古くから無機材料、木材等との
接着性が強力であることは知られているが、吸湿性があ
るため、オキシ酸塩の浸出による結露や金属材料の侵食
作用の欠点があり、一般的に利用されることがなく、研
磨材の結合材として一部使用されているに過ぎない。Further, as a third type, zinc cement, magnesia-zinc cement and magnesia cement (Sorel cement) are known which utilize the reaction of alkaline earth metal oxides with their oxy salts. Of these, magnesia-zinc-phosphate cement has been demonstrated as a dental material with rapid hardening and large adhesiveness, but its unit cost is high and it is suitable for general use because of its instantaneous hardening property. It has the drawback of not being available. Also,
It has long been known that magnesia cement has strong adhesiveness with inorganic materials and wood, but since it has hygroscopicity, it has the drawback of dew condensation due to the leaching of oxyacid salts and the erosion action of metallic materials. However, it is not generally used and is only partially used as a binder for abrasives.
【０００５】以上の通り、従来の接着性無機質材にはい
ずれも実用上の問題があり、より汎用性に優れ、軽量
で、不燃耐風化性の良好な、低コストの接着性無機質材
は実現されていなかった。この発明は以上の通りの事情
に鑑みてなされたものであり、従来の接着性無機質材の
欠点を解消し、特に、マグネシアセメント系接着材に注
目することにより、その特性である接着力と曲げ強度を
増大させ、無機質接着材として優れた安定性を有する、
新しいマグネシア−ゼオライト系の接着性無機質材を提
供することを目的としている。As described above, all of the conventional adhesive inorganic materials have problems in practical use, and a low cost adhesive inorganic material that is more versatile, lightweight, and has good nonflammability and weather resistance is realized. Was not done. This invention has been made in view of the circumstances as described above, eliminates the disadvantages of conventional adhesive inorganic materials, and in particular, by focusing on the magnesia cement adhesive, its adhesive strength and bending Increases strength and has excellent stability as an inorganic adhesive,
It is intended to provide a new magnesia-zeolite adhesive inorganic material.
【０００６】[0006]
【課題を解決するための手段】この発明は、上記の課題
を解決するものとして、酸化マグネシウム・マグネシウ
ムオキシ塩セメントとゼオライトまたはゼオライト岩石
からなる微粉体を含有し、必要に応じて無機または有機
の繊維を配合してなることを特徴とする不燃耐風化性の
接着性無機質材を提供する。Means for Solving the Problems The present invention, as a solution to the above-mentioned problems, contains a fine powder of magnesium oxide / magnesium oxysalt cement and zeolite or zeolite rock, and if necessary an inorganic or organic Provided is a non-combustible, weathering-resistant adhesive inorganic material characterized by containing fibers.
【０００７】[0007]
【作用】すなわち、この発明の接着性無機質材は、マグ
ネシウムオキシ塩セメントの欠点とされる吸湿性を完全
に封じ込めるため、ゼオライト〔（Ｃａ：Ｎａ2 ：
Ｋ2）、（Ａｌ2 Ｓｉ7 Ｏ18）〕の特徴である吸着性、
イオン交換機能に着目し、この作用と複合することによ
り優れた特性を実現する。In other words, the adhesive inorganic material of the present invention completely encapsulates the hygroscopicity, which is a drawback of magnesium oxysalt cement, so that the zeolite [(Ca: Na 2 :
K 2), adsorptive is characteristic of (Al 2 Si 7 O 18)],
Focusing on the ion exchange function and combining it with this action will achieve excellent characteristics.
【０００８】このゼオライトもしくはこれを主成分とす
るゼオライト岩は、通常、６〜７分子の結晶水を含み、
３００℃以下では、結晶格子が破壊されずに脱水、吸収
する。また、Ｓｉ4+の欠陥によるイオン交換性があるの
で、マグネシウムオキシ塩の吸湿性を封止し、さらに金
属類の侵食を防止することができる。そしてこの発明の
接着性無機質材を構成するマグネシウムオキシ塩セメン
トは、酸化マグネシウムとしての活性マグネシアを含有
するが、この活性マグネシアは、反応性が大きく、生成
した水酸化マグネシウムの結晶構造とマグネシウムオキ
シ塩との組織により、その表面が他材料との接着力に大
きく影響する。この影響は、活性マグネシアの原料であ
るマグネシウム塩の種類により異なり、炭酸マグネシウ
ムの低温熱分解によって生成した酸化マグネシウム（Ｍ
ｇＯ）の結晶格子の大きさをコントロールすることが、
最も大きな条件となるので、その結晶格子の大きさを５
００オングストローム以下、より好ましくは２００〜５
００オングストロームとすることが好ましい。この条件
とすることで、オリジンとなるマグネシウム塩、具体的
にはたとえば炭酸塩のスケルトンの中に層状構造を生成
し、これが優れた効果を実現することになる。The zeolite or the zeolite rock containing the zeolite as a main component usually contains 6 to 7 molecules of crystal water,
At a temperature of 300 ° C or lower, the crystal lattice is not destroyed and dehydrated and absorbed. Further, since it has an ion-exchange property due to defects of Si 4+ , it can seal the hygroscopic property of the magnesium oxysalt and further prevent corrosion of metals. And, the magnesium oxysalt cement constituting the adhesive inorganic material of the present invention contains active magnesia as magnesium oxide, but this active magnesia is highly reactive, and the crystal structure of magnesium hydroxide and magnesium oxysalt produced. Due to the structure of and, the surface greatly affects the adhesive force with other materials. This effect differs depending on the type of magnesium salt that is a raw material of active magnesia, and magnesium oxide (M
Controlling the size of the crystal lattice of gO)
The largest condition is that the size of the crystal lattice should be 5
00 angstroms or less, more preferably 200 to 5
It is preferably 00 angstrom. Under these conditions, a layered structure is generated in a magnesium salt serving as an origin, specifically, for example, a carbonate skeleton, and this achieves an excellent effect.
【０００９】さらに詳しくは、この活性マグネシアは、
４０μｍ以下の粉体であって、２０〜５０ｍ2 ／ｇの比
表面積を有し、含有させるマグネシウム塩類の比率が酸
化物に対して５：１〜１０：１であることが好ましい。
そして、この活性マグネシアは、リグニン酸塩、並びに
高分子エマルジョンを４％以下で添加配合することがで
き、２０〜８０％の割合で接着材に配合することが好適
でもある。More specifically, this active magnesia is
It is preferable that the powder is 40 μm or less, has a specific surface area of 20 to 50 m 2 / g, and the ratio of magnesium salts to be contained is 5: 1 to 10: 1 with respect to the oxide.
Then, this active magnesia can be added and blended with a lignate salt and a polymer emulsion in an amount of 4% or less, and it is also preferable that the active magnesia be blended in an adhesive material in a proportion of 20 to 80%.
【００１０】なお、ゼオライトについては、人工または
天然のゼオライト岩を１００μｍ以下に粉砕した、比表
面積が５〜３０ｍ2 ／ｇの粉末として、１０〜５０％以
下の割合で接着材に配合することが好ましい。またこの
発明では、接着性無機質材のもう一つの具備すべき特徴
である可塑性の増大が作業性に関与し、接着硬化体の靱
性（タフネス）も求められることから、マグネシアセメ
ントと親和性が良好な無機または有機の繊維、たとえば
炭素繊維や、セルロース系繊維、具体的にはパルプ、木
綿、木質類等を不燃性を失わない範囲の添加量である４
％以下の割合で配合することが有効でもある。Regarding zeolite, artificial or natural zeolite rock is pulverized to 100 μm or less and powder having a specific surface area of 5 to 30 m 2 / g may be added to the adhesive at a ratio of 10 to 50%. preferable. Further, in the present invention, since the increase in plasticity, which is another characteristic of the adhesive inorganic material, is involved in workability and the toughness of the cured adhesive is required, the affinity with magnesia cement is good. Inorganic or organic fibers such as carbon fibers and cellulosic fibers, specifically pulp, cotton, woods, etc., are added in an amount that does not lose incombustibility 4
It is also effective to blend in a proportion of not more than%.
【００１１】この場合には、炭素繊維としては、グラフ
ァイト化されたもので、アスペクト比が１０以上である
ものが、セルロース系繊維としては、長さが０．５〜３
０ｍｍに切断されたものが好適に使用される。以下実施
例を示し、さらに詳しくこの発明の無機質接着材につい
て説明する。In this case, the carbon fiber is a graphitized carbon fiber having an aspect ratio of 10 or more, while the cellulosic fiber has a length of 0.5 to 3.
Those cut to 0 mm are preferably used. Examples will be shown below to describe the inorganic adhesive material of the present invention in more detail.
【００１２】[0012]
【実施例】粉体の配合 まず活性マグネシアは、４０μｍ以下の粉体で、比表面
積ブレーン値が２５ｍ 2 ／ｇのものを用いた。ゼオライ
ト岩石（大谷石）は、１００μｍ未満の粉砕物で、ブレ
ーン値１０ｍ2 ／ｇのものを使用し、また、炭素繊維と
して、径が８μｍ、長さが５ｍｍを配合した。そしてこ
れらを表１の通りの配合比で配合し、活性マグネシア−
大谷石粉−炭素繊維配合物を調製した。【Example】Powder mix First, activated magnesia is a powder of 40 μm or less, and has a specific surface.
Product brane value is 25m 2/ G was used. Zeorai
Rock (Otani stone) is a crushed material of less than 100 μm,
Value 10m2/ G of carbon fiber and carbon fiber
Then, the diameter was 8 μm and the length was 5 mm. And this
These were compounded at the compounding ratio shown in Table 1, and the active magnesia-
An Otani stone powder-carbon fiber formulation was prepared.
【００１３】[0013]
【表１】 [Table 1]
【００１４】接着材の調製と試験体の作成 つぎに、活性マグネシウムに対し、塩化マグネシウム２
５％の溶液にアクリルエマルジョン３％を混合し、前
記、活性マグネシア−大谷石粉−黒鉛繊維配合物に対し
て重量比で７０％添加し、１０分間攪拌混合機で混練し
た後、２０ｍｍ×２０ｍｍ×８０ｍｍの金形に充填し、
２０℃で２４間養生した。この養生の後、金形をはず
し、３日間空気中で乾燥して試験体を作成した。この試
験体の物性を測定した結果を表２に示す。 Preparation of Adhesive and Preparation of Specimen Next, magnesium chloride 2
A 5% solution was mixed with 3% of an acrylic emulsion, 70% by weight of the active magnesia-Otani stone powder-graphite fiber mixture was added, and the mixture was kneaded with a stirring mixer for 10 minutes and then 20 mm x 20 mm x Fill 80mm mold,
It was cured for 24 hours at 20 ° C. After this curing, the mold was removed and dried in air for 3 days to prepare a test body. The results of measuring the physical properties of this test body are shown in Table 2.
【００１５】[0015]
【表２】 [Table 2]
【００１６】得られた試験体は、嵩比重が小さく、軽量
で、物性測定の時に０．１％以下の収縮で、亀裂は全く
認められなかった。優れた接着効果が得られ、従来材の
ような欠点は認められなかった。The obtained test body had a small bulk specific gravity, was light in weight, shrank by 0.1% or less at the time of measuring physical properties, and had no cracks. An excellent adhesive effect was obtained, and no defects such as those of conventional materials were recognized.
【００１７】[0017]
【発明の効果】以上詳しく説明した通り、この発明によ
り、嵩比重が小さく、乾燥・吸水の変化に対しても寸法
安定性に優れ、強度向上と耐候性を示し、軽質で不燃性
の良好な低コスト接着性無機質材が提供される。As described in detail above, according to the present invention, the bulk specific gravity is small, the dimensional stability is excellent even against changes in drying and water absorption, the strength and weather resistance are improved, and the material is light and has good nonflammability. A low cost adhesive inorganic material is provided.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｃ０４Ｂ 16/02 Ａ Ｃ０９Ｊ 1/00 ＪＡＡ //(Ｃ０４Ｂ 28/32 14:04 Ｚ 14:38 Ａ 16:02） Ａ ─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 6 Identification code Internal reference number FI Technical display location C04B 16/02 A C09J 1/00 JAA // (C04B 28/32 14:04 Z 14:38 A 16:02) A
Claims (4)
塩セメントとゼオライトまたはゼオライト岩石からなる
微粉体を含有し、必要に応じて無機または有機の繊維を
配合してなることを特徴とする不燃耐風化性の接着性無
機質材。1. A non-combustible, weathering-resistant adhesive characterized by containing magnesium oxide / magnesium oxysalt cement and fine powder of zeolite or zeolite rock, and if necessary inorganic or organic fibers are blended. Inorganic material.
ングストローム以下の活性マグネシアで、この活性マグ
ネシアが４０μｍ以下の粉体であって、２０〜５０ｍ2
／ｇの比表面積を有し、含有されるマグネシウム塩類の
比率が酸化物に対してモル比５：１〜１０：１であり、
必要に応じ、これにニグニン酸塩、並びに高分子エマル
ジョンを４％以下添加できる活性マグネシアを２０％〜
８０％含有してなる請求項１の無機質材。2. A magnesium oxide crystal having an active magnesia having a crystal lattice of 500 angstroms or less, and the active magnesia having a particle size of 40 μm or less, which is 20 to 50 m 2.
Has a specific surface area of / g, and the ratio of magnesium salts contained is 5: 1 to 10: 1 with respect to the oxide,
20% to 20% of active magnesia to which 4% or less of nignate and polymer emulsion can be added, if necessary.
The inorganic material according to claim 1, which contains 80%.
１００μｍ以下に粉砕した、粉体比表面積が５〜３０ｍ
2 ／ｇの粉末を１０％〜５０％以下含有してなる請求項
１または２の無機質材。3. Powder specific surface area of 5 to 30 m obtained by pulverizing zeolite or natural zeolite rock to 100 μm or less.
The inorganic material according to claim 1 or 2, which contains 10% to 50% of 2 / g of powder.
て、アスペクト比が、１０以上であるもの、および／ま
たは天然繊維を使用したセルロース繊維であって、その
長さが０．５ｍｍ〜３０ｍｍに切断されたものを４％以
下で配合してなる請求項１、２または３の無機質材。4. Graphitized graphite fibers having an aspect ratio of 10 or more, and / or cellulose fibers using natural fibers, the length of which is cut to 0.5 mm to 30 mm. The inorganic material according to claim 1, 2 or 3, which is obtained by mixing 4% or less.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13370693A JP3347809B2 (en) | 1993-06-03 | 1993-06-03 | Adhesive inorganic material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13370693A JP3347809B2 (en) | 1993-06-03 | 1993-06-03 | Adhesive inorganic material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0769706A true JPH0769706A (en) | 1995-03-14 |
| JP3347809B2 JP3347809B2 (en) | 2002-11-20 |
Family
ID=15110989
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13370693A Expired - Fee Related JP3347809B2 (en) | 1993-06-03 | 1993-06-03 | Adhesive inorganic material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3347809B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001055049A1 (en) * | 2000-01-27 | 2001-08-02 | Tececo Pty Ltd | Reactive magnesium oxide cements |
| WO2007069351A1 (en) * | 2005-12-14 | 2007-06-21 | Azmec Co., Ltd. | Adsorbent-containing cold-setting composition, adsorbent-containing molded object, and building material and impregnant for paving both containing adsorbent |
| JP2019503958A (en) * | 2015-12-01 | 2019-02-14 | ケルネオス | Fireproof magnesia cement |
-
1993
- 1993-06-03 JP JP13370693A patent/JP3347809B2/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001055049A1 (en) * | 2000-01-27 | 2001-08-02 | Tececo Pty Ltd | Reactive magnesium oxide cements |
| JP2003520749A (en) * | 2000-01-27 | 2003-07-08 | テセコ プロプライアタリー リミティド | Reactive magnesium oxide cement |
| US7347896B2 (en) | 2000-01-27 | 2008-03-25 | Tececo Pty Ltd | Reactive magnesium oxide cements |
| WO2007069351A1 (en) * | 2005-12-14 | 2007-06-21 | Azmec Co., Ltd. | Adsorbent-containing cold-setting composition, adsorbent-containing molded object, and building material and impregnant for paving both containing adsorbent |
| JPWO2007069351A1 (en) * | 2005-12-14 | 2009-05-21 | 株式会社Ａｚｍｅｃ | Adsorbent-containing room temperature solidifying composition, adsorbent-containing molded product, adsorbent-containing building material and pavement injection material |
| JP2019503958A (en) * | 2015-12-01 | 2019-02-14 | ケルネオス | Fireproof magnesia cement |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3347809B2 (en) | 2002-11-20 |
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