CN106497284A - A kind of reflective insulation texture multicolor finish and preparation method thereof - Google Patents
A kind of reflective insulation texture multicolor finish and preparation method thereof Download PDFInfo
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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Abstract
The invention discloses a kind of reflective insulation texture multicolor finish, the coating covers bag oil ingredient C compositions by basic texture component A, functionalization component B and light;By percentage to the quality, basic texture component A is made up of pure acrylic latex, OPEO, polycarboxylate sodium's type dispersant, organic silicon defoamer, common fillers, reflective insulation quartz sand, lithium magnesium silicate, hydroxyethyl cellulose, 2 amino, 2 methyl, 1 propanol, water;Functionalization component B is made up of lithium magnesium silicate, functional stuffing, ammonium polyacrylate dipersant, water;Light covers bag oil ingredient C and is constituted by emulsion, alcohol ester 12, water, thickening agent is coated.The invention also discloses the preparation method of the coating, the high parian decorative effect of the coating energy obtained by the present invention, the texture of rough rock more more standby than common multicolor finish are provided simultaneously with certain reflective insulation performance, more energy-conserving and environment-protective.
Description
Technical field
The present invention relates to a kind of reflective insulation material, specifically a kind of reflective insulation texture multicolor finish and its preparation side
Method.
Background technology
In recent years, with a large amount of exploitations of the non-renewable energy resources such as oil, colliery, natural gas, and energy danger experienced
After machine, people increasingly pay attention to power saving.Energy-saving, to increase economic efficiency be the basic mesh of scientific research and technological development
One of mark, coating technology is no exception.At present, heat-barrier material is experiencing the transformation to based on heat-insulating heat-insulated from industry,
This is also one of main development direction of heat-insulating heat-preserving material from now on.
The Main way of aqueouss reflective heat-insulation paint exactly body of wall energy-saving material.But aqueouss reflective heat-insulation paint is main at present
Based on ordinary white or light-coloured coating, it is difficult to meet requirement of the people to high-decoration instantly, so this coating is difficult greatly
Scope is promoted.And consumption increases year by year currently on the market, obtain more and more consumers is true mineral varnish and aqueous colorful
Coating these imitative stone class high-decoration coating, the especially imitative stone class coating with quartz sand as main stuffing.
CN201510346050.X discloses a kind of preparation method of the true mineral varnish of reflection heat-insulating type, mainly by adding two
Titanium oxide and the cenosphere with reflective insulation function are lifting the reflective insulation performance of coating.Although the method is in certain journey
Can lift the reflective insulation performance of coating on degree, but there is a problem that two serious:First, add titanium dioxide in true mineral varnish
Titanium will necessarily affect the prize color of sand of coating to represent, and limit the imitative stone of height of true mineral varnish;Second, cenosphere is existed with color sand
In production, due to the effect of agitating friction, cenosphere is easily broken, and cenosphere just loses reflective insulation once crushing
Effect, greatly reduce cenosphere effect in the coating.
CN103642344B discloses a kind of texture multicolor finish, is mixed and made into product, spray mo(u)lding by A, B component
Also there is while rock decorative pattern is presented after drying the coarse texture of rock itself, have the high simulated effect of natural granite,
Combine the advantage of water-soluble colorful coating and true mineral varnish.Compare with CN201510346050.X, CN103642344B has higher
Imitative stone, and color is more easy to adjust and controls, but this texture multicolor finish does not possess reflective insulation performance, it is impossible to well
Meet the energy-saving demand for development of modern architecture.
TiO2It is the material with high sun luminous reflectance and high near-infrared reflection ratio being currently known, by certain bag
Coating technique, by quartz sand surface through TiO2After cladding process, the reflective insulation performance of quartz sand can be also obviously improved, and incite somebody to action
When this modified quartz sand carries out coating material production as filler, the TiO that the coating also will be coated by quartz sand surface2Obtain
Obtain reflective insulation performance necessarily.
Nano antimony tin oxide and nano-indium stannum oxide are the known materials with higher near infrared reflectivity, heat-insulated
Also there is successfully application in glass and thermal isolation film.Obviously, if dispersion problem can be solved, this kind of materials application is applied in aqueouss
In material, the near infrared reflectivity for improving coating is also expected to.
The present invention is namely based on these functional materials, by special preparation technology, they is made and is had necessarily instead
The texture multicolor finish of heat-proof quality is penetrated, its energy saving is increased while coating stone is not affected, more meet and work as
The requirement that lower society lowers consumption to energy-conserving and environment-protective.
Content of the invention
The technical problem to be solved in the present invention is to overcome the deficiencies in the prior art, there is provided a kind of reflective insulation texture is colorful
Coating and preparation method thereof, the object of the invention are realized mainly employing reflective insulation quartz sand as main stuffing, the quartz
Sand is nano-TiO2Modification is formed has higher sun luminous reflectance, and the function quartz sand is combined water-soluble colorful coating technology
The sandstone texture multicolor finish with reflective insulation function is obtained.Simultaneously also by solution nano antimony tin oxide and nano indium oxide
Stably dispersing sex chromosome mosaicism of the stannum in water paint, by near-infrared reflection materials application stronger for both features in many color coatings
Material, and higher near infrared reflectivity is provided for coating.
In order to solve above-mentioned technical problem, the concrete technical scheme of the present invention is:A kind of reflective insulation texture multicolor finish,
It is prepared from by the component of following percentage by weight:
Basic texture component A 30%-70%
Functionalization component B 10%-30%
Light covers bag oil ingredient C 15%-50%
Described basic texture component A, each raw material weight percentage ratio is:
Described functionalization component B, each raw material weight percentage ratio is:
Described light covers bag oil ingredient C, and each raw material weight percentage ratio is:
The common fillers of above-mentioned basic texture component A are Kaolin, titanium dioxide, one or more mixing in mica powder
Thing.
The reflective insulation quartz sand of above-mentioned basic texture component A is through nano-TiO2The quartz sand of cladding.
The functional stuffing of above-mentioned functionalization component B is any one in nano antimony tin oxide and nano-indium stannum oxide.
It is any one in silicone acrylic emulsion and fluorine carbon emulsion that above-mentioned light covers the cladding emulsion of bag oil ingredient C.
It is hydrophobically-modified alkali swelling type thickening agent that above-mentioned light covers the thickening agent of bag oil ingredient C.
A kind of preparation method of reflective insulation texture multicolor finish of the present invention, the method include component A preparation, B successively
Prepared by component, prepared by component C and prepared by finished product;
First, basic texture component A, following raw materials by weight meter are prepared:
A) pour the water of 20%-60% into Scattered Kettle, be under 900-1500r/min, to add 0.3%- in dispersing speed
5% hydroxyethyl cellulose, disperses 15-30min, and the 2-amino-2-methyl-1-propanol for adding 0.05%-1% continues dispersion
30-60min;
B) add in Scattered Kettle described in step a the OPEO of 0.1%-0.5%, 0.2%-2% poly-
Carboxylic acid sodium salt form dispersant, the organic silicon defoamer of 0.5%-5%, disperse 15-45min;
C) common fillers of 2%-10% are added in Scattered Kettle described in step b, and adjustment dispersing speed is 1500
3000r/min, disperses 30-60min;
D) pure acrylic latex of 10%-50% is added in Scattered Kettle described in step c, disperses 30-60min;
E) the reflective insulation quartz sand of 25%-60% is added in Scattered Kettle described in step d, and adjusting dispersing speed is
500 1200r/min, disperse 30-60min;
F) lithium magnesium silicate of 0.1%-3% is added in Scattered Kettle described in step e, disperses 30-90min, discharging to obtain base
Plinth texture component A.
2nd, functionalization component B, following raw materials by weight meter are prepared:
G) pour 70%-85% water into Scattered Kettle, be under 900-1500r/min, to add 5%-15%'s in dispersing speed
Lithium magnesium silicate, disperses 30-60min, adds the ammonium polyacrylate dipersant of 0.5%-5%, disperses 15-30min;
H) functional stuffing of 5%-15% is added in Scattered Kettle described in step g, and adjustment dispersing speed is 2000
5000r/min, disperses 1-3h, discharging to obtain functionalization component B.
3rd, prepare light and cover bag oil ingredient C, following raw materials by weight meter:
I) pour the water of 10%-50% into Scattered Kettle, be under 500-1000r/min, to add 5%-15% in dispersing speed
Alcohol ester 12, disperse 30-60min;
J) the cladding emulsion of 40%-80% is added in Scattered Kettle described in step i, disperses 15-30min;
K) thickening agent of 1%-10% is added in Scattered Kettle described in step j, disperses 20-60min, discharging to obtain light and cover bag
Oil ingredient C.
4th, reflective insulation texture multicolor finish finished product is prepared, is made up of following steps:
L) basic texture component A is mixed colours with aqueous color paste, obtains required color, as needed adjustable multiple face
Basic texture component A of color is standby.
M) colour basis texture component A in 30%-70% obtained in step l is added to functionalization component B of 10%-30%
In, the mixed material is carried out pelletize by the screen cloth of different pore size, the colorful color tablets of the texture of various size and color are obtained.
N) light of 15%-50% is covered bag oil ingredient C to be added in the colorful color tablets of texture obtained in step m, is stirred
After obtain finished product reflective insulation texture multicolor finish.
Compared with prior art, the invention has the advantages that:
A kind of colorful texture coating of reflective insulation of the invention, not only possesses existing multicolor finish and can imitate natural flowers hilllock
Rock or the technological merit of marble decorative pattern, and the coating of the present invention is through a spray mo(u)lding, is presenting rock after drying
Also there is while shell stone patterns the coarse texture of rock itself, have the high simulated effect of natural granite, additionally, coating also has one
Fixed reflective insulation function, increased the feature of coating, can reduce the temperature of building masonry wall, so as to reduce building energy consumption,
Safety non-toxic more energy-conserving and environment-protective.
Specific embodiment
Below by embodiment, the invention will be further described, but the present invention is not limited only to these examples.
Embodiment one
1. the raw material of each component is prepared by following formula;Wherein:
Basic texture component A formula (percentage by weight):
Functionalization component B formula (percentage by weight):
Light covers bag oil ingredient C formula (percentage by weight):
Finished product coating each component formula (percentage by weight):
Basic texture component A 60%
Functionalization component B 20%
Light covers bag oil ingredient C 20%
2. the preparation of basic texture component A:Pour 29.9% water into Scattered Kettle, be 1000r/min in dispersing speed
The hydroxyethyl cellulose of lower addition 1%, disperses 15min, and the 2-amino-2-methyl-1-propanol for adding 0.1% continues dispersion
30min, sequentially adds 0.5% OPEO, 1% polycarboxylate sodium's type dispersant and 2% organosilicon froth breaking
Agent, disperses 15min, adds 5% Kaolin, and adjustment dispersing speed is 1500r/min, disperses 30min, adds 30%
Pure acrylic latex, disperse 30min, add 30% reflective insulation quartz sand, adjustment dispersing speed is 500r/min,
Dispersion 30min, is eventually adding 0.5% lithium magnesium silicate, disperses 30min, discharging to obtain basic texture component A.
3. prepared by functionalization component B:Pour 78% water into Scattered Kettle, be to add under 900r/min in dispersing speed
10% lithium magnesium silicate, disperses 30min, adds 2% ammonium polyacrylate dipersant, disperses 15min, adds 10% nanometer
Tin-antiomony oxide, adjustment dispersing speed are 2000r/min, disperse 1h, discharging to obtain functionalization component B.
4. light covers the preparation of bag oil ingredient C:Pour 26% water into Scattered Kettle, be to add under 500r/min in dispersing speed
Enter 10% alcohol ester 12, disperse 30min, add 60% silicone acrylic emulsion, disperse 15min, add 4% thickening agent,
Dispersion 20min, discharging obtain light and cover bag oil ingredient C.
5. the preparation of finished product reflective insulation texture multicolor finish:60% basic texture component A is divided into three equal parts, is used in combination
Aqueous color paste recalls basic texture component A of three kinds of different colours respectively, then adds it in 20% functionalization component B,
Then the mixed material is carried out pelletize by the screen cloth of different pore size, obtains the texture broken colour of various size and color
Grain.Finally, 20% light is covered bag oil ingredient C to be slowly added in the colorful color tablets of obtained texture, is obtained after stirring
Finished product reflective insulation texture multicolor finish.
With reflective insulation texture multicolor finish prepared by embodiment one, the sunlight of its coating after drying, is surveyed through making sheet of mixing colours
Reflectivity is 83%, and the sun luminous reflectance relative to the common texture multicolor finish coating 68% of same color improves
15%.
Embodiment two
1. the raw material of each component is prepared by following formula;Wherein:
Basic texture component A formula (percentage by weight):
Functionalization component B formula (percentage by weight):
Light covers bag oil ingredient C formula (percentage by weight):
Finished product coating each component formula (percentage by weight):
Basic texture component A 50%
Functionalization component B 15%
Light covers bag oil ingredient C 35%
2. the preparation of basic texture component A:Pour 24% water into Scattered Kettle, be under 1500r/min in dispersing speed
2% hydroxyethyl cellulose is added, disperses 20min, the 2-amino-2-methyl-1-propanol for adding 0.2% continues dispersion
45min, sequentially adds 0.3% OPEO, 0.8% polycarboxylate sodium's type dispersant and 2% organosilicon and disappears
Infusion, disperses 30min, adds 10% titanium dioxide, and adjustment dispersing speed is 2000r/min, disperses 50min, adds
20% pure acrylic latex, disperses 40min, adds 40% reflective insulation quartz sand, and adjustment dispersing speed is 800r/
Min, disperses 45min, is eventually adding 0.7% lithium magnesium silicate, disperses 45min, discharging to obtain basic texture component A.
3. prepared by functionalization component B:Pour 82% water into Scattered Kettle, be to add under 1200r/min in dispersing speed
8% lithium magnesium silicate, disperses 40min, adds 1.5% ammonium polyacrylate dipersant, disperses 25min, adds 8.5% to receive
Rice tin-antiomony oxide, adjustment dispersing speed are 3000r/min, disperse 2h, discharging to obtain functionalization component B.
4. light covers the preparation of bag oil ingredient C:Pour 37% water into Scattered Kettle, be to add under 800r/min in dispersing speed
Enter 8% alcohol ester 12, disperse 45min, add 50% silicone acrylic emulsion, disperse 25min, add 5% thickening agent, point
Scattered 30min, discharging obtain light and cover bag oil ingredient C.
5. the preparation of finished product reflective insulation texture multicolor finish:50% basic texture component A is divided into three equal parts, is used in combination
Aqueous color paste recalls basic texture component A of three kinds of different colours respectively, then adds it in 15% functionalization component B,
Then the mixed material is carried out pelletize by the screen cloth of different pore size, obtains the texture broken colour of various size and color
Grain.Finally, 35% light is covered bag oil ingredient C to be slowly added in the colorful color tablets of obtained texture, is obtained after stirring
Finished product reflective insulation texture multicolor finish.
With reflective insulation texture multicolor finish prepared by embodiment two, the sunlight of its coating after drying, is surveyed through making sheet of mixing colours
Reflectivity is 79%, and the sun luminous reflectance relative to the common texture multicolor finish coating 68% of same color improves
11%.
Embodiment three
1. the raw material of each component is prepared by following formula;Wherein:
Basic texture component A formula (percentage by weight):
Functionalization component B formula (percentage by weight):
Light covers bag oil ingredient C formula (percentage by weight):
Finished product coating each component formula (percentage by weight):
Basic texture component A 45%
Functionalization component B 30%
Light covers bag oil ingredient C 25%
2. the preparation of basic texture component A:Pour 10% water into Scattered Kettle, be under 1500r/min in dispersing speed
1.5% hydroxyethyl cellulose is added, disperses 30min, the 2-amino-2-methyl-1-propanol for adding 0.5% continues dispersion
55min, sequentially adds 0.5% OPEO, 1.5% polycarboxylate sodium's type dispersant and 3% organosilicon and disappears
Infusion, disperses 45min, adds 6% mica powder, and adjustment dispersing speed is 2500r/min, disperses 60min, adds
25% pure acrylic latex, disperses 60min, adds 50% reflective insulation quartz sand, and adjustment dispersing speed is 900r/
Min, disperses 55min, is eventually adding 2% lithium magnesium silicate, disperses 85min, discharging to obtain basic texture component A.
3. prepared by functionalization component B:Pour 70% water into Scattered Kettle, be to add under 1500r/min in dispersing speed
12% lithium magnesium silicate, disperses 60min, adds 3% ammonium polyacrylate dipersant, disperses 30min, adds 15% nanometer
Tin-antiomony oxide, adjustment dispersing speed are 4500r/min, disperse 1.5h, discharging to obtain functionalization component B.
4. light covers the preparation of bag oil ingredient C:Pour 7% water into Scattered Kettle, be to add under 600r/min in dispersing speed
Enter 10% alcohol ester 12, disperse 60min, add 80% silicone acrylic emulsion, disperse 30min, add 3% thickening agent,
Dispersion 60min, discharging obtain light and cover bag oil ingredient C.
5. the preparation of finished product reflective insulation texture multicolor finish:45% basic texture component A is divided into four parts, and uses water
Property mill base recalls basic texture component A of three kinds of different colours respectively, then adds it in 30% functionalization component B, so
The mixed material is carried out pelletize by the screen cloth of different pore size afterwards, the texture broken colour of various size and color is obtained
Grain.Finally, 25% light is covered bag oil ingredient C to be slowly added in the colorful color tablets of obtained texture, is obtained after stirring
Finished product reflective insulation texture multicolor finish.
With reflective insulation texture multicolor finish prepared by embodiment three, the sunlight of its coating after drying, is surveyed through making sheet of mixing colours
Reflectivity is 86%, and the sun luminous reflectance relative to the common texture multicolor finish coating 68% of same color improves
18%.
Claims (7)
1. a kind of reflective insulation texture multicolor finish, it is characterised in that by percentage to the quality, component is as follows:
Basic texture component A 30%-70%
Functionalization component B 10%-30%
Light covers bag oil ingredient C 15%-50%
Described basic texture component A, each raw material weight percentage ratio is:
Described functionalization component B, each raw material weight percentage ratio is:
Described light covers bag oil ingredient C, and each raw material weight percentage ratio is:
2. a kind of reflective insulation texture multicolor finish according to claim 1, is characterized in that:Described basic texture component
Common fillers in A are Kaolin, titanium dioxide, one or more mixture in mica powder.
3. a kind of reflective insulation texture multicolor finish according to claim 1, is characterized in that:Described basic texture component
Reflective insulation quartz sand in A is through nano-TiO2The quartz sand of cladding.
4. a kind of reflective insulation texture multicolor finish according to claim 1, is characterized in that:Described functionalization component B
Functional stuffing be nano antimony tin oxide and nano-indium stannum oxide in any one.
5. a kind of reflective insulation texture multicolor finish according to claim 1, is characterized in that:Described light covers bag oil ingredient
The cladding emulsion of C is any one in silicone acrylic emulsion and fluorine carbon emulsion.
6. a kind of reflective insulation texture multicolor finish according to claim 1, is characterized in that:Described light covers bag oil ingredient
The thickening agent of C is hydrophobically-modified alkali swelling type thickening agent.
7. a kind of preparation method of the reflective insulation texture multicolor finish described in claim 1, is characterized in that:The method is wrapped successively
Include following steps:
First, basic texture component A, following raw materials by weight meter are prepared:
A) pour the water of 20%-60% into Scattered Kettle, be under 900-1500r/min, to add 0.3%-5%'s in dispersing speed
Hydroxyethyl cellulose, disperses 15-30min, and the 2-amino-2-methyl-1-propanol for adding 0.05%-1% continues dispersion 30-
60min;
B) OPEO, the polycarboxylic acids of 0.2%-2% of 0.1%-0.5% are added in Scattered Kettle described in step a
Sodium-salt type dispersant, the organic silicon defoamer of 0.5%-5%, disperse 15-45min;
C) common fillers of 2%-10% are added in Scattered Kettle described in step b, and adjustment dispersing speed is 1500 3000r/
Min, disperses 30-60min;
D) pure acrylic latex of 10%-50% is added in Scattered Kettle described in step c, disperses 30-60min;
E) the reflective insulation quartz sand of 25%-60% is added in Scattered Kettle described in step d, and adjustment dispersing speed is 500
1200r/min, disperses 30-60min;
F) lithium magnesium silicate of 0.1%-3% is added in Scattered Kettle described in step e, disperses 30-90min, discharging to obtain basic matter
Sense component A.
2nd, functionalization component B, following raw materials by weight meter are prepared:
G) pour 70%-85% water into Scattered Kettle, be the silicic acid that 5%-15% is added under 900-1500r/min in dispersing speed
Magnesium lithium, disperses 30-60min, adds the ammonium polyacrylate dipersant of 0.5%-5%, disperses 15-30min;
H) functional stuffing of 5%-15% is added in Scattered Kettle described in step g, and adjustment dispersing speed is 2000 5000r/
Min, disperses 1-3h, discharging to obtain functionalization component B.
3rd, prepare light and cover bag oil ingredient C, following raw materials by weight meter:
I) pour the water of 10%-50% into Scattered Kettle, be the alcohol that 5%-15% is added under 500-1000r/min in dispersing speed
Ester 12, disperses 30-60min;
J) the cladding emulsion of 40%-80% is added in Scattered Kettle described in step i, disperses 15-30min;
K) thickening agent of 1%-10% is added in Scattered Kettle described in step j, disperses 20-60min, discharging to obtain light and cover bag line of oils
Divide C.
4th, reflective insulation texture multicolor finish finished product is prepared, is made up of following steps:
L) basic texture component A is mixed colours with aqueous color paste, obtains required color, as needed adjustable multiple color
Basic texture component A is standby.
M) colour basis texture component A in 30%-70% obtained in step l is added to functionalization component B of 10%-30%
In, the mixed material is carried out pelletize by the screen cloth of different pore size, the texture broken colour of various size and color is obtained
Grain.
N) light of 15%-50% is covered bag oil ingredient C to be added in the colorful color tablets of texture obtained in step m, after stirring
Arrive finished product reflective insulation texture multicolor finish.
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CN108926979A (en) * | 2018-07-12 | 2018-12-04 | 浙江大学宁波理工学院 | Graphene aldehyde removing agent and preparation method thereof |
CN109868012A (en) * | 2019-01-10 | 2019-06-11 | 嘉宝莉化工集团股份有限公司 | A kind of double cladded type reflective insulation lacquer and preparation method thereof |
CN110628277A (en) * | 2019-09-09 | 2019-12-31 | 青岛科技大学 | Heat insulation functional material for fire scene and preparation method thereof |
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CN103396713A (en) * | 2013-08-11 | 2013-11-20 | 深圳市文浩建材科技有限公司 | Semi-transparent aqueous heat insulation coating and preparation method thereof |
CN104151979A (en) * | 2014-08-28 | 2014-11-19 | 上海绿特丹保温工程有限公司 | W/W reflective thermal-insulation colorful paint |
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CN103396713A (en) * | 2013-08-11 | 2013-11-20 | 深圳市文浩建材科技有限公司 | Semi-transparent aqueous heat insulation coating and preparation method thereof |
CN104151979A (en) * | 2014-08-28 | 2014-11-19 | 上海绿特丹保温工程有限公司 | W/W reflective thermal-insulation colorful paint |
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CN108926979A (en) * | 2018-07-12 | 2018-12-04 | 浙江大学宁波理工学院 | Graphene aldehyde removing agent and preparation method thereof |
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CN110628277A (en) * | 2019-09-09 | 2019-12-31 | 青岛科技大学 | Heat insulation functional material for fire scene and preparation method thereof |
CN112898840A (en) * | 2019-09-09 | 2021-06-04 | 青岛科技大学 | Preparation method of heat insulation functional material for coping with fire scene |
CN112898840B (en) * | 2019-09-09 | 2021-10-22 | 青岛科技大学 | Preparation method of heat insulation functional material for coping with fire scene |
CN112662224A (en) * | 2020-12-07 | 2021-04-16 | 广东嘉宝莉科技材料有限公司 | Sand-in-water multicolor paint with high stability and preparation method thereof |
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CN114188668B (en) * | 2021-12-17 | 2024-02-13 | 蜂巢能源科技股份有限公司 | Coating slurry, preparation method thereof, composite diaphragm and lithium ion battery |
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