A kind of flat-plate solid-oxide fuel battery stack for double-layer connector
Technical field
The present invention relates to Solid Oxide Fuel Cell (SOFC), relate in particular to the structure of flat-plate solid-oxide fuel battery stack for double-layer connector.
Background technology
Oil price rises steadily; the fossil energy prospect allows of no optimist; the energy and crisis of resource become the matter of utmost importance that countries in the world face already, improve the efficient of energy resource system, and developing efficiently, power-saving technology is one of goal in research of being engaged in the energy and the research personnel of dynamics section.Fuel cell is the secondary energy sources device that solves the low and dual problem of environmental pollution of efficiency of energy utilization.That Solid Oxide Fuel Cell (SOFC) has is strong to suitability of fuel, energy utilization rate is high, need not outstanding feature such as noble metal catalyst, therefore has been subjected to attention more and more widely.In the stationary electric power plant field, Solid Oxide Fuel Cell (SOFC) has clear superiority than the fuel cell of other kinds.SOFC seldom needs fuel treatment, and inside reforming, integrated, the inner concetrated pipe of internal heat make system design more simple, and SOFC and gas turbine and other equipment also are easy to carry out the high efficiency thermoelectric coproduction.SOFC is a kind of high effect cleaning Blast Furnace Top Gas Recovery Turbine Unit (TRT) easily, be fit to do moves very much, decentralized power s and supply with the especially suitable departments such as important government and military affairs that are applied near terminal use's electric power.
Usually, SOFC adopts solid-state dense electrolyte layer, as zirconia ZrO
2Base electrolyte, cerium oxide CeO
2Base electrolyte etc., it has good electricity to lead to oxonium ion under high temperature or middle temperature, but to electronic isolation.Porous anode, dense electrolyte layer and porous cathode sintering successively constitute the parts of similar " sandwich " structure together, are commonly referred to as " monocell ".Oxidizing gas (as oxygen, air) imports from negative electrode one side of monocell, the oxonium ion that the catalytic decomposition of process negative electrode is transformed into passes through dielectric substrate, electrochemical reaction takes place with the fuel gas (as hydrogen, carbon monoxide gas, coal gas, natural gas, methane or other hydrocarbon fuel gas etc.) in importing of anode one side and process catalytic decomposition, electronics then passes through external circuit and passes through load flow to negative electrode from anode, and formation can be for the electric energy that utilizes.
Connector as one of SOFC vitals mainly plays a part transmission electronic between adjacent monocell, and connector also plays the effect of separating fuel gas and adjacent cell oxic gas in the existing flat SOFC heap.Connector adopts alloy materials such as chromium base, Ni-based and iron-based, connector not only requires processing cost low in operating temperature range, the ability that also should have high electrical conductivity and heat conductivity, good processing characteristics, enough mechanical strength, good anti-oxidant, corrosion and carbonization, and good heat and chemical matching.
At Chinese patent CN 200560026293.3, CN 200410020924.1, reach the design of all openly having reported flat SOFC heap among U.S. Pat 4663493, US 2624910, the US 2226032, adopt the monocell heap of writing board shape, fuel gas and oxidizing gas are imported to two faces of dull and stereotyped monocell respectively.Flat design has advantages such as the electric current collection distance is short, power density is high, preparation technology is simple.But existing flat SOFC heap all adopts the structure of the anode of a slice monocell over against the negative electrode of another sheet monocell.Usually oxidizing gas and fuel gas mostly are laminar flow state in the SOFC heap, are example with the fuel gas side, and fuel gas concentration is lower on the anode reaction interface, and higher but can't participate in anode reaction away from the fuel gas concentration of anode-side, can't utilize fully.In like manner,, also can't participate in cathode reaction, can't utilize fully away from the oxic gas concentration of cathode side is higher on the oxic gas side.Such structure causes perpendicular to fuel gas on the plane of monocell and oxidizing gas concentration difference bigger, and concentration polarization is higher, reduces the performance of SOFC heap.
Existing flat SOFC heap is bigger perpendicular to fuel gas on the plane of monocell and oxidizing gas concentration difference, though the SOFC pile structure of some patent disclosure adopts slot type structure or ripple struction to strengthen mass transfer, but these structures only can be come disturbance fuel gas and oxidizing gas from the plane that is parallel to monocell, can't come disturbance fuel gas and oxidizing gas from the bigger plane perpendicular to monocell of concentration difference; Mass transfer can't be strengthened effectively, fuel gas concentration on the anode reaction interface and the oxic gas concentration on the cathode side reaction interface can't be improved effectively.
Summary of the invention
In order to overcome above-mentioned prior art deficiency, the purpose of this invention is to provide a kind of flat-plate solid-oxide fuel battery stack for double-layer connector.This structure can be strengthened mass transfer effectively, improve fuel gas concentration on the anode reaction interface and the oxic gas concentration on the cathode side reaction interface effectively, utilize fuel gas and oxidizing gas fully, thereby the reduction concentration polarization improves the power density of flat-plate solid-oxide fuel battery stack greatly.
Technical scheme of the present invention is achieved in that a kind of flat-plate solid-oxide fuel battery stack for double-layer connector, comprise a plurality of by anode, dielectric substrate, the monocell that negative electrode constitutes, between adjacent monocell, be provided with connector, the arrangement form of described a plurality of monocells is the anode of the anode of a slice monocell over against another sheet monocell, the negative electrode of a slice monocell is over against the negative electrode of another sheet monocell, the double-layer connector that described connector is made of first connector and second connector is provided with the air inlet breach and the breach of giving vent to anger on first connector and second connector.
Described first connector constitutes network structure by the first connector vertical pole and the first connector cross bar, and second connector constitutes network structure by the second connector vertical pole and the second connector cross bar.
The first connector vertical pole and the second connector vertical pole are interlaced arrangement or arranged superposed, the first connector cross bar and the second connector cross bar are interlaced arrangement, exactly the first connector cross bar is arranged in the centre of two second connector cross bars, the second connector cross bar also is arranged in the centre of two first connector cross bars accordingly.
The cross section of the described first connector cross bar, the second connector cross bar is rectangle or triangle or semicircle.
Be connected with oxidizing gas between the negative electrode of adjacent two monocells, be connected with fuel gas between the anode of adjacent two monocells.
Described a plurality of monocell is anode support structure, dielectric substrate supporting construction, structure for supporting of cathode, connector support or cermet supporting construction.
The flow direction of described oxidizing gas and fuel gas is following current or adverse current or distributary.
The air inlet breach and the breach of giving vent to anger separately are arranged on second connector and first connector, perhaps the air inlet breach and the breach of giving vent to anger are arranged on first connector simultaneously, perhaps the air inlet breach and the breach of giving vent to anger are arranged on second connector simultaneously, and perhaps the air inlet breach and the breach of giving vent to anger are arranged on first connector and second connector simultaneously.
The present invention improves flat-plate solid-oxide fuel battery stack, the double-layer connector that connector is made of first connector and second connector, first connector constitutes by the first connector vertical pole that is parallel to fuel gas or oxidizing gas flow direction with perpendicular to the first connector cross bar of fuel gas or oxidizing gas flow direction, and first connector is network structure.Second connector constitutes by the second connector vertical pole that is parallel to fuel gas or oxidizing gas flow direction with perpendicular to the second connector cross bar of fuel gas or oxidizing gas flow direction, and second connector is network structure.The first connector vertical pole and the second connector vertical pole are interlaced arrangement or arranged superposed, the main collected current that plays a part, the first connector cross bar and the second connector cross bar are interlaced arrangement, exactly the first connector cross bar is arranged in the centre of two second connector cross bars, the second connector cross bar also is arranged in the centre of two first connector cross bars accordingly, gas is subjected to wriggle after the first connector cross bar and the second connector cross bar disturbance and flows, the first connector cross bar and the second connector cross bar play collected current, simultaneously from coming disturbance fuel gas and oxidizing gas perpendicular to the plane of monocell, this structure is strengthened mass transfer effectively, fuel gas or oxidizing gas transported effectively be delivered on anode or the cathode reaction interface, improve fuel gas concentration on the anode reaction interface and the oxic gas concentration on the cathode side reaction interface effectively, utilize fuel gas and oxidizing gas fully, thereby the reduction concentration polarization improves the power density of flat-plate solid-oxide fuel battery stack greatly.
The arrangement form of a plurality of monocells is the anode of the anode of a slice monocell over against another sheet monocell, is connected with fuel gas between the anode of adjacent two monocells, forms the both sides reaction interface in the anode air flue; The negative electrode of a slice monocell is connected with oxidizing gas over against the negative electrode of another sheet monocell between the negative electrode of adjacent two monocells, all forms the both sides reaction interface in the negative electrode air flue.Increased by a side reaction interface than existing flat-plate solid-oxide fuel battery stack, this structural advantages is to utilize fuel gas and oxidizing gas fully, improves the power density of flat-plate solid-oxide fuel battery stack greatly.
The cross section of the first connector cross bar, the second connector cross bar is rectangle or triangle or semicircle (face near anode or cathode side is the plane, is semi circular surface near the face in fuel air flue or the oxidizing gas air flue); A plurality of monocells are anode support structure, dielectric substrate supporting construction, structure for supporting of cathode, connector support or cermet supporting construction; The flow direction of oxidizing gas and fuel gas is following current or adverse current or distributary; The air inlet breach and the breach of giving vent to anger separately are arranged on second connector and first connector, perhaps the air inlet breach and the breach of giving vent to anger are arranged on first connector simultaneously, perhaps the air inlet breach and the breach of giving vent to anger are arranged on first connector simultaneously, and perhaps the air inlet breach and the breach of giving vent to anger are arranged on first connector and second connector simultaneously.These structures can improve the applicability of flat-plate solid-oxide fuel battery stack in energy resource system.
Description of drawings
Fig. 1 (a) is a structural representation of the present invention;
Fig. 1 (b) is a structure A-A section of the present invention;
Fig. 1 (c) is a structure B-B section of the present invention;
Fig. 2 (a) is the structural representation of the embodiment of the invention;
Fig. 2 (b) is the structure A-A section of the embodiment of the invention;
Fig. 2 (c) is the structure B-B section of the embodiment of the invention;
Fig. 3 (a) is arranged on second connector for air inlet breach of the present invention, and the breach of giving vent to anger is arranged on the structural representation on first connector;
Fig. 3 (b) is that the air inlet breach of the present invention and the breach of giving vent to anger are arranged on the structural representation on first connector simultaneously;
Fig. 3 (c) is that the air inlet breach of the present invention and the breach of giving vent to anger are arranged on the structural representation on first connector and second connector simultaneously.
Below in conjunction with accompanying drawing content of the present invention is described in further detail.
Embodiment
With reference to Fig. 1 (a), Fig. 1 (b), shown in Fig. 1 (c), a kind of flat-plate solid-oxide fuel battery stack for double-layer connector of the present invention, comprise a plurality of by anode 1-1, dielectric substrate 1-2, the monocell 1 that negative electrode 1-3 constitutes, between adjacent monocell 1, be provided with connector, the arrangement form of a plurality of monocells 1 is the anode 1-1 of the anode 1-1 of a slice monocell 1 over against another sheet monocell 1, the negative electrode 1-3 of a slice monocell 1 is over against the negative electrode 1-3 of another sheet monocell 1, the double-layer connector that connector is made of first connector 2 and second connector 3, first connector 2 constitutes network structure by the first connector vertical pole 2-1 that is parallel to fuel gas 6 or oxidizing gas 4 flow directions with perpendicular to the first connector cross bar 2-2 of fuel gas 6 or oxidizing gas 4 flow directions, second connector 3 constitutes network structure by the second connector vertical pole 3-1 that is parallel to fuel gas 6 or oxidizing gas 4 flow directions with perpendicular to the second connector cross bar 3-2 of fuel gas 6 or oxidizing gas 4 flow directions, the first connector vertical pole 2-1 and the second connector vertical pole 3-1 are arranged superposed, it perhaps is interlaced arrangement, the first connector cross bar 2-2 and the second connector cross bar 3-2 are interlaced arrangement, exactly the first connector cross bar 2-2 is arranged in the centre of two second connector cross bar 3-2, the second connector cross bar 3-2 also is arranged in the centre of two first connector cross bar 2-2 accordingly, and oxidizing gas 4 and fuel gas 6 are subjected to wriggle after the first connector cross bar 2-2 and the second connector cross bar 3-2 disturbance mobile.The cross section of the first connector cross bar 2-2, the second connector cross bar 3-2 is a rectangle, or adopts triangle or semicircle all can.Be connected with oxidizing gas 4 between the negative electrode 1-3 of adjacent two monocells 1, be connected with fuel gas 6 between the anode 1-1 of adjacent two monocells 1.A plurality of monocells 1 are anode support structure, perhaps adopt dielectric substrate supporting construction, structure for supporting of cathode, connector support or cermet supporting construction all can.Oxidizing gas 4 is a distributary with the flow direction of fuel gas 6, or adopter's adverse current or following current.Air inlet breach 7 is arranged on second connector 3, and the breach 8 of giving vent to anger is arranged on first connector 2.
With reference to Fig. 2 (a), Fig. 2 (b), shown in Fig. 2 (c), a kind of flat-plate solid-oxide fuel battery stack for double-layer connector of the present invention, comprise a plurality of by anode 1-1, dielectric substrate 1-2, the monocell 1 that negative electrode 1-3 constitutes, between adjacent monocell 1, be provided with connector, the arrangement form of a plurality of monocells 1 is the anode 1-1 of the anode 1-1 of a slice monocell 1 over against another sheet monocell 1, the negative electrode 1-3 of a slice monocell 1 is over against the negative electrode 1-3 of another sheet monocell 1, the double-layer connector that connector is made of first connector 2 and second connector 3, first connector 2 constitutes network structure by the first connector vertical pole 2-1 that is parallel to fuel gas 6 or oxidizing gas 4 flow directions with perpendicular to the first connector cross bar 2-2 of fuel gas 6 or oxidizing gas 4 flow directions, second connector 3 constitutes network structure by the second connector vertical pole 3-1 that is parallel to fuel gas 6 or oxidizing gas 4 flow directions with perpendicular to the second connector cross bar 3-2 of fuel gas 6 or oxidizing gas 4 flow directions, the first connector vertical pole 2-1 and the second connector vertical pole 3-1 are interlaced arrangement, it perhaps is arranged superposed, the first connector cross bar 2-2 and the second connector cross bar 3-2 are interlaced arrangement, exactly the first connector cross bar 2-2 is arranged in the centre of two second connector cross bar 3-2, the second connector cross bar 3-2 also is arranged in the centre of two first connector cross bar 2-2 accordingly, and oxidizing gas 4 and fuel gas 6 are subjected to wriggle after the first connector cross bar 2-2 and the second connector cross bar 3-2 disturbance mobile.The cross section of the first connector cross bar 2-2, the second connector cross bar 3-2 is a triangle, or adopts rectangle or semicircle all can.Be connected with oxidizing gas 4 between the negative electrode 1-3 of adjacent two monocells 1, be connected with fuel gas 6 between the anode 1-1 of adjacent two monocells 1.A plurality of monocells 1 are structure for supporting of cathode, or adopt dielectric substrate supporting construction, anode support structure, connector support or cermet supporting construction all can.Oxidizing gas 4 is an adverse current with the flow direction of fuel gas 6, or adopts distributary person or following current.Air inlet breach 7 is arranged on second connector 3, and the breach 8 of giving vent to anger is arranged on first connector 2.
With reference to Fig. 3 (a), Fig. 3 (b), shown in Fig. 3 (c), the double-layer connector that connector of the present invention is made of first connector 2 and second connector 3, first connector 2 constitutes network structure by the first connector vertical pole 2-1 that is parallel to fuel gas 6 or oxidizing gas 4 flow directions with perpendicular to the first connector cross bar 2-2 of fuel gas 6 or oxidizing gas 4 flow directions, second connector 3 constitutes network structure by the second connector vertical pole 3-1 that is parallel to fuel gas 6 or oxidizing gas 4 flow directions with perpendicular to the second connector cross bar 3-2 of fuel gas 6 or oxidizing gas 4 flow directions, the first connector vertical pole 2-1 and the second connector vertical pole 3-1 are interlaced arrangement, it perhaps is arranged superposed, the first connector cross bar 2-2 and the second connector cross bar 3-2 are interlaced arrangement, exactly the first connector cross bar 2-2 is arranged in the centre of two second connector cross bar 3-2, the second connector cross bar 3-2 also is arranged in the centre of two first connector cross bar 2-2 accordingly, and oxidizing gas 4 and fuel gas 6 are subjected to wriggle after the first connector cross bar 2-2 and the second connector cross bar 3-2 disturbance mobile.The cross section of the first connector cross bar 2-2, the second connector cross bar 3-2 is a triangle, or adopts rectangle or semicircle all can.Fig. 3 (a) air inlet breach 7 is arranged on second connector 3, the breach 8 of giving vent to anger is arranged on first connector 2, Fig. 3 (b) air inlet breach 7 and the breach 8 of giving vent to anger are arranged on first connector 2 simultaneously, and Fig. 3 (c) air inlet breach 7 and the breach 8 of giving vent to anger are arranged on first connector 2 and second connector 3 simultaneously.