CN106498799A - A kind of desiccant wheel manufacture environment-friendly paper pulp fiber composite cardboard - Google Patents

A kind of desiccant wheel manufacture environment-friendly paper pulp fiber composite cardboard Download PDF

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Publication number
CN106498799A
CN106498799A CN201610961278.4A CN201610961278A CN106498799A CN 106498799 A CN106498799 A CN 106498799A CN 201610961278 A CN201610961278 A CN 201610961278A CN 106498799 A CN106498799 A CN 106498799A
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CN
China
Prior art keywords
desiccant wheel
fiber composite
paper pulp
friendly paper
composite cardboard
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Application number
CN201610961278.4A
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Chinese (zh)
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CN106498799B (en
Inventor
贾东新
焦德华
何玲丽
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PWS environmental technology Wuxi Co.,Ltd.
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WUXI PUAIDE ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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Priority to CN201610961278.4A priority Critical patent/CN106498799B/en
Publication of CN106498799A publication Critical patent/CN106498799A/en
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Publication of CN106498799B publication Critical patent/CN106498799B/en
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
    • D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
    • D21H15/10—Composite fibres
    • D21H15/12—Composite fibres partly organic, partly inorganic
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675—Oxides, hydroxides or carbonates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
    • D21H17/74—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/34—Ignifugeants

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Paper (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)

Abstract

The invention discloses a kind of manufacture of desiccant wheel uses the environment-friendly paper pulp fiber composite cardboard, the mass fraction of the combination board each component to be：Without asbestos mineral fiber 30%～40%, carbon fibre 8%～20%, polyster fibre 8%～20%, wood pulp 5%～15%, straw pulp 5%～15%, bamboo pulp 5%～15%, bromide fire retardant 8%～15%, sizing agent 5%～10%, auxiliary agent 5%～10%.Combination board of the present invention while intensity, toughness is improved, increases fire retardant, extends desiccant wheel service life all using environment-friendly type raw material.

Description

A kind of desiccant wheel manufacture environment-friendly paper pulp fiber composite cardboard
Technical field
The present invention relates to desiccant wheel manufacture field, more particularly to a kind of manufacture of desiccant wheel is multiple with environment-friendly paper pulp fibres Combined paper plate.
Background technology
Rotary wheel type Dehumidifier is usually used in the occasions such as hypogee, pharmacy, food, operating room, and which combines fortune with air conditioning system OK, environment is reached required humiture.As the core component of rotary wheel type Dehumidifier, the raw material of desiccant wheel, i.e. paper The quality of plate directly determines its effect on moisture extraction.But, often there is low intensity, poor toughness in existing cardboard.
Meanwhile, the fire retardant used in present desiccant wheel nearly 80% is halogen containing flame-retardant, wherein with PBDEs and Polybrominated biphenyl material is representative.Halogenated flame retardant good flame retardation effect, addition are few, and the performance impact to material is less.But send out Smoke is big, and the hydrogen halide for discharging has corrosivity, and can produce many bromo benzo evil Ying Heduo of poisonous carcinogen Bromo dibenzofurans, affect human homergy.European Union is starting strict restriction PBDEs PBDE, PBBs The use of PBB.
Bromide fire retardant is the new product of Recent study exploitation, and its flame retarding efficiency is high, consumption is few, the performance shadow to material Sound is little, and moderate.As TDE, 345 DEG C of just fusing point, heat stability are high, light resistance is high and is difficult dialysis, and which hinders The plastics of combustion even can reclaim use, be economic and environment-friendly type fire retardant.But, bromide fire retardant in desiccant wheel also not by Use.
Content of the invention
Goal of the invention：It is an object of the invention to provide a kind of desiccant wheel manufacture environment-friendly paper pulp fiber composite cardboard, The combination board increases fire retardant all using environment-friendly type raw material while intensity, toughness is improved, and extending desiccant wheel makes Use the life-span.
Technical scheme：A kind of desiccant wheel manufacture environment-friendly paper pulp fiber composite cardboard of the present invention, its feature It is：The mass fraction of the combination board each component is：Without asbestos mineral fiber 30%～40%, carbon fibre 8%～20%, Polyster fibre 8%～20%, wood pulp 5%～15%, straw pulp 5%～15%, bamboo pulp 5%～15%, bromide fire retardant 8%～ 15%th, sizing agent 5%～10%, auxiliary agent 5%～10%.
Described including without asbestos mineral fiber is a kind of or many in silicon dioxide, aluminium oxide, calcium oxide, boron oxide Kind.Wherein, described without the mixture that asbestos mineral fiber is silicon dioxide, aluminium oxide, calcium oxide, boron oxide, wherein dioxy SiClx, aluminium oxide, calcium oxide, the mass ratio of boron oxide are 1.2～1.5：1.3～1.5:1.2:1.
Described bromide fire retardant include the one kind in TDE, brominated epoxy resin, brominated Polystyrene or Person is multiple.Wherein, described bromide fire retardant be TDE, brominated epoxy resin, the mixture of brominated Polystyrene, Wherein TDE, brominated epoxy resin, the mass ratio of brominated Polystyrene are 1.2～1.3：1.3～1.5:1.
Described auxiliary agent include aluminium hydroxide, sodium hydroxide, calcium sulfate one or more.Wherein, described auxiliary agent For aluminium hydroxide, sodium hydroxide, calcium sulfate mixture, wherein aluminium hydroxide, sodium hydroxide, calcium sulfate mass ratio be 1.2 ～1.5:1～1.5:1.
Beneficial effect：Compared with prior art, the present invention has following remarkable advantage：The present invention is all former using environment-friendly type Material, or can degrade or can be recycled, will not be a kind of environment-friendly type combination board to environment；And, should Combination board is made by the way of multiple fiber is mixed with multiple paper pulp, improves strength and toughness, and keeping, paper is original Processing characteristics while, meet high efficiency, the demand of big load operation, better than existing cardboard；Meanwhile, the combination board increases Plus fire retardant be environment-friendly type bromide fire retardant, when desiccant wheel operate, will not also damage when temperature is high, prolongation desiccant wheel Service life.
Specific embodiment
Embodiment 1：
The mass fraction of the combination board each component is：Without asbestos mineral fiber 40%, carbon fibre 10%, polyster fibre 10%th, wood pulp 5%, straw pulp 5%, bamboo pulp 10%, bromide fire retardant 10%, sizing agent 5%, auxiliary agent 5%；Without asbestos mineral fiber For silicon dioxide, the mixture of aluminium oxide, wherein silicon dioxide, the mass ratio of aluminium oxide are 1：1.1；Bromide fire retardant is ten bromines Diphenylethane, brominated epoxy resin, the mixture of brominated Polystyrene, wherein TDE, brominated epoxy resin, bromination The mass ratio of polystyrene is 1.2：1.3:1；Auxiliary agent is aluminium hydroxide, sodium hydroxide, the wherein mixture of calcium sulfate, hydroxide Aluminum, sodium hydroxide, the mass ratio of calcium sulfate are 1.2:1.5:1.
Embodiment 2：
The mass fraction of the combination board each component is：Without asbestos mineral fiber 35%, carbon fibre 15%, polyster fibre 8%th, wood pulp 7%, straw pulp 7%, bamboo pulp 8%, bromide fire retardant 6%, sizing agent 8%, auxiliary agent 6%；Without asbestos mineral fiber it is Silicon dioxide, aluminium oxide, calcium oxide, the mixture of boron oxide, the wherein quality of silicon dioxide, aluminium oxide, calcium oxide, boron oxide Than for 1.4：1.4:1.2:1；Bromide fire retardant be TDE, brominated epoxy resin, the mixture of brominated Polystyrene, Wherein TDE, brominated epoxy resin, the mass ratio of brominated Polystyrene are 1.3：1.4:1；Auxiliary agent be aluminium hydroxide, Sodium hydroxide, the mixture of calcium sulfate, wherein aluminium hydroxide, sodium hydroxide, the mass ratio of calcium sulfate are 1.2:1.3:1.
Embodiment 3：
The mass fraction of the combination board each component is：Without asbestos mineral fiber 30%, carbon fibre 10%, polyster fibre 10%th, wood pulp 5%, straw pulp 10%, bamboo pulp 8%, bromide fire retardant 12%, sizing agent 6%, auxiliary agent 9%；Without asbestos mineral fiber For aluminium oxide, calcium oxide, boron oxide mixture, wherein aluminium oxide, calcium oxide, boron oxide mass ratio be 1.4:1.2:1；Bromine Flame retardant is brominated epoxy resin, the mixture of brominated Polystyrene, the wherein matter of brominated epoxy resin, brominated Polystyrene Amount is than being 1.4:1；Auxiliary agent is aluminium hydroxide, sodium hydroxide, the mixture of calcium sulfate, wherein aluminium hydroxide, sodium hydroxide, sulphuric acid The mass ratio of calcium is 1.5:1.5:1.
Embodiment 4：
The mass fraction of the combination board each component is：Without asbestos mineral fiber 30%, carbon fibre 10%, polyster fibre 10%th, wood pulp 8%, straw pulp 8%, bamboo pulp 14%, bromide fire retardant 8%, sizing agent 6%, auxiliary agent 6%；Without asbestos mineral fiber For calcium oxide；Bromide fire retardant is TDE, the mixture of brominated epoxy resin, wherein TDE, bromination The mass ratio of epoxy resin is 1:1；Auxiliary agent is sodium hydroxide.
Embodiment 5：
The mass fraction of the combination board each component is：Without asbestos mineral fiber 35%, carbon fibre 10%, polyster fibre 8%th, wood pulp 7%, straw pulp 5%, bamboo pulp 5%, bromide fire retardant 10%, sizing agent 10%, auxiliary agent 10%；Without asbestos mineral fiber For silicon dioxide, aluminium oxide, boron oxide mixture, wherein silicon dioxide, aluminium oxide, boron oxide mass ratio be 1.3：1.5: 1；Bromide fire retardant is TDE, brominated epoxy resin, the mixture of brominated Polystyrene, wherein decabrominated dipheny second Alkane, brominated epoxy resin, the mass ratio of brominated Polystyrene are 1.3：1.3:1；Auxiliary agent is aluminium hydroxide.

Claims (7)

1. a kind of desiccant wheel is manufactured and uses environment-friendly paper pulp fiber composite cardboard, it is characterised in that：The combination board each component Mass fraction is：Without asbestos mineral fiber 30%～40%, carbon fibre 8%～20%, polyster fibre 8%～20%, wood pulp 5%～15%, straw pulp 5%～15%, bamboo pulp 5%～15%, bromide fire retardant 8%～15%, sizing agent 5%～10%, help Agent 5%～10%.
2. desiccant wheel according to claim 1 is manufactured and uses environment-friendly paper pulp fiber composite cardboard, it is characterised in that：Described Include in silicon dioxide, aluminium oxide, calcium oxide, boron oxide without asbestos mineral fiber one or more.
3. desiccant wheel according to claim 2 is manufactured and uses environment-friendly paper pulp fiber composite cardboard, it is characterised in that：Described Without asbestos mineral fiber be silicon dioxide, aluminium oxide, calcium oxide, the mixture of boron oxide when, wherein silicon dioxide, oxidation Aluminum, calcium oxide, the mass ratio of boron oxide are 1.2～1.5：1.3～1.5:1.2:1.
4. desiccant wheel according to claim 1 is manufactured and uses environment-friendly paper pulp fiber composite cardboard, it is characterised in that：Described Bromide fire retardant include in TDE, brominated epoxy resin, brominated Polystyrene one or more.
5. desiccant wheel according to claim 4 is manufactured and uses environment-friendly paper pulp fiber composite cardboard, it is characterised in that：Described Bromide fire retardant when being TDE, brominated epoxy resin, the mixture of brominated Polystyrene, wherein decabrominated dipheny second Alkane, brominated epoxy resin, the mass ratio of brominated Polystyrene are 1.2～1.3：1.3～1.5:1.
6. desiccant wheel according to claim 1 is manufactured and uses environment-friendly paper pulp fiber composite cardboard, it is characterised in that：Described Auxiliary agent include aluminium hydroxide, sodium hydroxide, calcium sulfate one or more.
7. desiccant wheel according to claim 6 is manufactured and uses environment-friendly paper pulp fiber composite cardboard, it is characterised in that：Described Auxiliary agent when being aluminium hydroxide, sodium hydroxide, the mixture of calcium sulfate, the wherein quality of aluminium hydroxide, sodium hydroxide, calcium sulfate Than for 1.2～1.5:1～1.5:1.
CN201610961278.4A 2016-11-04 2016-11-04 A kind of desiccant wheel manufacture environment-friendly paper pulp fiber composite cardboard Active CN106498799B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109649828A (en) * 2018-12-04 2019-04-19 常州市正文印刷有限公司 A kind of manufacture craft of high-strength corrugated case
CN114525697A (en) * 2022-02-25 2022-05-24 昆山傲毅包装制品有限公司 Environment-friendly paper pulp, environment-friendly paper pulp manufacturing process and environment-friendly paper
CN114875706A (en) * 2022-04-02 2022-08-09 浙江凯恩新材料有限公司 Raw paper of high-performance all-in-one machine thermosensitive version paper, production process and thermosensitive version paper prepared by production process

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Publication number Priority date Publication date Assignee Title
CN1287955A (en) * 2000-11-03 2001-03-21 尚德库 Basalt-pearlspar composite fiber paper
JP2001226894A (en) * 2000-02-10 2001-08-21 Daifuku Seishi Kk Flame retardant shoji paper and method for producing the same
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CN104499353A (en) * 2014-12-31 2015-04-08 苏州太阳雪新能源科技有限公司 Ceramic fiber paper for turning wheel of dehumidifier

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Publication number Priority date Publication date Assignee Title
JP2001226894A (en) * 2000-02-10 2001-08-21 Daifuku Seishi Kk Flame retardant shoji paper and method for producing the same
CN1287955A (en) * 2000-11-03 2001-03-21 尚德库 Basalt-pearlspar composite fiber paper
CN104195870A (en) * 2014-08-28 2014-12-10 无锡普爱德环保科技有限公司 Ceramic fiber paper
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109649828A (en) * 2018-12-04 2019-04-19 常州市正文印刷有限公司 A kind of manufacture craft of high-strength corrugated case
CN114525697A (en) * 2022-02-25 2022-05-24 昆山傲毅包装制品有限公司 Environment-friendly paper pulp, environment-friendly paper pulp manufacturing process and environment-friendly paper
CN114875706A (en) * 2022-04-02 2022-08-09 浙江凯恩新材料有限公司 Raw paper of high-performance all-in-one machine thermosensitive version paper, production process and thermosensitive version paper prepared by production process

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Address after: 214192 No. three, No. 99, Furong Road, Xishan Economic Development Zone, Jiangsu, Wuxi

Patentee after: PWS environmental technology Wuxi Co.,Ltd.

Address before: 214192 No. three, No. 99, Furong Road, Xishan Economic Development Zone, Jiangsu, Wuxi

Patentee before: WUXI PUAIDE ENVIRONMENTAL PROTECTION SCIENCE & TECHNOLOGY Co.,Ltd.

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