CN106495622B - A kind of entity decorative board and preparation method thereof and application - Google Patents
A kind of entity decorative board and preparation method thereof and application Download PDFInfo
- Publication number
- CN106495622B CN106495622B CN201610966955.1A CN201610966955A CN106495622B CN 106495622 B CN106495622 B CN 106495622B CN 201610966955 A CN201610966955 A CN 201610966955A CN 106495622 B CN106495622 B CN 106495622B
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- China
- Prior art keywords
- crystal
- entity
- decorative board
- mineral
- punch forming
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/06—Aluminous cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/30—Oxides other than silica
- C04B14/308—Iron oxide
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/36—Inorganic materials not provided for in groups C04B14/022 and C04B14/04 - C04B14/34
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00025—Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection
Abstract
The present invention relates to a kind of entity decorative boards and its preparation method and application, which includes the following steps：Pyroelectricity detection carried out to the mineral crystal with pyroelectricity, selection meet granularity requirements mineral crystal with thermoelectricity capability and crude tourmaline crystal it is spare；The mineral crystal with pyroelectricity is uniformly mixed with inorganic coagulation material, injection mold carries out punch forming, and the crude tourmaline crystal described in the uniform spreading of one side of plank when punch forming obtains punch forming plank；Sheet forming obtains mechanical strength using conservation system, and tourmaline crystal face described in sanding and polishing obtains entity decorative board.The entity decorative board includes：Mineral crystal, crude tourmaline crystal with thermoelectricity capability and high temperature resistant inorganic cementitious material.The preparation method production stage of the present invention is simple and of low cost；The entity decorative board can use under temperature difference thermal environment, can not only promote microcirculation in human body, moreover it is possible to purify air.
Description
Technical field
The present invention relates to a kind of entity decorative boards and preparation method thereof and application, belong to building material field.
Background technology
Architectural decoration stone material has lithotome and artificial stone's two major classes.Lithotome refers to being exploited from natural rock mass
Out, and it is processed at blocky or board-like material general name.Natural stone used in construction and decoration mainly has granite and Dali
Two big kinds of stone.Marble refers to the rock of deposition or rotten carbonate rock, have griotte, dolomite, limestone, sandstone,
Shale and slate etc..If the famous white marble in China is exactly the dolomite that is produced from Fangshan, Beijing, Dali stone is then to originate in Dali
The griotte in county, green famous Dandong is then serpentinization skarn.As all kinds of magmatic rocks of stone mining, as granite,
Andesite, diabase, Lv Changyan, gneiss etc. are referred to as granite.If the white granite in Beijing white tiger ravine is granite, Ji
Nan Qing is gabbro, and the black granite in Qingdao is then diabase.
Artificial stone is a kind of artificial synthesized ornament materials.According to binder used difference, it is artificial organic can be divided into
Two class of stone material and inorganic artificial stone.By the difference of its production process, and polyester artificial marble, compound can be divided into
Type artificial marble, silicate-type artificial marble, four type of slug type artificial marble.
The building decoration panel produced at present as main raw material(s) using stone matter class material, major function are to meet beautifying and decorating
Etc. general sexual function.That is, technology is required to reach Architectural Mechanics intensity requirement, size qualification is easy to construction.From production
Manufacture craft can be divided into two major classes：One kind is that raw material are directly carried out Physical Processing, and lithotome is such as passed through cutting/grinding and polishing
It becomes a useful person；Another kind of is that stone matter class powder is become a useful person by techniques such as sintering/gelling/polymerization/compound/moldings.
With the raising of human life quality, new requirement is proposed to the decorative board used under the conditions of varying environment,
Require plank can not only decorative beautifying environment, additionally it is possible to generate the physical field for being conducive to environment, it is thus possible to have both ecological spy
Matter improves environmental quality.This overall ecological demand has expedited the emergence of the development of green ecological decorative board.
How to develop that a kind of production stage is simple and of low cost, obtained decorative board, which has both decoration and ecological functions, is
One developing direction of decoration panel industry.
Invention content
Technical problem underlying solved by the invention is to provide a kind of entity decorative board, not only can be in temperature difference heat
It is used under environment, and can generate the physical field for being conducive to environment, have both ecological speciality.
On the one hand, the present invention provides a kind of preparation method of entity decorative board, include the following steps：
1) to pyroelectricity mineral crystal carry out pyroelectricity detection, selection meet granularity requirements have thermoelectricity capability
Mineral crystal and crude tourmaline crystal it is spare；
2) mineral crystal with pyroelectricity is uniformly mixed with inorganic coagulation material, injection mold is struck out
Type, the crude tourmaline crystal described in the uniform spreading of one side of plank when punch forming, obtains punch forming plank；
3) the punch forming plank is obtained into mechanical strength using conservation system, tourmaline crystal described in sanding and polishing
Face obtains entity decorative board.
In specific embodiments of the present invention, the additive amount of the mineral crystal with pyroelectricity：2-35%, it is described
Crude tourmaline crystal additive amount：5-20%, the additive amount of the inorganic coagulation material：10-20%.
Further, the conservation system is：To 40 DEG C, the time is no less than 72 hours room temperature.
On the other hand, the present invention also provides a kind of entity decorative boards, are made according to above-mentioned preparation method, the entity
The composition of decorative board includes：Meet the mineral crystals with thermoelectricity capability of granularity requirements, crude tourmaline crystal and resistance to
High temperature inorganic cementitious material.Inventor is for many years about mineral crystal and mineral crystal the study found that the mine with thermoelectricity capability
Object crystal releasing negative oxygen ion and can generate the far ir ray consistent with body shake frequency simultaneously.Further, resistance to height
Warm inorganic coagulation material can be Ca-Si-Al cementitious materials and common face brick aggregate.
In the present invention, the mineral crystal with thermoelectricity capability may include in chalcopyrite, galena and magnetic iron ore
A kind of or its arbitrary combination；It further requires, the Seebeck coefficient of the mineral crystal with thermoelectricity capability>0.2mV/℃.
In specific embodiments of the present invention, the particle size range 0.1- of the control mineral crystal with thermoelectricity capability
2mm。
In specific embodiments of the present invention, the static anion numerical value of tourmaline crystal>300ions/cm3, dynamic
Anion numerical value>30000ions/g.s far infrared radiation rate>90%；In addition, the selection Granularity of Tourmaline is less than
The ratio of 0.075mm>90%.
On the other hand, the application the present invention also provides above-mentioned entity decorative board on different size plank.
The preparation method of entity decorative board provided by the invention, difference with the prior art one：Natural electricity in raw material
Gas stone crystal with releasing negative oxygen ion and can generate the far ir ray consistent with body shake frequency；Difference two：In raw material
Mineral crystal have thermoelectricity attribute, weak thermoelectric field can be generated under temperature difference heat effect, produce it is a kind of can be in temperature difference heat ring
The multifunctional ecological decorative board used under border (floor tile and spa pool face brick that such as use geothermal heating).
The present invention has the advantages that：
1, entity decorative board preparation method production stage provided by the present invention is simple and of low cost；
2, entity decorative board provided by the present invention is a kind of environment, spa pool equal temperature difference heat ring that can be in geothermal heating
The decorative board used under border, since the use condition of temperature difference heat can excite entity decorative board generation to be conducive to improve environment
The physical field of quality, this physical field have both improvement environmental quality, promote Human Physiology cycle and metabolism, reinforce human body reason
Treat the effect of health care；In addition, temperature difference heat condition can also excite semiconductor mineral in plank to generate weak electric field in plank both sides
And magnetic field, thus human tissue cell can be stimulated, promote the microcirculation of blood of human body and lymphoid tissue liquid, it is newly old to improve human body
Metabolism；
3, entity decorative board provided by the present invention can not only promote microcirculation in human body, moreover it is possible to purify air；Because should
Uniformly paving has added tourmaline crystal for entity decorative board side, electric microfield can be also generated under heat condition, moreover it is possible to transmitting and human body
Infrared-ray similar in frequency promotes microcirculation in human body；In addition, the tourmaline on surface can be with releasing negative oxygen ion, to net
Change air, improve environment.
Specific implementation mode
To make the object, technical solutions and advantages of the present invention clearer, below in conjunction with the embodiment of the present invention, to this hair
Bright technical solution is clearly and completely described, it is clear that and described embodiments are some of the embodiments of the present invention, without
It is whole embodiment.Based on the embodiments of the present invention, those of ordinary skill in the art are not before making creative work
The every other embodiment obtained is put, shall fall within the protection scope of the present invention.
Embodiment 1：
1) using dedicated HB08 types thermoelectrometry apparatus test chalcopyrite, the thermoelectricity capability of galena and magnetic iron ore, thermoelectricity is chosen
Coefficient range>0.2mV/ DEG C of chalcopyrite, galena and Seebeck coefficient range>0.04mV/ DEG C of magnetic iron ore is as thermoelectricity crystalline substance
Body is spare；
It is detected using EB-15 type anion test instrument, chooses static anion numerical value>300ions/cm3, dynamically negative
Ion numerical value>30000ions/g.s far infrared radiation rate>90% tourmaline crystal powder is spare, controls granularity in tourmaline
Ratio less than 0.075mm is 93%；
2) chalcopyrite by particle size range in 0.1-2mm, galena and magnetic iron ore mix, enough to ensure to obtain
Thermoelectricity field intensity；Then the chalcopyrite, galena and the magnetic iron ore that 20% are mixed and 15%Ca-Si-Al cementitious materials with
And 50% common face brick aggregate uniformly mix, inject mold together and carry out punch forming, one side when punch forming in plank is equal
Crude tourmaline crystal described in even spreading controls the additive amount 15% of crude tourmaline crystal, obtains punch forming plank；
3) the punch forming plank is placed in room temperature to 40 DEG C of steam boxes 75 hours, tourmaline crystal described in sanding and polishing
Face obtains entity decorative board 1.
Embodiment 2：
1) using dedicated HB08 types thermoelectrometry apparatus test chalcopyrite, the thermoelectricity capability of galena and magnetic iron ore, thermoelectricity is chosen
Coefficient range>0.2mV/ DEG C of chalcopyrite, galena and Seebeck coefficient range>0.04mV/ DEG C of magnetic iron ore is as thermoelectricity crystalline substance
Body is spare；
It is detected using EB-15 type anion test instrument, chooses static anion numerical value>300ions/cm3, dynamically negative
Ion numerical value>30000ions/g.s far infrared radiation rate>90% tourmaline crystal powder is spare, controls granularity in tourmaline
Ratio less than 0.075mm is 90%；
2) chalcopyrite by particle size range in 0.1-2mm, galena and magnetic iron ore mix, enough to ensure to obtain
Thermoelectricity field intensity；Then the chalcopyrite, galena and the magnetic iron ore that 30% are mixed and 10%Ca-Si-Al cementitious materials with
And 40% common face brick aggregate uniformly mix, inject mold together and carry out punch forming, one side when punch forming in plank is equal
Crude tourmaline crystal described in even spreading controls the additive amount 20% of crude tourmaline crystal, obtains punch forming plank；
3) the punch forming plank is placed in room temperature to 40 DEG C of steam boxes 82 hours, tourmaline crystal described in sanding and polishing
Face obtains entity decorative board 2.
Embodiment 3：
1) using dedicated HB08 types thermoelectrometry apparatus test chalcopyrite, the thermoelectricity capability of galena and magnetic iron ore, thermoelectricity is chosen
Coefficient range>0.2mV/ DEG C of chalcopyrite, galena and Seebeck coefficient range>0.04mV/ DEG C of magnetic iron ore is as thermoelectricity crystalline substance
Body is spare；
It is detected using EB-15 type anion test instrument, chooses static anion numerical value>300ions/cm3, dynamically negative
Ion numerical value>30000ions/g.s far infrared radiation rate>90% tourmaline crystal powder is spare, controls granularity in tourmaline
Ratio less than 0.075mm is 92%；
2) chalcopyrite by particle size range in 0.1-2mm, galena and magnetic iron ore mix, enough to ensure to obtain
Thermoelectricity field intensity；Then the chalcopyrite, galena and the magnetic iron ore that 25% are mixed and 10%Ca-Si-Al cementitious materials with
And 55% common face brick aggregate uniformly mix, inject mold together and carry out punch forming, one side when punch forming in plank is equal
Crude tourmaline crystal described in even spreading controls the additive amount 10% of crude tourmaline crystal, obtains punch forming plank；
3) the punch forming plank is placed in room temperature to 40 DEG C of steam boxes 72 hours, tourmaline crystal described in sanding and polishing
Face obtains entity decorative board 3.
Comparative example
The entire body floor tile that inventor will be fired using common stone lumber such as marble, granite and cement prefab
As a comparison case, the entire body floor tile of above-mentioned 1-3 entities decorative board and comparative example is carried out respectively for following 4 indexs
Detection, specific data are as shown in table 1.
Entity decorative board product contrast table in 1 embodiment 1-3 of table and comparative example
From the testing result of 4 indexs in table 1：It entity decorative board in the embodiment of the present invention and commonly fires
Entire body floor tile compares, and entity decorative board of the invention not only has low-grade fever electricity and far infrared radiation, additionally it is possible to which release is negative
Oxonium ion.
Finally it should be noted that：The above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations；To the greatest extent
Present invention has been described in detail with reference to the aforementioned embodiments for pipe, it will be understood by those of ordinary skill in the art that：Its according to
So can with technical scheme described in the above embodiments is modified, either to which part or all technical features into
Row equivalent replacement；And these modifications or replacements, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution
The range of scheme.
Claims (7)
1. a kind of preparation method of entity decorative board, which is characterized in that include the following steps：
1）Pyroelectricity detection is carried out to the mineral crystal with pyroelectricity, selection meets the mine with thermoelectricity capability of granularity requirements
Object crystal and crude tourmaline crystal are spare；
2）The mineral crystal with pyroelectricity is uniformly mixed with inorganic coagulation material, injection mold carries out punch forming,
The crude tourmaline crystal described in the uniform spreading of the one side of plank, obtains punch forming plank when punch forming；
3）The punch forming plank is obtained into mechanical strength using conservation system, tourmaline crystal face described in sanding and polishing obtains
To entity decorative board；
Wherein, the mineral crystal with thermoelectricity capability is a kind of in chalcopyrite, galena and magnetic iron ore or arbitrarily combination；
Wherein, the Seebeck coefficient of the mineral crystal with thermoelectricity capability>0.2mV/℃.
2. the preparation method of entity decorative board according to claim 1, which is characterized in that the mine with pyroelectricity
The additive amount of object crystal：2-35%, the crude tourmaline crystal additive amount：5-20%, the additive amount of the inorganic coagulation material：
10-20%。
3. the preparation method of entity decorative board according to claim 1 or 2, which is characterized in that the conservation system is：
To 40 DEG C, the time is no less than 72 hours room temperature.
4. a kind of entity decorative board, which is characterized in that it is made according to any preparation method in claims 1 to 3, it is described
The composition of entity decorative board includes：Meet the mineral crystal with thermoelectricity capability, the crude tourmaline crystal of granularity requirements with
And inorganic coagulation material；
Wherein, the mineral crystal with thermoelectricity capability is a kind of in chalcopyrite, galena and magnetic iron ore or arbitrarily combination；
Wherein, the Seebeck coefficient of the mineral crystal with thermoelectricity capability>0.2mV/℃.
5. entity decorative board according to claim 4, which is characterized in that the mineral crystal with thermoelectricity capability
Particle size range 0.1-2mm.
6. entity decorative board according to claim 4, which is characterized in that the static state of the crude tourmaline crystal bear from
Subnumber value>300ions/cm3, dynamic anion numerical value>30000ions/g.s far infrared radiation rate>90%.
7. entity decorative board according to claim 6, which is characterized in that granularity is less than in the crude tourmaline crystal
The ratio of 0.075mm>90%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610966955.1A CN106495622B (en) | 2016-10-28 | 2016-10-28 | A kind of entity decorative board and preparation method thereof and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610966955.1A CN106495622B (en) | 2016-10-28 | 2016-10-28 | A kind of entity decorative board and preparation method thereof and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106495622A CN106495622A (en) | 2017-03-15 |
| CN106495622B true CN106495622B (en) | 2018-10-12 |
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| CN201610966955.1A Expired - Fee Related CN106495622B (en) | 2016-10-28 | 2016-10-28 | A kind of entity decorative board and preparation method thereof and application |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1742661A (en) * | 2004-08-30 | 2006-03-08 | 江皓 | Lopolith bath for processing stone and using method |
| CN101250052A (en) * | 2007-11-15 | 2008-08-27 | 张宇成 | Covering of composite plate having air purification function |
| CN101391203A (en) * | 2007-09-21 | 2009-03-25 | 叶正涛 | Compound powder capable of releasing negative ion with high efficiency and adhesive material thereof |
| CN104211325A (en) * | 2014-08-25 | 2014-12-17 | 北京太和洁源科技发展有限公司 | Asphalt concrete |
| CN106013683A (en) * | 2016-07-11 | 2016-10-12 | 中民筑友科技投资有限公司 | Decorative layer for brown high-strength concrete decorative hanging plate |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060157676A1 (en) * | 2005-01-14 | 2006-07-20 | Zaxxon Usa, Inc. | Ionic or ion-generating floor covering and method for embedding ion particles within a floor covering |
-
2016
- 2016-10-28 CN CN201610966955.1A patent/CN106495622B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1742661A (en) * | 2004-08-30 | 2006-03-08 | 江皓 | Lopolith bath for processing stone and using method |
| CN101391203A (en) * | 2007-09-21 | 2009-03-25 | 叶正涛 | Compound powder capable of releasing negative ion with high efficiency and adhesive material thereof |
| CN101250052A (en) * | 2007-11-15 | 2008-08-27 | 张宇成 | Covering of composite plate having air purification function |
| CN104211325A (en) * | 2014-08-25 | 2014-12-17 | 北京太和洁源科技发展有限公司 | Asphalt concrete |
| CN106013683A (en) * | 2016-07-11 | 2016-10-12 | 中民筑友科技投资有限公司 | Decorative layer for brown high-strength concrete decorative hanging plate |
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| CN106495622A (en) | 2017-03-15 |
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