CN107057207A - Fire-type organic foam insulation material - Google Patents
Fire-type organic foam insulation material Download PDFInfo
- Publication number
- CN107057207A CN107057207A CN201610984561.9A CN201610984561A CN107057207A CN 107057207 A CN107057207 A CN 107057207A CN 201610984561 A CN201610984561 A CN 201610984561A CN 107057207 A CN107057207 A CN 107057207A
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- China
- Prior art keywords
- fire
- organic foam
- insulation material
- type organic
- foam insulation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The present invention relates to a kind of fire-type organic foam insulation material, including organic foam, described organic foam is polystyrene or polyurethane or phenol formaldehyde foam, and described fire-type organic foam insulation material includes according to the raw material of percentage by weight：Organic foam material 10 ~ 25%, nano level flame retardant 25 ~ 40%, inherent fire-retardant fiber 40 ~ 55%.Environmentally friendly, water proof fire retardant performance is good and intensity is high.
Description
Technical field
The invention belongs to fire-fighting quipment field, and in particular to a kind of fire-type organic foam insulation material.
Background technology
The relative inadequacy of resources of China, but power consumption day is huge, and energy problem has become the principal element of restriction economic development,
Save the energy very urgent.Continuous attention with China to the saving energy and environmental protection, the insulation skill of building maintenance structure
Art is also increasingly being strengthened, and especially external walls heating insulation obtains significant progress, and as one important building energy conservation of China
Technology.The foam type organic insulation material of current outer wall heat insulating energy saving application includes polystyrene（EPS）, polyurethane（PU）, phenol
Aldehyde（PF）.The advantage of these materials is that heat-insulating property is superior, but its fire-protection rating is poor, only B2 or B1 grades, meets fire melting, combustion
Burn.As National Fire is incubated the execution of associated documents, the strictly application of B grades of organic materials of limitation, fireproof heat insulating turns into be had
The door that machine external-wall heat-insulation material must be crossed over.Fire-type organic foam insulation material on existing market generally passes through dispensing halogen
Compound plays a part of fireproof heat insulating, but halide the problem of have not environmentally in itself, for example, PBDEs (PBDPO)
And with its fire-retardant material thermal cracking and burning when can generate many bromo dibenzodioxin English (PBDD) of poisonous carcinogen and
PBDF (PBDF), also, halogenated flame retardant fire-retardant high polymer in part can generate greatly in hot tearing and burning
The flue dust and corrosive gas of amount, have harmfulness to environment and biology.So match out environment-friendly type, water proof fire retardant excellent performance and
The high fire-type organic foam insulation material of intensity turns into the design problem in industry.
The content of the invention
It is an object of the present invention to provide a kind of fire-type organic foam insulation material, environmental protection, water proof fire retardant performance be good and intensity
It is high.
In order to realize the above object the technical solution adopted by the present invention is：A kind of fire-type organic foam insulation material, bag
Organic foam is included, described organic foam is polystyrene or polyurethane or phenol formaldehyde foam, and described fire-type organic foam is protected
Adiabator includes according to the raw material of percentage by weight：Organic foam material 10 ~ 25%, nano level flame retardant 25 ~ 40%, essence resistance
Fire fiber 40 ~ 55%.
It is preferred that, described fire-type organic foam insulation material includes according to the raw material of percentage by weight：Organic foam
Material 20%, nano level flame retardant 30%, inherent fire-retardant fiber 50%.
Further, described nano level flame retardant is nano layered double hydroxides.
Further, described inherent fire-retardant fiber includes polybenzimidazoles 10 ~ 20%, polyphenylene sulfide 12 ~ 20%, polyethers ether
Ketone 10 ~ 18%, polyamide-imides 10 ~ 20%, Ju Fang oxadiazoles 15 ~ 25%, polyimides 15 ~ 25%, silicon carbide fibre 13 ~
22%。
The technical effects of the invention are that：The present invention has abandoned the halide fire-proof flame-retarded agent commonly used on existing market, adopts
The nano level flame retardant developed with nanometer technology, has the advantages that purity height, granularity fine, fire resistance are good, can prevent fires
Radioresistance, intensity is high, and high temperature resistant, comfortableness is good.And inherent flame retardant material is used, inherent flame retardant material is different from passing through outer addition
Fire retardant and assign Flame Retardancy energy, inherent flame retardant material inherently have excellent fire resistance, at present research it is hotter
The inherent flame retardant material of door mainly includes：Ju is to penylene benzo-dioxazole（PBO）, polybenzimidazoles（PBI）, melamine fiber
（Basofil）, polyphenylene sulfide（PPS), polyether-ether-ketone（PEEK）, polyamide-imides（Kermal）, phenolic fibre（Kynol）、
It is meta-aramid, PSA fiber, polyphenylene sulfide, Vinyon N, inherent flame retardant polyamide fibre, Ju Fang oxadiazoles (POD), high-strength fire-retarding polyvinyl, poly-
Acid imide (P84), oxidization fiber, carbon fiber, flame-proof sea silk, basalt fibre, silicon carbide fibre etc..Halogen inherent flame retardant material
Material is fire-retardant and environmental-protecting performance is very excellent.The fire-type organic foam insulation material intensity obtained by said ratio is also very high.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment 1：A kind of fire-type organic foam insulation material, including organic foam, described organic foam are polyphenyl
Ethene or polyurethane or phenol formaldehyde foam, described fire-type organic foam insulation material include according to the raw material of percentage by weight：
Organic foam material 20%, nano level flame retardant 30%, inherent fire-retardant fiber 50%.
Further, described nano level flame retardant is nano layered double hydroxides.
Further, described inherent fire-retardant fiber includes polybenzimidazoles 10 ~ 20%, polyphenylene sulfide 12 ~ 20%, polyethers ether
Ketone 10 ~ 18%, polyamide-imides 10 ~ 20%, Ju Fang oxadiazoles 15 ~ 25%, polyimides 15 ~ 25%, silicon carbide fibre 13 ~
22%。
Nano level flame retardant-nano layered double hydroxides are developed using nanometer technology, it is ultra-fine with purity height, granularity
The good advantage of change, fire resistance, can prevent fires radioresistance, and intensity is high, and high temperature resistant, comfortableness is good.And using inherent flame retardant material,
Inherent flame retardant material is different from assigning Flame Retardancy energy by outer addition fire retardant, and inherent flame retardant material inherently has excellent
Different fire resistance, the fire-type organic foam insulation material intensity obtained by said ratio is very high.
Embodiment 2：A kind of fire-type organic foam insulation material, including organic foam, described organic foam are polyphenyl
Ethene or polyurethane or phenol formaldehyde foam, described fire-type organic foam insulation material include according to the raw material of percentage by weight：
Organic foam material 10%, nano level flame retardant 35%, inherent fire-retardant fiber 55%.
Further, described nano level flame retardant is nano layered double hydroxides.
Further, described inherent fire-retardant fiber includes polybenzimidazoles 10 ~ 20%, polyphenylene sulfide 12 ~ 20%, polyethers ether
Ketone 10 ~ 18%, polyamide-imides 10 ~ 20%, Ju Fang oxadiazoles 15 ~ 25%, polyimides 15 ~ 25%, silicon carbide fibre 13 ~
22%。
The fire-type organic foam insulation material environmental protection that is obtained by said ratio, water proof fire retardant performance be good and intensity height.
Embodiment 3：A kind of fire-type organic foam insulation material, including organic foam, described organic foam are polyphenyl
Ethene or polyurethane or phenol formaldehyde foam, described fire-type organic foam insulation material include according to the raw material of percentage by weight：
Organic foam material 15%, nano level flame retardant 35%, inherent fire-retardant fiber 50%.
Further, described nano level flame retardant is nano layered double hydroxides.
Further, described inherent fire-retardant fiber includes polybenzimidazoles 10 ~ 20%, polyphenylene sulfide 12 ~ 20%, polyethers ether
Ketone 10 ~ 18%, polyamide-imides 10 ~ 20%, Ju Fang oxadiazoles 15 ~ 25%, polyimides 15 ~ 25%, silicon carbide fibre 13 ~
22%。
The fire-type organic foam insulation material environmental protection that is obtained by said ratio, water proof fire retardant performance be good and intensity height.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.
Claims (4)
1. a kind of fire-type organic foam insulation material, including organic foam, described organic foam are polystyrene or poly- ammonia
Ester or phenol formaldehyde foam, it is characterised in that described fire-type organic foam insulation material includes according to the raw material of percentage by weight：
Organic foam material 10 ~ 25%, nano level flame retardant 25 ~ 40%, inherent fire-retardant fiber 40 ~ 55%.
2. fire-type organic foam insulation material according to claim 1, it is characterised in that according to the original of percentage by weight
Material includes：Organic foam material 20%, nano level flame retardant 30%, inherent fire-retardant fiber 50%.
3. fire-type organic foam insulation material according to claim 1 or 2, it is characterised in that described nanoscale resistance
Combustion agent is nano layered double hydroxides.
4. fire-type organic foam insulation material according to claim 1 or 2, it is characterised in that described inherent flame retardant
Fiber includes polybenzimidazoles 10 ~ 20%, and polyphenylene sulfide 12 ~ 20%, polyether-ether-ketone 10 ~ 18%, polyamide-imides 10 ~ 20% gathers
Fang oxadiazoles 15 ~ 25%, polyimides 15 ~ 25%, silicon carbide fibre 13 ~ 22%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610984561.9A CN107057207A (en) | 2016-11-09 | 2016-11-09 | Fire-type organic foam insulation material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610984561.9A CN107057207A (en) | 2016-11-09 | 2016-11-09 | Fire-type organic foam insulation material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107057207A true CN107057207A (en) | 2017-08-18 |
Family
ID=59618461
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610984561.9A Pending CN107057207A (en) | 2016-11-09 | 2016-11-09 | Fire-type organic foam insulation material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107057207A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107514115A (en) * | 2017-08-22 | 2017-12-26 | 智慧超洋建设工程股份有限公司 | A kind of fireproof heat insulating exterior wall composite decorating board |
| CN109456587A (en) * | 2018-11-14 | 2019-03-12 | 安徽兆拓新能源科技有限公司 | A kind of polyurethane foam plastics applied to solar water heater |
| CN109456588A (en) * | 2018-11-14 | 2019-03-12 | 安徽兆拓新能源科技有限公司 | Solar water heater polyurethane foam plastics and its application |
| CN109485902A (en) * | 2018-11-14 | 2019-03-19 | 安徽兆拓新能源科技有限公司 | A kind of preparation method of solar water heater foamed plastics |
| CN115287798A (en) * | 2022-08-29 | 2022-11-04 | 烟台华维特防新材料有限公司 | Method for blending alginate fibers and poly (p-phenylene benzobisoxazole) fibers |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101575759A (en) * | 2009-06-16 | 2009-11-11 | 四川省纺织科学研究院 | Polyphenyl thioether woven fabric and fabricating technique thereof |
| CN102977489A (en) * | 2012-12-25 | 2013-03-20 | 胶州市富田化工有限公司 | Polystyrene heat insulation material |
| CN105694346A (en) * | 2014-11-25 | 2016-06-22 | 天津市煜辉机械加工有限公司 | High-flame retardation phenolic foam heat insulation plate |
-
2016
- 2016-11-09 CN CN201610984561.9A patent/CN107057207A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101575759A (en) * | 2009-06-16 | 2009-11-11 | 四川省纺织科学研究院 | Polyphenyl thioether woven fabric and fabricating technique thereof |
| CN102977489A (en) * | 2012-12-25 | 2013-03-20 | 胶州市富田化工有限公司 | Polystyrene heat insulation material |
| CN105694346A (en) * | 2014-11-25 | 2016-06-22 | 天津市煜辉机械加工有限公司 | High-flame retardation phenolic foam heat insulation plate |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107514115A (en) * | 2017-08-22 | 2017-12-26 | 智慧超洋建设工程股份有限公司 | A kind of fireproof heat insulating exterior wall composite decorating board |
| CN109456587A (en) * | 2018-11-14 | 2019-03-12 | 安徽兆拓新能源科技有限公司 | A kind of polyurethane foam plastics applied to solar water heater |
| CN109456588A (en) * | 2018-11-14 | 2019-03-12 | 安徽兆拓新能源科技有限公司 | Solar water heater polyurethane foam plastics and its application |
| CN109485902A (en) * | 2018-11-14 | 2019-03-19 | 安徽兆拓新能源科技有限公司 | A kind of preparation method of solar water heater foamed plastics |
| CN115287798A (en) * | 2022-08-29 | 2022-11-04 | 烟台华维特防新材料有限公司 | Method for blending alginate fibers and poly (p-phenylene benzobisoxazole) fibers |
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| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170818 |