CN106486688A - A kind of fuel battery combination device and fuel cell module - Google Patents

A kind of fuel battery combination device and fuel cell module Download PDF

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Publication number
CN106486688A
CN106486688A CN201510526998.3A CN201510526998A CN106486688A CN 106486688 A CN106486688 A CN 106486688A CN 201510526998 A CN201510526998 A CN 201510526998A CN 106486688 A CN106486688 A CN 106486688A
Authority
CN
China
Prior art keywords
connecting portion
fuel cell
metal bottom
cell module
battery combination
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510526998.3A
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Chinese (zh)
Inventor
狄彼德
彦斯·贝肯
丁力·罗伯特
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qoros Automotive Co Ltd
Ooros Automotive Co Ltd
Original Assignee
Ooros Automotive Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ooros Automotive Co Ltd filed Critical Ooros Automotive Co Ltd
Priority to CN201510526998.3A priority Critical patent/CN106486688A/en
Publication of CN106486688A publication Critical patent/CN106486688A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/249Grouping of fuel cells, e.g. stacking of fuel cells comprising two or more groupings of fuel cells, e.g. modular assemblies
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1097Fuel cells applied on a support, e.g. miniature fuel cells deposited on silica supports
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • H01M8/247Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
    • H01M8/2475Enclosures, casings or containers of fuel cell stacks
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

The present invention provides a kind of fuel battery combination device, and this device is used for combining plural tubular solid oxide fuel cell, including:First metal bottom and the second metal bottom;Described first metal bottom and the second metal bottom are symmetrically arranged with two to above host cavity, this host cavity is used for fixing tubular solid oxide fuel cell, described collecting intracavity is provided with a conflict platform, this conflict platform, in order to keep out tubular solid oxide fuel cell in case sliding stop, this conflict platform includes a through hole.The present invention also provides a kind of fuel cell module that above-mentioned fuel battery combination device links together.The fuel battery combination device of the present invention and fuel cell module can combine any number of tubular solid oxide fuel cells, thus providing required various capacity cells.

Description

A kind of fuel battery combination device and fuel cell module
Technical field
The present invention relates to fuel cell field, more particularly, to a kind of fuel battery combination device and fuel cell Assembly.
Background technology
Fuel cell is that a kind of fuel that will be present in is converted into electric energy with the chemical energy in oxidant TRT.Two kinds of common fuel cells are Proton Exchange Membrane Fuel Cells (PEMFC) and solid oxygen Compound fuel cell (SOFC).Proton Exchange Membrane Fuel Cells is usually used the gas conduct of hydrogen etc Fuel, chemical energy just can be converted into electric energy by a lower temperature.SOFC Then energy conversion is carried out based on high-temperature reaction process, it generally can be using the gas of various difference high concentrations Fuel, such as carbon monoxide, hydrogen.
A very big advantage of SOFCs is:Produce electric energy gaseous fuel can from ethanol, gasoline, Obtain in diesel oil, the various material such as natural gas, even biomass or coal.These materials can fire at one Gasified, such that it is able to produce abundant carbon monoxide and hydrogen in material reforming reaction device.This fuel Catalyst is comprised, this catalyst makes fuel reactant gas produce carbon monoxide and hydrogen in reforming reaction device Gas.
SOFC is manufactured on a ceramic substrate mostly, is the plate armature of bidimensional.Planar SOFC s Multiple flat boards be stacked and become a battery pile.The defect of the maximum of planar SOFC s is to make pottery Ceramic chip unit is easily broken.Although, to a certain extent, can be by slowing down heating or cooling pottery The time of ceramic chip reduces the possibility of this rupture;But if so, produce the process of electric energy Will take for long time, such as some hours or some skies.
For the splintering problem overcoming above-mentioned thermal expansion to lead to, tubular type fuel cell gradually grows up.This The pipe of kind of tubular type fuel cell is smaller, such as length is 50mm or 60mm, external diameter be 4mm extremely 6mm, internal diameter are 3mm to 4mm.The stock of pipe can be pure pottery, or containing relatively The metalloid of many nickel.This metalloid containing more nickel makes gas or gas ion diffusion more convenient. Scribble coating in the inner and outer wall of pipe, these coatings define anode and the negative electrode of fuel cell.
Please join a kind of tubular type fuel cell shown in Fig. 1.This tubular type fuel cell is by anode layer, cathode layer And the dielectric substrate composition between the two poles of the earth.It is passed through H2 or other fuel gas in anode layer side, The air leading to into O2 or comprising O2 in cathode layer side.
Although tubular type fuel cell has many good qualities, it also there is a problem of one very big:Single pipe Formula fuel cell can only produce the power of very little.According to temperature and gas concentration, generally this is undersized Between 0.65V to 0.85V, the electric current of output is less than 1A to the voltage of single tubular cells output.Super Cross 2A or during more tubular type fuel cell is also in exploitation.Either 1A or 2A, The power of this SOFC is still smaller.
For empirical angle, we can assume that the power that single tubular fuel cell unitt is provided is 0.7V x 1A=0.7W.In order to obtain the power of 1kW, needs will about 1300 tubular type fuel cells Unit couples together one battery pile of formation;And in order to obtain the electric power system of 30kW, this quantity one Under brought up to about 40000.
How multiple tubular type fuel cell units to be combined as a kind of electric power system is to need to solve Problem;And the combination of these tubular type fuel cells needs to be flexible, simple, that is, for different Power requirement, all can be required with the satisfaction of non-customized formula.
Content of the invention
In view of this, the present invention provides a kind of fuel battery combination device and by this fuel battery combination device The fuel cell module combined.
This fuel battery combination device is used for being combined in plural tubular solid oxide fuel cell group Together, including:First metal bottom and the second metal bottom;Described first metal bottom and the second metal Bottom symmetrical is provided with two to above host cavity, and this host cavity is used for fixing Tubular solid oxide fuel electricity Pond, described collecting intracavity is provided with a conflict platform, and this conflict platform is in order to keep out pipe type solid oxidation Thing fuel cell, in case sliding stop, this conflict platform includes a through hole.
Two or more fuel battery combination device is linked together by this fuel cell module, this fuel cell Assembly also includes, first connecting portion and second connecting portion, and one end of this first connecting portion connects described battery First metal bottom of combination unit, one end of this second connecting portion connects the of another battery combination device Two metal bottom, the other end of the other end of this first connecting portion and second connecting portion connects;First metal The gas that bottom, the second metal bottom, first connecting portion and second connecting portion form hollow homogenizes chamber.
Another kind of fuel cell module of the present invention, including:First connecting portion, second connecting portion and company Acting flange, one end of this first connecting portion connects the first metal bottom of described battery combination device, and this One end of two connecting portions connects the second metal bottom of another battery combination device, this first connecting portion another One end of one end and adpting flange connects, and the other end of the other end of this second connecting portion and adpting flange is even Connect, the first metal bottom, the second metal bottom, first connecting portion, second connecting portion and adpting flange Form gas and homogenize unit.
Compared to prior art, the fuel battery combination device of the present invention and fuel cell module can combine Any number of tubular solid oxide fuel cells, thus provide required various capacity cells.In combination During the tubular solid oxide fuel cell of varying number, multiple fuel cell modules may be used;By Can be with large-scale production, so allowing for combining the pipe type solid oxide of varying number in this assembly Fuel cell is very convenient and flexible.
Brief description
Fig. 1 is a kind of existing tubular type fuel cell schematic diagram.
Fig. 2 is a kind of structural representation of present invention fuel battery combination device.
Fig. 3 (a) is a kind of sectional view of the host cavity of present invention fuel battery combination device.
Fig. 3 (b) is a kind of axonometric chart of the host cavity of present invention fuel battery combination device.
Fig. 4 is a kind of present invention fuel battery combination bottom of device shape graph.
Fig. 5 is the electrical connection graph of fuel battery combination device and fuel cell.
Fig. 6 is a kind of present invention fuel cell module figure.
Fig. 7 is present invention another kind fuel cell module figure.
Fig. 8 is the fuel cell module figure with extraneous gas introduction part.
Fig. 9 (a), Fig. 9 (b) are a kind of tubular solid oxide fuel cell schematic diagrams.
Specific embodiment
For solving the technical problem mentioned in background technology, the present invention provides a kind of fuel battery combination device And a kind of fuel cell module.Below in conjunction with the accompanying drawings, of the present invention fuel battery combination device is discussed in detail Shape and structure with assembly.
Please join Fig. 2, Fig. 2 gives the structural representation of fuel battery combination device.This fuel cell unit Attach together put including:Metal bottom 11 and metal bottom 12.Four collectings are provided with this metal bottom 11 Chamber 11a~11d;Likewise, four host cavity 12a~12d are also equipped with this metal bottom 12.Wherein, Host cavity 11a and host cavity 12a forms a pair of host cavity, one end quilt of pipe type solid oxidized fuel cell It is housed in host cavity 11a, the other end is housed in host cavity 12a.Likewise, host cavity 11b With host cavity 12b formed another to host cavity, in order to fix another SOFC;Receive Cavity volume 11c and host cavity 12c forms the 3rd pair of host cavity, in order to fix the 3rd solid oxide fuel Battery;Host cavity 11d and host cavity 12d forms the 4th pair of host cavity, in order to fix the 4th solid oxygen Compound fuel cell.The example of Fig. 2 gives the combination of four tubular solid oxide fuel cells of combination Device.Indeed, it is possible to the factor such as space size placed according to power demand, battery pile is in metal bottom The host cavity of other quantity is arranged on portion, such as 2,3, or more.
Fig. 3 (a) gives the sectional view of host cavity, and Fig. 3 (b) gives the axonometric chart of host cavity.Often Suitable to the length of the length between host cavity and tubular solid oxide fuel cell;In order to prevent solid Oxide fuel cell slides in length direction, houses intracavity and is provided with a conflict platform 130.This supports Scratch in the middle of tactile platform except rear formation one through hole 140.When the two ends of SOFC are respectively placed in After two host cavities, the conflict platform that two host cavities each include withstands the two ends of this battery respectively, by it Fixing.It is passed through gas, these gases can be spread to through hole in the pipe of tubular solid oxide fuel cell In 140.When two-stage or multi-level tubular SOFC connect, it is diffused into through hole 140 In gas can flow in the pipe of next stage tubular solid oxide fuel cell, in further detail below Description.
The surface of metal bottom 11 and metal bottom 12 can be circle, hexagon, square or its Its some shape, please join Fig. 4.Metal bottom 11 and 12 can be by high temperature resistant, corrosion resistant steel system Make.
Please join Fig. 5, metal bottom 11 is electrically connected with the anode of tubular solid oxide fuel cell, metal Bottom 12 is electrically connected with the negative electrode of tubular solid oxide fuel cell.Specifically a kind of realization is as follows:
Please join a kind of tubular solid oxide fuel cell, negative electrode and the sun shown in Fig. 9 (a) Fig. 9 (b) Pole achieves electrical connection by cathode conductive layer and anode conductive layer.This cathode conductive layer and anode conductive layer Invest the surface of negative electrode and anode.Electric isolution gap is included between anode conductive layer and cathode conductive layer. When external electrical conductor needs to connect the negative electrode of this SOFC and anode, preferably permissible It is connected with the cathode conductive layer junction q in Fig. 9 (a) and anode conductive layer junction p respectively.So This tubular solid oxide fuel cell when being placed in fuel battery combination device, can lead to by metal bottom 11 Cross and realize electrically connecting with the anode of this battery with connecting of anode conductive layer junction p;Metal bottom 12 Can be by realizing electrically connecting with the negative electrode of this battery with connecting of cathode conductive layer junction q.Metal bottom Portion 11 and anode conductive layer junction p can be in the way of with high-temperature soldering when connecting, same metal Bottom 12 and cathode conductive layer junction can also be by the way of high-temperature soldering when connecting.
In order to realize the multistage connection of tubular solid oxide fuel cell, present invention also offers a kind of combustion Material battery component.
Please join Fig. 6, it gives the embodiment one of fuel cell module.This fuel cell module includes Fuel battery combination device, also includes connecting portion 61 and connecting portion 62, and one end of this connecting portion 61 connects The metal bottom 12 of battery combination device, one end of this connecting portion 62 connects another battery combination device Metal bottom 11, the other end of the other end of this connecting portion 61 and connecting portion 62 connects;Metal bottom 11, The gas that metal bottom 12, connecting portion 61 and connecting portion 62 form hollow homogenizes chamber.If Fig. 6 left side Fuel battery combination device combination SOFC be first order set of cells, the combustion on the right The SOFC of material battery combination device combination is second level set of cells, connecting portion 61 and even This two-stage set of cells is connected together by socket part 62.Gas (as H2, CO) is from first order set of cells After inputting in the pipe of battery, a portion can reach gas by the through hole 140 of metal bottom and homogenize chamber, Gas reaches second level electricity after gas homogenizes and homogenizes in chamber, then by the through hole 140 of another metal bottom In the pipe of the battery of pond group.
Connecting portion 61 and connecting portion 62 are flexible electrical conductor, by the metal bottom of the battery of first order set of cells The metal bottom 11 of the battery of portion 12 and second level set of cells is electrically connected with.
The section of connecting portion 61 and connecting portion 62 is circle, the diameter in connecting portion 61 section and connecting portion The diameter dimension in 62 sections can be different, is so more beneficial for both and connects.
Please join Fig. 7, it gives the embodiment two of fuel cell module.This fuel cell module and Fig. 6 The difference of fuel cell module be, increased an adpting flange 70.One end of connecting portion 61 connects The metal bottom 12 of battery combination device, one end of connecting portion 62 connects the gold of another battery combination device Belong to bottom 11, one end of the other end of connecting portion 61 and adpting flange 70 connects, connecting portion 62 another The other end of one end and adpting flange 70 connects, metal bottom 11, metal bottom 12, connecting portion 61, Connecting portion 62 and adpting flange 70 form gas and homogenize unit.Adpting flange 70 can be conductor, It can be insulator;Can be made up of porous ceramicss or metal foam.
Homogenize with the gas of embodiment one that chamber is the same, the gas of embodiment two homogenizes unit and is also used to gas Body carries out fully homogenized.
When being connected with multistage set of cells, gas (as H2, CO) enters from first order set of cells pipe After start occur chemical reaction to produce electric energy, with reaction carrying out, the battery that gas continues after entering During group, its concentration can decrease, the generation of impact electric energy.In order to make-up gas (as H2, CO) arrives Gas homogenizes in unit to keep gas concentration, makes set of cells produce more electric energy, can lead a gas Enter part 71 to be connected on adpting flange 70, Fig. 8 please be join.After Input gas in gas introduction part 71, This gas homogenizes being imported into gas in unit so that the gas concentration participating in reaction is higher.Producing more Moreover it is possible to solve the problems, such as fuel availability in the case of many electric energy.This gas introduction part 71 can lead to Cross different modes and adpting flange 70 connects, such as arc welding (soldering), electric spot welding (electro Spot welding), frictional connection (friction) etc..
Can be seen that fuel battery combination device and the fuel cell of the present invention by above-described embodiment description Assembly can combine any number of tubular solid oxide fuel cells, thus providing required various power Battery.When combining the tubular solid oxide fuel cell of varying number, multiple fuel may be used Battery component;Because this assembly can be with large-scale production, so allowing for combining the pipe of varying number Formula SOFC is very convenient and flexible.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all this Within the spirit of invention and principle, any modification, equivalent substitution and improvement done etc., should be included in Within the scope of protection of the invention.

Claims (13)

1. a kind of fuel battery combination device, this device is used for firing plural pipe type solid oxide Material battery combination is together it is characterised in that this combination unit includes:
First metal bottom and the second metal bottom;Described first metal bottom and the second metal bottom are symmetrical It is provided with two to above host cavity, this host cavity is used for fixing tubular solid oxide fuel cell, described House intracavity and be provided with a conflict platform, this conflict platform is in order to keep out Tubular solid oxide fuel electricity Pond, in case sliding stop, this conflict platform includes a through hole.
2. fuel battery combination device as claimed in claim 1 is it is characterised in that described first metal The surface of bottom and the second metal bottom is circular, hexagon or square.
3. fuel battery combination device as claimed in claim 1 is it is characterised in that described first metal The material of bottom and the second metal bottom is high temperature resistant, corrosion resistant steel.
4. fuel battery combination device as claimed in claim 1 is it is characterised in that the first metal bottom Electrically connect with the anode of tubular solid oxide fuel cell, the second metal bottom and pipe type solid oxide The negative electrode electrical connection of fuel cell.
5. a kind of fuel cell module is it is characterised in that this fuel cell module includes such as claim 1 To any one of 4 fuel battery combination devices, this fuel cell module also includes,
First connecting portion and second connecting portion, one end of this first connecting portion connects described battery combination device The first metal bottom, one end of this second connecting portion connects the second metal bottom of another battery combination device Portion, the other end of the other end of this first connecting portion and second connecting portion connects;First metal bottom, The gas that two metal bottom, first connecting portion and second connecting portion form hollow homogenizes chamber.
6. fuel cell module as claimed in claim 5 it is characterised in that described first connecting portion and Second connecting portion is electric conductor, by the first metal bottom and the electrical connection of the second metal bottom.
7. fuel cell module as claimed in claim 6 it is characterised in that described first connecting portion and Second connecting portion is flexible material.
8. a kind of fuel cell module is it is characterised in that this fuel cell module will for connecting right such as Seek any one of 1 to 4 fuel battery combination device, this fuel cell module includes:
First connecting portion, second connecting portion and adpting flange, one end connection of this first connecting portion is described First metal bottom of battery combination device, one end of this second connecting portion connects another battery combination device The second metal bottom, one end of the other end of this first connecting portion and adpting flange connects, and this is second even The other end of the other end of socket part and adpting flange connects, the first metal bottom, the second metal bottom, the One connecting portion, second connecting portion and adpting flange form gas and homogenize unit.
9. fuel cell module as claimed in claim 8 is it is characterised in that this adpting flange is conductor Or insulator.
10. fuel cell module as claimed in claim 9 is it is characterised in that this adpting flange is many Hole pottery or metal foam.
11. fuel cell modules as claimed in claim 8 are it is characterised in that this fuel cell module Also include a gas introduction part, this gas introduction part is connected with adpting flange, import gas to gas Homogenize unit.
12. fuel cell modules as claimed in claim 8 are it is characterised in that described first connecting portion It is electric conductor with second connecting portion, by the first metal bottom and the electrical connection of the second metal bottom.
13. fuel cell modules as claimed in claim 12 are it is characterised in that described first connecting portion It is flexible material with second connecting portion.
CN201510526998.3A 2015-08-25 2015-08-25 A kind of fuel battery combination device and fuel cell module Pending CN106486688A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510526998.3A CN106486688A (en) 2015-08-25 2015-08-25 A kind of fuel battery combination device and fuel cell module

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510526998.3A CN106486688A (en) 2015-08-25 2015-08-25 A kind of fuel battery combination device and fuel cell module

Publications (1)

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CN106486688A true CN106486688A (en) 2017-03-08

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1574438A (en) * 2003-05-30 2005-02-02 三洋电机株式会社 Solid oxide fuel cell, solid oxide fuel cell assembly, solid oxide fuel cell module, and solid oxide fuel cell power generator
US20050282051A1 (en) * 2003-08-28 2005-12-22 Zhigang Zhou Integrated honeycomb solid electrolyte fuel cells
US20110065022A1 (en) * 2009-09-14 2011-03-17 Min Kyong Bok Solid oxide fuel cell
CN205028966U (en) * 2015-08-25 2016-02-10 观致汽车有限公司 Fuel battery attach together put with fuel battery spare

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1574438A (en) * 2003-05-30 2005-02-02 三洋电机株式会社 Solid oxide fuel cell, solid oxide fuel cell assembly, solid oxide fuel cell module, and solid oxide fuel cell power generator
US20050282051A1 (en) * 2003-08-28 2005-12-22 Zhigang Zhou Integrated honeycomb solid electrolyte fuel cells
US20110065022A1 (en) * 2009-09-14 2011-03-17 Min Kyong Bok Solid oxide fuel cell
CN205028966U (en) * 2015-08-25 2016-02-10 观致汽车有限公司 Fuel battery attach together put with fuel battery spare

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