CN106489969A - A kind of containing chlorine fluorine cyanogen insect amide and the Pesticidal combination of HEXAFLUMURON - Google Patents
A kind of containing chlorine fluorine cyanogen insect amide and the Pesticidal combination of HEXAFLUMURON Download PDFInfo
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- CN106489969A CN106489969A CN201610903506.2A CN201610903506A CN106489969A CN 106489969 A CN106489969 A CN 106489969A CN 201610903506 A CN201610903506 A CN 201610903506A CN 106489969 A CN106489969 A CN 106489969A
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- Prior art keywords
- hexaflumuron
- chlorine fluorine
- insect amide
- cyanogen insect
- fluorine cyanogen
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
Abstract
The present invention relates to a kind of composition pesticide comprising chlorine fluorine cyanogen insect amide and HEXAFLUMURON, the composition pesticide active component includes chlorine fluorine cyanogen insect amide and HEXAFLUMURON, and wherein, the weight ratio of chlorine fluorine cyanogen insect amide and HEXAFLUMURON is 1:50‑50:1, preferably 1:20‑20:1.Mutually act synergistically between the two kinds of active components of the composition of the present invention, prevention effect can be improved from each other, reduce Pesticide use amount, and environmentally safe, it is worthy of popularization.
Description
Technical field
The present invention relates to agriculture field, and in particular to a kind of Pesticidal combination, particularly a kind of containing chlorine fluorine
The Pesticidal combination and its application of cyanogen insect amide and HEXAFLUMURON.
Background technology
As the expansion of planting scale, the application of chemical prevention agricultural pests are more and more, the agricultural pests for bringing therewith
Resistance problem evolves as global problem.With agricultural pests chemical prevention medication history prolongation, science does not make agricultural chemicals
With etc. factor impact, in recent years, agricultural pests resistance is increasingly serious, produce resistance pest species persistently increasing, especially
It is the Lepidoptera class pest for easily producing resistance, resistance level is higher, and resistance development speed is relatively fast.Agriculture chemical compounding is mixed
The features such as with insecticidal spectrum is expanded, pest resistance and the resistance to the action of a drug is delayed, be to solve the problems, such as that pest resistance is more effectively square
One of method.Therefore, efficient, low toxicity, the Pesticidal combination of environmental protection are researched and developed, to agricultural sustainable development, there is positive effect.
Chlorine fluorine cyanogen insect amide（ZJ4042, Cas.NO：1262605-53-7）It is the adjacent benzene of Zhejiang Provincial Chemical Engineering Research Inst development
Diformamide insecticides, are the unique novel pesticides of a kind of efficient, low toxicity and mechanism of action, and which acts on insect ryania
Acceptor, promotes the endogenous calcium ion release of insect cell, affects contraction of muscle, and then cause insect death；To Lepidoptera, elytrum
The larva of mesh, Diptera and Homoptera has very high activity, but main effect model is based on stomach toxicity, with certain interior suction
Property, can be used for the primary pest preventing and treating of paddy rice, vegetables, fruit tree, cotton.
HEXAFLUMURON（Cas.NO：86479-06-3）It is acyl group urea insecticide, is killed by suppressing insect chitin synthesis
Dead insect, with insecticidal activity is high, insecticidal spectrum compared with wide, knock down power strong the features such as.Especially noctuidae pests work well, to mite without
Effect.Knock down power strong, insecticidal effect is rapider than other acylureas, with higher contact ovicidal activity, alone can also can use with.
Dispenser period requires strictly, to prevent and treat the insect for having produced organophosphor and pyrethroid resistance.
Recently as the adjustment of pattern of farming, the popularization of vegetables, corn, peanut and booth equipment so that lepidopterous
Insect generation is more and more, and generation generation is more and more chaotic, and damage to crops is more, Harm period is longer, and easily wildness is caused disaster.In advance
Survey forecast and there is very big difficulty, therefore chemical prevention becomes main means of prevention, substantially based on " seeing that worm is gone and buy Chinese medicine ", from
And cause control of insect when worm age generally bigger than normal, difficulty of prevention and cure is also more.Therefore, develop rational Pesticidal composition, delay insect
Resistance development is the problem of primary solution at present.The mixture of different pesticide species, be the agriculture resistance disease of preventing and treating, worm, crop smothering normal
Square method.Screened by formulation of pesticide, filter out rational formula, actual prevention effect can be effectively improved, reduce dosage, drop
Low cost, delays the generation of disease drug resistance, is disease, worm, the important means of the crop smothering comprehensive regulation.
Content of the invention
The present invention seeks to providing a kind of desinsection group containing chlorine fluorine cyanogen insect amide Yu HEXAFLUMURON for above-mentioned weak point
Compound.
The present inventor have passed through long-term research, and be found surprisingly that on the basis of many experiments, by chlorine fluorine cyanogen worm acyl
Amine with hexaflumuron compounded after, produce synergistic function, can effectively prevent and treat agricultural pests, especially lepidoptera pest, such as tiltedly
Autographa spp, beet armyworm, cabbage caterpillar, diamondback moth etc., and can effectively delay pest resistance to develop.
Therefore, the technical problem to be solved is to provide one kind and can effectively prevent and treat agricultural pests, delay insect
The Synergistic composition of development of drug resistance.
In order to solve the above problems, the present invention adopts following technical scheme：
One object of the present invention is to provide a kind of Pesticidal combination containing chlorine fluorine cyanogen insect amide Yu HEXAFLUMURON, and its feature exists
In the Pesticidal combination contains active component for chlorine fluorine cyanogen insect amide and HEXAFLUMURON.
In the Pesticidal combination, chlorine fluorine cyanogen insect amide is 50 with the weight ratio of HEXAFLUMURON:1-1:50th, preferably 20:1-
1:20
The Pesticidal combination is re-dubbed the formulation that allow on agricultural chemicals with known auxiliary agent and excipient：Can for example be missible oil,
Wettable powder, water dispersible granules, suspending agent, aqueous emulsion, microemulsion, suspension emulsion, dispersible in oil-suspending agent, microcapsule suspending agent
Any one.Various compounds and/or reagent used by the present invention are commercially available, easily can buy from the market.
Beneficial effects of the present invention show：
A, synergistic effect substantially, to lepidoptera pest prevention effect significantly, overcome the shortcoming of each single dose.
B, proper control time are complementary, are more beneficial for the controlling mode of " seeing that worm is got rid of intestinal parasites by means of drugs "：Chlorine fluorine cyanogen insect amide has the lasting period long
The characteristics of, so the period of being suitable for width, has good killing effect to low age worm and high instar larvae；HEXAFLUMURON is 2-3 days after medicine
Just effective to larva, both are mixed to play good complementation.
C, the generation for having delayed resistance：Both mechanisms of action and the mode of action are entirely different, to low age and height after combination
Instar larvae has good killing action, so as to delay the generation of resistance.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, present invention specific examples below
Illustrate, but the present invention is limited to absolutely not these examples.Described below is only the present invention preferably embodiment, is used only for explaining
The present invention, but can not be therefore understands that being the restriction to the scope of the claims of the present invention.It should be pointed out that all the present invention spirit and
Any modification, equivalent or improvement for being made within principle etc., should be included within the scope of the present invention, therefore,
The protection domain of patent of the present invention should be defined by claims.
First, example of formulations
+ 7% HEXAFLUMURON of 1 7% chlorine fluorine cyanogen insect amide of embodiment dispersibles oil-suspending agent
Chlorine fluorine cyanogen insect amide 7%
HEXAFLUMURON 7%
Calcium dodecyl benzene sulfonate 10%
Castor oil polyoxyethylene ether 5%
OPEO 5%
Organobentonite 3%
Methyl oleate polishing is to 100%
Said composition dispersibles the concrete procedure of processing of oil-suspending agent：Above-mentioned formula is pressed by oil and dispersant, thickener, emulsification
Agent mixes, and is well mixed through high speed shear, adds chlorine fluorine cyanogen insect amide and HEXAFLUMURON, continues shearing and mixes, subsequently into horizontal
Grind in sand mill, preparation particle diameter is made all in below 10UM, be obtained of the present invention containing chlorine fluorine cyanogen insect amide and fluorine bell
Urea dispersibles oil-suspending agent.
+ 1% HEXAFLUMURON of 2 20% chlorine fluorine cyanogen insect amide of embodiment dispersibles oil-suspending agent
Chlorine fluorine cyanogen insect amide 20%
HEXAFLUMURON 1%
Calcium dodecyl benzene sulfonate 20%
Castor oil polyoxyethylene ether 6%
AEO 4%
Organobentonite 3%
Methyl oleate polishing is to 100%
Said composition dispersibles the concrete procedure of processing of oil-suspending agent：Above-mentioned formula is pressed by oil and dispersant, thickener, emulsification
Agent mixes, and is well mixed through high speed shear, adds chlorine fluorine cyanogen insect amide and HEXAFLUMURON, continues shearing and mixes, subsequently into horizontal
Grind in sand mill, preparation particle diameter is made all in below 10UM, be obtained of the present invention containing chlorine fluorine cyanogen insect amide and fluorine bell
Urea dispersibles oil-suspending agent.
+ 1% 5 percent of hexaflumuron emulsifiable concentrate of 3 5% chlorine fluorine cyanogen insect amide of embodiment
Chlorine fluorine cyanogen insect amide 5%
HEXAFLUMURON 1%
Cyclohexanone 5%
Dimethylformamide 5%
Calcium dodecyl benzene sulfonate 3%
AEO 4%
Castor oil polyoxyethylene ether 4%
Solvent naphtha complementary
Said composition dispersibles the concrete procedure of processing of oil-suspending agent：Above-mentioned formula is pressed by solvent naphtha and cyclohexanone, dimethyl
Formamide mixes, and adds chlorine fluorine cyanogen insect amide, HEXAFLUMURON to be allowed to be completely dissolved afterwards, is subsequently adding emulsifier for mixing uniformly, system
Obtain the missible oil containing chlorine fluorine cyanogen insect amide and HEXAFLUMURON of the present invention.
+ 5% HEXAFLUMURON suspending agent of 4 1% chlorine fluorine cyanogen insect amide of embodiment
Chlorine fluorine cyanogen insect amide 1%
HEXAFLUMURON 5%
Neopelex 3%
Sodium methylene bis-naphthalene sulfonate 4%
Xanthans 1%
Propane diols 4%
Defoamer 1%
Water polishing is to 100%
The concrete procedure of processing of said composition suspending agent is：By in above-mentioned formula by water and wetting agent, dispersant, thickener, anti-
Freeze agent and defoamer mixing, be well mixed through high speed shear, add chlorine fluorine cyanogen insect amide and HEXAFLUMURON, continue shearing and mix,
Grind subsequently in horizontal sand mill, preparation particle diameter is made all in below 5UM, be obtained of the present invention containing chlorine fluorine cyanogen worm
Acid amides and the suspending agent of HEXAFLUMURON.
+ 1% HEXAFLUMURON wettable powder of 5 50% chlorine fluorine cyanogen insect amide of embodiment
Chlorine fluorine cyanogen insect amide 50%
HEXAFLUMURON 1%
Lauryl sodium sulfate 5%
Sodium methylene bis-naphthalene sulfonate 5%
Sodium lignin sulfonate 8%
Precipitated calcium carbonate polishing is to 100%
The concrete procedure of processing of said composition wettable powder is：And divide chlorine fluorine cyanogen insect amide and HEXAFLUMURON by above-mentioned formula
The mixing of powder, wetting agent and filler, uniform stirring in stirred tank are well mixed after air-flow crushing, you can the present invention is obtained
The described wettable powder containing chlorine fluorine cyanogen insect amide and HEXAFLUMURON.
+ 50% HEXAFLUMURON wettable powder of 6 1% chlorine fluorine cyanogen insect amide of embodiment
Chlorine fluorine cyanogen insect amide 1%
HEXAFLUMURON 50%
Lauryl sodium sulfate 5%
Sodium methylene bis-naphthalene sulfonate 5%
Sodium lignin sulfonate 8%
Polycarboxylate 3%
Precipitated calcium carbonate polishing is to 100%
The concrete procedure of processing of said composition wettable powder is：And divide chlorine fluorine cyanogen insect amide and HEXAFLUMURON by above-mentioned formula
The mixing of powder, wetting agent and filler, uniform stirring in stirred tank are well mixed after air-flow crushing, you can the present invention is obtained
The described wettable powder containing chlorine fluorine cyanogen insect amide and HEXAFLUMURON.
+ 20% HEXAFLUMURON suspending agent of 7 1% chlorine fluorine cyanogen insect amide of embodiment
Chlorine fluorine cyanogen insect amide 1%
HEXAFLUMURON 20%
Neopelex 4%
Sodium methylene bis-naphthalene sulfonate 4%
Xanthans 1%
Propane diols 4%
Defoamer 1%
Water polishing is to 100%
The concrete procedure of processing of said composition suspending agent is：By in above-mentioned formula by water and wetting agent, dispersant, thickener, anti-
Freeze agent and defoamer mixing, be well mixed through high speed shear, add chlorine fluorine cyanogen insect amide and HEXAFLUMURON, continue shearing and mix,
Grind subsequently in horizontal sand mill, preparation particle diameter is made all in below 5UM, be obtained of the present invention containing chlorine fluorine cyanogen worm
Acid amides and the suspending agent of HEXAFLUMURON.
+ 4% 5 percent of hexaflumuron emulsifiable concentrate of 8 6% chlorine fluorine cyanogen insect amide of embodiment
Chlorine fluorine cyanogen insect amide 6%
HEXAFLUMURON 4%
Cyclohexanone 5%
Dimethylformamide 5%
Calcium dodecyl benzene sulfonate 3%
AEO 4%
OPEO 5%
Castor oil polyoxyethylene ether 4%
Solvent naphtha complementary
Said composition dispersibles the concrete procedure of processing of oil-suspending agent：Above-mentioned formula is pressed by solvent naphtha and cyclohexanone, dimethyl
Formamide mixes, and adds chlorine fluorine cyanogen insect amide, HEXAFLUMURON to be allowed to be completely dissolved afterwards, is subsequently adding emulsifier for mixing uniformly, system
Obtain the missible oil containing chlorine fluorine cyanogen insect amide and HEXAFLUMURON of the present invention.
2nd, Assays Example
1st, Toxicity Determination
For understanding chlorine fluorine cyanogen insect amide and definite virulence of the HEXAFLUMURON mixture composition to wild cabbage prodenia litura, indoor poison is first passed through
Power is determined is screened for its proportioning, clear and definite two kinds of medicaments compound by a certain percentage after co-toxicity coefficient（CTC）, CTC ＜
80 is antagonism, and 80≤CTC≤120 are summation action, and CTC ＞ 120 are synergistic effect.
Concrete test method：The mother liquor of each mixed agent is diluted to five series concentrations respectively, is respectively placed in standby in beaker
With.Using the method that first leaching leaf is followed by worm, the blade of the same size not in contact with any medicament is put in the liquid for having configured
Immersion 5s, dries after taking-up naturally, is put in insect box, then connects for examination larva, raises under the conditions of 26 DEG C, each process
Be repeated 3 times, repeat test worm number used every time for 50, while setting blank, after 72h, check dead borer population, calculate the death rate and
Corrected mortality, tries to achieve virulence regression equation and calculates LC50Value.If the control death rate is considered as invalid test more than 10%.Meter
Calculate formula as follows：
The death rate（%）=（Borer population living after borer population medicine living before medicine）Borer population × 100 living before/medicine
Corrected mortality（%）=（The treatment group mortality rate control group death rate）/（The 1 control group death rate）×100
Insect corrected mortality is converted into probit value（y）, concentration for the treatment of（μg/ml）It is converted into logarithm value（x）, with least square
Method draws virulence regression equation, and thus calculates the LC of every kind of medicament50Value.Co-toxicity coefficient is calculated according to the abundant equations of Sun Yun
CTC.Computing formula is as follows（With chlorine fluorine cyanogen insect amide as standard agent, its toxicity index is 100）：
The toxicity index of HEXAFLUMURON（TI）The LC of=chlorine fluorine cyanogen insect amide50The LC of HEXAFLUMURON50×100
The actual toxicity index of M（ATI）The LC of=chlorine fluorine cyanogen insect amide50The LC of M50×100
The theoretical toxicity index of M（TTI）TI × the P of=chlorine fluorine cyanogen insect amideChlorine fluorine cyanogen insect amideTI × the P of+HEXAFLUMURONHEXAFLUMURON
Co-toxicity coefficient（CTC）TTI × 100 of the ATI M of=M
In formula：M is the mixture of chlorine fluorine cyanogen insect amide and HEXAFLUMURON different ratio
PHEXAFLUMURONFor the shared ratio in mixture of HEXAFLUMURON
PChlorine fluorine cyanogen insect amideFor the ratio that chlorine fluorine cyanogen insect amide is accounted in mixture
For trying insect：Wild cabbage prodenia litura
Test medicine is provided by Foshan Brightmart Crop Science Co., Ltd..Experimental design：Chlorine fluorine is determined through pilot study
Cyanogen insect amide and HEXAFLUMURON active compound and effective lethasl concentration scope of the two different ratio mixture.Experimental result such as following table：
As can be seen from Table 1, chlorine fluorine cyanogen insect amide and HEXAFLUMURON are 1:50-50:Preventing and treating in the range of 1 to wild cabbage prodenia litura
Synergistic function is shown, wherein, when both proportionings are 1:20-20:In the range of 1, the preventing and treating to wild cabbage prodenia litura is common
, more than 200, synergistic function is more notable for malicious coefficient.
3rd, field control effectiveness test
Experiment process：This experiment separately designs two dosings according to the difference of each composition, and dosing is active ingredient
The quality of chlorine fluorine cyanogen insect amide and HEXAFLUMURON and.Comparison medicament is 20% chlorine fluorine cyanogen insect amide suspending agent and 20% HEXAFLUMURON suspending agent
And blank clean water experiment.
Test method：Each plot area is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating and prevent and treat before dispenser
Method is 5 points of grab sample in the test process area, carries out insect population investigation according to national field test relevant criterion, calculates preventive effect.
Result of the test such as following table：
From table 2, field control effectiveness test result shows, chlorine fluorine cyanogen insect amide and hexaflumuron compounded after can effectively prevent and treat wild cabbage
There is obvious synergistic function, preventive effect to be above chlorine fluorine cyanogen insect amide single dose and fluorine for prodenia litura, the composition of the present invention
Bell urea single dose, illustrates that the composition pesticide of the present invention can prevent and treat wild cabbage prodenia litura well, reduces dosage, reduces cost,
Delay the drug-fast generation of prodenia litura, reduce the pollution to environment.To sum up, composition pesticide of the invention is worth in production
Upper popularization and application.
Claims (7)
1. a kind of composition pesticide, it is characterised in that active component includes chlorine fluorine cyanogen insect amide and HEXAFLUMURON.
2. composition pesticide according to claim 1, it is characterised in that the weight of the chlorine fluorine cyanogen insect amide and HEXAFLUMURON
Than for 1:50-50:1.
3. composition pesticide according to claim 2, it is characterised in that the weight of the chlorine fluorine cyanogen insect amide and HEXAFLUMURON
Than for 1:20-20:1.
4. described Pesticidal combination is required according to any one of claims 1 to 3, it is characterised in that the Pesticidal combination
It is aided with insecticidal preparation processing auxiliary element and is processed into any one formulation for being suitable for agriculturally using.
5. Pesticidal combination according to claim 4, it is characterised in that the formulation of the pesticide combination is suspending agent, water
In emulsion, microemulsion, missible oil, wettable powder, microcapsule suspending agent, water dispersible granules, solvable pulvis, soluble granule any one.
6. Pesticidal combination according to any one of Claims 1 to 5 claim is used for the use for preventing and kill off crop pests
On the way.
7. purposes according to claim 6, it is characterised in that the crop pests are preferably prodenia litura.
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| CN201610903506.2A CN106489969B (en) | 2016-10-17 | 2016-10-17 | A kind of Pesticidal combination of containing chlorine fluorine cyanogen insect amide and flubenzuron |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108184884A (en) * | 2018-02-28 | 2018-06-22 | 佛山市海力盈生物科技有限公司 | A kind of composition pesticide containing bromine cyanogen insect amide and flubenzuron |
| CN115299453A (en) * | 2021-06-25 | 2022-11-08 | 华南农业大学 | Application of Fatostatin as synergist of insect growth regulator in preparing insecticide |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105325438A (en) * | 2014-08-07 | 2016-02-17 | 江苏龙灯化学有限公司 | Insecticidal composition containing cyhalodiamide and lufenuron |
| CN106577709A (en) * | 2015-10-20 | 2017-04-26 | 浙江省化工研究院有限公司 | Pesticide compound containing cyhalodiamide and hexaflumuron |
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2016
- 2016-10-17 CN CN201610903506.2A patent/CN106489969B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105325438A (en) * | 2014-08-07 | 2016-02-17 | 江苏龙灯化学有限公司 | Insecticidal composition containing cyhalodiamide and lufenuron |
| CN106577709A (en) * | 2015-10-20 | 2017-04-26 | 浙江省化工研究院有限公司 | Pesticide compound containing cyhalodiamide and hexaflumuron |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108184884A (en) * | 2018-02-28 | 2018-06-22 | 佛山市海力盈生物科技有限公司 | A kind of composition pesticide containing bromine cyanogen insect amide and flubenzuron |
| CN115299453A (en) * | 2021-06-25 | 2022-11-08 | 华南农业大学 | Application of Fatostatin as synergist of insect growth regulator in preparing insecticide |
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