CN106480741A - A kind of method for sorting of multifunctional textile product - Google Patents
A kind of method for sorting of multifunctional textile product Download PDFInfo
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- CN106480741A CN106480741A CN201610844012.1A CN201610844012A CN106480741A CN 106480741 A CN106480741 A CN 106480741A CN 201610844012 A CN201610844012 A CN 201610844012A CN 106480741 A CN106480741 A CN 106480741A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/16—Processes for the non-uniform application of treating agents, e.g. one-sided treatment; Differential treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
- D06M15/568—Reaction products of isocyanates with polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/11—Oleophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
Abstract
The present invention discloses a kind of method for sorting of multifunctional textile product, and wherein one side has the anti-pollution function of water and oil repellant, and another side then has the moisture absorption sweat discharging functions of hydrophilic and oleophilic.This method includes dip-coating of the cross-linking agent solution to textile, the spraying of hydrophobic oleophobic component, spraying of the hydrophilic and oleophilic component to textile another side, and the preliminary drying of textile and training are dried after arranging.Textile one side after this method is arranged has self-cleaning function, another side can wear next to the skin the comfortable einnehmen function with moisture absorbing and sweat releasing, each exclusive-OR function on two sides is respectively provided with certain water-wash resistance, raw material sources are extensive, simple for process, there is certain compatibility with other textile finishing auxiliary agents, can be applicable to the functional topical finishing field of textile.
Description
Technical field
The present invention relates to a kind of one side has the self-cleaning function of hydrophobic oleophobic, another side has the comfortable clothes of moisture absorbing and sweat releasing
With function, the method for sorting of the different textile of two sides function.
Background technology
Textile is the important materials for supporting human lives and social development.The mankind be unable to do without textile, and to textile
Cleaning and safeguard but consumed the too many time and efforts of people.Through the fluorine-containing weaving for waiting low surface energy compounds modification
Product can be with water and oil repellant self-cleaning function, it is clear that the extensive application of this kind of automatically cleaning textile a certain degree of can mitigate us
The burden of the generations such as clean clothing.However, the at present waterproofing agent used by textile is present, and product variety is single, cause textile color
The problems such as difference, impact textile touch, the performance having a strong impact on self-cleaning function textile and such chemicals
Extensively apply.
Content of the invention
The purpose of the present invention is the integration for textile self-cleaning function and moisture absorption sweat discharging functions, proposes a kind of new
One side there is self-cleaning function, another side has a moisture absorption perspiration-discharging einnehmen function, the textile of two sides Various Functions whole
Reason method, solves the problems, such as that waterproofing agent single varieties, textile aberration are big, feel is poor.
A kind of method for sorting of multifunctional textile product, arranges step as follows：
A () is textile dip-coating in cross-linking agent solution；
B () sprays hydrophobic oleophobic solution crosslinking for dip-coating dose of textile one side；
C () makes the textile another side spraying hydrophilic and oleophilic solution processed through step (b) textile one side have and dredges
Water oleophobic effect, another side have hydrophilic and oleophilic effect；
D () carries out preliminary drying the textile processed through step (c)；
E () carries out training baking the textile processed through step (d).
Further, crosslinking agent is dissolved in solvent in preparation 0.1～20wt% cross-linking agent solution, the step (a) will
Textile dip-coating 1h in the cross-linking agent solution；
Hydrophobic oleophobic component and catalyst are dissolved in preparation 0.1～20wt% hydrophobic oleophobic solution in solvent, in step (b)
The one side of textile is sprayed 0.1～20wt% hydrophobic oleophobic solution；
Hydrophilic and oleophilic component and catalyst are dissolved in preparation 0.1～20wt% hydrophilic and oleophilic solution in solvent, in step (c)
The another side of textile is sprayed 0.1～20wt% oleophylic hydrophilic solution；
90 DEG C of 0.1～1h of preliminary drying in step (d),
In step (e), 0.5～24h is dried in 120 DEG C of trainings.
Further, the textile includes the textile in bafta, the fabric of cotton blend and fiber with hydroxyl.
Further, the crosslinking agent is can to divide by functional group with the isocyanate ester compound of hydroxyl reaction, has two different
Cyanate, triisocyanate and polyisocyanates；Connection by isocyanates core base or alkyl or aryl and isocyanate groups
Point, there are aromatic series, araliphatic, aliphatic, alicyclic and cyclic aliphatic.
Further, the crosslinking agent include toluene di-isocyanate(TDI) (TDI), methyl diphenylene diisocyanate (MDI),
Naphthalene diisocyanate (NDI), PPDI (PPDI), dimethyl diphenyl diisocyanate (TODI), polymethylene are many
Phenyl isocyanate (PAPI), 1,6- hexamethylene diisocyanate (HDI), trimethyl -1,6- hexamethylene diisocyanate
(m-TMXDI), isoflurane chalcone diisocyanate (IPDI), 1,4- cyclohexane diisocyanate (CHDI), dicyclohexyl methyl hydride two
Isocyanates (H12MDI), isocyanatomethyl (HTDI), cyclohexanedimethyleterephthalate diisocyanate (HXDI), drop ice
Piece alkane dimethylene isocyanates (NB-DI), HDI trimer, IPDI tripolymer, and hydrophilic modifying or close modified above-mentioned
Compound.
Further, the compound in the hydrophobic oleophobic component contain reactive group, i.e. hydroxyl, containing amino, siliceous
Oxyalkyl group or isocyanato；Also containing low-surface-energy (hydrophobic oleophobic) group, i.e. fluorochemical polyether, contain fluoroalkyl, poly- silicon
Oxyalkyl, octadecyl ester base.
Further, the hydrophobic oleophobic component includes：Hydroxyl fluorochemical polyether, fluorocarbon alcohol, hydroxy silicon oil, octadecyl alcolol,
Stearyl alcohol, ester type waxes alcohol, fluorochemical polyether containing amino, amino fluorine carbon, amido silicon oil, octadecylamine, methoxyl group silicon fluoride, ethyoxyl fluorine silicon
Alkane, propoxyl group silicon fluoride, perfluoroalkyl trichlorosilane, fluorine-containing isocyanates, siliceous isocyanates, octadecylisocyanate.
Further, hydrophilic and oleophilic component refers to containing hydrophilic radical and containing hydroxyl, amino, siloxanes or isocyanato
Compound,
The compound of hydrophilic and oleophilic component can be divided into anion, cation or non-ionic compound by ionic,
Anionic includes：Hydroxy sulfonate, Hydroxysulfate, sulfamate, amidosulphuric acid salt, siloxanes or isocyanide
The sulfonate of sulfonate groups modification or sulfate；
Cationic includes：The quaternary ammonium salt of hydroxyl quaternary ammonium salt, amino quaternary ammonium salt, siloxanes or isocyanato modification；
Non-ionic including：The PPG of hydroxy polyethers, amino-polyether, siloxanes or isocyano end-blocking.
Further, catalyst can be all separately added in the hydrophobic oleophobic component and hydrophilic and oleophilic component, catalyst exists
Accounting in hydrophobic oleophobic component is 0.01-10wt%, and accounting of the catalyst in hydrophilic and oleophilic component is 0.01-10wt%,
The catalyst includes triethylenediamine, double (dimethylaminoethyl) ethers, organotin or organic bismuth catalyst, is catalyzed isocyanic acid
There is chemical reaction to accelerate film forming with hydroxyl or amino in ester, shorten the training baking time.
Further, used in the dip-coating and spraying solvent be not hydroxyl or amino each component is had well molten
The solvent of solution property, including：Acetone, ethyl acetate, butyl acetate, toluene, tetrahydrofuran, glycol monoethyl ether, propane diols list first
Ether, ethylene glycol monobutyl ether, propylene glycol monobutyl ether, glycol methyl ether acetate, propylene glycol methyl ether acetate, dioxane and halo
Any one or a few mixture in hydrocarbon.
It is an advantage of the current invention that：
New technology proposed by the invention is the finishing technique combined by dip-coating and spraying, using crosslinking agent, hydrophobic
Oleophobizing components and hydrophilic and oleophilic component substep carry out functional treatment to textile, based between hydroxyl and isocyanato
Polycondensation reaction, prepares the multifunctional textile product with certain fastness to washing of two sides Various Functions；
Textile after present invention arrangement, scribbles the one side of hydrophobic oleophobic component, with good hydrophobic oleophobic automatically cleaning
Function, simultaneously as hydroxyl or amino can be reacted with crosslinker isocyanate class compound in compound structure, forms and has one
Determine the firm coating of washability；In addition siloxanes in structure or isocyanato can be directly anti-with the hydroxyl in textile
Should, can also form the coating with certain fastness to washing；
The another side of hydrophilic and oleophilic component is scribbled, the einnehmen function with moisture absorption perspiration-discharging, simultaneously as compound knot
In structure, hydrophilic radical can give the function of coating moisture absorbing and sweat releasing, and hydroxyl, amino, siloxanes and isocyanato can be with crosslinking agents
Or textile reacts the coating to be formed with certain fastness to washing；
Textile color and luster nothing is affected, does not affect textile touch；
Raw material sources are extensive, simple for process, and have certain compatibility with other textile finishing auxiliary agents, preferably
The technique for improving the arrangement of conventional textile water proof and technology, and can effectively promote development and the correlation of functional textile
Field product and the update of technology, with certain economic benefit and social benefit.
Description of the drawings
Accompanying drawing described herein is used for providing a further understanding of the present invention, constitutes the part of the application, not
Inappropriate limitation of the present invention is constituted, in the accompanying drawings：
Fig. 1 is water, red wine, vegetable oil, cola, milk, coffee cannot soak textile after arranging and have self-cleaning function
One side experiment picture.
Specific embodiment
The arrangement step of multifunctional textile product provided by the present invention includes the dip-coating of crosslinking agent, the spray of hydrophobic oleophobic component
Apply, the spraying of hydrophilic and oleophilic component, and the preliminary drying of textile and training are dried after arranging.The raw material type of each link and technique are to whole
After reason, the self-cleaning function of textile, moisture absorption sweat discharging functions and water-wash resistance have a certain impact.With reference to specific embodiment
The invention will be further described, but the present invention is not limited to following examples.
Embodiment 1：Multifunctional textile product method for sorting A
About 0.05g cotton is dipped in 1 hour in 10wt%TDI acetone soln, the cotton one side after immersion sprays 10wt%
Hydroxyl fluorine ether and the acetone soln of 0.01-10wt% organotin, then 10wt% hydroxyl sulfoacid sodium and 0.01- is sprayed to another side
The acetone soln of 10wt% organotin, the textile after spraying are put in baking oven 90 DEG C of preliminary dryings 30 minutes, and 120 DEG C of trainings are dried 6 hours,
Obtain the fabric samples A after method A is arranged.
Embodiment 2：Multifunctional textile product method for sorting B
About 0.05g cotton is dipped in 1 hour in 10wt%MDI ethyl acetate solution, the cotton one side after immersion is sprayed
10wt% hydroxyl fluorine ether and the ethyl acetate of 1wt% organotin, then have to another side spraying 10wt% hydroxyl sulfoacid sodium and 1wt%
The ethyl acetate solution of machine tin, the textile after spraying are put in baking oven 90 DEG C of preliminary dryings 30 minutes, and 120 DEG C of trainings are dried 6 hours, obtain
Fabric samples B after the arrangement of method B.
Embodiment 3：Multifunctional textile product method for sorting C
About 0.05g cotton is dipped in 1 hour in 10wt%HDI ethylene glycol monobutyl ether solution, the cotton one side after immersion is sprayed
The ethylene glycol monobutyl ether of 10wt% hydroxyl fluorine ether and 0.01-10wt% organo-bismuth is applied, then 10wt% hydroxyl sulphur is sprayed to another side
The ethylene glycol monobutyl ether solution of sour sodium and 0.01-10wt% organo-bismuth, the textile after spraying are put in 90 DEG C of preliminary dryings 30 in baking oven
Minute, 120 DEG C of trainings are dried 6 hours, obtain the fabric samples C after method C is arranged.
Embodiment 4：Multifunctional textile product method for sorting D
About 0.05g cotton is dipped in the cotton one 1 hour in 10wt%IPDI glycol methyl ether acetate solution, after immersion
Face spraying 10wt% hydroxyl fluorine ether and the glycol methyl ether acetate of 0.01-10wt% organo-bismuth, then spray to another side
The glycol methyl ether acetate solution of 10wt% sulfamic acid sodium and 0.01-10wt% organo-bismuth, the textile after spraying are put in
90 DEG C of preliminary dryings 30 minutes in baking oven, 120 DEG C of trainings dry 6 hours, obtain the fabric samples D after method D is arranged.
Embodiment 5：Multifunctional textile product method for sorting E
About 0.05g cotton is dipped in the cotton one 1 hour in 5wt%HTDI propylene glycol methyl ether acetate solution, after immersion
Face spraying 10wt% fluorocarbon alcohol and the propylene glycol methyl ether acetate of 0.01-10wt% triethylenediamine, then spray to another side
The propylene glycol methyl ether acetate solution of 10wt% sulfamic acid sodium and 0.01-10wt% triethylenediamine, the weaving after spraying
Product are put in baking oven 90 DEG C of preliminary dryings 30 minutes, and 120 DEG C of trainings are dried 6 hours, obtain the fabric samples E after method E is arranged.
Embodiment 6：Multifunctional textile product method for sorting F
About 0.05g cotton is dipped in 1 hour in 5wt%HDI tripolymer propylene glycol methyl ether acetate solution, the cotton after immersion
Cloth one side sprays the propylene glycol methyl ether acetate of 10wt% hydroxy silicon oil and 0.01-10wt% triethylenediamine, then to another
Face spraying 10wt% hydroxy polyethers and the propylene glycol methyl ether acetate solution of 0.01-10wt% triethylenediamine, after spraying
Textile is put in baking oven 90 DEG C of preliminary dryings 30 minutes, and 120 DEG C of trainings are dried 6 hours, obtains the fabric samples F after method F is arranged.
Embodiment 7：Multifunctional textile product method for sorting G
About 0.05g cotton is dipped in 1 hour in 5wt%IPDI tripolymer propylene glycol methyl ether acetate solution, after immersion
Cotton one side sprays the propylene glycol methyl ether acetate of 10wt% hydroxy silicon oil and 0.01-10wt% triethylenediamine, then to another
The propylene glycol methyl ether acetate solution of 10wt% hydroxy polyethers and 0.01-10wt% triethylenediamine is simultaneously sprayed, after spraying
Textile be put in baking oven 90 DEG C of preliminary dryings 30 minutes, 120 DEG C of trainings are dried 6 hours, obtain the fabric samples G after method G is arranged.
Textile to present invention manufacture carries out performance test below：
1st, textile hydrophobic oleophobic performance test after arranging
Water droplet and oil droplet textile tool after arrangement is determined using video optics contact angle measurement (JC2000C, China)
There is the contact angle of the one side of self-cleaning function.
Experiment finds that water droplet has the contact for being respectively provided with 150 degree or so in the one side of self-cleaning function with oil droplet in textile
Angle.Additionally, water droplet and oil droplet will not still soak or penetrate into textile after placing 1 day on the textile.As can be seen here, textile tool
There is the self-cleaning function of good water and oil repellant.
As shown in figure 1, drop from left to right is followed successively by water, red wine, vegetable oil, cola, milk, coffee, cannot all moisten
Textile after dressing, the textile that the present invention is arranged have the one side of self-cleaning function.
2nd, textile moisture absorbing and sweat releasing performance test after arranging
Synthetic perspiration is prepared, synthetic perspiration's composition includes lactic acid, acetic acid, sodium chloride, disodium hydrogen phosphate, propylene glycol monomethyl ether,
Dimethicone, distilled water.Said components proportioning and addition manner reference L.Y.L.Wu, S.K.Ngian, Z.Chen,
The method of D.T.T.Xuan, Appl, Surf.Sci.2011,257,2965-2969.Investigate synthetic perspiration's textile after arrangement
The contact angle of the one side with moisture absorption sweat discharging functions and the change of contact angle.
Experiment shows that the one side that synthetic perspiration has moisture absorption sweat discharging functions in textile can be soaked quickly and penetrate into textile,
As can be seen here, textile has good moisture absorption sweat discharging functions and einnehmen function.
3rd, the washability of arrange after textile self-cleaning function and moisture absorption sweat discharging functions is investigated
After arrangement, the washing conditions of cotton are that cotton is dipped in the aqueous solution containing 1wt% washing powder, stir under 300 rotating speeds
15min is designated as the washing experiment of 1 wheel.
Experiment shows that textile, through the above washing experiment of 10 wheels, still has good self-cleaning function and moisture absorbing and sweat releasing
Function.Therefore, textile of the present invention has good fastness to washing.
The technical scheme for above embodiment of the present invention being provided is described in detail, specific case used herein
Principle and embodiment to the embodiment of the present invention is set forth, and the explanation of above example is only applicable to help and understands this
The principle of inventive embodiments；Simultaneously for one of ordinary skill in the art, according to the embodiment of the present invention, in specific embodiment party
All will change in formula and range of application, in sum, this specification content should not be construed as limiting the invention.
Claims (10)
1. a kind of method for sorting of multifunctional textile product, it is characterised in that arrange step as follows：
A () is textile dip-coating in cross-linking agent solution；
B () sprays hydrophobic oleophobic solution crosslinking for dip-coating dose of textile one side；
C () makes textile one side have hydrophobic dredging the textile another side spraying hydrophilic and oleophilic solution processed through step (b)
Oil effect, another side have hydrophilic and oleophilic effect；
D () carries out preliminary drying the textile processed through step (c)；
E () carries out training baking the textile processed through step (d).
2. the method for sorting of a kind of multifunctional textile product according to claim 1, it is characterised in that crosslinking agent is dissolved in molten
0.1～20wt% cross-linking agent solution is prepared in agent, in the step (a) by textile dip-coating in the cross-linking agent solution 1h；
Hydrophobic oleophobic component and catalyst are dissolved in spinning in preparation 0.1～20wt% hydrophobic oleophobic solution, step (b) in solvent
One side spraying 0.1～20wt% hydrophobic oleophobic solution of fabric；
Hydrophilic and oleophilic component and catalyst are dissolved in spinning in preparation 0.1～20wt% hydrophilic and oleophilic solution, step (c) in solvent
Another side spraying 0.1～20wt% oleophylic hydrophilic solution of fabric；
90 DEG C of 0.1～10h of preliminary drying in step (d),
In step (e), 0.5～24h is dried in 120 DEG C of trainings.
3. the method for sorting of a kind of multifunctional textile product according to claim 2, it is characterised in that the textile includes
Textile in bafta, the fabric of cotton blend and fiber with hydroxyl.
4. a kind of method for sorting of the multifunctional textile product according to claim 1 or 2 or 3, it is characterised in that the crosslinking
Agent is can to divide by functional group with the isocyanate ester compound of hydroxyl reaction, has diisocyanate, triisocyanate and many isocyanides
Acid esters；Divide with the connection of isocyanate groups by isocyanates core base or alkyl or aryl, have aromatic series, araliphatic, aliphatic,
Alicyclic and cyclic aliphatic.
5. the method for sorting of a kind of multifunctional textile product according to claim 4, it is characterised in that the crosslinking agent includes
Toluene di-isocyanate(TDI) (TDI), methyl diphenylene diisocyanate (MDI), naphthalene diisocyanate (NDI), to two isocyanic acid of benzene
Ester (PPDI), dimethyl diphenyl diisocyanate (TODI), polymethylene multi-phenenyl isocyanate (PAPI), 1,6- hexa-methylene
Diisocyanate (HDI), trimethyl -1,6- hexamethylene diisocyanate (m-TMXDI), isoflurane chalcone diisocyanate
(IPDI), 1,4- cyclohexane diisocyanate (CHDI), dicyclohexyl methyl hydride diisocyanate (H12MDI), methylcyclohexyl is different
Cyanate (HTDI), cyclohexanedimethyleterephthalate diisocyanate (HXDI), norboneol alkyl dimethyl isocyanates (NB-DI),
HDI trimer, IPDI tripolymer, and hydrophilic modifying or the modified above-claimed cpd of closing.
6. a kind of method for sorting of multifunctional textile product according to claim 5, it is characterised in that the hydrophobic oleophobic group
Compound in point contains reactive group, i.e. hydroxyl, contains amino, silicone-containing group or isocyanato；Also containing low
Surface energy (hydrophobic oleophobic) group, i.e. fluorochemical polyether, contain fluoroalkyl, polysiloxane group, octadecyl ester base.
7. a kind of method for sorting of multifunctional textile product according to claim 6, it is characterised in that the hydrophobic oleophobic group
Dividing includes：Hydroxyl fluorochemical polyether, fluorocarbon alcohol, hydroxy silicon oil, octadecyl alcolol, stearyl alcohol, fluorochemical polyether containing amino, amino fluorine carbon,
Amido silicon oil, octadecylamine, methoxyl group silicon fluoride, ethyoxyl silicon fluoride, propoxyl group silicon fluoride, perfluoroalkyl trichlorosilane, fluorine-containing
Isocyanates, siliceous isocyanates, octadecylisocyanate.
8. the method for sorting of a kind of multifunctional textile product according to claim 1, it is characterised in that hydrophilic and oleophilic component refers to
Compound containing hydrophilic radical and containing hydroxyl, amino, siloxanes or isocyanato,
The compound of hydrophilic and oleophilic component can be divided into anion, cation or non-ionic compound by ionic,
Anionic includes：Hydroxy sulfonate, Hydroxysulfate, sulfamate, amidosulphuric acid salt, siloxanes or isocyano
The sulfonate of base group modification or sulfate；
Cationic includes：The quaternary ammonium salt of hydroxyl quaternary ammonium salt, amino quaternary ammonium salt, siloxanes or isocyanato modification；
Non-ionic including：The PPG of hydroxy polyethers, amino-polyether, siloxanes or isocyano end-blocking.
9. a kind of method for sorting of multifunctional textile product according to claim 1, it is characterised in that the hydrophobic oleophobic group
Dividing and catalyst being all separately added into in hydrophilic and oleophilic component, accounting of the catalyst in hydrophobic oleophobic component is 0.01-
10wt%, accounting of the catalyst in hydrophilic and oleophilic component be 0.01-10wt%, the catalyst include triethylenediamine,
There is chemical reaction with hydroxyl or amino in double (dimethylaminoethyl) ethers, organotin or organic bismuth catalyst, catalysis isocyanates
To accelerate film forming, shorten the training baking time.
10. the method for sorting of a kind of multifunctional textile product according to claim 1, it is characterised in that the dip-coating and spray
Used in painting, solvent is the solvent for having good solubility to each component of not hydroxyl or amino, including：Acetone, acetic acid second
Ester, butyl acetate, toluene, tetrahydrofuran, glycol monoethyl ether, propylene glycol monomethyl ether, ethylene glycol monobutyl ether, propyleneglycol monobutyl
Any one or a few mixing in ether, glycol methyl ether acetate, propylene glycol methyl ether acetate, dioxane and halogenated hydrocarbons
Thing.
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| CN112281493A (en) * | 2020-11-16 | 2021-01-29 | 五邑大学 | Fluoride-free waterproof finishing agent and preparation method thereof |
| CN113021548A (en) * | 2021-03-09 | 2021-06-25 | 福建省顺昌县升升木业有限公司 | Bamboo hydrophobic modification treatment method |
| CN113227486A (en) * | 2018-12-21 | 2021-08-06 | 日华化学株式会社 | Water repellent composition and method for producing water repellent fiber product |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1922355A (en) * | 2004-02-18 | 2007-02-28 | 美利肯公司 | Dual function fabrics and method of making same |
| CN101074524A (en) * | 2006-05-15 | 2007-11-21 | 稳健实业(深圳)有限公司 | Production of non-woven cotton cloth with coating function finishing |
| CN101694063A (en) * | 2009-10-16 | 2010-04-14 | 无锡泰伯服饰有限公司 | Finishing method of single-absorption and single-prevention fabric |
| CN102154834A (en) * | 2010-12-17 | 2011-08-17 | 湖南大学 | Simple and easy preparation method for super-hydrophobic fiber and textile and application thereof |
| CN104790202A (en) * | 2015-04-22 | 2015-07-22 | 广州大学 | Fluorine-free durable super-hydrophobic cotton fabric finishing agent and cotton fabric finishing method thereof |
-
2016
- 2016-09-22 CN CN201610844012.1A patent/CN106480741A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1922355A (en) * | 2004-02-18 | 2007-02-28 | 美利肯公司 | Dual function fabrics and method of making same |
| CN101074524A (en) * | 2006-05-15 | 2007-11-21 | 稳健实业(深圳)有限公司 | Production of non-woven cotton cloth with coating function finishing |
| CN101694063A (en) * | 2009-10-16 | 2010-04-14 | 无锡泰伯服饰有限公司 | Finishing method of single-absorption and single-prevention fabric |
| CN102154834A (en) * | 2010-12-17 | 2011-08-17 | 湖南大学 | Simple and easy preparation method for super-hydrophobic fiber and textile and application thereof |
| CN104790202A (en) * | 2015-04-22 | 2015-07-22 | 广州大学 | Fluorine-free durable super-hydrophobic cotton fabric finishing agent and cotton fabric finishing method thereof |
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| CN110578255A (en) * | 2018-06-11 | 2019-12-17 | 尚科纺织企业工业及贸易公司 | method for providing antimicrobial and anti-pilling effects and improved dye uptake for textiles, novel copolymers and textiles |
| CN110578255B (en) * | 2018-06-11 | 2024-01-02 | 尚科纺织企业工业及贸易公司 | Method for providing antimicrobial and anti-pilling effects to textiles, novel copolymers and textiles with improved dye uptake |
| CN109680492A (en) * | 2018-11-28 | 2019-04-26 | 安徽尚尚家纺有限公司 | A kind of eiderdown shell fabric and preparation method thereof |
| CN113227486B (en) * | 2018-12-21 | 2024-01-02 | 日华化学株式会社 | Water repellent composition and method for producing water repellent fiber product |
| CN113227486A (en) * | 2018-12-21 | 2021-08-06 | 日华化学株式会社 | Water repellent composition and method for producing water repellent fiber product |
| CN109778524B (en) * | 2019-01-11 | 2021-07-09 | 丹东优耐特纺织品有限公司 | Processing method of durable waterproof, oil-proof, antifouling, waterproof and moisture-permeable fabric |
| CN109778524A (en) * | 2019-01-11 | 2019-05-21 | 丹东优耐特纺织品有限公司 | Durable waterproof, grease proofing, antifouling, waterproof moisture permeable fabric processing and treating method |
| CN111270522A (en) * | 2020-04-14 | 2020-06-12 | 北京邦维高科特种纺织品有限责任公司 | Vinyl chloride acrylonitrile copolymer fabric and its production process |
| CN111335032A (en) * | 2020-04-20 | 2020-06-26 | 陕西科技大学 | Super-hydrophobic figured nylon superfine fiber non-woven fabric and preparation method thereof |
| CN111501201A (en) * | 2020-04-20 | 2020-08-07 | 陕西科技大学 | Super-hydrophobic split-type superfine fiber non-woven fabric and preparation method thereof |
| CN111335031A (en) * | 2020-04-20 | 2020-06-26 | 陕西科技大学 | Super-hydrophobic figured polyester superfine fiber non-woven fabric and preparation method thereof |
| CN111926574A (en) * | 2020-08-04 | 2020-11-13 | 广东湛丰精细化工有限公司 | Finishing process capable of achieving single-side water resistance and single-side hydrophilicity of cotton knitted fabric |
| CN112281493A (en) * | 2020-11-16 | 2021-01-29 | 五邑大学 | Fluoride-free waterproof finishing agent and preparation method thereof |
| CN113021548A (en) * | 2021-03-09 | 2021-06-25 | 福建省顺昌县升升木业有限公司 | Bamboo hydrophobic modification treatment method |
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