CN106489939A - A kind of surfactant containing terpene compound and application thereof - Google Patents
A kind of surfactant containing terpene compound and application thereof Download PDFInfo
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- CN106489939A CN106489939A CN201610815163.4A CN201610815163A CN106489939A CN 106489939 A CN106489939 A CN 106489939A CN 201610815163 A CN201610815163 A CN 201610815163A CN 106489939 A CN106489939 A CN 106489939A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N27/00—Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/04—Oxygen or sulfur attached to an aliphatic side-chain of a carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/06—Oxygen or sulfur directly attached to a cycloaliphatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aliphatically bound aldehyde or keto groups, or thio analogues thereof; Derivatives thereof, e.g. acetals
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N49/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds containing the group, wherein m+n>=1, both X together may also mean —Y— or a direct carbon-to-carbon bond, and the carbon atoms marked with an asterisk are not part of any ring system other than that which may be formed by the atoms X, the carbon atoms in square brackets being part of any acyclic or cyclic structure, or the group, wherein A means a carbon atom or Y, n>=0, and not more than one of these carbon atoms being a member of the same ring system, e.g. juvenile insect hormones or mimics thereof
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- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Wood Science & Technology (AREA)
- Agronomy & Crop Science (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Insects & Arthropods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of surfactant, and the surfactant includes that agricultural surfactant, terpene compound and solvent, the mass percent shared by each component are：Agricultural surfactant 1～83%；Terpene compound 0.2～48%；Solvent 0～20%.The surfactant that the present invention is provided can significantly improve the bad smell of most of agricultural chemicals, improve agricultural chemicals dispenser environment, it is provided simultaneously with good compatibility, can be mixed by any ratio with agricultural chemicals, and pesticide activity component dispersion stabilization in aqueous can be improved, improve wetting, the infiltration spreading property of spray liquor, and anti-volatilization, the anti-drift performance of spraying droplet, delay or solve the resistance problem of pesticide activity component, extend the life cycle of pesticide activity component.
Description
Technical field
The present invention relates to agriculture field, more particularly to a kind of surfactant containing terpene compound component and its use
On the way.
Background technology
Agricultural agent is typically the material of some more inert fractions, is added in pesticidal preparations product and can change agricultural chemicals
Surface tension between spray droplet and plant leaf surface, is preferably soaked, spread and permeance property, so as to improve agricultural chemicals medicine
Effect.
Agricultural agent can be divided into activated form auxiliary agent and practical two big class of adjustment type auxiliary agent.Wherein activated form auxiliary agent occupies whole
The 80% or so of the individual agricultural agent market share, mainly include surfactant, oil-type adjuvant and ammonium fertilizer etc..Practical adjustment type is helped
Agent then includes compatibility agent, deposition agent, anti-drift agent, defoamer, water modifier etc..Agricultural agent is mainly used in herbicide products,
Next to that bactericide, agrochemical.
From the sixties in last century, people to find that and can reduce herbicide and spray using surfactant and oil-type adjuvant
The consumption for spilling liquid improves blade face to spraying the absorption of liquid.Thereafter, in the case where agricultural chemicals manufacturer recommends energetically and promotes, promote and help
The research and development of agent, and developed rapidly and widely applied.To the nineties, people more notice the physicochemical property of agricultural chemicals and
Requirement of the biologically active to additive performance is different.Therefore, external several big agro-chemical companies (such as Jie Likang, rom-Haas,
Du Pont, BASF, Bayer, Meng Shan is etc.) and the auxiliary agent of oneself is all developed, as the complementation of their Pesticidal products.In some situations
Under, the auxiliary agent that uses actually is suitable only for the mixed product of bucket of certain Pesticidal products.The growth and application of more reliable auxiliary agent
Be derived from market constantly expanding use, research, the exploitation of product, the report to achievement and popularization in science.Due to auxiliary agent
Effect be so numerous and also be changeable, therefore actually each company be merely able to exploitation and our company's Pesticidal products phase
Closing, helpful and supporting special assistant.
External agro-chemical companies attach great importance to the application and development and research of auxiliary agent, and produce with a series of of various performances
Product such as has the usage of corresponding tank-mix adjuvants on herbicide label；Pesticide new product is being released while also releasing matched
Tank-mix adjuvants.Foreign countries are mixed into particularly common using bucket in auxiliary agent use.
In China's auxiliary agent using mainly adding in preparation processing formula, purpose is mainly satisfaction and improves formulation physics and chemistry
Can such as emulsify, suspend, requirement and the drug effect such as spread, freeze proof, froth breaking and heat storage stability.To the application and development of tank-mix adjuvants and grind
Study carefully seldom, kind is also few, usage amount is few and carries larger blindness, causes some preparation drug effects bad, it is difficult in market
Upper competition.
In recent years, many factors also become the main drive of agricultural agent market growth, the convenience that for example applies, elder generation
The increase of production measure, creative product, convenience and the disease pest infringement entered.
Such as China's agricultural production is to intensive, mechanization makes the transition, and the occupation mode of Agrotechnical formulation also there occurs significantly
Change.Insecticide-applying way gradually change to mechanization spraying or even unmanned plane dispenser from manually being sprayed, pesticides packaging also by
Independent small dimension packaging gradually changes to high-capacity packaging, to raise labour productivity.Thus, spray pattern transformation is generated
Transformation to pesticidal preparations formula and its auxiliary agent quality requirements is correspondingly proposed.Develop and use and be suitable for the agricultural of new spray pattern
Additives Products seem very urgent.
At the same time, with the day by day raising of environmental protection requirement, the original agricultural agent kind in part is because having to environment
Long-term illeffects and gradually prohibitted the use of by every country or limit use.Typical such as nonyl phenol ethoxy compound class
Auxiliary agent is disabled, because which is in the environment being once discharged into, can exist for a long time in the environment, and can enter food
Chain, and amplified by food chain step by step.Meanwhile, after also there is the effect of simulation estrogen to enter biology in vivo for it, Jiu Huiying
Ring the normal reproduction of organism and development.Thus, use from now on will be that toxicity is lower, Environmental compatibility more preferably, properties
More prominent environment-friendly agricultural agent kind.
Terpene compound refers generally to formula for (C5H8) n chain or cyclic olefin.Such compound is that a class is extensive
The natural origin hydrocarbon being present in plant body, can obtain from many plants, particularly coniferous tree, it is also possible to from ocean
Biological extraction in vivo.As the ramie in lemon oil, the australene in turpentine oil, nopinene all belong to such.Terpenes is generally lighter than water
Colourless liquid, with fragrance.Water is insoluble or poorly soluble in, ethanol is soluble in.Its oxygenatedchemicals such as citral, menthol is (thin
Lotus alcohol), camphor etc. be all important industrial chemicals and spices, there is in paint industry extensive use.Terpenes can be by some appearances
The raw material of industry for easily obtaining is artificial synthesized.According to statistics, the sum of the terpenoid being currently known has exceeded 22000 kinds.A lot
Terpenoid has important physiologically active, is the important sources for studying natural products and developing new drug.
Terpenoid has the physiologically active of many, such as eliminating the phlegm, cough-relieving, wind dispelling, sweating, expelling parasite, analgesia.And natural terpene
There is ene compound the fragrant pungent smell of stronger volatilization more, therefore be commonly used in spices and food additives.Such as a kind of entitled method
The terpene substances of Buddhist nun's alcohol, are one of constituents in rose oil, while which has played the role of juvenile hormone to insect larvae, resistance
Its pupa is hindered to sprout wings；And for example α-santalol and β-santalol are a kind of sesquiterpenoids being present in sandalwood oil, are
The maximum contribution thing of santal fragrance is provided, equally there is certain anthelmintic action；Additionally, also valencia Orange alkene, nootkatone,
α-and β-vetivone, and the terpenoid such as khusimone is a part for natural essence spices.
But application of the above-mentioned terpenoid in agricultural production is seldom, the application in agricultural agent is less.Such
Compound is natural, there is certain fragrance and itself also has certain desinsection, biocidal efficacies.Show through checking test, should
Class compound is used as the bad smell that the active matter of agricultural agent not only can significantly improve most of agricultural chemicals, improves agricultural chemicals dispenser
Environment, and effect of the medication in agricultural production can be significantly improved.
Content of the invention
In view of this, the present invention provides a kind of surfactant containing terpene compound component and application thereof, the table
Comprising terpene compound component in the activating agent of face, cosurfactant and solvent is still further comprised.
The present invention provide surfactant each component mass percent be：
Agricultural surfactant：1～83%；
Terpene compound：0.2～48%；
Solvent：0～20%.
Described terpene compound includes half terpene, monoterpenes, sesquiterpenoids, Diterpenes, sesterterpenoids, triterpene
One or more in class, tetraterpenes, poly terpene.
Preferably, the terpene compound is one or more in monoterpenes or sesquiterpenoids.
Described monoterpenes include chain monoterpene, monocyclic monoterpene, Tropolones, bicyclic diterpene.
The choosing of chain monoterpenes includes but is not limited to geranial (α-citral), citronellal, neral (neral), spiceleaf
Alcohol (geraniol), nerol, citronellol, laurene, ocimenum, alloocimene, linalool, dihydromyrcenol, citral
In one kind.
Monocyclic monoterpene includes but is not limited to Menthol, terpinol, carveol, menthol, limonene, menthene, pine
Oily alkene, α-ionone, cantharidine, alpha, beta-lonone, spot huge legendary turtle amine, peaceful alkene, perillaldehyde, carvol, menthones, perilla ketone, water
One kind in celery aldehyde.
It is a kind of that Tropolones includes but is not limited to α-arborvitae element, β-arborvitae element (chamaecin), gamma-thujaplicin.
Bicyclic diterpene class include but is not limited to camphor, 1- borneol, d- borneol, to oxycamphor, π-oxycamphor, Chinese herbaceous peony
Glycosides, aucubin, catalposide, Mentzeloside, decaloside, loganin, asperuloside, cloves ether glycosides,
Loniceroside, gentiamarin, foliamenthin, ligstroside, gentapicrin, Sylvestroside-III,
GI-3, smelly ant lactone, neomatatabiol, gempin, rough gentian lactone, plumericin, oruwacin, firpene, pinocarveol, peach
One kind in golden ma's enol.
The sesquiterpenoids includes but is not limited to acyclic sesquiterpene, ring-type sequiterpene, analog derivative difficult to understand, bicyclic sequiterpene.
Acyclic sesquiterpene includes but is not limited to the one kind in α-farnesene, β-farnesene, fanesol.
Ring-type sequiterpene includes but is not limited to qinghaosu, Artemtherin, yingzhaosu A, wormwood artemisia A prime, dihydroartemisinine, wormwood artemisia
One kind in methyl ether, artesunic acid monoester, Bisabolane, turmerone, α-humulene, germacrone, α-santonin.
Analog derivative choosing difficult to understand includes being not limited to guaiaci lignum, guaiol, 2,4- dimethyl -7- isopropyls, Herba Lycopi's hardship
One kind in lactone, eupachlorin, snow lotus of big bud lactones.
Bicyclic sequiterpene includes but is not limited to Nootkatone, carypohyllene, santalol, Patchoulicalcohol, eucalyptol, atractylone, cotton
One kind in phenol.
Described sesquiterpenoids can also from but be not limited to maliane, aristolane, aromadendrane, guainane,
Eudesmane, valerane, eremophilane, humulane, caryophyllane, illudane, proto-illudane, hirsutane,
Marasmene, bisabolane, santalane, bergamot alkane, acorane, himachalane, Chamigrane, thujopsane, Widdrane, flower
Thujane, laurane, Trichothecane, cadinane, cubeb alkane, Yilan alkane, himachalane, longifolane,
longifolane、longipinane、sativane、capane.
Described agricultural surfactant includes but is not limited to polyethenoxy ether class, Sulfonates, sulfuric acid ester, siliceous table
Face activating agent, perfluorinated surfactant, alkyl polyglycoside, phosphoric acid ester, alkanolamide class, polyalcohols, cation surface activating
Agent.
Wherein, polyethenoxy ether class includes but is not limited to AEO, APES, aliphatic acid
APEO, aliphatic amine polyoxyethylene ether, alkoxy polyoxy ethers, alkanolamide polyethenoxy ether class, fatty acid ester
Polyethenoxy ether class, fatty acid methyl ester ethoxylate, castor oil oxirane and derivative, castor oil expoxy propane and
One or more in derivative, rosin acid oxirane and the like.
Sulfonates includes but is not limited to alkyl ether carboxy acid salt, alkylbenzenesulfonate, alkylsulfonate, alpha-alkene sulfonate
(AOS), fatty acid ester α-sulfonate, fatty acyl-oxygen ethylsulfonic acid sodium, fatty acid amide taurine salt, amber acid ester sulfonate
One or more in class, naphthalene formaldehyde sulfonates, alkyl naphthalene sulfonate.
Sulfuric acid ester includes but is not limited to alkyl sulfate, aliphatic alcohol sulfate, aliphatic acid polyethenoxy ether sulfate, fat
One or more in fat alcohol polyoxyethylene ether sulfate.
Alkanolamide class includes but is not limited to fatty diglycollic amide, fatty monoethanol amide, coconutalkyl two
One or more in glycollic amide, lauramide diethanol amine.
Polyalcohols include but is not limited to ethylene glycol fatty acid, fatty acid glyceride, sorbitan fatty acid and its
One or more in ethylene oxide adduct, sucrose ester, pentaerythritol fatty ester.
Cationic surfactant includes but is not limited to ammonium salt class, quaternary ammonium salt, amine salt, heterocyclic type, aggretion type, father-in-law's salt
One or more in type, glycine betaine, imidazoline type, amino acids, lecithin epoxy-type, amine oxide type.
Described solvent but it is not limited to water, isoamyl alcohol, isobutanol, sec-butyl alcohol, MEK, ethylene glycol monoethyl ether, diethyl two
Alcohol ether, butyl glycol ether, diethylene glycol monobutyl ether, alcohol ethers solvent, alcohol solvent of ether ester type, 2-Butoxyethyl acetate, second
Glycol ether acetate, isoamyl acetate, SCFA methyl esters, soybean oil methyl ester, palm oil methyl ester, cottonseed oil methyl esters, vegetable seed
Oily methyl esters, sunflower oil methyl esters, rosin base oil vegetable oil, peanut oil methyl esters, linseed oil methyl esters, 6# solvent naphthas, 120# solvent naphthas,
200# solvent naphthas, 150# solvent naphthas, mineral oil one or more.
Surfactant of the present invention can also further include NMF, adhesive agent, synergist, stabilizer, pH adjusting agent, fill out
Material etc..
The pH adjusting agent can be organic acid or inorganic acid, alkali, nertralizer or buffer, optimization citric acid, acetic acid, breast
Acid, sodium carbonate, potassium carbonate, hydrochloric acid, NaOH, potassium dihydrogen phosphate, sodium dihydrogen phosphate, dipotassium hydrogen phosphate, disodium hydrogen phosphate；
The stabilizer include but is not limited to ethylenediamine tetra-acetic acid, disodium ethylene diamine tetraacetate, tetrasodium ethylenediamine tetraacetate,
One or more in sodium tripolyphosphate and citric acid；
It is sub- that the NMF includes but is not limited to amino acid, PCA, sodium lactate, urea, ethoxy urea, lactic acid, dimethyl
Sulfone, certain herbaceous plants with big flowers acid glyceride, glycerol caprylate, pyrrolidone sodium carboxylate, polyalcohol, wherein polyalcohol include but is not limited to glycerine, fourth
Glycol, polyethylene glycol, propane diols, hexylene glycol, xylitol, polypropylene glycol, D-sorbite, pentanediol；
The adhesive agent include but is not limited to Arabic gum, polyethylene glycol, polyvinyl alcohol, polyvinylpyrrolidone, dextrin,
Carboxymethylcellulose calcium, sodium carboxymethyl starch, rosin, sodium sulphate, glucose, lactose, sucrose, fructose, methylcellulose, macromolecule
Polyoxyethylene, polyacrylamide；
Described filler includes but is not limited to pyrophosphate, sulfate, carbonate, urea, glucose, lactose, sucrose, really
Sugar, ammonium chloride, potassium chloride, sodium chloride.
Surfactant containing terpene compound component of the present invention is according to well known to those skilled in the art
Preparation method prepare.
The surfactant of the bright offer of this law can be added directly to used in pesticidal preparations product is filled a prescription or and pesticidal preparations
Product mix is watered Direct spraying use.
The present invention principle be：Surfactant of the present invention is by terpenoid and agricultural surfactant, molten
The components such as agent mix in proportion, make homogeneous, stable liquid, are applied in formulation of pesticide or pesticidal preparations product.The present invention
Described terpenoid is volatility oil compounds, is insoluble or poorly soluble in water, directly applies in pesticidal preparations product, sprays
Mist using when the problem that is divided into, flocculates or precipitate in a large number occurs.The hydrophilic group that the present invention is provided by agricultural surfactant
Group and kith and kin's group enable terpenoid to form homogeneous emulsion in aqueous.Terpenoid selected by the present invention
For plant source volatile compound, aromatic odor can be distributed, gained surfactant will be prepared and be used in mixed way with insecticide, one
Aspect alleviates insecticide allows the insufferable smell of people, and on the other hand which distributes special smell, to insect, there is attracting action,
Insect comes to contact, sucks or eat insecticide for induction；In addition, surfactant provided by the present invention itself is with certain
Insecticidal bioactivity, by stomach toxicity, tags, fumigates or interior suction mode, affects growing and digestive system, breathing system for insect
System, nervous system or muscle systems etc., so as to improve the insecticidal effect of insecticide, add it to formulation of pesticide or with agricultural chemicals system
Agent is used in mixed way, and can control the size of spraying droplet particle diameter, and the volatile oil constituents in surfactant can suppress water
The volatilization for dividing, improves the droplet number in Target crops unit area, so as to improve the utilization rate and preventive effect of agricultural chemicals.
Advantage of the invention is that：
1st, surfactant of the present invention can significantly improve the bad smell of most of agricultural chemicals, improve agricultural chemicals dispenser
Environment；
2nd, surfactant of the present invention is compatible good with various pesticidal preparations products, can be by arbitrarily than mixed
Close, and pesticide activity component dispersion stabilization in aqueous can be improved；
3rd, the surfactant of the present invention and pesticidal preparations product are used in mixed way, it is possible to increase the wetting of spray liquor,
Infiltration spreading property, while the anti-volatilization of spraying droplet, anti-drift performance can also be improved；
4th, surfactant of the present invention can improve the biologically active of pesticide activity component, so as to reduce drug cost, subtract
Few environmental pollution；
5th, the collective effect of surfactant of the present invention and pesticidal preparations product, can delay or solve pesticide activity component
Resistance problem, extend pesticide activity component life cycle.
Specific embodiment
Specific description is done to present aspect below by embodiment, it is necessary to it is pointed out here that be that following examples are served only for
The present invention is further described, it is impossible to be interpreted as limiting the scope of the invention, the person skilled in the art in the field
Nonessential modifications and adaptations can be made according to the present invention.
Surfactant of the embodiment 1 containing geraniol
Geraniol 0.2kg is accurately weighed, and in AEO 1.0kg to mixing kettle, turn on agitator, side are stirred
Side is heated up, and is warming up to 40 DEG C, continues stirring 30min or so, forms uniform mixture.
Surfactant of the embodiment 2 containing menthol
Menthol 15.0kg, water 8.0kg is accurately weighed, in AEO 1.0kg to mixing kettle, stirring is opened
Device, warming while stirring are warming up to 40 DEG C, continue stirring 30min or so, form uniform mixture.
Surfactant of the embodiment 3 containing guaiol
Guaiol 30.0kg, propane diols 15.0kg are accurately weighed, in AEO 1.0kg to mixing kettle,
Turn on agitator, warming while stirring are warming up to 40 DEG C, continue stirring 30min or so, form uniform mixture.
Surfactant of the embodiment 4 containing Nootkatone
Nootkatone 48.0kg, water 20.0kg are accurately weighed, and in APES 1.0kg to mixing kettle, unlatching is stirred
Device is mixed, warming while stirring is warming up to 40 DEG C, continue stirring 30min or so, form uniform mixture.
Surfactant of the embodiment 5 containing carypohyllene
Carypohyllene 0.2kg, diethylene glycol ether 8.0kg are accurately weighed, in polyoxyethylene ether amide 30.0kg to mixing kettle,
Turn on agitator, warming while stirring are warming up to 40 DEG C, continue stirring 30min or so, form uniform mixture.
Surfactant of the embodiment 6 containing citronellal
Citronellal 15.0kg is accurately weighed, and aralkyl phenol (R) APEO 30.0kg opens stirring into mixing kettle
Device, warming while stirring are warming up to 40 DEG C, continue stirring 30min or so, form uniform mixture.
Surfactant of the embodiment 7 containing sirein
Sirein30.0kg accurately weighed, ethanol 20kg, oxirane and propylene oxide block copolymer 30.0kg are to mixed
Close in kettle, turn on agitator, warming while stirring are warming up to 40 DEG C, continue stirring 30min or so, form uniform mixture
?.
Surfactant of the embodiment 8 containing neral
Accurately weigh neral 48.0kg, turpentine-based vegetable oil 15kg, castor oil oxirane 30.0kg into mixing kettle,
Turn on agitator, warming while stirring are warming up to 40 DEG C, continue stirring 30min or so, form uniform mixture.
Surfactant of the embodiment 9 containing terpinene
Terpinene 0.2kg, solvent naphtha 120#15kg, oxirane and propylene oxide block copolymer 60.0kg are accurately weighed
Into mixing kettle, turn on agitator, warming while stirring are warming up to 40 DEG C, continue stirring 30min or so, are formed uniform mixed
Compound.
Surfactant of the embodiment 10 containing yingzhaosu A
Yingzhaosu A 15.0kg, ethyl acetate 20kg are accurately weighed, in AEO 60.0kg to mixing kettle,
Turn on agitator, warming while stirring are warming up to 40 DEG C, continue stirring 30min or so, form uniform mixture.
Surfactant of the embodiment 11 containing fanesol
Fanesol 30.0kg is accurately weighed, in AEO 60.0kg to mixing kettle, turn on agitator, side
Stirring side is heated up, and is warming up to 40 DEG C, continues stirring 30min or so, forms uniform mixture.
Surfactant of the embodiment 12 containing carvol
Carvol 48.0kg, ethylene glycol monoethyl ether 8.0kg are accurately weighed, and AEO 60.0kg is to mixing kettle
In, turn on agitator, warming while stirring are warming up to 40 DEG C, continue stirring 30min or so, form uniform mixture.
Surfactant of the embodiment 13 containing asperuloside
Asperuloside 0.2kg accurately weighed, water 20.0kg, oxirane and propylene oxide block copolymer 83.0kg are to mixed
Close in kettle, turn on agitator, warming while stirring are warming up to 40 DEG C, continue stirring 30min or so, form uniform mixture
?.
Surfactant of the embodiment 14 containing santalol
Santalol 15.0kg, soy methyl ester oil 15.0kg, oxirane and propylene oxide block copolymer are accurately weighed
Into mixing kettle, turn on agitator, warming while stirring are warming up to 40 DEG C to 83.0kg, continue stirring 30min or so, are formed
Even mixture.
Surfactant of the embodiment 15 containing Nootkatone
Nootkatone 30.0kg, mineral oil 8.0kg is accurately weighed, in AEO 83.0kg to mixing kettle, is opened
Agitator is opened, warming while stirring is warming up to 40 DEG C, continue stirring 30min or so, form uniform mixture.
Surfactant of the embodiment 16 containing eucalyptol
Eucalyptol 48.0kg is accurately weighed, and in alkanolamide 83.0kg to mixing kettle, turn on agitator is risen while stirring
Temperature, is warming up to 40 DEG C, continues stirring 30min or so, forms uniform mixture.
Smell test of 17 combination application of the present invention of embodiment in Pesticidal products
After the present composition is mixed with dissimilar Pesticidal products, in the case where disturbing without environment smell, take
A certain amount of mixture is placed in beaker, and sample is evaluated.
1 present composition of table confuses the smell test result of Pesticidal products
As shown in data in table, the present composition is used in mixed way with pesticidal preparations product, can significantly improve agricultural chemicals
Bad smell, improves working environment of the operator during making up a prescription, spraying.
18 present composition of embodiment and the compatibility of pesticidal preparations product
After the present composition is mixed with dissimilar Pesticidal products, after diluting according to spray concentration, stand under normal temperature
30min, observes the problem whether dilution occurs being layered, flocculating, precipitate in a large number, evaluates the present composition and produces with pesticidal preparations
The compatibility of product.
2 present composition of table and the compatibility test result of Pesticidal products
| Pesticidal preparations product title | The present composition | Mass ratio | Extension rate | 30min phenomenons |
| Kang Kuan | Embodiment 1 | 1∶1 | 50 | Stable homogeneous emulsion |
| Rice rises | Embodiment 2 | 1∶1 | 50 | Stable homogeneous emulsion |
| Te Fuli | Embodiment 3 | 1∶1 | 50 | Stable homogeneous emulsion |
| Take enemy steady | Embodiment 4 | 1∶1 | 50 | Stable homogeneous emulsion |
| 80% alkene pyridine pymetrozine WDG | Embodiment 5 | 1∶1 | 50 | Stable homogeneous emulsion |
| 325g/L benzene first Fluoxastrobin SC | Embodiment 9 | 1∶1 | 50 | Stable homogeneous emulsion |
| Prothioconazoles | Embodiment 10 | 1∶1 | 50 | Stable homogeneous emulsion |
| 40% trifloxystrobin SC | Embodiment 12 | 1∶1 | 50 | Stable homogeneous emulsion |
| 20% mesotrione WDG | Embodiment 11 | 5∶1 | 50 | Stable homogeneous emulsion |
| 720g/L2,4-D AS | Embodiment 8 | 5∶1 | 50 | Stable homogeneous emulsion |
| 25% Tebuconazole EW | Embodiment 13 | 5∶1 | 50 | Stable homogeneous emulsion |
| 40% Prochloraz EW | Embodiment 6 | 10∶1 | 50 | Stable homogeneous emulsion |
| 21% Diacloden SC | Embodiment 14 | 10∶1 | 50 | Stable homogeneous emulsion |
| 30% 3 ring epoxiconazole SC | Embodiment 7 | 10∶1 | 50 | Stable homogeneous emulsion |
| Efficient bifenthrin | Embodiment 15 | 100∶1 | 50 | Stable homogeneous emulsion |
| 3% ethiprole ME | Embodiment 16 | 100∶1 | 50 | Stable homogeneous emulsion |
As shown in data in table, the present composition is used in mixed way with pesticidal preparations product, compatible with pesticidal preparations product
Property good, be easily separated in water with stable emulsion, and keep stable for a long time.The present composition and pesticidal preparations
Product mix spray liquid can also be placed for a long time, be not in the problems such as flocculating, precipitate, for disposable preparation in a large number not
The spray liquid being finished can be temporarily stored within container, without abandoning, reduced to waste and saved drug cost.
Impact of 19 present composition of embodiment to spray liquor performance of keeping humidity
First, spray liquid is prepared.By Pesticidal products with reference to spray concentration dilute with water, to be mixed uniform after, add in proportion
Plus the composition of a certain amount of present invention, stir stand-by.Secondly, determine.By pluck return green vegetables blade make 4cm ×
The confession examination blade of 4cm sizes, the liquid drop for producing 0.2 μ L with syringe, zero velocity is placed on blade, then in microscope
Observe under (16 times of focal lengths).The droplet on green vegetables blade face is taken pictures (interval time using Timershot image capturing softwares
For 1s), finally complete the measure to pesticide droplet evaporation time.Each test replication 3 times, is averaged respectively.Especially
It should be noted that needing the temperature and humidity of strictly controlled environment in continuous mode.
3 present composition of table confuses the volatilization time test result of Pesticidal products
20 present composition of embodiment is applied to the field test in pesticidal preparations product
The Field information of the present composition and Pesticidal products is related to the preventing and treating of disease pest and weed, according to the type of Pesticidal products
With reference to corresponding test method, specific test method is as follows：
The field test of insecticide：Suitable experimental plot is selected according to the controlling object of test medicine, selects insect pest situation consistent
Experimental plot.Little Division is carried out, plot area is 50m2, test and set treatment agent and comparison medicament, and set clear water being processed as
Blank, wherein treatment agent are the mixture of Pesticidal products and the present composition, and comparison medicament is Pesticidal products.Each
3 repetitions are processed, respectively repeats random alignment, and set clear water to be processed as blank.Before dispenser, respectively each cell is entered
Before row medicine, insect population is investigated, then spray pesticide.According to test medicine different from the residual worm amount of periodic investigation after medicine, per cell
5 points of samplings, per is looked into 5 plants, and calculates Rectifying efficacies by following formula：
The field test of herbicide：Suitable experimental plot is selected according to the controlling object of test medicine, weeds growing way is selected
Basically identical experimental plot.Little Division is carried out, plot area is 20m2, test sets treatment agent and comparison medicament, and sets clear
Water process is blank, and wherein treatment agent is the mixture of Pesticidal products and the present composition, and comparison medicament is agricultural chemicals
Product.4 repetitions of each process, respectively repeat random alignment, at 3～4 leaf phase of weeds, using knapsack sprayer dispenser.According to
According to test medicine different from periodic investigation strain preventive effect after medicine.Every time before efficacy survey, after range estimation area's preventive effect and the uniformity, per little
3 points of area's random searching, per sampling 0.25m2, investigate per the weeds radix in point, and strain calculated by following computing formula prevent
Effect：
The field test of bactericide：Suitable experimental plot is selected according to the controlling object of test medicine, selects disease basic
Consistent experimental plot.Little Division is carried out, plot area is 12m2, test sets treatment agent and comparison medicament, and sets at clear water
Manage as blank, wherein treatment agent is the mixture of Pesticidal products and the present composition, and comparison medicament is Pesticidal products.
3 repetitions of each process, respectively repeat random alignment, and using back-pack electric compression sprayer, the dispenser same day is sunny calm, record
The dispenser same day and the thereafter synoptic data of 2 weeks.According to test medicine different from the periodic investigation state of an illness after medicine.Each cell is random
Investigate at 4 points, per whole blades for investigating 2 plants, every leaf lesion area account for leaf area percentage classification record.The 7th after dispenser
Its investigation, dispenser 2 times altogether, investigating each cell disease refers to, calculate preventive effect, its Leaf grade scale is as follows：
0 grade：Disease-free spot；
1 grade：Lesion area accounts for less than the 5% of whole leaf area；
3 grades：Lesion area accounts for the 6%～10% of whole leaf area；
5 grades：Lesion area accounts for the 11%～20% of whole leaf area；
7 grades：Lesion area accounts for the 21%～40% of whole leaf area；
9 grades：Lesion area accounts for more than the 40% of whole leaf area.
The present composition is shown in table 4 below -21 from the mixed field control effectiveness test result of different Pesticidal products.
4 health width of table and insecticidal properties of the present composition to rice terrace rice leaf roller
| Numbering | Medicament title | Every mu of preparation dosage | Insecticidal effect (%) |
| Treatment group 1 | Health is wide+embodiment 1 | 10mL+10mL | 100 |
| Treatment group 2 | Health is wide+embodiment 1 | 7mL+10mL | 100 |
| Control group | Kang Kuan | 10mL | 92 |
Enemy's bactericidal property surely with the present composition to rice green smut taken by table 5
6 80% alkene pyridine pymetrozine WDG of table and insecticidal properties of the present composition to navel orange arrowhead scales
| Numbering | Medicament title | Every mu of dosage | Insecticidal effect (%) |
| Treatment group 1 | 80% alkene pyridine pymetrozine WDG+ embodiments 5 | 6g+6g | 100 |
| Treatment group 2 | 80% alkene pyridine pymetrozine WDG+ embodiments 5 | 4g+6g | 98 |
| Control group | 80% alkene pyridine pymetrozine WDG | 6g | 93 |
7 prothioconazoles of table and bactericidal property of the present composition to wheat sharp eyespot
| Numbering | Medicament title | Every mu of dosage | Bactericidal effect (%) |
| Treatment group 1 | Prothioconazoles+embodiment 10 | 10.0g+10g | 100 |
| Treatment group 2 | Prothioconazoles+embodiment 10 | 6.0g+10g | 100 |
| Control group | Prothioconazoles | 10.0g | 90 |
8 40% trifloxystrobin SC of table and bactericidal property of the present composition to apple tree brown spot
| Numbering | Medicament title | Dosage | Bactericidal effect (%) |
| Treatment group 1 | 40% trifloxystrobin SC+ embodiment 12 | 71mg/kg+71mg/kg | 100 |
| Treatment group 2 | 40% trifloxystrobin SC+ embodiment 12 | 35mg/kg+71mg/kg | 96 |
| Control group | 40% trifloxystrobin SC | 71mg/kg | 87 |
9 21% Diacloden SC of table and insecticidal properties of the present composition to phyllocnistis citrella stainton
| Numbering | Medicament title | Every mu of dosage | Insecticidal effect (%) |
| Treatment group 1 | 21% Diacloden SC+ embodiments 14 | 4g+0.4g | 98 |
| Treatment group 2 | 21% Diacloden SC+ embodiments 14 | 3g+0.4g | 82 |
| Control group | 21% Diacloden SC | 4g | 78 |
10 Te Fuli of table and insecticidal properties of the present composition to cotton aphid
| Numbering | Medicament title | Every mu of preparation dosage | Insecticidal effect (%) |
| Treatment group 1 | Te Fuli+embodiment 3 | 20mL+20mL | 100 |
| Treatment group 2 | Te Fuli+embodiment 3 | 10mL+20mL | 95 |
| Control group | Te Fuli | 20mL | 86 |
11 efficient bifenthrin of table and insecticidal properties of the present composition to cockroach
12 3% ethiprole ME of table and insecticidal properties of the present composition to fly
| Numbering | Medicament title | Dosage | Insecticidal effect (%) |
| Treatment group 1 | 3% ethiprole ME+ embodiments 16 | 20 times+1600 times of dilution | 100 |
| Treatment group 2 | 3% ethiprole ME+ embodiments 16 | 40 times+1600 times of dilution | 96 |
| Control group | 3% ethiprole ME | 20 times of dilution | 90 |
13 25% Tebuconazole EW of table and bactericidal property of the present composition to powdery mildew of cucumber
| Numbering | Medicament title | Every mu of dosage | Bactericidal effect (%) |
| Treatment group 1 | 25% Tebuconazole EW+ embodiments 13 | 8g+800g | 100 |
| Treatment group 2 | 25% Tebuconazole EW+ embodiments 13 | 5g+800g | 95 |
| Control group | 25% Tebuconazole EW | 8g | 78 |
14 325g/L benzene first Fluoxastrobins SC of table and bactericidal property of the present composition to watermelon anthrax
| Numbering | Medicament title | Every mu of dosage | Bactericidal effect (%) |
| Treatment group 1 | 325g/L benzene first Fluoxastrobin SC+ embodiments 9 | 15g+15g | 95 |
| Treatment group 2 | 325g/L benzene first Fluoxastrobin SC+ embodiments 9 | 11g+15g | 90 |
| Control group | 325g/L benzene first Fluoxastrobin SC | 15g | 82 |
15 20% mesotrione OD of table and herbicidal performance of the present composition to corn field
| Numbering | Medicament title | Every mu of dosage | Herbicidal effect (%) |
| Treatment group 1 | 20% mesotrione OD+ embodiments 11 | 10g+2g | 98 |
| Treatment group 2 | 20% mesotrione OD+ embodiments 11 | 5g+2g | 86 |
| Control group | 20% mesotrione OD | 10g | 75 |
Bactericidal properties of the 16 40% Prochloraz EW of table with the present composition to grape black soya bean disease
| Numbering | Medicament title | Every mu of dosage | Bactericidal effect (%) |
| Treatment group 1 | 40% Prochloraz EW+ embodiments 6 | 25g+2.5g | 100 |
| Treatment group 2 | 40% Prochloraz EW+ embodiments 6 | 12g+2.5g | 92 |
| Control group | 40% Prochloraz EW | 25g | 86 |
17 30% 3 ring epoxiconazole SC of table and bactericidal property of the present composition to rice terrace rice blast
| Numbering | Medicament title | Every mu of dosage | Bactericidal effect (%) |
| Treatment group 1 | 30% 3 ring epoxiconazole SC+ embodiments 7 | 18g+180g | 100 |
| Treatment group 2 | 30% 3 ring epoxiconazole SC+ embodiments 7 | 12g+180g | 95 |
| Control group | 30% 3 ring epoxiconazole SC | 18g | 80 |
18 720g/L2 of table, 4-D AS and herbicide performance of the present composition to wheat paddock
| Numbering | Medicament title | Every mu of dosage | Herbicide effect (%) |
| Treatment group 1 | 720g/L2,4-D AS+ embodiments 8 | 88g+2g | 100 |
| Treatment group 2 | 720g/L2,4-D AS+ embodiments 8 | 48g+2g | 89 |
| Control group | 720g/L2,4-D AS | 88g | 72 |
19 rice of table rises the insecticidal properties with the present composition to rice terrace striped rice borer
| Numbering | Medicament title | Every mu of preparation dosage | Insecticidal effect (%) |
| Treatment group 1 | Rice rises+embodiment 2 | 20ml+20ml | 100 |
| Treatment group 2 | Rice rises+embodiment 2 | 10ml+20ml | 100 |
| Control group | Rice rises | 20ml | 84 |
20 glyphosate of table and herbicide performance of the present composition to bare place weeds
| Numbering | Medicament title | Every mu of dosage | Herbicide effect (%) |
| Treatment group 1 | Agriculture is prosperous+embodiment 3 | 70g+70g | 100 |
| Treatment group 2 | Agriculture is prosperous+embodiment 3 | 50g+70g | 100 |
| Control group | Agriculture is prosperous | 70g | 90 |
21 glufosinate-ammonium of table and herbicide performance of the present composition to bare place eleusine indica
| Numbering | Medicament title | Every mu of dosage | Herbicide effect (%) |
| Treatment group 1 | Glufosinate-ammonium+embodiment 4 | 50g+20g | 100 |
| Treatment group 2 | Glufosinate-ammonium+embodiment 4 | 20g+20g | 95 |
| Control group | Glufosinate-ammonium | 50g | 88 |
As shown in upper table 4-21 data, the present composition is remarkably improved pesticide efficacy, can reduce under equal preventive effect
Pesticide dosage 20%-60%, effectively reduces effective dosage, overcomes and delay the resistance to the action of a drug of harmful organism.
Claims (8)
1. a kind of surfactant, it is characterised in that including agricultural surfactant, terpene compound and solvent, each group
Point shared mass percent is：Agricultural surfactant 1～83%；Terpene compound 0.2～48%；Solvent 0～20%.
2. surfactant as claimed in claim 1, it is characterised in that described terpene compound includes half terpene, list
One or more in terpene, sesquiterpenoids, Diterpenes, sesterterpenoids, triterpenes, tetraterpenes, poly terpene.
3. surfactant as claimed in claim 2, it is characterised in that the terpene compound is preferably monoterpenes or again
One or more in half terpene.
4. surfactant as claimed in claim 1, it is characterised in that described agricultural surfactant is included but is not limited to
Polyethenoxy ether class, Sulfonates, sulfuric acid ester, silicon-containing surfactant, perfluorinated surfactant, alkyl polyglycoside, phosphate
Class, alkanolamide class, polyalcohols, castor oil oxirane and derivative, castor oil expoxy propane and derivative, rosin
Sour oxirane and the like, cationic surfactant.
5. surfactant as claimed in claim 2, it is characterised in that described monoterpenes include chain monoterpene, monocyclic list
Terpene, Tropolones, bicyclic diterpene.
6. surfactant as claimed in claim 2, it is characterised in that described sesquiterpenoids includes acyclic sesquiterpene, ring
Shape sequiterpene, analog derivative difficult to understand, bicyclic sequiterpene.
7. surfactant as claimed in claim 1, it is characterised in that described solvent but be not limited to water, isoamyl alcohol, isobutyl
Alcohol, sec-butyl alcohol, MEK, ethylene glycol monoethyl ether, diethylene glycol ether, butyl glycol ether, diethylene glycol monobutyl ether, alcohol ethers are molten
Agent, alcohol solvent of ether ester type, 2-Butoxyethyl acetate, ethylene glycol ether acetate, isoamyl acetate, SCFA methyl esters,
Soybean oil methyl ester, palm oil methyl ester, cottonseed oil methyl esters, rapeseed methylester, sunflower oil methyl esters, rosin base oil vegetable oil, peanut oil
Methyl esters, linseed oil methyl esters, 6# solvent naphthas, 120# solvent naphthas, 200# solvent naphthas, 150# solvent naphthas, mineral oil one or two
More than.
8. surfactant as claimed in claim 1, it is characterised in that can be added directly in pesticidal preparations product formula makes
With or mix with pesticidal preparations product and to be watered Direct spraying use.
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| CN201610815163.4A CN106489939A (en) | 2016-08-31 | 2016-08-31 | A kind of surfactant containing terpene compound and application thereof |
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| CN107251895A (en) * | 2017-06-08 | 2017-10-17 | 深圳诺普信农化股份有限公司 | Spray adjuvantses and its preparation and application |
| CN109619098A (en) * | 2019-02-14 | 2019-04-16 | 浙江大学 | A kind of rice antimicrobial agent and its application |
| CN110326629A (en) * | 2019-07-01 | 2019-10-15 | 河北上瑞生物科技有限公司 | A kind of agricultural essential oil auxiliary agent and its preparation method and application |
| CN110463696A (en) * | 2018-05-09 | 2019-11-19 | 江苏龙灯化学有限公司 | It is a kind of to be suitble to fly the anti-pesticide dry suspending agent and its preparation method and application used |
| CN111194744A (en) * | 2019-12-03 | 2020-05-26 | 浙江威原天盛作物科技有限公司 | Environment-friendly synergistic spray additive and preparation method and application thereof |
| CN111226996A (en) * | 2020-03-25 | 2020-06-05 | 浙江新安化工集团股份有限公司 | Spraying auxiliary agent and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109619098A (en) * | 2019-02-14 | 2019-04-16 | 浙江大学 | A kind of rice antimicrobial agent and its application |
| CN109619098B (en) * | 2019-02-14 | 2020-07-14 | 浙江大学 | Rice antibacterial agent and application thereof |
| CN110326629A (en) * | 2019-07-01 | 2019-10-15 | 河北上瑞生物科技有限公司 | A kind of agricultural essential oil auxiliary agent and its preparation method and application |
| CN111194744A (en) * | 2019-12-03 | 2020-05-26 | 浙江威原天盛作物科技有限公司 | Environment-friendly synergistic spray additive and preparation method and application thereof |
| CN111226996A (en) * | 2020-03-25 | 2020-06-05 | 浙江新安化工集团股份有限公司 | Spraying auxiliary agent and application thereof |
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