CN106479363A - High polymer SBS modified pitch water-emulsifying type waterproof coatings - Google Patents
High polymer SBS modified pitch water-emulsifying type waterproof coatings Download PDFInfo
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- CN106479363A CN106479363A CN201610985691.4A CN201610985691A CN106479363A CN 106479363 A CN106479363 A CN 106479363A CN 201610985691 A CN201610985691 A CN 201610985691A CN 106479363 A CN106479363 A CN 106479363A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a kind of high polymer SBS modified pitch water-emulsifying type waterproof coatings, belong to building waterproofing technique field, meter includes following component by weight：100 250 parts of SBS modified pitch, 10 50 parts of the rubber latex of solid content 30 50%, 10 50 parts of emulsion, 5 20 parts of fine powder, 5 20 parts of anion emulsifier, 5 20 parts of firming agent, 5 20 parts of binding agent, 50 150 parts of water.The present invention does not almost have a volatile matter, environmental protection, pollution-free；Durability, endurance, good-extensibility；All can bond with any foreign body；Pliability is good, adhesive force is good, does not ftracture, does not peel off；Easy construction；Good water-proof effect.
Description
Technical field
The present invention relates to building waterproofing technique field, specifically a kind of high polymer SBS modified pitch water-emulsifying type waterproof coatings.
Background technology
The seepage of building structure is to perplex a difficult problem, building waterproofing technique and the waterproof material of building trade for a long time
Always scientific research personnel puts forth effort the important topic studied.China's leakage of buildings situation situation is surprising and severe.
There is problems with existing waterproof material and waterproof construction technology：Rigidity water-proofing material is easily deformed by basic unit
Affect and lead to the cracking of waterproof layer, directly affect its water-proof function；Flexible waterproof material in use, because of construction or outer
Power causes basal plane or waterproof material to damage, and can lead to water inlet between waterproof layer and basal plane, if waterproof roll is using point paving or bar
The mode of paving, then easily cause channeling water after water inlet, once there is leakage of buildings phenomenon, is difficult to find source, to maintenance
Cause difficulty.And if by the way of full paving, although because the bonding between waterproof material and basal plane, can play certain
Intercept the effect of water, but because material adheres to substrate surface, what during base course crack, waterproof material still showed is zero extension：I.e.
Make material have certain elongation percentage in itself, but when base course crack, material also destroys therewith, or only small extension, and not
Possesses real anti-base course crack ability.The concept of " zero extension " is in the industry cycle recognized.Viscous in flexible waterproof layer and basic unit
, there is a contradiction always in knot aspect.If waterproof layer is firmly bonded with basic unit, advantage is to be not in drum phenomenon, also not
Channeling water phenomenon under waterproof layer easily occurs.Shortcoming is that waterproof layer is deformed by basic unit and affected big, once base course crack, waterproof layer is subject to
During to action of pulling stress, the waterproof layer of crack both sides does not almost have stripping area, and tension can only cannot be concentrated to both sides transmission
In cracking position, waterproof layer may be caused by drawing crack in the crack of very little；Even if not by drawing crack, the waterproof layer of location of cracks also can
Due to being chronically at high-stress state and accelerated ageing, or because stretching repeatedly produces fatigue rupture.Therefore just have
Predictable location of cracks such as plate end seam etc. takes empty paving to process, or waterproof layer is all spread, put viscous or bar paving using empty
Waterproofing process, this is also one of way that current specification is recommended.But thus create another question, that is, once preventing again
Water layer produces minuscule hole or crack and leak at certain position, arises that channeling water as and being difficult to find under waterproof layer
The source of seepage, brings very big difficulty to patch work.
Content of the invention
In view of this, the present invention is intended to provide a kind of durability, endurance, caking property is good, pliability is good, easy construction
High polymer SBS modified pitch water-emulsifying type waterproof coatings.
For reaching above-mentioned purpose, the technical scheme is that and be achieved in that：A kind of high polymer SBS modified pitch water and milk
Type water-repellent paint, by weight meter include following component：SBS modified pitch 100-250 part, the rubber of solid content 30-50%
Latex 10-50 part, emulsion 10-50 part, fine powder 5-20 part, anion emulsifier 5-20 part, firming agent 5-20 part, binding agent 5-20
Part, water 50-150 part.
Further, meter includes following component by weight：SBS modified pitch 150-200 part, solid content 30-50%
Rubber latex 30-50 part, emulsion 30-50 part, fine powder 10-20 part, anion emulsifier 10-20 part, firming agent 10-20 part,
Binding agent 10-20 part, water 80-120 part.
Further, meter includes following component by weight：180 parts of SBS modified pitch, the rubber of solid content 30-50%
40 parts of glue latex, 40 parts of emulsion, 15 parts of fine powder, 15 parts of anion emulsifier, 15 parts of firming agent, 15 parts of binding agent, 100 parts of water.
Further, described emulsion is EU, polyvinyl alcohol, butadiene-styrene rubber and tripolycyanamide with 1-15：1-
10：10-20：The mixture of 10-20 quality proportioning.
Further, described fine powder is that one or more of Pulvis Talci, titanium dioxide, porcelain powder are mixed with arbitrary proportion.
Further, described anion emulsifier is metal carboxylate, sulfuric ester salt, Sulfonateses or phosphate ester salt apoplexy due to endogenous wind
One or more with arbitrary proportion mix.
Further, described firming agent is calcium chloride, sodium chloride, zinc oxide, ferrum oxide and copper oxide with 1-10：1-10：
1-10：The mixture of 1-10 quality proportioning.
Further, described binding agent is polyacrylate, acrylonitrile polymer, Polystyrene-acrylate, polyethylene
One or more of polyvinyl butyral resin is mixed with arbitrary proportion.
Present invention also offers the preparation method of above-mentioned high polymer SBS modified pitch water-emulsifying type waterproof coatings, including as follows
Step：
(1) weigh each component by weight, by SBS modified pitch, the rubber latex of solid content 30-50% and emulsion are mixed
Close, be at the uniform velocity stirred and heated to 150-200 DEG C of melting；
(2) to the mixture uniform stirring of described step (1) and be cooled to 60-90 DEG C, add fine powder, anionic emulsifying
Agent, binding agent and water, at the uniform velocity stir；
(3) mixture of described step (2) is at the uniform velocity stirred and be cooled to 40-50 DEG C of addition firming agent, at the uniform velocity stirring fall
To room temperature.
Present invention also offers above-mentioned high polymer SBS modified pitch water-emulsifying type waterproof coatings answering in preparing waterproof roll
With.
With respect to prior art, the present invention has the advantage that：
The present invention does not almost have a volatile matter, environmental protection, pollution-free；Durability, endurance, good-extensibility；Different with any
Thing all can bond；Pliability is good, adhesive force is good, does not ftracture, does not peel off；Easy construction；Good water-proof effect.
Specific embodiment
With reference to embodiment, the present invention will be described.
Embodiment one
A kind of high polymer SBS modified pitch water-emulsifying type waterproof coatings, by weight meter include following component：SBS is modified
180 parts of Colophonium, 40 parts of the rubber latex of solid content 30-50%, emulsion：10 parts of EU, 10 parts of polyvinyl alcohol, butylbenzene
10 parts of rubber, 10 parts of tripolycyanamide, fine powder：15 parts of Pulvis Talci, anion emulsifier：15 parts of carboxylic acid sodium, firming agent：Calcium chloride 3
Part, 3 parts of sodium chloride, 3 parts of zinc oxide, 3 parts of ferrum oxide, 3 parts of copper oxide, binding agent：15 parts of polyacrylate, 100 parts of water.
The preparation method of above-mentioned high polymer SBS modified pitch water-emulsifying type waterproof coatings, comprises the steps：
(1) weigh each component by weight, by SBS modified pitch, the rubber latex of solid content 30% and emulsion mix,
At the uniform velocity it is stirred and heated to 150 DEG C of meltings；
(2) to the mixture uniform stirring of described step (1) and be cooled to 70 DEG C, add fine powder, anion emulsifier, glue
Knot agent and water, at the uniform velocity stir；
(3) mixture of described step (2) is at the uniform velocity stirred and be cooled to 45 DEG C of addition firming agent, room is down at the uniform velocity stirring
Temperature.
Embodiment two
A kind of high polymer SBS modified pitch water-emulsifying type waterproof coatings, by weight meter include following component：SBS is modified
150 parts of Colophonium, 30 parts of the rubber latex of solid content 30-50%, emulsion：5 parts of EU, 5 parts of polyvinyl alcohol, butylbenzene rubber
10 parts of glue, 10 parts of tripolycyanamide, fine powder：10 parts of Pulvis Talci, 10 parts of titanium dioxide, anion emulsifier：20 parts of cycloalkanes sodium sulfate, Gu
Agent：4 parts of calcium chloride, 4 parts of sodium chloride, 4 parts of zinc oxide, 4 parts of ferrum oxide, 4 parts of copper oxide, binding agent：Acrylonitrile polymer 20
Part, 120 parts of water.
The preparation method of above-mentioned high polymer SBS modified pitch water-emulsifying type waterproof coatings, comprises the steps：
(1) weigh each component by weight, by SBS modified pitch, the rubber latex of solid content 35% and emulsion mix,
At the uniform velocity it is stirred and heated to 180 DEG C of meltings；
(2) to the mixture uniform stirring of described step (1) and be cooled to 60 DEG C, add fine powder, anion emulsifier, glue
Knot agent and water, at the uniform velocity stir；
(3) mixture of described step (2) is at the uniform velocity stirred and be cooled to 40 DEG C of addition firming agent, room is down at the uniform velocity stirring
Temperature.
Embodiment three
A kind of high polymer SBS modified pitch water-emulsifying type waterproof coatings, by weight meter include following component：SBS is modified
200 parts of Colophonium, 50 parts of the rubber latex of solid content 30-50%, emulsion：15 parts of EU, 5 parts of polyvinyl alcohol, butylbenzene
15 parts of rubber, 15 parts of tripolycyanamide, fine powder：5 parts of titanium dioxide, 5 parts of porcelain powder, anion emulsifier：NPE sulphur
10 parts of hydrochlorate, firming agent：2 parts of calcium chloride, 2 parts of sodium chloride, 2 parts of zinc oxide, 2 parts of ferrum oxide, 2 parts of copper oxide, binding agent：Polyphenyl
10 parts of ethylene-acrylate, 80 parts of water.
The preparation method of above-mentioned high polymer SBS modified pitch water-emulsifying type waterproof coatings, comprises the steps：
(1) weigh each component by weight, by SBS modified pitch, the rubber latex of solid content 45% and emulsion mix,
At the uniform velocity it is stirred and heated to 200 DEG C of meltings；
(2) to the mixture uniform stirring of described step (1) and be cooled to 90 DEG C, add fine powder, anion emulsifier, glue
Knot agent and water, at the uniform velocity stir；
(3) mixture of described step (2) is at the uniform velocity stirred and be cooled to 50 DEG C of addition firming agent, room is down at the uniform velocity stirring
Temperature.
Example IV
A kind of high polymer SBS modified pitch water-emulsifying type waterproof coatings, by weight meter include following component：SBS is modified
250 parts of Colophonium, 10 parts of the rubber latex of solid content 30-50%, emulsion：5 parts of EU, 5 parts of polyvinyl alcohol, butylbenzene rubber
20 parts of glue, 20 parts of tripolycyanamide, fine powder：5 parts of Pulvis Talci, 5 parts of titanium dioxide, 10 parts of porcelain powder, anion emulsifier：Dodecyl phosphorus
20 parts of sour sodium, firming agent：4 parts of calcium chloride, 4 parts of sodium chloride, 4 parts of zinc oxide, 4 parts of ferrum oxide, 4 parts of copper oxide, binding agent：Poly- second
5 parts of enol butyral resin, 50 parts of water.
Present invention also offers the preparation method of above-mentioned high polymer SBS modified pitch water-emulsifying type waterproof coatings, including as follows
Step：
(1) weigh each component by weight, by SBS modified pitch, the rubber latex of solid content 50% and emulsion mix,
At the uniform velocity it is stirred and heated to 150 DEG C of meltings；
(2) to the mixture uniform stirring of described step (1) and be cooled to 90 DEG C, add fine powder, anion emulsifier, glue
Knot agent and water, at the uniform velocity stir；
(3) mixture of described step (2) is at the uniform velocity stirred and be cooled to 40 DEG C of addition firming agent, room is down at the uniform velocity stirring
Temperature.
Contrast test
The indices of the product of various embodiments of the present invention and commercially available prod are detected, testing result is as shown in table 1.
The each embodiment of table 1 and commercially available prod indices testing result
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Within god and principle, any modification, equivalent substitution and improvement made etc., should be included within the scope of the present invention.
Claims (10)
1. a kind of high polymer SBS modified pitch water-emulsifying type waterproof coatings it is characterised in that：Meter is included as the following group by weight
Point：SBS modified pitch 100-250 part, rubber latex 10-50 part of solid content 30-50%, emulsion 10-50 part, fine powder 5-20
Part, anion emulsifier 5-20 part, firming agent 5-20 part, binding agent 5-20 part, water 50-150 part.
2. a kind of high polymer SBS modified pitch water-emulsifying type waterproof coatings according to claim 1 it is characterised in that：By weight
Amount number meter includes following component：SBS modified pitch 150-200 part, rubber latex 30-50 part of solid content 30-50%, emulsion
30-50 part, fine powder 10-20 part, anion emulsifier 10-20 part, firming agent 10-20 part, binding agent 10-20 part, water 80-120
Part.
3. a kind of high polymer SBS modified pitch water-emulsifying type waterproof coatings according to claim 1 it is characterised in that：By weight
Amount number meter includes following component：180 parts of SBS modified pitch, 40 parts of the rubber latex of solid content 30-50%, 40 parts of emulsion, carefully
15 parts of powder, 15 parts of anion emulsifier, 15 parts of firming agent, 15 parts of binding agent, 100 parts of water.
4. a kind of high polymer SBS modified pitch water-emulsifying type waterproof coatings according to claim 1 it is characterised in that：Described
Emulsion is EU, polyvinyl alcohol, butadiene-styrene rubber and tripolycyanamide with 1-15：1-10：10-20：10-20 quality proportioning
Mixture.
5. a kind of high polymer SBS modified pitch water-emulsifying type waterproof coatings according to claim 1 it is characterised in that：Described
Fine powder is that one or more of Pulvis Talci, titanium dioxide, porcelain powder are mixed with arbitrary proportion.
6. a kind of high polymer SBS modified pitch water-emulsifying type waterproof coatings according to claim 1 it is characterised in that：Described
Anion emulsifier be one or more of metal carboxylate, sulfuric ester salt, Sulfonateses or phosphates with arbitrarily than
Example mixing.
7. a kind of high polymer SBS modified pitch water-emulsifying type waterproof coatings according to claim 1 it is characterised in that：Described
Firming agent is calcium chloride, sodium chloride, zinc oxide, ferrum oxide and copper oxide with 1-10：1-10：1-10：1-10 quality proportioning mixed
Compound.
8. a kind of high polymer SBS modified pitch water-emulsifying type waterproof coatings according to claim 1 it is characterised in that：Described
Binding agent is one of polyacrylate, acrylonitrile polymer, Polystyrene-acrylate, polyvinyl butyral resin
Or several with arbitrary proportion mixing.
9. the preparation method of the high polymer SBS modified pitch water-emulsifying type waterproof coatings as described in a kind of any one as claim 1-8,
It is characterized in that：Comprise the steps：
(1) weigh each component by weight, by SBS modified pitch, the rubber latex of solid content 30-50% and emulsion mix,
At the uniform velocity it is stirred and heated to 150-200 DEG C of melting；
(2) to the mixture uniform stirring of described step (1) and be cooled to 60-90 DEG C, add fine powder, anion emulsifier, glue
Knot agent and water, at the uniform velocity stir；
(3) mixture of described step (2) is at the uniform velocity stirred and be cooled to 40-50 DEG C of addition firming agent, room is down at the uniform velocity stirring
Temperature.
10. the high polymer SBS modified pitch water-emulsifying type waterproof coatings as described in a kind of any one as claim 1-8 are in preparation waterproof
Application in coiled material.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610985691.4A CN106479363A (en) | 2016-11-09 | 2016-11-09 | High polymer SBS modified pitch water-emulsifying type waterproof coatings |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610985691.4A CN106479363A (en) | 2016-11-09 | 2016-11-09 | High polymer SBS modified pitch water-emulsifying type waterproof coatings |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107474716A (en) * | 2017-08-22 | 2017-12-15 | 安徽艾米伦特建材科技有限公司 | Polyurethane water-proof paint and preparation method thereof |
| CN112942447A (en) * | 2021-03-15 | 2021-06-11 | 福建筑兆建设有限公司 | Construction method of high-viscosity anti-slip waterborne polymer modified asphalt waterproof coating in basement waterproofing |
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| CN103525106A (en) * | 2013-10-14 | 2014-01-22 | 浙江鲁班建筑防水有限公司 | Water-emulsion type modified asphalt with creep characteristic and preparation method thereof |
| CN103788662A (en) * | 2012-10-29 | 2014-05-14 | 中国石油化工股份有限公司 | Emulsified asphalt, a preparation method thereof, applications thereof, a water-proof coating material and a water-proof coating |
| CN105315471A (en) * | 2015-11-25 | 2016-02-10 | 北京东方雨虹防水技术股份有限公司 | Emulsified SBS modified asphalt and reparation method thereof, waterproof coating and reparation method thereof |
| CN105482705A (en) * | 2015-12-30 | 2016-04-13 | 张力元 | Waterproof coating |
-
2016
- 2016-11-09 CN CN201610985691.4A patent/CN106479363A/en active Pending
Patent Citations (5)
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| CN103788662A (en) * | 2012-10-29 | 2014-05-14 | 中国石油化工股份有限公司 | Emulsified asphalt, a preparation method thereof, applications thereof, a water-proof coating material and a water-proof coating |
| CN103525307A (en) * | 2013-10-14 | 2014-01-22 | 浙江鲁班建筑防水有限公司 | Machine-spraying quick-demulsifying solidification film formation creep waterproof coating and preparation method thereof |
| CN103525106A (en) * | 2013-10-14 | 2014-01-22 | 浙江鲁班建筑防水有限公司 | Water-emulsion type modified asphalt with creep characteristic and preparation method thereof |
| CN105315471A (en) * | 2015-11-25 | 2016-02-10 | 北京东方雨虹防水技术股份有限公司 | Emulsified SBS modified asphalt and reparation method thereof, waterproof coating and reparation method thereof |
| CN105482705A (en) * | 2015-12-30 | 2016-04-13 | 张力元 | Waterproof coating |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107474716A (en) * | 2017-08-22 | 2017-12-15 | 安徽艾米伦特建材科技有限公司 | Polyurethane water-proof paint and preparation method thereof |
| CN112942447A (en) * | 2021-03-15 | 2021-06-11 | 福建筑兆建设有限公司 | Construction method of high-viscosity anti-slip waterborne polymer modified asphalt waterproof coating in basement waterproofing |
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Application publication date: 20170308 |
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