CN106498799B - A kind of desiccant wheel manufacture environment-friendly paper pulp fiber composite cardboard - Google Patents
A kind of desiccant wheel manufacture environment-friendly paper pulp fiber composite cardboard Download PDFInfo
- Publication number
- CN106498799B CN106498799B CN201610961278.4A CN201610961278A CN106498799B CN 106498799 B CN106498799 B CN 106498799B CN 201610961278 A CN201610961278 A CN 201610961278A CN 106498799 B CN106498799 B CN 106498799B
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- CN
- China
- Prior art keywords
- desiccant wheel
- oxide
- fire retardant
- paper pulp
- fiber composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
- D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
- D21H15/10—Composite fibres
- D21H15/12—Composite fibres partly organic, partly inorganic
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
- D21H17/74—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/34—Ignifugeants
Abstract
The invention discloses a kind of desiccant wheel manufacture environment-friendly paper pulp fiber composite cardboard, the mass fraction of the combination board each component is:Without asbestos mineral fiber 30%~40%, carbon fibre 8%~20%, polyester fiber 8%~20%, wood pulp 5%~15%, straw pulp 5%~15%, bamboo pulp 5%~15%, bromide fire retardant 8%~15%, sizing agent 5%~10%, auxiliary agent 5%~10%.Combination board of the present invention is all using environment-friendly type raw material, while improving intensity, toughness, increases fire retardant, extends desiccant wheel service life.
Description
Technical field
The present invention relates to desiccant wheel manufacturing field more particularly to a kind of manufacture of desiccant wheel are multiple with environment-friendly paper pulp fibres
Combined paper plate.
Background technology
Rotary wheel type Dehumidifier is usually used in the occasions such as hypogee, pharmacy, food, operating room, and fortune is combined with air-conditioning system
Environment is reached required humiture by row.As the core component of rotary wheel type Dehumidifier, the raw material of desiccant wheel, i.e. paper
The quality of plate directly determines its effect on moisture extraction.But existing cardboard often has that intensity is low, poor toughness.
Meanwhile the fire retardant nearly 80% used in present desiccant wheel is halogen containing flame-retardant, wherein with polybrominated diphenyl ethers and
Polybrominated biphenyls substance is representative.Halogenated flame retardant good flame retardation effect, additive amount is few, is influenced on the performance of material smaller.But it sends out
Smoke is big, and the hydrogen halide released has corrosivity, and will produce the more bromo benzos of toxic carcinogen and dislike Ying Heduo
Bromo dibenzofurans, influences human homergy.European Union is starting stringent limitation polybrominated diphenyl ethers PBDE, polybrominated biphenyls
The use of PBB.
Bromide fire retardant is the new product of Recent study exploitation, and flame retarding efficiency is high, dosage is few, to the performance shadow of material
Sound is small, and moderate.Such as decabromodiphenylethane, 345 DEG C of just fusing point, thermal stability is high, and light resistance is high and is not easy dialysis, hinders
The plastics of combustion even can recycle use, be economic and environment-friendly type fire retardant.But bromide fire retardant in desiccant wheel also not by
It uses.
Invention content
Goal of the invention:The object of the present invention is to provide a kind of desiccant wheel manufacture environment-friendly paper pulp fiber composite cardboard,
The combination board is all using environment-friendly type raw material, while improving intensity, toughness, increases fire retardant, and extending desiccant wheel makes
Use the service life.
Technical solution:A kind of desiccant wheel manufacture environment-friendly paper pulp fiber composite cardboard of the present invention, feature
It is:The mass fraction of the combination board each component is:Without asbestos mineral fiber 30%~40%, carbon fibre 8%~20%,
Polyester fiber 8%~20%, wood pulp 5%~15%, straw pulp 5%~15%, bamboo pulp 5%~15%, bromide fire retardant 8%~
15%, sizing agent 5%~10%, auxiliary agent 5%~10%.
Described includes a kind of or more in silica, aluminium oxide, calcium oxide, boron oxide without asbestos mineral fiber
Kind.Wherein, the no asbestos mineral fiber is the mixture of silica, aluminium oxide, calcium oxide, boron oxide, wherein dioxy
SiClx, aluminium oxide, calcium oxide, boron oxide mass ratio be 1.2~1.5:1.3~1.5:1.2:1.
The bromide fire retardant include one kind in decabromodiphenylethane, brominated epoxy resin, brominated Polystyrene or
Person is a variety of.Wherein, the bromide fire retardant be decabromodiphenylethane, brominated epoxy resin, brominated Polystyrene mixture,
Wherein decabromodiphenylethane, brominated epoxy resin, brominated Polystyrene mass ratio be 1.2~1.3:1.3~1.5:1.
The auxiliary agent includes the one or more of aluminium hydroxide, sodium hydroxide, calcium sulfate.Wherein, the auxiliary agent
For aluminium hydroxide, the mixture of sodium hydroxide, calcium sulfate, wherein aluminium hydroxide, sodium hydroxide, calcium sulfate mass ratio be 1.2
~1.5:1~1.5:1.
Advantageous effect:Compared with prior art, the present invention has following remarkable advantage:The present invention is all using environment-friendly type original
Material, or can degrade or can be recycled, it not can cause environmental pollution, be a kind of environment-friendly type combination board;Moreover, should
Combination board is made in such a way that multiple fiber is mixed with a variety of paper pulp, improves strength and toughness, is keeping paper original
Processing performance while, meet the needs of high efficiency, big load operation, be better than existing cardboard;Meanwhile the combination board increases
The fire retardant added, which is environment-friendly type bromide fire retardant, will not damage when desiccant wheel operates when temperature is high, extend desiccant wheel
Service life.
Specific implementation mode
Embodiment 1:
The mass fraction of the combination board each component is:Without asbestos mineral fiber 40%, carbon fibre 10%, polyester fiber
10%, wood pulp 5%, straw pulp 5%, bamboo pulp 10%, bromide fire retardant 10%, sizing agent 5%, auxiliary agent 5%;Without asbestos mineral fiber
For silica, the mixture of aluminium oxide, wherein silica, aluminium oxide mass ratio be 1:1.1;Bromide fire retardant is ten bromines
The mixture of diphenylethane, brominated epoxy resin, brominated Polystyrene, wherein decabromodiphenylethane, brominated epoxy resin, bromination
The mass ratio of polystyrene is 1.2:1.3:1;Auxiliary agent is the mixture of aluminium hydroxide, sodium hydroxide, calcium sulfate, wherein hydroxide
Aluminium, sodium hydroxide, calcium sulfate mass ratio be 1.2:1.5:1.
Embodiment 2:
The mass fraction of the combination board each component is:Without asbestos mineral fiber 35%, carbon fibre 15%, polyester fiber
8%, wood pulp 7%, straw pulp 7%, bamboo pulp 8%, bromide fire retardant 6%, sizing agent 8%, auxiliary agent 6%;No asbestos mineral fiber is
The quality of the mixture of silica, aluminium oxide, calcium oxide, boron oxide, wherein silica, aluminium oxide, calcium oxide, boron oxide
Than being 1.4:1.4:1.2:1;Bromide fire retardant be decabromodiphenylethane, brominated epoxy resin, brominated Polystyrene mixture,
Wherein decabromodiphenylethane, brominated epoxy resin, brominated Polystyrene mass ratio be 1.3:1.4:1;Auxiliary agent be aluminium hydroxide,
The mixture of sodium hydroxide, calcium sulfate, wherein aluminium hydroxide, sodium hydroxide, calcium sulfate mass ratio be 1.2:1.3:1.
Embodiment 3:
The mass fraction of the combination board each component is:Without asbestos mineral fiber 30%, carbon fibre 10%, polyester fiber
10%, wood pulp 5%, straw pulp 10%, bamboo pulp 8%, bromide fire retardant 12%, sizing agent 6%, auxiliary agent 9%;Without asbestos mineral fiber
For aluminium oxide, the mixture of calcium oxide, boron oxide, wherein aluminium oxide, calcium oxide, boron oxide mass ratio be 1.4:1.2:1;Bromine
Flame retardant is the mixture of brominated epoxy resin, brominated Polystyrene, the wherein matter of brominated epoxy resin, brominated Polystyrene
Amount is than being 1.4:1;Auxiliary agent is the mixture of aluminium hydroxide, sodium hydroxide, calcium sulfate, wherein aluminium hydroxide, sodium hydroxide, sulfuric acid
The mass ratio of calcium is 1.5:1.5:1.
Embodiment 4:
The mass fraction of the combination board each component is:Without asbestos mineral fiber 30%, carbon fibre 10%, polyester fiber
10%, wood pulp 8%, straw pulp 8%, bamboo pulp 14%, bromide fire retardant 8%, sizing agent 6%, auxiliary agent 6%;Without asbestos mineral fiber
For calcium oxide;Bromide fire retardant be decabromodiphenylethane, brominated epoxy resin mixture, wherein decabromodiphenylethane, bromination
The mass ratio of epoxy resin is 1:1;Auxiliary agent is sodium hydroxide.
Embodiment 5:
The mass fraction of the combination board each component is:Without asbestos mineral fiber 35%, carbon fibre 10%, polyester fiber
8%, wood pulp 7%, straw pulp 5%, bamboo pulp 5%, bromide fire retardant 10%, sizing agent 10%, auxiliary agent 10%;Without asbestos mineral fiber
For silica, the mixture of aluminium oxide, boron oxide, wherein silica, aluminium oxide, boron oxide mass ratio be 1.3:1.5:
1;Bromide fire retardant be decabromodiphenylethane, brominated epoxy resin, brominated Polystyrene mixture, wherein decabrominated dipheny second
Alkane, brominated epoxy resin, brominated Polystyrene mass ratio be 1.3:1.3:1;Auxiliary agent is aluminium hydroxide.
Claims (4)
1. a kind of desiccant wheel manufacture environment-friendly paper pulp fiber composite cardboard, it is characterised in that:The combination board each component
Mass fraction is:Without asbestos mineral fiber 30%~40%, carbon fibre 8%~20%, polyester fiber 8%~20%, wood pulp
5%~15%, straw pulp 5%~15%, bamboo pulp 5%~15%, bromide fire retardant 8%~15%, sizing agent 5%~10%, help
Agent 5%~10%;It is described without asbestos mineral fiber include one kind in silica, aluminium oxide, calcium oxide, boron oxide or
It is a variety of;The bromide fire retardant includes a kind of or more in decabromodiphenylethane, brominated epoxy resin, brominated Polystyrene
Kind;The auxiliary agent includes the one or more of aluminium hydroxide, sodium hydroxide, calcium sulfate.
2. desiccant wheel manufacture environment-friendly paper pulp fiber composite cardboard according to claim 1, it is characterised in that:It is described
Without asbestos mineral fiber be silica, aluminium oxide, calcium oxide, boron oxide mixture, wherein silica, aluminium oxide,
Calcium oxide, boron oxide mass ratio be 1.2~1.5:1.3~1.5:1.2:1.
3. desiccant wheel manufacture environment-friendly paper pulp fiber composite cardboard according to claim 1, it is characterised in that:It is described
Bromide fire retardant be decabromodiphenylethane, brominated epoxy resin, brominated Polystyrene mixture, wherein decabrominated dipheny second
Alkane, brominated epoxy resin, brominated Polystyrene mass ratio be 1.2~1.3:1.3~1.5:1.
4. desiccant wheel manufacture environment-friendly paper pulp fiber composite cardboard according to claim 1, it is characterised in that:It is described
Auxiliary agent be aluminium hydroxide, sodium hydroxide, calcium sulfate mixture, the wherein mass ratio of aluminium hydroxide, sodium hydroxide, calcium sulfate
It is 1.2~1.5:1~1.5:1.
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CN201610961278.4A CN106498799B (en) | 2016-11-04 | 2016-11-04 | A kind of desiccant wheel manufacture environment-friendly paper pulp fiber composite cardboard |
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CN106498799B true CN106498799B (en) | 2018-09-14 |
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CN109649828A (en) * | 2018-12-04 | 2019-04-19 | 常州市正文印刷有限公司 | A kind of manufacture craft of high-strength corrugated case |
CN114525697A (en) * | 2022-02-25 | 2022-05-24 | 昆山傲毅包装制品有限公司 | Environment-friendly paper pulp, environment-friendly paper pulp manufacturing process and environment-friendly paper |
CN114875706B (en) * | 2022-04-02 | 2023-02-10 | 浙江凯恩新材料有限公司 | Raw paper of high-performance all-in-one machine thermosensitive version paper, production process and thermosensitive version paper prepared by production process |
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JP3445951B2 (en) * | 2000-02-10 | 2003-09-16 | 大福製紙株式会社 | Flameproof shoji paper and method for producing the same |
CN1177733C (en) * | 2000-11-03 | 2004-12-01 | 尚德库 | Basalt-pearlspar composite fiber paper |
CN104195870A (en) * | 2014-08-28 | 2014-12-10 | 无锡普爱德环保科技有限公司 | Ceramic fiber paper |
CN104499353A (en) * | 2014-12-31 | 2015-04-08 | 苏州太阳雪新能源科技有限公司 | Ceramic fiber paper for turning wheel of dehumidifier |
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Address after: 214192 No. three, No. 99, Furong Road, Xishan Economic Development Zone, Jiangsu, Wuxi Patentee after: PWS environmental technology Wuxi Co.,Ltd. Address before: 214192 No. three, No. 99, Furong Road, Xishan Economic Development Zone, Jiangsu, Wuxi Patentee before: WUXI PUAIDE ENVIRONMENTAL PROTECTION SCIENCE & TECHNOLOGY Co.,Ltd. |
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