CN106456818A - Composition for removing undesired molecules - Google Patents
Composition for removing undesired molecules Download PDFInfo
- Publication number
- CN106456818A CN106456818A CN201580023323.5A CN201580023323A CN106456818A CN 106456818 A CN106456818 A CN 106456818A CN 201580023323 A CN201580023323 A CN 201580023323A CN 106456818 A CN106456818 A CN 106456818A
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- Prior art keywords
- compositionss
- cyclodextrin
- branched chain
- highly branched
- mentioned
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- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 1
- COLNVLDHVKWLRT-QMMMGPOBSA-N L-phenylalanine Chemical compound OC(=O)[C@@H](N)CC1=CC=CC=C1 COLNVLDHVKWLRT-QMMMGPOBSA-N 0.000 description 1
- 244000147568 Laurus nobilis Species 0.000 description 1
- 235000017858 Laurus nobilis Nutrition 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- PICZJQWBACIZOM-UHFFFAOYSA-N S(=O)(=O)(O)O.C(CCCCCCCCCCC)(=O)[K] Chemical compound S(=O)(=O)(O)O.C(CCCCCCCCCCC)(=O)[K] PICZJQWBACIZOM-UHFFFAOYSA-N 0.000 description 1
- LKVZSCFGTYHYBT-UHFFFAOYSA-N S(=O)(=O)(O)O.C(CCCCCCCCCCC)(=O)[Na] Chemical compound S(=O)(=O)(O)O.C(CCCCCCCCCCC)(=O)[Na] LKVZSCFGTYHYBT-UHFFFAOYSA-N 0.000 description 1
- PHIIYDSPMYGDAF-UHFFFAOYSA-N S(=O)(=O)(O)O.C(CCCCCCCCCCC)[K] Chemical compound S(=O)(=O)(O)O.C(CCCCCCCCCCC)[K] PHIIYDSPMYGDAF-UHFFFAOYSA-N 0.000 description 1
- HREUQCWXLFXWGA-UHFFFAOYSA-N S(=O)(=O)([O-])[O-].C(CCCCCCCCCCC)(=O)[NH3+].C(CCCCCCCCCCC)(=O)[NH3+] Chemical compound S(=O)(=O)([O-])[O-].C(CCCCCCCCCCC)(=O)[NH3+].C(CCCCCCCCCCC)(=O)[NH3+] HREUQCWXLFXWGA-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000004147 Sorbitan trioleate Substances 0.000 description 1
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 208000006011 Stroke Diseases 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 235000005212 Terminalia tomentosa Nutrition 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- OOCCDEMITAIZTP-UHFFFAOYSA-N allylic benzylic alcohol Natural products OCC=CC1=CC=CC=C1 OOCCDEMITAIZTP-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- YPZUZOLGGMJZJO-LQKXBSAESA-N ambroxan Chemical compound CC([C@@H]1CC2)(C)CCC[C@]1(C)[C@@H]1[C@]2(C)OCC1 YPZUZOLGGMJZJO-LQKXBSAESA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N beta-methyl-butyric acid Natural products CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- MKHVZQXYWACUQC-UHFFFAOYSA-N bis(2-hydroxyethyl)azanium;dodecyl sulfate Chemical compound OCCNCCO.CCCCCCCCCCCCOS(O)(=O)=O MKHVZQXYWACUQC-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- MIZGSAALSYARKU-UHFFFAOYSA-N cashmeran Chemical compound CC1(C)C(C)C(C)(C)C2=C1C(=O)CCC2 MIZGSAALSYARKU-UHFFFAOYSA-N 0.000 description 1
- 210000000085 cashmere Anatomy 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 230000001149 cognitive effect Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- HRKQOINLCJTGBK-UHFFFAOYSA-N dihydroxidosulfur Chemical compound OSO HRKQOINLCJTGBK-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- WKCCHCOTEVHSER-UHFFFAOYSA-L disodium propane-1,2,3-triol sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.OCC(O)CO WKCCHCOTEVHSER-UHFFFAOYSA-L 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229940093468 ethylene brassylate Drugs 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- GDSRMADSINPKSL-HSEONFRVSA-N gamma-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO GDSRMADSINPKSL-HSEONFRVSA-N 0.000 description 1
- 229940080345 gamma-cyclodextrin Drugs 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 150000005619 secondary aliphatic amines Chemical class 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 235000019615 sensations Nutrition 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 235000012976 tarts Nutrition 0.000 description 1
- KRTNITDCKAVIFI-UHFFFAOYSA-N tridecyl benzenesulfonate Chemical compound CCCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 KRTNITDCKAVIFI-UHFFFAOYSA-N 0.000 description 1
- PVNIQBQSYATKKL-UHFFFAOYSA-N tripalmitin Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCC PVNIQBQSYATKKL-UHFFFAOYSA-N 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Fats And Perfumes (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Detergent Compositions (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention comprises highly branched cyclic dextrin (HBCD) or derivatives thereof, a perfume included in at least one or more internal spaces of the HBCD, and a solvent, thereby being capable of eliminating undesired foreign materials such as molecules, for example, remarkably enhanced odor sources while producing a fragrance having a highly preferable scent. Also, the composition for removing undesired molecules according to the present invention further comprises a plant extract, thereby producing a synergistic effect on the removal of odors.
Description
Technical field
The present invention relates to one kind can remove does not need molecule, and the compositionss of fragrance material can be transmitted.
The application is based on 2014 04 month korean patent application filed in 28 days No. 10-2014-0050740,2014
07 month korean patent application filed in 11 days the 10-2014-0087656th and 2015 01 month Korea S filed in 07 day are special
Profit application 10-2015-0002127 CLAIM OF PRIORITY, and will be all disclosed in the specification and drawings of above-mentioned application
Content is quoted in the application.
Background technology
Generally, the source of the stench producing in living space is varied, and most stench is mainly sulfur system or nitrogen
Being composited of the multiple compositions such as system.Method as removing this stench, has physical method, chemical method, biological method
Or aesthetic deodorizing method etc..Physical method refers to, is entered by porous masses such as activated carbon, silica gel, zeolite, aluminium oxide or potteries
The method of row absorption, or the method being absorbed by surfactant etc..Chemical method refers to, using neutralization reaction, contracting
Close reaction, additive reaction, oxidation reaction or reduction reaction etc., will there is to odor pollutant the material of high response or become with stench
The material dividing reacting generating complex is used as the method that deodorizer removes stench.Biological method refers to, using surfactant, second
Glycol, microorganism or enzyme etc., the antibacterial (bacteria) to the producing cause as stench is sterilized or is prevented corruption from (being divided
Solution), thus the method for deodorization.Aesthetic deodorizing method refers to, stench is stimulated into line replacement by aromatic substances such as spice or
The method of neutralization.In addition to the method described above, also multiple technology for removing stench are known, but current situation
It is a lack of can persistently removing the technology of stench.
For removing numerous requirements that the abnormal flavour being present in medicated clothing, living space, limited interior space etc. proposes, look forward to
Industry is by using to laundry detergents, softening agent for fibres, surface cleaning agent, kitchen detergent, deodorizer, shampoo, hair conditioner, body
The various use of product, bromhidrosis remover etc. is studied it is intended to be reached above-mentioned purpose.In numerous researchs, remove as effective
One of material, has the example (US6,878,695) using cyclodextrin (cyclodextrine).Above-mentioned cyclodextrin is 6～12
Glucose passes through the polysaccharide of the bonded circulus of α -1,4.As one of the most cyclodextrin of application, α-ring paste
Spermatophore contains 6 glucoses；As another example, beta-schardinger dextrin-comprises 7 glucoses；As another example, gamma-cyclodextrin comprises
8 glucoses, these are respectively provided with the ring structure of cast (doughnut).
Specific combination between glucose or structure, make cyclodextrin present the firm circle with designated volume space
Pyramidal structure." arrangement " of each inner space, is to be formed by defining the crosslinked oxygen atom of glucoside with hydrogen atom.Cause
This, interior surface thereof has very strong hydrophobicity, and, specific interior shape and physicochemical characteristicss are so as to have energy
Enough absorb the structure of a part for the shape organic molecule consistent with the inner space of cyclodextrin or derivatives thereof or organic molecule
Characteristic.Thus, when in the body surface preparation containing cyclodextrin for the coating, the inside of the foreign body inclusion such as abnormal flavour to cyclodextrin is empty
Between such that it is able to go to eliminate the unusual smell.In addition, by the fabrication process, some spice being impregnated in product such that it is able to make
With during continue fragrant.
However, the inner space size of above-mentioned cyclodextrin is certain, therefore there is the fragrance material being capable of inclusion and different
Shortcoming limited by taste material, and, in the case of containing the water-soluble solvents such as water in preparation, due to the slightly solubility of cyclodextrin,
Limited by the performance of its efficiency.Especially, usually as the material with outstanding residual perfume characteristic and good abnormal flavour spreadability it is
The fragrance material that known to people, ClogP is more than 250 DEG C for more than 3 and b.p. (boiling points), it is fully removed different based on cyclodextrin
There is limit in the transmission of the ability of taste material and fragrance material.In addition, the dissolubility of cyclodextrin is low, in order to overcome this problem,
Develop derivant, as the example of cyclodextrin, have：The material that a part for OH base is replaced by OR base；R is taken by methyl or ethyl
The form in generation；R is by-CH2-CH(OH)-CH3Or-CH2CH2The form that the hydroxypropyls such as-OH base replace；Sun with cationic in pH
Ion cyclodextrin etc..
The present invention relates to a kind of can remove the material not needing molecule, more specifically, it is related to one kind different in order to remove
Taste and the problems referred to above present in the conventional cyclodextrin using are carried out perfect, and being capable of the more kinds of fragrance material of inclusion and foreign body
The material of material.
Content of the invention
Invent problem to be solved
Therefore, the invention solves the problems that problem be, using the inner space with wider more kinds of size cyclisation paste
Smart (Cyclic Dextrin), not only easily removes and was unable to a greater variety of in cyclodextrin of inclusion in the past and does not need molecule,
More specifically not only easily remove various sources of odor, and, can inclusion to be unable to inclusion more kinds of in cyclodextrin in the past
There is hydrophobicity and the big fragrance material of molecular weight.
In addition, the invention solves the problems that problem be, provide a kind of using having the inner space of wider more kinds of size
Cyclodextrin, discharge the fragrance material in cyclodextrin inner space for the inclusion, and inclusion sources of odor, thus go to eliminate the unusual smell and
The compositionss of transmission fragrance and its expression method.
In addition, the invention solves the problems that problem be, provide a kind of employ highly branched chain cyclodextrin for remove not
Need the manufacture method of the compositionss of molecule.
The technical scheme of solve problem
In order to solve above-mentioned problem, the present invention provide a kind of for removing the compositionss not needing molecule it is characterised in that
Including：Highly branched chain cyclodextrin (Highly Branched Cyclic Dextrin, HBCD) or derivatives thereof；Above-mentioned branched
The spice of inclusion at least more than one inner space of chain cyclization dextrin；And solvent.
According to a currently preferred embodiment, above-mentioned highly branched chain cyclodextrin can be by α -1,6- glycosidic bond
(alpha-1,6-glucosidic bond) is connected with the form of the D-Glucose within 16～100.
In addition, according to currently preferred another embodiment, the dextrose equivalent value of above-mentioned highly branched chain cyclodextrin
(Dextrose equivalent value) can be less than 5.
In addition, according to currently preferred another embodiment, above-mentioned highly branched chain cyclodextrin can be by alpha-D-glucose
As the oligosaccharide of monomer, it is by chemical formula (C6H10O5)xH2The compound that O (x is 200～5000 integer) represents.
In addition, according to currently preferred another embodiment, the mean molecule quantity of above-mentioned highly branched chain cyclodextrin can be
30000～1000000g/mol.
In addition, according to currently preferred another embodiment, the content of above-mentioned highly branched chain cyclodextrin is with respect to compositionss
Gross weight is 0.01 weight %～20 weight %.
In addition, according to currently preferred another embodiment, above-mentioned solvent can comprise water.
In addition, according to currently preferred another embodiment, above-mentioned composition can also comprise surfactant.
In addition, according to currently preferred another embodiment, above-mentioned composition can also comprise water-soluble polymer.
In addition, according to currently preferred another embodiment, above-mentioned composition can also comprise plant extract.
Below, describe the present invention in detail.Term and word used in this specification and interest field, should not limit to
Meaning in common meaning and dictionary explaining it should based in order to the invention of oneself is illustrated with optimal method,
Inventor can suitably define the principle of term concept, to be explained with the meaning and concept being suitable for the technology of the present invention thought.
Therefore, the embodiment described in this specification and the composition described in accompanying drawing, only one of preferred embodiment, can not generation
The all of technological thought of the table present invention is it should be understood that these embodiments can be replaced with multiple equipollents and variation.
The present invention relates to a kind of compositionss not needing molecule for removal, it includes：Highly branched chain cyclodextrin (Highly
Branched Cyclic Dextrin, HBCD) or derivatives thereof；Inclusion above-mentioned highly branched chain cyclodextrin at least one with
Spice in upper inner space；And solvent.
The inventors discovered that being certain for going the cyclodextrin eliminating the unusual smell, its inner space and shape, therefore, institute's inclusion
Sources of odor or spice limited by, in order to improve this problem it is proposed that the dextrin of highly branched chain circulus, wider more kinds of to have
The inner space of size, and there is unlike cyclodextrin single structure space.Compared with the conventional cyclodextrin using, confirm
The dextrin of this highly branched chain circulus not only goes the ability of eliminating the unusual smell to be significantly improved, and being capable of the conventional cyclodextrin of inclusion
The molecular weight being unable to inclusion greatly and has hydrophobic fragrance material, can improve abnormal flavour removal ability further, thus completing
The present invention.
And, surprisingly, it was found that work as also containing specific plant extract together with highly branched chain cyclodextrin
In the case of, compared with the individually situation containing highly branched chain cyclodextrin or plant extract, raising abnormal flavour can be worked in coordination with
Removal effect, thus complete the present invention.
In the present invention it is not necessary to molecule refers to, there is the sources of odor of undesirable abnormal smells from the patient as organic aromatic molecules.This
Plant sources of odor and be present in the fabric faces such as carpet；Cooking table for kitchen use, plate, ground, refuse receptacle, ceiling, wall, carpet,
The household supplies such as air cleaning filter；And the surface of skin, hair etc., the present invention can remove and this not need the molecule to be
Sources of odor.As this sources of odor, for example, as it is known that (E) -5- methyl -2- hexenoic acid, 5- methyl -4- hexenoic acid, 6- heptenoic acid,
The materials such as isovaleric acid, 4- methylhexenoic acid or ethyl octanoic acid are possible to the smell component (Flavor producing in dry goods
And Fragrance Journal, 2012, vol.27,89-94), and, the smell component from human body has been also carried out respectively
Kind research (Anti-Aging Medicine, 2010,7 (6):60-65).Sources of odor described in the present invention, refer to usually from
Human body, in the daily life such as fabric it may happen that general smell component it is not limited to above-mentioned example.
The compositionss of the present invention can be with emulsion/dispersion phase or transparent single phase soln Form deposit
?.
In the case of the abnormal flavour for removing fabric or human body, the compositionss of the present invention are preferably transparent single-phase molten
Liquid, has transparent or semitransparent character, preferably has the transparent character as clear water.
In addition, in the case that the compositionss of the present invention are as detergent, softening agent, shampoo, surfactant detergent, preferably
For emulsion/dispersion phase, generally have size be more than about 0.05 μm, be preferably from about more than 0.1 μm, be even more preferably about 0.2 μm with
On micelle (micell) or vesicle (Vesicle) molecule aggregation.This composition according to the substance classes in compositionss and
Concentration, can be presented in transparent, translucent, nontransparent.
The compositionss of the present invention can effectively transmit highly branched chain (hyperbranched) circulus dextrin or derivatives thereof
Compositionss are it is not limited to above-mentioned dosage form.
Below, describe the composition for removing the compositionss not needing molecule in detail.
1) highly branched chain cyclodextrin (Highly branched Cyclic Dextrin, HBCD)
Under normal circumstances, in the past for removing in the compositionss not needing material, always using cyclodextrin and its derivative
Thing.Cyclodextrin comprises 6～8 glucoses, and these glucoses have the circulus of cast (doughnut).This cyclodextrin
In, the particular key between glucose and structure, cyclodextrin can be made to become the firm cone knot with designated volume space
Structure.The arrangement of each inner space, to be formed by constituting the crosslinked oxygen atom of glucoside with hydrogen atom.Therefore, interior surface tool
There is very strong hydrophobicity, its internal given shape and physicochemical properties, cyclodextrin and its derivant can be enable to inhale
Receive a part for the space organic molecule consistent with it with shape or organic molecule such that it is able to remove smell substance.In addition,
There is in this internal given shape the spice for giving fresh feel, thus having in the presence of abnormal flavour, replace spice and
Mechanism in cyclodextrin for the inclusion.
Used in the present invention, cyclodextrin is different from the above-mentioned cyclodextrin with single space structure, but has wider
The inner space of more kinds of sizes, to make up the limitation of cyclodextrin.
Used in the present invention, cyclodextrin is highly branched chain cyclodextrin, and above-mentioned highly branched chain cyclodextrin refers to, is such as propping up
On the linear chain of chain starch, by α -1,6 keys destroy the link of the glucose polymer polysaccharide with hyperbranched shape
Close, and the chain combination that these are damaged forms the chemical constitution of closed chain by branching enzyme (branching enzyme), make
For one, formed by the method illustrated in Fig. 1.
More specifically, the highly branched chain cyclodextrin that the present invention uses can be by (C6H10O5)xH2O (x be 200～5000 whole
Number) represent, it is tasteless, the white powdery oligosaccharide using alpha-D-glucose as monomer (monomer)
(oligosaccharide), every mole of mean molecule quantity (g/mol) is about 30000～1000000, preferably from about 100000
～900000, even more preferably about 200000～800000, more preferably about 300000～700000, most preferably about
400000～600000.When above-mentioned mean molecule quantity is less than 30000g/mol, inner space is narrow, thus the stench big to size
Composition or the Binding ability reduction of the spice to all size, when more than 1000000g/mol, hinder the steady of combination dosage form
Qualitative and stability of molecule.The degree of polymerization is 2500 glucose unit.In addition, dextrose equivalent value (dextrose
Equivalent (DE) value), i.e. D-Glucose reducing power be preferably less than 5.Additionally, it is preferred that being by α-Isosorbide-5-Nitrae bond formed
Linear chain on, by α -1 on side chain, 6- glycosidic bond (alpha-1,6-glucosidic bond) be connected with 16～100 with
The form of interior D-Glucose.By such bonding structure, highly branched chain cyclodextrin is made to have the alpha-glucanses part of ring-type
(cyclic alpha-glucan moiety).
As described above, when the highly branched chain cyclodextrin of the present invention meets D- on above-mentioned mean molecule quantity, equivalent value and side chain
During the conditions such as amount of glucose, can preferably be dissolved in water, the Binding ability of fragrance is more suitable for, thus more meeting the present invention's
Purpose.
In addition, the derivant of highly branched chain circulus dextrin refers to, in the highly branched chain circulus keeping the invention described above
The basic structure of dextrin, under conditions of being obtained in that present invention institute based on this architectural feature is functional, on not affecting this
The structure that the atom of the part of bright function or atomic group are replaced.
As noted previously, as employing the highly branched chain circulus paste with hyperbranched phase in the present compositions
Essence, on the surface for the treatment of compositions, is improved with the ability not needing molecule to be combined, compared with cyclodextrin derivative,
That can more effectively reduce or remove surface under lower concentration does not need molecule.
More specifically, because the feature in the structure of highly branched chain cyclodextrin of the present invention, can make its absorb with above-mentioned
A part for the consistent each organic molecular species of at least one interior space shape of highly branched chain cyclodextrin or organic molecule is (with shape
Become polymer), the numerous foreign substances include the body surface not needed including organic molecule containing odor molecules can be connect
Receive inner space.Therefore, there is highly branched chain cyclodextrin (the hyperbranched ring of the present invention of the inner space of all size
Shape structure dextrin), abnormal flavour that there are various active groups, broadly being produced can not only be removed by organic aromatic molecules, and
And residual perfume excellent, can effectively transmit that the good ClogP of abnormal flavour covering power is more than 3 and boiling point is more than 250 DEG C
Various fragrance materials or abnormal flavour remove material.
In the present compositions, in order to make highly branched chain cyclodextrin function act on, with respect to combination
Thing total amount, the content of this highly branched chain cyclodextrin is about 0.01～20 weight %, is preferably from about 0.05～10 weight %, more preferably
It is about 0.1～5 weight %.When for above-mentioned content range, can not only go to eliminate the unusual smell, and the transmission of fragrance component also has
Effect, when highly branched chain cyclodextrin content is less than 0.01 weight %, deodorizing effect is faint, when more than 20 weight %, in combination
Have problems on the dosage form stability of thing.
2) spice
The spice of the present invention, is to be deposited at least more than one circulus of above-mentioned highly branched chain cyclodextrin by inclusion
Thus constituting stable compositionss.By the composition that the present invention is stable, provide the organoleptic quality of good fragrance, and, knitting
When the surfaces such as thing, human body are processed, foreign body can be removed and be abnormal flavour and give pure and fresh sensation.In the present invention, spice is extremely
The fragrance with vitality can be provided less.
For can inclusion for the spice in the highly branched chain circulus dextrin of the present invention, with hydrophilic spice,
Hydrophobic perfume independently, can the various spice of inclusion, this point, can not only by the highly branched chain circulus dextrin of the present invention
The spice of enough inclusion cyclodextrin energy inclusions, but also the spice of inclusion can be unable to it is also possible to know that it can wrap by inclusion cyclodextrin
Close various spice.That is, spice in the highly branched chain circulus dextrin of the present invention for the inclusion is not limited to specific spice, has energy
Enough comprise the ability of various spice.
In addition, the ratio that fragrant rate refers to the alcohol (ethanol) with respect to perfume stock solution assigned by perfume, the tax of the perfume of the present invention is fragrant
Rate is about the 0%～about 3% of component total amount, preferably from about 0.003%～about 2%, even more preferably about 0.005%～about 1%.
In the present invention, eliminate the unusual smell to go and make the fragrance on surface more to continue for a long time, to add spice.When needing intensity high
During fragrance, the spice of fragrant rate can be assigned or using the outstanding spice of residual fragrance using high.Any kind of spice all goes for
In the composition of the present invention, fragrance component both can be hydrophobicity or hydrophilic.
In order that fragrance more long duration, spice needs at least there is partially hydrophobic and relatively high boiling point.That is, fragrant
Material is formed by belonging to the perfume material in following two groups.That is, (a) ClogP more than 3.0, preferably more than ClogP3.5's is hydrophobic
Property composition；B () molecular weight is more than 205, preferably more than 210, more preferably more than 220 fragrance component.
For the property of above-mentioned fragrance component, the species of its isomer is also varied, to the material that periphery exists
Impact big it is difficult to by clearly distinguishing as numerical value such as the ClogP of physical characteristics and molecular weight.Therefore, the numerical value of above-mentioned record
It is the numerical value substantially showing to represent perfuming properties, above-mentioned numerical range should neatly be explained.
For above-mentioned hydrophobic perfume, highly branched chain cyclodextrin is about 2 with the weight ratio of spice:1～about 200:1, excellent
Elect about 4 as:1～about 100:1, even more preferably about 6:1～about 50:1, more preferably about 8:1～about 30:1 (branched chain cyclization
Dextrin:Spice).
Hydrophobic perfume has the strong property combining with cyclodextrin.The hydrophobicity of fragrance component is just pungent with its composition
Alcohol/water partition coefficient P has a relation, the Octanol/water Partition Coefficients of spice be under poised state spice in the concentration ratio of pungent alcohol and water.
The partition coefficient P that spice has is higher, and hydrophobicity is higher, and on the contrary, partition coefficient P is lower, then hydrophilic is higher.Due to perfume (or spice)
The partition coefficient of material is generally higher, therefore, it is possible to the logarithm being 10 by the truth of a matter, is easily represented in the form of logP.Thus,
Other spice in the present invention, have about more than 3, preferably from about more than 3.1, most preferably about more than 3.2 logP value.
In addition, the content of hydrophobic perfume composition is respectively relative to spice composition total amount is at least about 5%～80 weight %,
It is preferably from about 10%～60 weight %, even more preferably about 15%～40 weight %.
More specifically, the highly branched chain cyclodextrin of the present invention can inclusion be selected from by galaxolid (Galxolide),
Ambrotone (Iso-E Super), extra large Buddhist Moschus (Helvetolide), cashmere wood Moschus (Cashmeran), musk lactone
(Cervolide) at least one above spice and in the group of composition such as anrantiol (Aurantiol), and these spice are
It was unable to the spice in cyclodextrin for the inclusion in the past.The covering power to abnormal flavour for this spice and the preference to fragrance are outstanding, and
Molecular weight is big, therefore, it is possible to more easily improve the vitality of fragrance.
Table 1 below represent several residual perfume spice and cyclodextrin and be combined with the highly branched chain cyclodextrin of the present invention can
Can property.Compared with cyclodextrin, the highly branched chain cyclodextrin of the present invention has various broader inner spaces, therefore, it is possible to inclusion
More than ClogP3.0, in the past can not be by the big spice of the molecular weight of cyclodextrin inclusion compound.Thus, the branched chain link based on the present invention
Change dextrin, more fragrance can be used, the fragrance spectrum (spectrum) of the present composition can be widened, improve residual perfume
Persistence.
【Table 1】
For the fragrance formulations of the present invention, typically at least comprise 4 hydrophobicitys residual perfume spice, preferably comprise 5, more preferably
Comprise 6, further preferably comprise 7 hydrophobicity residual perfume spice.In addition, the most frequently used natural perfume material, it is to be made up of into multiple
Divide and formed.
In addition, hydrophilic fragrance has the property easily departing from water solublity composition from highly branched chain cyclodextrin, and this
Kind of hydrophilic fragrance is mainly about 3.5 by ClogP, be preferably from about less than 3.0 composition is constituted.
If fragrance component have hydrophilic in the case of, its water solublity composition in dissolve, the knot with cyclodextrin
Right not high.Function, hydrophilic fragrance and the highly branched chain cyclodextrin of foreign body such as eliminate the unusual smell to keep cyclodextrin to reduce/go
Weight ratio be below about 90 weight %, be preferably below 50 weight %, below more preferably 30 weight %, most preferably 10 weights
Amount below %.This hydrophilic fragrance is about 8 with respect to the ratio of cyclodextrin:More than 1, it is preferably from about 10:More than 1, more excellent
Elect about 20 as:More than 1, most preferably about 70:More than 1 (cyclodextrin:Hydrophilic fragrance).
In addition, in the present compositions, in order that spice plays its effect, the content of spice is total with respect to compositionss
Weight is 0.1～10.0 weight %, preferably 0.5～5.0 weight %.When the content of spice is in above range, base can be made
Organoleptic quality optimization in spice.
3) solvent (Solvent)
In the present invention, solvent means to convey body, is preferably recommended as water, can use distilled water or deionized water, also may be used
To use tap water.Water can not only be used as the conveying body of highly branched chain cyclodextrin, and the abnormal flavour processing surface can also be promoted to divide
The foreign bodies such as son and the combination of highly branched chain cyclodextrin.Additionally, it is known that by polarity and the little organic amine of molecular weight, acid, mercaptan etc.
When the surface aqueous solution of the smell pollution producing is processed, intensity can reduce.Think the water being used as solvent in the present invention, can make
Polarity and low molecular odor molecules solubilising, reduce vapour pressure, thus reducing the intensity of abnormal flavour.
Solvent used in the present composition, that is, the concentration of water can be become according to the purposes (such as dosage form etc.) of compositionss
Change.In the composition of the spray application manually or automatically spraying, with respect to composition total weight, the weight of water is about 30 weight %
～about 99.9 weight %, preferably from about 50 weight %～about 99.9 weight %, even more preferably about 60 weight %～more 95 weight %,
Content is very high.
In addition, in the composition for removing fabric abnormal flavour, as solvent, alcohol can be used, preferably use carbon number 1-4
Lower alcohol, for example, methanol or ethanol etc. can be used, with respect to composition total weight, the weight of alcohol is below about 20 weight %,
It is preferably from about below 10 weight %, below even more preferably about 5 weight %.
The dilution of aqueous solution, can widen coating scope on fabric for the highly branched chain cyclodextrin, thus to greatest extent
Improve the chance that highly branched chain cyclodextrin molecule is combined with odor molecules.
4) surfactant
In the present invention, for suitably reducing, removing the foreign body of body surface, and fragrance component is enable to discharge perfume (or spice) for a long time
Taste, the compositionss of the present invention can also comprise surfactant.In order to suitably go to eliminate the unusual smell, surfactant includes holding
Change places the stable surfactant being combined with the highly branched chain cyclodextrin of the present invention.In addition, it is important that, be not easy by this
The smell substance of invention highly branched chain cyclodextrin inclusion constitutes polymer, produces low surface tension such that it is able to be easier and equal
It is diffused in the characteristic of the hydrophobic surfaces such as fabric evenly.
Surfactant used in the present invention, can comprise to be commonly used to detergent, softening agent for fibres, shampoo, table
Kind in face detergent, cosmetics, human body articles for use, cleaning agent for mouth cavity, bath gel, shaving product, composition of skin moisturizer etc.
Class.
When using the compositionss comprising the surfactant stable to highly branched chain cyclodextrin, according to the surface being used
The species of activating agent and characteristic, can promote drying, therefore, it is possible to remove the abnormal flavour of handled object more quickly.In some groups
In the composition of compound, spice that inclusion is not easily separate in highly branched chain circulus dextrin etc., promote and branched chain cyclization paste
Essence and the micelle (micell) of surfactant or the formation of vesicle (Vesicle), keep the spice of proper strength during use,
Thus contributing to strengthening the advantage that in use, residual perfume is maintained at handled surface for a long time.
Surfactant and the adhesion of the highly branched chain cyclodextrin of the present invention, can pass through to be confirmed whether to add surface activity
The change of surface tension (dyne/cm) when highly branched chain cyclodextrin for the agent aqueous solution to understand.Aqueous surfactant solution bag
Containing concentration be about 0.5%, about 0.1%, about 0.01%, about 0.005% surfactant, comprising the surface with concentration known
The surfactant of the equal concentration of aqueous surfactant solutions surface tension, and also comprise the highly branched chain cyclodextrin of about 1 weight %
Aqueous solution in, when the capillary raising of this aqueous solution is about more than 10% it is meant that surfactant with cyclisation paste
There is strong combination between essence.
In the compositionss of the present invention, preferred surfactant is, with cyclodextrin in above-mentioned capillary change
Combination weak (capillary improve less than about 5%) or the surface activity not combining (capillary improve less than about 1%)
Agent.
In the present compositions, the concentration of usual surfactant is about 0.01 weight with respect to composition total weight
Amount %～about 2 weight %, preferably from about 0.03 weight %～about 0.6 weight %, even more preferably about 0.05 weight %～about 0.3 weight
Amount %.In the composition of concentrated surfactant, the concentration of surfactant is typically about 0.1 weight %～about 20 weight %,
It is preferably from about 0.2 weight %～about 15 weight %, even more preferably about 0.3 weight %～about 10 weight %, but be not limited to this.
In the composition, for example, effective surfactant is selected from block polymer surfactant, siloxane surface
Activating agent, anion surfactant, amphoteric surfactant, cationic surfactant, castor oil surfactant, dehydration
Sorbitol ester surfactants, the fatty alcohol surfactant of ethoxylation, glycerol unary fatty acid ester surfactant, poly- second
In diol fatty acid ester surfactant, fluorocarbon surfactant and their mixture, but it is not limited to this.
As above-mentioned block polymer surfactant, including the block polymer of oxirane, expoxy propane, can useWithDeng.
Above-mentioned silicone surfactant is anion surfactant, applicable polyalkylene oxide polysiloxanes, has conduct
The poly- Asia hydrocarbon chain of the dimethyl polysiloxane of hydrophobic parts and more hydrophilic property.As one of this surfactant, haveClass.Polyether chain (R1) internal oxidition ethylene (- C2H4O) the quantity of unit, is so that polyalkylene oxide polysiloxanes is enough to
There is the quantity of water solublity degree.If polypropylene epoxide is present in the hydrocarbon chain of poly- Asia, can be deposited in the form of random or block
?.In addition to surface-active effect, polyalkylene oxide polysiloxane surfactant also has prevents from producing electrostatic, tax on fabric
Give the additional effect of flexibility etc..
As one of above-mentioned anion surfactant, there are alkyl diphenyl ether disulfonate, alkyl ether sulfate etc..Separately
Outward, as the anion surfactant be applied to detergent and shampoo, have：Ammonium lauryl sulfate, Laurel alcohol sulfuric ester
Ammonium, triethylamine lauryl base sulfate, triethylamine lauryl alcohol sulfate, monoethanolamine lauryl base sulfate, monoethanolamine lauryl alcohol
Sulfate, diethanolamine lauryl sulfate, diethanolamine lauryl alcohol sulfate, lauryl one glycerol sodium sulfate, lauryl sulfur
Sour sodium, lauryl potassium sulfate, lauryl alcohol potassium sulfate, cocoyl ammonium sulfate, lauroyl ammonium sulfate, cocoyl sodium sulfate,
Lauroyl sodium sulfate, cocoyl potassium sulfate, lauroyl potassium sulfate, triethanolamine lauryl base sulfate, the triethanolamine moon
Cinnamic alcohol sulfate, monoethanolamine cocoyl sulfate, monoethanolamine lauryl base sulfate, N- lauroyl-N- methyl cattle sulphur
Sour sodium, tridecyl benzene sulfonate and dodecylbenzene sodium sulfonate.Detergent use anion as suitable present invention composition
Surfactant, selected from lauryl alcohol -3 ammonium sulfate, lauryl alcohol -3- sulfate chloride, ammonium lauryl sulfate, lauryl sulfate
In salt chloride and their mixture.When using cationic antibacterial active or preservative, above-mentioned anionic surface is lived
Property agent class reduce and the combination of cationic surfactant, thus reducing the effect of surfactant and antibacterial, thus unexcellent
Choosing.
The compositionss of the present invention can be using the various amphoteric surfactantes comprising above-mentioned zwitterionic surfactant class.
Particularly preferably use secondary aliphatic amine, the derivant of tertiary amine, aliphatic radical therein has wire or dendritic morphology, and its
One of there is such as carboxyl, sulfonate radical, sulfate radical, phosphate radical etc. be capable of the water solublity functional group of ionizing.As both sexes or
The example of zwitterionic surfactant, has glycine betaine, sulfobetaines and hydroxy sulfo lycine.As glycine betaine, can lift
Go out coco dimethyl carboxymethyl glycine betaine, lauryl dimethyl carboxymethyl glycine betaine, lauryl dimethyl α carboxy-ethyl betaine
(the Lonzaine 16SP of Lonzq Company), lauryl two-(2- ethoxy) carboxymethyl c glycine betaine, stearyl two-
(2- hydroxypropyl) carboxymethyl betaine, oleyl d- methyl γ-carboxylic CAB, lauryl be double-(2- hydroxypropyl) α-hydroxyl carboxylic
Ethyl glycine betaine, coco dimethyl sulfopropyl glycine betaine, stearyl dimethyl sulfopropyl betaine, stearyl betaine,
Lauryl dimethyl sulfoethyl glycine betaine, lauryl be double-(2- ethoxy) azochlorosulfonate propyl lycine, amido betaines, acylamino-
Thetine (RCONH (CH2)3Free radical is combined with the nitrogen-atoms of glycine betaine), oleyl betaine alkali (Henkel Company
Aliphatic Velvetex OLB-50), cocamido propyl betaine (the Velvetex BK-35 of Henkel Company and
BA-35).As sulfobetaines and hydroxy sulfo lycine, cocoamido propyl hydroxy sulfobetaine (Rhone can be enumerated
The Mirataine CBS of Poulenc Company).
In addition, as other surfaces activating agent, the surfactant from aminoacid and the table from aminoacid can be enumerated
Face activating agent, this surfactant comprises the basic chemical structure of aminoacid, that is, comprise natural amino acid structure.Generally, surface
Activating agent is derived from the sarcosine such as glycine, sarcosine, sarcosine, arginine, alanine, Phenylalanine.
Above-mentioned cationic surfactant generally comprises quaternary nitrogen, and fatty acid in addition to carbon and hydrogen, can also comprise amino
Deng other functional groups or in connection.There is the fatty acid of the long-chain that carbon number is about more than 12, can be saturation or insatiable hunger
And fatty acid.It is particularly preferred to there is carbon number and being about 12～about 22, be preferably from about 16～about 22 two long alkyl
Chain and carbon number are about 1～about 3, are preferably from about 1～about 2 two short alkyl chains, or have a long alkyl chain and
The cationic substance of three short alkyl chains.In addition, it is necessary at least one replacement is hydroxy alkyl, preferably ethoxy or hydroxyl
The total ethoxylation of propyl group or polyoxyalkylene, preferably intramolecular or the polyoxyethylene or poly- that degree of propoxylation is about 5～20
Oxypropylene.Primary amine, secondary amine, the salt of tertiary amine also are suitable as cationic surfactant.The carbon number of the alkyl of this amine is excellent
Elect about 12～22 as, both can be using replacement alkyl, it is possible to use non substituted alkyl.
Above-mentioned castor oil surfactant is castor oil polyoxyethylene ether, the polyoxyethylene castor partially or fully being processed by hydrogen
Oleum Sesami ester, polyoxyethylene compression Oleum Ricini Or its mixture, have
Beneficial to the Molecularly Imprinted Polymer forming micelle or vesicle etc. with cyclodextrin-non-interchangeable property surfactant.
Above-mentioned sorbitan ester surfactant apoplexy due to endogenous wind, the length comprising there are 14～18 or 16～18 carbon atoms
The sorbitan ester of fatty acid chain, is cyclodextrin-interchangeability surfactant, with the cyclodextrin of the present invention-non-interchangeable
Property material formed Molecularly Imprinted Polymer.As the common example of the anhydrous sorbitol polyesters of the fatty acid chain comprising length, can lift
Go out anhydrous sorbitol tripalmitate, sorbitan trioleate, anhydrous sorbitol tallow fatty acids three ester In addition, as other anhydrous sorbitol ester surfactants,
The sorbitan fatty acid ester class that local has monobasic ester and ternary ester can be enumerated.In addition, as other sorbitan esters
Surfactant-based, the also sorbitan fatty acid ester class of polyethoxylated.
As the fatty alcohol surfactant class of above-mentioned polyethoxylated, there is the fatty alcohol surface activity of polyethoxylated
Agent.Branch's (polyethoxylated) fatty alcohol plays a role as cyclodextrin-interchangeability surfactant in this composition.As
The glycerol unary fatty acid ester of glycerol unary fatty acid ester surfactant class, can enumerate glycerol unitary stearate, oleate,
Palmitate, moon silicate.Cithrol is surfactant-based to be sent out as cyclodextrin-interchangeability surfactant
Wave effect.Fluorocarbon surfactant has at least a portion of linear or annular functional group based on carbon, i.e. amphiprotic substance
The fluorine that is combined with carbon of hydrophobic parts, be generally combined with carbon together with hydrogen and constitute hydrophilic parts.As several common
Fluorocarbon surfactant, including fluorinated alkyl polyoxyalkylene and fluorinated alkyl esters plasma surface activating agent.
5) water-soluble polymer
The compositionss of the present invention can also comprise water-soluble polymer.Water-soluble cationic polymer and water soluble anion
The water-soluble polymers such as polymer, also have additional abnormal flavour removal effect, it is therefore preferable that being included in the compositionss of the present invention
In.As the typical case of water-soluble cationic polymer, there is polyamine etc..Water-soluble cationic polymer contain amino, amide groups,
And their mixture, for removing specific tart flavour.
In addition, the water-soluble anionic polymer such as polyacrylic acid and its water soluble salt, for removing specific amine taste.Poly- third
Olefin(e) acid and its alkali metal salt have average less than about 20000 molecular weight, preferably have less than 5000 molecular weight.Can also make
With comprising the polymer of sulfate radical, phosphate radical, the mixture of phosphonate radical, their water soluble salt and mixture, carboxylic acid and carboxyl.
Can also be using the water-soluble polymer with Cationic functional groups and anionic functional group.Using water-soluble polymer
When, generally its usage amount is about 0.001 weight %～about 3 weight % with respect to composition total weight, preferably from about 0.01 weight
Amount %～about 1 weight %, even more preferably about 0.05 weight %～about 0.5 weight %.
6) plant extract
The compositionss not needing molecule for removal of the present invention, also wrap while comprising above-mentioned highly branched chain cyclodextrin
Containing the outstanding plant extract of deodorizing effect, thus obtaining the cooperative effect improving deodorizing effect.Above-mentioned plant extract is to evil
Smelly carry out adsorbing, decompose, therefore, the persistence of deodorization power and deodorization power is outstanding, and safe to the human body, by the stench being adsorbed
Forever decompose so it does not distributing again.
The above-mentioned plant extract that can use in the present invention, can comprise selected from by green tea, Folium Kaki, Pericarpium Citri Reticulatae and
The extract of more than one plants selecting in the group that Fructus Anisi Stellati is formed.Preferably, above-mentioned plant extract can be equal
Comprise green tea, the mixture of the extract of Folium Kaki, Pericarpium Citri Reticulatae and anistree fennel, it is highly preferred that above-mentioned plant extract be by green tea,
The extract of Folium Kaki, Pericarpium Citri Reticulatae and Fructus Anisi Stellati is with about 1:1:1:1 weight is than the mixture containing.Now, with the present invention's
When purpose considers, the deodorizing effect for removing the compositionss not needing molecule is the most outstanding.
The plant extract that can use in the present invention, can be by conventional use of water or to comprise ethanol, caproic acid
Deng the plant solvent extract that extracts from plant of organic solvent.Preferably, above-mentioned plant solvent extract is by hot water
Extraction method is from the extract of plant extract.It is highly preferred that as above-mentioned plant extract, can be using containing polyphenyl class plants essential oil
Plant solvent extract and mineral product.As above-mentioned mineral, Talcum, Muscovitum, Kaolin, boiling can be used
Stone, or the silicate mineral of Muscovitum etc., preferably use zeolite.
Above-mentioned plant solvent extract and the product of mineral are different from simple plant extract, containing a large amount of
Ionised species.O is contained by the plant extract that said method manufactures2, the ionised species of H, OH etc., and repeatedly induce
The repercussion effect of these atoms is so as to be reacted with the malodor molecule of amine, thio-alcohol or sulfur etc., thus changing
The molecular structure of malodor source, plays excellent deodorization power.In addition, above-mentioned plant extract is safe to the human body, and to being adsorbed
Stench carries out permanent decomposition, thus preventing stench from remaining in deodorizer, therefore, deodorization vitality is outstanding.
The present invention does not need in the compositionss of molecule for removal, and the content of plant extract is with respect to compositionss gross weight
Measure as 0.01 weight %～10 weight %, preferably 0.05 weight %～5 weight %, more preferably 0.1 weight %～3 weight
Amount %.If the content of above-mentioned plant extract is less than 0.01 weight % it is difficult to give full play to deodorizing effect, and more than 10 weight %
When, nor obtain the lifting further of deodorizing effect that content increase brings, increase composition on the contrary, and dosage form stability also becomes
Difference.Preferably, the above-mentioned weight ratio for removing highly branched chain cyclodextrin and plant extract in the compositionss not needing molecule
Can be 0.1:1～1:0.1, preferably 0.2:1～1:0.2, more preferably 0.3:1～1:0.3 (highly branched chain cyclodextrin:Plant
Thing extract).
7) other compositions
In the composition of the present invention, can also comprise diluent, excipient, antibacterial, Derma-Guard, antistatic additive,
Wetting agent or plant (except green tea, Folium Kaki, Pericarpium Citri Reticulatae and Fructus Anisi Stellati) extract etc..
In addition, the present invention's does not need the compositionss of molecule to can be applicable to laundry detergents, softening agent for fibres, surface for removing
In the purposes of detergent, kitchen detergent, deodorizer, shampoo, hair conditioner, human body articles for use or bromhidrosis remover etc., but not
It is defined in this.
In addition, the present invention is provided to removing the compositionss not needing molecule, wherein, including：Highly branched chain cyclodextrin
(Highly Branched Cyclic Dextrin, HBCD) or derivatives thereof；And comprise green tea, Folium Kaki, Pericarpium Citri Reticulatae and eight
The plant extract of Radix Hypecol Erecti, and, with respect to composition total weight, above-mentioned highly branched chain cyclodextrin (Highly Branched
Cyclic Dextrin, HBCD) or derivatives thereof content be 0.01 weight %～10 weight %, the containing of above-mentioned plant extract
Measure as 0.01 weight %～10 weight %.Preferably, the mean molecule quantity of above-mentioned highly branched chain cyclodextrin be 30000～
1000000g/mol.From the purpose of the present invention consider, when for remove do not need the compositionss of molecule to comprise above-mentioned weight ratio
During composition, deodorizing effect is very outstanding.
In addition, the manufacture method for removing the compositionss not needing molecule of the present invention, including：(s1) will comprise relatively
The plant extract of the polyphenyl class plants essential oil being 0.01 weight %～10 weight % in composition total weight is carried out with mineral
The step of reaction；And, (s2) adds the highly branched chain of 0.01 weight %～10 weight % in the reactant of above-mentioned (s1) step
Cyclodextrin or derivatives thereof, and the step being mixed.Preferably, the mean molecule quantity of above-mentioned highly branched chain cyclodextrin is
30000～1000000g/mol.Preferably, above-mentioned plant comprises selected from by green tea, Folium Kaki, Pericarpium Citri Reticulatae and Fructus Anisi Stellati institute group
One or more of the group becoming plant, more preferably comprises green tea, Folium Kaki, Pericarpium Citri Reticulatae and Fructus Anisi Stellati simultaneously.
In addition, the present invention provides a kind of minimizing technology not needing molecule, do not need molecule including processing for removing
The step of compositionss, wherein, above-mentioned for remove do not need the compositionss of molecule to include：Highly branched chain cyclodextrin or it is derivative
Thing；Spice at least more than one inner space inclusion of above-mentioned highly branched chain cyclodextrin；Solvent；And optional (according to
Need to add) surfactant, water-soluble polymer, plant extract or their mixture.Preferably, above-mentioned do not need
The minimizing technology of molecule is used for removing because of the stench of the generations such as ammonia or methanthiol.
Invention effect
The compositionss not needing molecule for removal of the present invention, have the internal sky of wider more kinds of size due to employing
Between cyclodextrin, be unable to inclusion in the past and do not need molecule in cyclodextrin therefore, it is possible to remove, more specifically, not only
Easily remove various sources of odor, can with inclusion be unable in the past inclusion in cyclodextrin, more have hydrophobicity and point
The big fragrance material of son amount.By this compositionss, the fragrance material in highly branched chain cyclodextrin is replaced by sources of odor, therefore,
Covering power is outstanding, and while the release fragrance outstanding to the preference of fragrance, can remove sources of odor etc. does not need molecule
Deng foreign body.
Further, since the present invention's does not need the compositionss of molecule also to comprise plant extract for removing, therefore, it is possible to
Obtain the synergy going to eliminate the unusual smell.
Brief description
In this specification, appended the following drawings is used for the preferred embodiments of the present invention are described, with foregoing summary one
Same, play the effect contributing to understanding the technology of the present invention thought, but the present invention can not be construed to and now schedule these accompanying drawings following.
Fig. 1 is the signal ideograph of the forming process representing highly branched chain cyclodextrin of the present invention.
Specific embodiment
Below, in order to contribute to understanding the present invention, enumerate embodiment etc. and be described in detail.But, can be to the present invention
Embodiment carry out various forms of deformation, be not construed as the scope of the present invention and be limited to following embodiments.The present invention's
Embodiment is to provide to be described more fully the present invention to those skilled in the art.
<Embodiment>
The compositionss of the present invention, by material compositions such as highly branched chain cyclodextrin, spice and solvents, therefore, combine in the present invention
It is important that making the function of highly branched chain cyclodextrin be present in composition in the manufacture process of thing.In order that feature highly branched chain
Cyclodextrin is maintained in composition, needs to be mixed highly branched chain cyclodextrin and surfactant at first.As a result, passing through
After the Molecularly Imprinted Polymer of micelle or vesicle molecule etc. is formed, in the Molecularly Imprinted Polymer of highly branched chain cyclodextrin-surfactant
The materials such as interior dipping spice, thus, it is possible to effectively separate from highly branched chain cyclodextrin inner space, thus be maintained in composition
Play the compositionss of function affect.
In the present invention, in order to remove fabric, particularly remove the abnormal smells from the patient of dry fabric, with spray form manufacture combination
Thing, and evaluated.But, the efficiency of the present invention is not limited to above-mentioned dosage form.As the spraying for removing fabric abnormal flavour
Preparation, in order to leave spot to fabric under conditions of the amount of being usually used, preferably uses the highly branched chain employing low concentration
The composition of cyclodextrin, under common use condition, the solution being coated on body surface should not with the naked eye be seen after the drying
Observe.
At typical condition, in composition, the gross weight of highly branched chain cyclodextrin is typically about 0.01 weight %～20 weight
Amount %, preferably from about 0.05 weight %～10 weight %, even more preferably about 0.1 weight %～5 weight %.In order to send out in composition
Wave the function of highly branched chain cyclodextrin, most preferably comprise about 0.1 weight %～5 weight %.There is the composition of high concentration, be dried
During can leave the spot that can be observed visually in fabric, particularly, thin and carry in coloured synthetic textiles,
Problem can be become.
The constituent comprising spice in an embodiment of the present invention is as described in Table 2, comprises the group of this spice
The content of compound is as described in Table 3.
【Table 2】
| No. | Spice title | CAS No. | Content (%) |
| 1 | Anrantiol (Aurantiol) | 89-43-0 | 10.0 |
| 2 | Symplocoris Paniculatae alcohol (bacdanol) | 28219-61-6 | 10.0 |
| 4 | Brazilic acid glycol ester (Ethylene brassylate) | 105-95-3 | 10.0 |
| 5 | Galaxolid (Galaxolide) | 1222-05-5 | 10.0 |
| 6 | 1-Hexyl salicylate (Hexyl Salicylate) | 6259-76-3 | 10.0 |
| 7 | Ambrotone (Iso-E Super) | 54464-57-2 | 5.0 |
| 8 | LYRAL (Lyral) | 31906-04-4 | 10.0 |
| 9 | MDJ (Methyl dihydrojasmonate) | 24851-98-7 | 10.0 |
| 10 | Ethyl phenylacetate (Phenyl ethyl phenylacetate) | 102-20-5 | 10.0 |
| 11 | Super ambroxide (Trisamber) | 338735-71-0 | 5.0 |
| Total | 100.0 |
【Table 3】
1. abnormal flavour intensity evaluation
Implement the evaluation to abnormal flavour removal effect of the compositionss of comparative example and embodiment as described below.
1) as fabric to be evaluated, the cotton towel being cut to 30cm × 30cm is carried out using no fragrant detergent use washing machine
After washing, it is dried with drying machine.
2) by the abnormal flavour formula of about 80 μ L, it is coated with the spreading area of 5cm × 5cm respectively in cotton towel after the drying
Afterwards, put in plastic bag and sealed, and place an evening at room temperature.
3) through training evaluation personnel the initial stage abnormal flavour intensity of the fabric being coated with abnormal flavour is evaluated, and according under
State the marking of abnormal flavour evaluation criterion.
4) and then, formula to be evaluated is coated on fabric with isodose, and be dried 30 seconds.
5), after fabric drying, evaluation personnel is according to following abnormal flavour evaluation criterions, strong to the abnormal flavour of the fabric being coated with abnormal flavour
Degree is given a mark.
6) record initial stage fraction and final score, and abnormal flavour reduced value is calculated by score difference.
Evaluation personnel amounts to 8, for correct cognitive standard abnormal flavour, they is trained in advance.Evaluation is in tool
In the single evaluation compartment of standby forced ventilation equipment, everyone is individually carried out, and, in order to improve the accuracy of evaluation, limit
Make the evaluation of more than 3.
Table 4 below is abnormal flavour evaluation criterion.
【Table 4】
| Fraction | Evaluation content |
| 0 point | There is no abnormal flavour |
| 1 point | There is faint abnormal flavour |
| 2 points | There is moderate abnormal flavour |
| 3 points | There is slightly strong abnormal flavour |
| 4 points | There is strong abnormal flavour |
| 5 points | There is very strong abnormal flavour |
In addition, in order to evaluate the residual perfume (or spice) based on cyclodextrin, the aroma strength after 10 minutes, after 30 minutes is commented
Valency, thus have rated the residual perfume reinforced effects of cyclodextrin.
Table 5 below is residual perfume evaluation criterion.
【Table 5】
2. evaluation result
In the cotton towel being cut to 30cm × 30cm, by the abnormal flavour formula of about 80 μ L, respectively with the coated face of 5cm × 5cm
Long-pending be coated after, put in plastic bag and sealed, and after placing an evening at room temperature, through the evaluation personnel pair trained
Abnormal flavour intensity is evaluated, and evaluation result is 4.2 points.
Coating comparative example 1, embodiment 1～7 and drying 30 seconds after, evaluated, and by this evaluation result be only coated with
The difference of evaluation result during sources of odor is shown in Table 6.
【Table 6】
| Evaluation personnel No. | Comparative example 1 | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 |
| Averagely | 1.3 | 2.0 | 2.1 | 2.3 | 2.7 | 2.4 | 2.9 | 3.4 |
Compared with the comparative example 1 that cyclodextrin is used as abnormal flavour removal substrate, employ cyclodextrin (Cyclic
Dextrin embodiment 1～7) has more excellent abnormal flavour removal effect.Comparative example 1 is only that abnormal flavour with the difference of embodiment 1
Remove substrate, and embodiment 1 is identical with the content that the abnormal flavour of embodiment 2 removes substrate, but species differs.Understand to go when abnormal flavour
Except the content of substrate identical when, compared with cyclodextrin, the abnormal flavour removal effect of cyclodextrin is more excellent.
In addition, knowable to embodiment 2 and embodiment 3, when employing the copolymer as cyclodextrin interchangeability polymer
When 958, the abnormal flavour removal effect based on cyclodextrin strengthens.Understand from the comparison of embodiment 4 and embodiment 5, when spice
Content be respectively 0.10%, 0.06% different when, content high embodiment 4 is more outstanding.In addition, working as amophoteric surface active
When being suitable for different embodiments 2 and being compared with embodiment 4 of agent Velvetex BK-35, employs Velvetex BK-35's
The result of embodiment 4 is more outstanding.By the comparison of embodiment 6 and embodiment 7, different to cyclodextrin when also added
When taste removes cyclodextrin interchangeability polymer, the amphoteric surfactant that can provide multiplication effect, abnormal flavour can be strengthened and go
Except effect.
In addition, will be evaluated to residual perfume intensity after 10 minutes, after 30 minutes, and evaluation result is shown in Table 7.Will
Comparative example 1 is compared with embodiment 1～7 and understands, for residual fragrant attribute, the difference after 30 minutes compare 10 minutes after greatly.This is
Because compared with cyclodextrin, the fragrance component of the ClogP more than 3.0 of cyclodextrin inclusion and more than 250 DEG C of boiling point is many, and with
The reason of time release.
In addition, the content from cyclodextrin is more, after 10 minutes residual fragrant and after 30 minutes the difference between residual perfume less
Result, also can confirm that the above-mentioned fact.From relatively can confirm that of embodiment 6 and embodiment 7, perfume (or spice) can be improved when adding further
With the being attached to each other property between fiber when being polymerized species, amphoteric surfactant, more the residual fragrant of lifting cyclodextrin increases material
Potent fruit.
【Table 7】
| Time | Comparative example 1 | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 |
| After 10 minutes | 2.4 | 2.8 | 2.9 | 2.8 | 2.8 | 2.3 | 2.8 | 2.8 |
| After 30 minutes | 0.8 | 1.5 | 1.9 | 2.2 | 2.0 | 1.6 | 1.9 | 2.4 |
<Embodiment 8～16 and the manufacture of comparative example 2>
When manufacturing the deodorant compositions of embodiment 8～16 and comparative example 2, as highly branched chain cyclodextrin (Highly
Branched Cyclic Dextrin, HBCD), the mean molecule quantity (g/mol) employing every mole is 30000～1000000
Scope, mixed as the tasteless white powder oligosaccharide (oligosaccharide) of monomer (monomer) using alpha-D-glucose
Compound, usage amount is the scope of 0～0.8 weight %.
As plant extract, employ the plant that the mineral qualitative responses such as polyphenyl class plant-derived essential oil and zeolite are obtained
Thing extract, usage amount be 0～1 weight %, wherein, polyphenyl class plant-derived essential oil be by by green tea, Folium Kaki, Pericarpium Citri Reticulatae and
Fructus Anisi Stellati respectively with 50g weight mixing after 110 DEG C in 5L pure water at carry out 60 minutes hot water extract and manufacture.
Highly branched chain cyclodextrin and plant extract and other surfaces activating agent, spice, additive etc. are added on pure
In water purification and mixed, embodiment 8～16 and the deodorizer of comparative example 2 are manufactured according to the ratio of components shown in table 8 below
Compositionss.
3. the deodorization power of the deodorant compositions of embodiment 8～16 and comparative example 2 is evaluated
Deodorization power is tested, employ for ammonia and methanthiol in ASTM D1988 described in detection pipe, detection pump measures
Method and connect the sensory evaluation method that evaluation personnel trained is evaluated to stench intensity by for food stench.
As methanthiol, employ the SILVER REAGENT methanthiol that concentration in benzene is 0.1%, in addition, with water by ammonia with 0.05%
It is used as malodor source after concentration dilution, as food stench, Pickles soup is used with 0.1% concentration dilution in water.As suction
Air pump, employs GV-100S air sampling pump (Air Sampling Pump, Gastec co. (japan)).As detection pipe,
Employ Gastec detection pipe No.71 (methanthiol), Gastec detection pipe No.3La (ammonia).
Deodorizing rate evaluation to ammonia and methanthiol, is carried out with being discussed further below.The pure of ormal weight is added in 250mL container
After water purification or sample stock solution, put into stench solution and seal, after 10 minutes, detection pipe is drawn into by asepwirator pump, and describes
Detected odour concentration.
The calculating of deodorizing rate is to calculate percentage rate by following calculating formulas and be used as deodorizing rate.
(using detection pipe stench detectable concentration during pure water, ppm)-(dense using detection pipe stench detection during sample
Degree, ppm)/(using detection pipe stench detectable concentration during pure water, ppm) × 100 (%)
The deodorizing rate of Pickles soup is calculated with being discussed further below.That is, through training evaluation personnel according to evaluation criterion pair
The initial stage stench intensity being coated with cacodorous fabric is evaluated, and then, formula to be evaluated is coated on fabric with isodose
In and be dried 30 minutes, the stench intensity after fabric drying is evaluated, by the difference of evaluation score, calculates stench and subtract
Few value.The evaluation criterion of Pickles soup food stench is to be evaluated with 0～5 point, and fraction is higher, then mean that deodorization power is got over
Good.
【Table 8】
Knowable to evaluation result, compared with the comparative example 2 being used alone plant extract, it is used alone branched chain cyclization paste
The deodorization power to ammonia and methanthiol for the deodorant compositions of embodiment 8～16 that is smart or being used in mixed way plant extract thereon,
And it is all outstanding to the deodorization power of Pickles soup food stench.
Claims (16)
1. a kind of for remove do not need molecule compositionss it is characterised in that include：
Highly branched chain cyclodextrin or derivatives thereof；
The spice of inclusion at least more than one inner space of above-mentioned highly branched chain cyclodextrin；And
Solvent.
2. according to claim 1 for remove do not need molecule compositionss it is characterised in that
Above-mentioned highly branched chain cyclodextrin is by α -1, and 6- glycosidic bond is connected with the form of the D-Glucose within 16～100.
3. according to claim 1 for remove do not need molecule compositionss it is characterised in that
The dextrose equivalent value of above-mentioned highly branched chain cyclodextrin is less than 5.
4. according to claim 1 for remove do not need molecule compositionss it is characterised in that
Above-mentioned highly branched chain cyclodextrin is the oligosaccharide using alpha-D-glucose as monomer, is by chemical formula (C6H10O5)xH2O table
The compound showing, wherein, x is 200～5000 integer.
5. according to claim 1 for remove do not need molecule compositionss it is characterised in that
The mean molecule quantity of above-mentioned highly branched chain cyclodextrin is 30000～1000000g/mol.
6. according to claim 1 for remove do not need molecule compositionss it is characterised in that
The content of above-mentioned highly branched chain cyclodextrin is 0.01 weight %～20 weight % with respect to composition total weight.
7. according to claim 1 for remove do not need molecule compositionss it is characterised in that
Above-mentioned solvent includes water.
8. according to claim 1 for remove do not need molecule compositionss it is characterised in that
Above-mentioned composition also comprises surfactant.
9. according to claim 1 for remove do not need molecule compositionss it is characterised in that
Above-mentioned composition also comprises water-soluble polymer.
10. according to claim 1 for remove do not need molecule compositionss it is characterised in that
Above-mentioned composition also comprises plant extract.
11. according to claim 10 for remove do not need molecule compositionss it is characterised in that
Above-mentioned plant extract is to comprise selected from appointing in the group being made up of green tea, Folium Kaki, Pericarpium Citri Reticulatae and Fructus Anisi Stellati
Anticipate the extract of more than one plant.
12. according to claim 10 for remove do not need molecule compositionss it is characterised in that
The content of above-mentioned plant extract is 0.01 weight %～10 weight % with respect to composition total weight.
13. according to claim 10 for remove do not need molecule compositionss it is characterised in that
Above-mentioned plant extract is the product of the plant solvent extract containing polyphenyl class plants essential oil and mineral.
14. according to claim 10 for remove do not need molecule compositionss it is characterised in that
With respect to composition total weight, the described highly branched chain cyclodextrin containing 0.01 weight %～10 weight % or it is derivative
Thing；
With respect to composition total weight, comprise green tea, Folium Kaki, Pericarpium Citri Reticulatae and anistree fennel containing 0.01 weight %～10 weight %
Fragrant plant extract.
15. according to claim 10 for remove do not need molecule compositionss it is characterised in that above-mentioned composition by
Including the manufacture method manufacture of following s1 steps and s2 step,
S1 step, the plant extract containing polyphenyl class plants essential oil is reacted with mineral；
S2 step, adds highly branched chain cyclodextrin or derivatives thereof in the reactant of above-mentioned s1 step and is mixed.
The method that a kind of 16. removals do not need molecule, the step including processing for removing the compositionss not needing molecule,
Described for remove do not need the compositionss of molecule to comprise：Highly branched chain cyclodextrin or derivatives thereof；In above-mentioned highly branched chain
The spice of inclusion at least more than one inner space of cyclodextrin；Solvent；And selectivity add surfactant, water
Soluble polymer, plant extract or their mixture.
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|---|---|---|---|
| CN202210637951.4A CN114870057A (en) | 2014-04-28 | 2015-04-28 | Composition for removing unwanted molecules and method for removing unwanted molecules |
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| Application Number | Priority Date | Filing Date | Title |
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| KR1020140050740A KR102020250B1 (en) | 2014-04-28 | 2014-04-28 | Composition for removing unwanted molecular |
| KR10-2014-0050740 | 2014-04-28 | ||
| KR20140087656 | 2014-07-11 | ||
| KR10-2014-0087656 | 2014-07-11 | ||
| KR1020150002127A KR102076265B1 (en) | 2014-07-11 | 2015-01-07 | Deodorant composition comprising highly branched cyclic dextrin and plant extract |
| KR10-2015-0002127 | 2015-01-07 | ||
| PCT/KR2015/004257 WO2015167221A1 (en) | 2014-04-28 | 2015-04-28 | Composition for removing undesired molecules |
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|---|---|---|---|---|
| CN109481713A (en) * | 2018-09-29 | 2019-03-19 | 壹田（广州）生活健康用品有限公司 | A kind of liquid deodorant and preparation method thereof |
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| JP6742914B2 (en) | 2020-08-19 |
| JP2022140453A (en) | 2022-09-26 |
| JP2017520635A (en) | 2017-07-27 |
| JP2020125496A (en) | 2020-08-20 |
| CN114870057A (en) | 2022-08-09 |
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