CN106480714A - A kind of preparation method of environment-friendly type antibiotic functional finishing agent - Google Patents
A kind of preparation method of environment-friendly type antibiotic functional finishing agent Download PDFInfo
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic System
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
Abstract
The invention provides a kind of preparation method of environment-friendly type antibiotic functional finishing agent.Preparation process is as follows：（1）Leaf of Moringa powder and American lotus powder are mixed, deionized water and absolute ethyl alcohol are extracted；（2）Decolourize, filter, rotary evaporation after filter residue is removed, dries to obtain mixed-powder A；（3）By mao bamboon powder and Chinese fiber crops powder mixing, solvent is removed with revolving after petroleum ether extraction, dry to obtain mixture B；（4）By NaOH and deionized water mixed dissolution；（5）Add mixed-powder A, mixture B, carboxymethyl chitosan, mannosylerythritol lipid, citric acid and tartaric acid, sodium chloride and sodium hypophosphite stirring；（6）Add lauroylamidopropyl betaine and NPE stirring；（7）Sonic oscillation is obtained final product.Finishing agent prepared by this preparation method has extraordinary fungistatic effect, and antibiotic property is lasting, with good washability, while with very high ultimate strength and bursting strength, with extraordinary pliability.
Description
Technical field
The present invention relates to textile material field, and in particular to a kind of preparation method of environment-friendly type antibiotic functional finishing agent.
Background technology
In our living environments, microorganism is nearly ubiquitous, when nutrition, moisture, air and suitable temperature base
When this condition all possesses, textile cotton especially with cellulose, collagen, fibroin and keratin as main component, fiber crops, silk and
Wool etc. is highly prone to the infringement of microorganism.Textile is made up of fiber, its porous type body form and high molecular polymerization
The chemical constitution of thing is conducive to the attachment of microorganism, thus become microbe survival and breeding well post body；Again because of textile
Sweat, sebum and human secretion can be infected with human body wearing process, at the same can also by other pollutants in environment dirt
Dye, particularly under conditions of high temperature and humidity, textile is even more the good nutrition source for becoming various microorganisms.As can be seen here, exist
In pathogenic bacteria breeding, transmittance process, textile serves as the role of important carrier.Bacterium passes through on the textile after amount reproduction
Skin, respiratory tract, alimentary canal and blood cause certain harm to human body, in addition, can also pollute fiber, make fiber oxygen
Change, go bad, changing colour, sending special smell.Therefore, the antibacterial of fabric is particularly important, and fabric is general itself not to be had
Antibiotic property, and pass through to obtain anti-microbial property after antibacterial finishing agent is arranged, so, research and development anti-microbial property is good and can
The antibacterial finishing agent for improving fabric property can be effectively reduced the cross-infection rate in PE, prevent from infecting disease, protect
Card health and comfortable and easy to wear, makes fabric obtain preferable health care function, from or encroached on by harmful microbe less.
Content of the invention
Technical problem to be solved：It is an object of the invention to provide a kind of preparation side of environment-friendly type antibiotic functional finishing agent
Method, prepared finishing agent have extraordinary fungistatic effect, and antibiotic property is lasting, with good washability, while having very
High ultimate strength and bursting strength, with extraordinary pliability.
Technical scheme：A kind of preparation method of environment-friendly type antibiotic functional finishing agent, comprises the following steps：
（1）100-150g leaf of Moringa powder and 100-200g American lotus powder are mixed, add 200-300ml deionized water and
300-500ml absolute ethyl alcohol, extracts 20-24 hour at 35-50 DEG C；
（2）Add 5-10g activated carbon to be decolourized and drainage, filter, after removing filter residue, rotary evaporation is carried out, be put into vacuum and do
Mixed-powder A is dried to obtain in dry case at temperature 40-60 DEG C；
（3）By 40-60g mao bamboon powder and the fiber crops powder mixing of the 60-100g Chinese, 100-150ml petroleum ether is added to carry out soxhlet type
After 12-14 hour, revolving removes solvent, is put in vacuum drying chamber and dries to obtain mixture B at temperature 40-60 DEG C；
（4）By 15-20g NaOH and 100-150g deionized water mixed dissolution；
（5）Add mixed-powder A, mixture B, 0.5-1g carboxymethyl chitosan, 0.5-1g mannosylerythritol lipid, 0.2-
0.5g citric acid and 0.3-0.7g tartaric acid, 0.2-0.5g sodium chloride, 0.4-1g sodium hypophosphite, with magnetic stirrer in rotating speed
Stir 10-30 minute under 300-500r/min；
（6）1-2g lauroylamidopropyl betaine and 2-5g NPE is added, with magnetic stirrer in rotating speed
Stir 20-40 minute under 400-600r/min；
（7）Being put in Ultrasound Instrument carries out sonic oscillation 10-20 minute and obtains final product.
It is further preferred that step（1）Middle extraction temperature is 40-45 DEG C, and extraction time is 21-23 hour.
It is further preferred that step（2）Middle baking temperature is 45-55 DEG C.
It is further preferred that step（3）Middle extraction times are 13 hours, and baking temperature is 50 DEG C.
It is further preferred that step（5）Middle rotating speed is 350-450r/min, and mixing time is 15-25 minute.
It is further preferred that step（6）Middle rotating speed is 450-550r/min, and mixing time is 25-35 minute.
It is further preferred that step（7）Middle ultrasonic time is 15 minutes.
Beneficial effect：A kind of preparation method of environment-friendly type antibiotic functional finishing agent of the present invention, prepared finishing agent have
There is extraordinary fungistatic effect, cotton inhibiting rate after treatment to Escherichia coli, Candida albicans and staphylococcus aureus
95.2%, 74.2% and 99.1% can reach respectively, and after scrubbed 10 times, which is to Escherichia coli, Candida albicans and golden yellow
Staphylococcic inhibiting rate still may be up to 81.9%, 61.9% and 84.8%, and antibiotic property is lasting, with good washability.Fracture
Strength be one of most important physical performance index of fabric, be express fabric opposing stretching ability index, collated after
The ultimate strength of bafta may be up to 911.7N, more high than unfinished 898.3N, and bursting strength highest also reaches
708.3N, more unfinished 683.7N are higher by 24.6N, with extraordinary pliability.
Specific embodiment
Embodiment 1
A kind of preparation method of environment-friendly type antibiotic functional finishing agent, comprises the following steps：
（1）100g leaf of Moringa powder and 100g American lotus powder are mixed, adds 200ml deionized water and the anhydrous second of 300ml
Alcohol, extracts 20 hours at 35 DEG C；
（2）Add 5g activated carbon to be decolourized and drainage, filter, rotary evaporation is carried out after removing filter residue, be put into vacuum drying chamber
In dry to obtain mixed-powder A at 40 DEG C of temperature；
（3）By 40g mao bamboon powder and the fiber crops powder mixing of the 60g Chinese, add 100ml petroleum ether to carry out soxhlet type and revolve after 12 hours
Boil off except solvent, be put in vacuum drying chamber and mixture B dried to obtain at 40 DEG C of temperature；
（4）By 15g NaOH and 100g deionized water mixed dissolution；
（5）Add mixed-powder A, mixture B, 0.5g carboxymethyl chitosan, 0.5g mannosylerythritol lipid, 0.2g lemon
Acid and 0.3g tartaric acid, 0.2g sodium chloride, 0.4g sodium hypophosphite, stir 10 points with magnetic stirrer under rotating speed 300r/min
Clock；
（6）1g lauroylamidopropyl betaine and 2g NPE is added, with magnetic stirrer in rotating speed 400r/
Stir 20 minutes under min；
（7）Being put in Ultrasound Instrument carries out sonic oscillation and obtains final product for 10 minutes.
Embodiment 2
A kind of preparation method of environment-friendly type antibiotic functional finishing agent, comprises the following steps：
（1）110g leaf of Moringa powder and 120g American lotus powder are mixed, adds 220ml deionized water and the anhydrous second of 350ml
Alcohol, extracts 21 hours at 40 DEG C；
（2）Add 6g activated carbon to be decolourized and drainage, filter, rotary evaporation is carried out after removing filter residue, be put into vacuum drying chamber
In dry to obtain mixed-powder A under temperature 45 C；
（3）By 45g mao bamboon powder and the fiber crops powder mixing of the 70g Chinese, after adding 110ml petroleum ether to carry out soxhlet type 12.5 hours
Revolving removes solvent, is put in vacuum drying chamber and dries to obtain mixture B under temperature 45 C；
（4）By 17g NaOH and 110g deionized water mixed dissolution；
（5）Add mixed-powder A, mixture B, 0.6g carboxymethyl chitosan, 0.6g mannosylerythritol lipid, 0.3 citric acid
With 0.4g tartaric acid, 0.3g sodium chloride, 0.5g sodium hypophosphite, stirred 15 minutes under rotating speed 350r/min with magnetic stirrer；
（6）1.2g lauroylamidopropyl betaine and 3g NPE is added, with magnetic stirrer in rotating speed
Stir 25 minutes under 450r/min；
（7）Being put in Ultrasound Instrument carries out sonic oscillation and obtains final product for 15 minutes.
Embodiment 3
A kind of preparation method of environment-friendly type antibiotic functional finishing agent, comprises the following steps：
（1）125g leaf of Moringa powder and 150g American lotus powder are mixed, adds 250ml deionized water and the anhydrous second of 400ml
Alcohol, extracts 22 hours at 42 DEG C；
（2）Add 7.5g activated carbon to be decolourized and drainage, filter, rotary evaporation is carried out after removing filter residue, be put into vacuum drying
Mixed-powder A is dried to obtain in case under temperature 50 C；
（3）By 50g mao bamboon powder and the fiber crops powder mixing of the 80g Chinese, add 125ml petroleum ether to carry out soxhlet type and revolve after 13 hours
Boil off except solvent, be put in vacuum drying chamber and mixture B is dried to obtain under temperature 50 C；
（4）By 17.5g NaOH and 125g deionized water mixed dissolution；
（5）Add mixed-powder A, mixture B, 0.75g carboxymethyl chitosan, 0.75g mannosylerythritol lipid, 0.35 lemon
Lemon acid and 0.5g tartaric acid, 0.35g sodium chloride, 0.7g sodium hypophosphite, stir 20 with magnetic stirrer under rotating speed 400r/min
Minute；
（6）1.5g lauroylamidopropyl betaine and 3.5g NPE is added, with magnetic stirrer in rotating speed
Stir 30 minutes under 500r/min；
（7）Being put in Ultrasound Instrument carries out sonic oscillation and obtains final product for 15 minutes.
Embodiment 4
A kind of preparation method of environment-friendly type antibiotic functional finishing agent, comprises the following steps：
（1）140g leaf of Moringa powder and 180g American lotus powder are mixed, adds 280ml deionized water and the anhydrous second of 450ml
Alcohol, extracts 23 hours at 45 DEG C；
（2）Add 9g activated carbon to be decolourized and drainage, filter, rotary evaporation is carried out after removing filter residue, be put into vacuum drying chamber
In dry to obtain mixed-powder A at 55 DEG C of temperature；
（3）By 55g mao bamboon powder and the fiber crops powder mixing of the 90g Chinese, after adding 140ml petroleum ether to carry out soxhlet type 13.5 hours
Revolving removes solvent, is put in vacuum drying chamber and dries to obtain mixture B under temperature 50 C；
（4）By 19g NaOH and 140g deionized water mixed dissolution；
（5）Add mixed-powder A, mixture B, 0.9g carboxymethyl chitosan, 0.9g mannosylerythritol lipid, 0.4 citric acid
With 0.6g tartaric acid, 0.4g sodium chloride, 0.9g sodium hypophosphite, stirred 25 minutes under rotating speed 450r/min with magnetic stirrer；
（6）1.8g lauroylamidopropyl betaine and 4g NPE is added, with magnetic stirrer in rotating speed
Stir 35 minutes under 550r/min；
（7）Being put in Ultrasound Instrument carries out sonic oscillation and obtains final product for 15 minutes.
Embodiment 5
A kind of preparation method of environment-friendly type antibiotic functional finishing agent, comprises the following steps：
（1）150g leaf of Moringa powder and 200g American lotus powder are mixed, adds 300ml deionized water and the anhydrous second of 500ml
Alcohol, extracts 24 hours at 50 DEG C；
（2）Add 10g activated carbon to be decolourized and drainage, filter, rotary evaporation is carried out after removing filter residue, be put into vacuum drying
Mixed-powder A is dried to obtain in case under temperature 60 C；
（3）By 60g mao bamboon powder and the fiber crops powder mixing of the 100g Chinese, add 150ml petroleum ether to carry out soxhlet type and revolve after 14 hours
Boil off except solvent, be put in vacuum drying chamber and mixture B is dried to obtain under temperature 60 C；
（4）By 20g NaOH and 150g deionized water mixed dissolution；
（5）Add mixed-powder A, mixture B, 1g carboxymethyl chitosan, 1g mannosylerythritol lipid, 0.5 citric acid and
0.7g tartaric acid, 0.5g sodium chloride, 1g sodium hypophosphite, are stirred 30 minutes under rotating speed 500r/min with magnetic stirrer；
（6）2g lauroylamidopropyl betaine and 5g NPE is added, with magnetic stirrer in rotating speed 600r/
Stir 40 minutes under min；
（7）Being put in Ultrasound Instrument carries out sonic oscillation and obtains final product for 20 minutes.
Comparative example 1
A kind of preparation method of environment-friendly type antibiotic functional finishing agent, comprises the following steps：
（1）100g leaf of Moringa powder and 100g American lotus powder are mixed, adds 200ml deionized water and the anhydrous second of 300ml
Alcohol, extracts 20 hours at 35 DEG C；
（2）Add 5g activated carbon to be decolourized and drainage, filter, rotary evaporation is carried out after removing filter residue, be put into vacuum drying chamber
In dry to obtain mixed-powder A at 40 DEG C of temperature；
（3）By 15g NaOH and 100g deionized water mixed dissolution；
（4）Add mixed-powder A, 0.5g carboxymethyl chitosan, 0.5g mannosylerythritol lipid, 0.2g citric acid and 0.3g
Tartaric acid, 0.2g sodium chloride, 0.4g sodium hypophosphite, are stirred 10 minutes under rotating speed 300r/min with magnetic stirrer；
（5）1g lauroylamidopropyl betaine and 2g NPE is added, with magnetic stirrer in rotating speed 400r/
Stir 20 minutes under min；
（6）Being put in Ultrasound Instrument carries out sonic oscillation and obtains final product for 10 minutes.
Comparative example 2
A kind of preparation method of environment-friendly type antibiotic functional finishing agent, comprises the following steps：
（1）By 40g mao bamboon powder and the fiber crops powder mixing of the 60g Chinese, add 100ml petroleum ether to carry out soxhlet type and revolve after 12 hours
Boil off except solvent, be put in vacuum drying chamber and mixture B dried to obtain at 40 DEG C of temperature；
（2）By 15g NaOH and 100g deionized water mixed dissolution；
（3）Add mixture B, 0.5g carboxymethyl chitosan, 0.5g mannosylerythritol lipid, 0.2g citric acid and 0.3g wine
Stone acid, 0.2g sodium chloride, 0.4g sodium hypophosphite, are stirred 10 minutes under rotating speed 300r/min with magnetic stirrer；
（4）1g lauroylamidopropyl betaine and 2g NPE is added, with magnetic stirrer in rotating speed 400r/
Stir 20 minutes under min；
（5）Being put in Ultrasound Instrument carries out sonic oscillation and obtains final product for 10 minutes.
Pure cotton fabric impregnated in dressing liquid certain time, an immersing and rolling, pick-up is 85%, preliminary drying 5min at 80 DEG C,
After process 3min is baked at 170 DEG C, fabric is soaked 15min (bath raio 1 with running water:50) and constantly stir, then rinse
5min, removes residual reactant matter on fabric, last 80 DEG C of low temperature dryings.
Assay method：
According to GB/T8629-2001 standard, the fabric through antibiotic finish is washed, determines its anti-microbial property
According to GB/T3923.1-2013 standard, ultimate strength and the bursting strength of textile is determined
The antibacterial of the embodiment and comparative example of material of the present invention and take performance indications and see the table below, it will be seen that the present invention
Material has extraordinary fungistatic effect, and cotton is after treatment to Escherichia coli, Candida albicans and staphylococcus aureus
Inhibiting rate can reach 95.2%, 74.2% and 99.1%, after scrubbed 10 times respectively, its to Escherichia coli, Candida albicans and
The inhibiting rate of staphylococcus aureus still may be up to 81.9%, 61.9% and 84.8%, antibiotic property persistently, with good washable
Property.Ultimate strength is one of most important physical performance index of fabric, is the index of the ability for expressing fabric opposing stretching, through whole
The ultimate strength of the bafta after reason may be up to 911.7N, more high than unfinished 898.3N, and bursting strength highest also reaches
708.3N is arrived, more unfinished 683.7N is higher by 24.6N, with extraordinary pliability.
The antibacterial of the finishing agent of the present invention of table 1 and take performance indications
Claims (7)
1. a kind of preparation method of environment-friendly type antibiotic functional finishing agent, it is characterised in that：Comprise the following steps：
（1）100-150g leaf of Moringa powder and 100-200g American lotus powder are mixed, add 200-300ml deionized water and
300-500ml absolute ethyl alcohol, extracts 20-24 hour at 35-50 DEG C；
（2）Add 5-10g activated carbon to be decolourized and drainage, filter, after removing filter residue, rotary evaporation is carried out, be put into vacuum and do
Mixed-powder A is dried to obtain in dry case at temperature 40-60 DEG C；
（3）By 40-60g mao bamboon powder and the fiber crops powder mixing of the 60-100g Chinese, 100-150ml petroleum ether is added to carry out soxhlet type
After 12-14 hour, revolving removes solvent, is put in vacuum drying chamber and dries to obtain mixture B at temperature 40-60 DEG C；
（4）By 15-20g NaOH and 100-150g deionized water mixed dissolution；
（5）Add mixed-powder A, mixture B, 0.5-1g carboxymethyl chitosan, 0.5-1g mannosylerythritol lipid, 0.2-
0.5g citric acid and 0.3-0.7g tartaric acid, 0.2-0.5g sodium chloride, 0.4-1g sodium hypophosphite, with magnetic stirrer in rotating speed
Stir 10-30 minute under 300-500r/min；
（6）1-2g lauroylamidopropyl betaine and 2-5g NPE is added, with magnetic stirrer in rotating speed
Stir 20-40 minute under 400-600r/min；
（7）Being put in Ultrasound Instrument carries out sonic oscillation 10-20 minute and obtains final product.
2. the preparation method of a kind of environment-friendly type antibiotic functional finishing agent according to claim 1, it is characterised in that：The step
Suddenly（1）Middle extraction temperature is 40-45 DEG C, and extraction time is 21-23 hour.
3. the preparation method of a kind of environment-friendly type antibiotic functional finishing agent according to claim 1, it is characterised in that：The step
Suddenly（2）Middle baking temperature is 45-55 DEG C.
4. the preparation method of a kind of environment-friendly type antibiotic functional finishing agent according to claim 1, it is characterised in that：The step
Suddenly（3）Middle extraction times are 13 hours, and baking temperature is 50 DEG C.
5. the preparation method of a kind of environment-friendly type antibiotic functional finishing agent according to claim 1, it is characterised in that：The step
Suddenly（5）Middle rotating speed is 350-450r/min, and mixing time is 15-25 minute.
6. the preparation method of a kind of environment-friendly type antibiotic functional finishing agent according to claim 1, it is characterised in that：The step
Suddenly（6）Middle rotating speed is 450-550r/min, and mixing time is 25-35 minute.
7. the preparation method of a kind of environment-friendly type antibiotic functional finishing agent according to claim 1, it is characterised in that：The step
Suddenly（7）Middle ultrasonic time is 15 minutes.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107794755A (en) * | 2017-09-27 | 2018-03-13 | 江苏新瑞贝科技股份有限公司 | A kind of Antibiotic-odor Resistant Agent and preparation method thereof |
| CN108625171A (en) * | 2018-05-29 | 2018-10-09 | 叶建民 | A kind of preparation method of vamp fabric finishing agent |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103031716A (en) * | 2011-09-30 | 2013-04-10 | 天津市中科健新材料技术有限公司 | Finishing solution for deodorant wet tissue |
| CN104695219A (en) * | 2015-03-05 | 2015-06-10 | 苏州经贸职业技术学院 | Anti-wrinkle antibiotic finishing agent as well as preparation method and application thereof |
| CN104695214A (en) * | 2015-03-05 | 2015-06-10 | 苏州经贸职业技术学院 | Real silk polyphenol finishing agent and preparation method thereof |
| CN105544192A (en) * | 2016-01-21 | 2016-05-04 | 苏州经贸职业技术学院 | Natural antibacterial finishing agent and preparation method thereof |
-
2016
- 2016-10-27 CN CN201610953831.XA patent/CN106480714A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103031716A (en) * | 2011-09-30 | 2013-04-10 | 天津市中科健新材料技术有限公司 | Finishing solution for deodorant wet tissue |
| CN104695219A (en) * | 2015-03-05 | 2015-06-10 | 苏州经贸职业技术学院 | Anti-wrinkle antibiotic finishing agent as well as preparation method and application thereof |
| CN104695214A (en) * | 2015-03-05 | 2015-06-10 | 苏州经贸职业技术学院 | Real silk polyphenol finishing agent and preparation method thereof |
| CN105544192A (en) * | 2016-01-21 | 2016-05-04 | 苏州经贸职业技术学院 | Natural antibacterial finishing agent and preparation method thereof |
Non-Patent Citations (5)
| Title |
|---|
| 张建春、何锦风: "《汉麻籽综合利用加工技术》", 31 December 2010, 中国轻工业出版社 * |
| 张袁松: "《新型纤维材料概论》", 31 March 2012, 西南师范大学出版社 * |
| 王献培: "《食用小竹笋栽培与笋竹加工实用技术》", 31 January 2003, 上海科学普及出版社 * |
| 王红旗等: "《土壤微生物对石油烃的吸附摄取与跨膜运输》", 30 September 2015, 中国环境出版社 * |
| 盛军: "《现代辣木生物学》", 31 January 2015, 云南科技出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107794755A (en) * | 2017-09-27 | 2018-03-13 | 江苏新瑞贝科技股份有限公司 | A kind of Antibiotic-odor Resistant Agent and preparation method thereof |
| CN108625171A (en) * | 2018-05-29 | 2018-10-09 | 叶建民 | A kind of preparation method of vamp fabric finishing agent |
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