CN106436443B - A kind of light-high-strength glass fiber filter paper and preparation method thereof - Google Patents

A kind of light-high-strength glass fiber filter paper and preparation method thereof Download PDF

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Publication number
CN106436443B
CN106436443B CN201610834464.1A CN201610834464A CN106436443B CN 106436443 B CN106436443 B CN 106436443B CN 201610834464 A CN201610834464 A CN 201610834464A CN 106436443 B CN106436443 B CN 106436443B
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glass fibre
paper
glass
filter paper
adhesive
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CN106436443A (en
Inventor
陈照峰
吴操
李斌斌
王蕾
叶信立
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Nanjing University of Aeronautics and Astronautics
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Nanjing University of Aeronautics and Astronautics
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/36Inorganic fibres or flakes
    • D21H13/38Inorganic fibres or flakes siliceous
    • D21H13/40Inorganic fibres or flakes siliceous vitreous, e.g. mineral wool, glass fibres
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D21F11/14Making cellulose wadding, filter or blotting paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22Addition to the formed paper
    • D21H23/50Spraying or projecting
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/04Physical treatment, e.g. heating, irradiating
    • D21H25/06Physical treatment, e.g. heating, irradiating of impregnated or coated paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/08Filter paper

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Paper (AREA)
  • Filtering Materials (AREA)
  • Glass Compositions (AREA)

Abstract

A kind of light-high-strength glass fiber filter paper, it is made of with adhesive two-component hollow glass fibre, it is characterized in that the two-component hollow glass fibre hollow rate is 0.60~0.95, average diameter is 0.8~7.2 μm, draw ratio is 16~78, section be round or ellipse in a kind of or both mixing, the two-component glass fibre forms mixed liquor after two furnaces respectively by the glass raw material of two kinds of components, then is blown wire drawing through 1450~1550 DEG C of thermal-flames and is formed.The invention also discloses a kind of preparation methods of light-high-strength glass fiber filter paper, it is characterised in that includes the following steps:(1) beater disperses;(2) it stirs, remove Slag treatment;(3) it manufactures paper with pulp, ground paper is made in vaccum dewatering and squeezing;(4) glue spraying;(5) it dries.Advantageous effect possessed by the present invention is:1. lightweight, environmental protection;2. intensity is high.

Description

A kind of light-high-strength glass fiber filter paper and preparation method thereof
Technical field
The invention belongs to field of air filtration, are related to a kind of air filter paper, more particularly to a kind of light-high-strength glass Fiber filter paper and preparation method thereof.
Background technology
All-glass paper/felt has fabulous fire-retardant, sound-absorbing, heat-insulating property, is provided simultaneously with the advantages that light, inexpensive.Mesh Before, all-glass paper is widely used in fields such as household decoration, building external wall energy-saving heat preservation, air purification.Glass Fiber air filter paper is the key components of filtering element for air filter, and the performances such as thickness, grammes per square metre, intensity, rigidity determine The performance of air filter.Glass fibre air filter paper is mainly used in the air filtration under particular surroundings, will be in air The oil molecule of diffusion stops by air filting material or is trapped in that outside, protection are polluted the space of environment by oil molecule.Due to Filter is that glass fibre air filter paper is converted into filter core by discounting, machine, and outline border is fixed on by hot melt adhesive is fixed-type On, therefore the thickness of glass fibre air filter paper, intensity must satisfy the requirement of filter applying working condition, and filter is made to be suitble to In different wind speed, flow, it is suitable for different environment temperature requirements.
Disclosed on the Chinese patent of Publication No. CN103721477 A a kind of high-strength glass fiber air filter paper and Preparation method, the high-strength glass fiber air filter paper are made of glass fibre and adhesive, and glass fibre is put down at one Uniform random distribution in face forms micron-sized gap between multiple glass fibres, and adhesive wraps the friendship between glass fibre It knits on a little, forms netted joint face.Glass fibre is made of glass chopped silk and/or glass fibre cotton, and adhesive is by nothing Machine silica gel or colloidal alumina or combination thereof overcome existing all-glass paper intensity low and high temperature filter effect bad equal scarce Point, this kind of high-strength glass fiber air filter paper can be used as the heat insulating element in fields such as building, machinery, thermal energy or heat-insulated fill out Material, can be used for air cleaning unit.But filter paper unit weight prepared by this method is larger, and filter efficiency is poor.
A kind of high-strength glass fiber air filter paper is disclosed on the Chinese patent of Publication No. CN102505554A, The organic fibers such as terylene, aramid fiber, acrylic fibers, polypropylene fibre, polyvinyl, fibre length preferably 3~15mm, fibre diameter are added in organic fiber It is preferred that 0.3~5dan.The intensity and deflection under glass fibre air filter paper normality are not only increased, while being dispersed in paper Organic fiber in page is melted into binder at high temperature, compensates for strong because what is lost after acrylic adhesive pyrolytic Degree.The high resiliency of organic fiber simultaneously, ensure that the gas permeability and filter efficiency of air filter paper, it is ensured that manufactured highly effective air Filter can at a temperature of more than or equal to 250 DEG C continuous work.But this design still remains that filter paper unit weight is larger to ask Topic causes equipment energy consumption higher during use.
Invention content
The purpose of the present invention overcomes the shortcomings of the prior art, provide a kind of light-high-strength glass fiber filter paper and its Preparation method.By using two-component hollow glass fibre as the material for making filter material, bicomponent fibers nature had both been played The characteristic of bending, mutually button solution so that it is difficult to slide between fiber, the stability of filter paper is improved, in conjunction with the viscous of adhesive Knot acts on, and the intensity maximum of filter paper improves, in addition, bicomponent fibers are made hollow form, has both alleviated the weight of filter material itself Amount, but also the specific surface area of filter material greatly increases, filter efficiency is greatly improved.
To achieve the purpose of the present invention the technical solution adopted is that:A kind of light-high-strength glass fiber filter paper, by double groups Part hollow glass fibre is formed with adhesive, it is characterised in that and the two-component hollow glass fibre hollow rate is 0.60~ 0.95, average diameter is 0.8~7.2 μm, draw ratio is 16~78, and section is one kind or two in round either ellipse The mixing of person, the two-component glass fibre form mixing after two furnaces respectively by the glass raw material of two kinds of components Liquid, then be blown wire drawings through 1450~1550 DEG C of thermal-flames and formed, wherein the first component glass raw material coefficient of expansion is 4.5 × 10-6~6.0 × 10-6/ DEG C, ingredient is calculated by mass to be:45~76%SiO2, 6~22%Al2O3, 6~20%MgO, 0~3% CaO, 0~2%FeO, 0~2%Na2O+K2O;Second of component glass raw material coefficient of expansion is 8.0 × 10-6~10.0 × 10-6/ DEG C, ingredient is calculated by mass to be:45~76%SiO2, 6~22%Al2O3, 6~20%MgO, 0~3%CaO, 0~2%FeO, 8 ~22%Na2O+K2O。
The first component glass raw material accounts for 30%~60%wt of the glass raw material of two kinds of components in the glass fibre, Wherein preferably 45%~55%.
The adhesive position is in phenolic resin adhesive or melamine and urea-modified phenolic resin adhesive One kind, wherein it is preferred that melamine and urea-modified phenolic resin adhesive.
The invention also discloses a kind of preparation methods of light-high-strength glass fiber filter paper, it is characterised in that including following Step:
(1) glass fibre is added in beater and is disperseed, using water as dispersant and solvent, glass fibre raw material It is dissociated into cotton pulp;
(2) cotton pulp, aqueous solution, which are delivered in mud pit, stirs and carries out slagging-off processing, and the solid content control in slurry exists 3~7, air content is controlled 3~6% for 0.25~0.6%wt, pH control;
(3) mixed slurry stirred evenly is delivered on the filter screen of twin-wire press and is manufactured paper with pulp, thickness control exists Between 0.1~2mm, the gains that will manufacture paper with pulp carry out vacuum suction water removal and ground paper are made after squeezing;
(4) adhesive is diluted to 10~40 times, be equably sprayed on glass fibre ground paper, extra adhesive is by taking out Suction box aspirates, and is come back to after knockout drum detaches in cycle glue tank;
(5) will sizing treated that glass fibre ground paper enters baking oven under the conditions of 260~300 DEG C, dry 1~5min, Obtain light-high-strength glass fiber filter paper.
Advantageous effect possessed by the present invention is:1. lightweight, as a result of the structure of hollow glass fibre, therefore filter paper Under conditions of ensureing identical filter efficiency, quality lighter this allows for filter paper and applies to when on removable facility oil consumption more It is few, energy saving, environmental protection;2. intensity is high, since fiber uses two-component form, mutually winds between fiber, to buckle solution even closer, make The raising for obtaining the intensity maximum of filter paper, increases its service life.
Specific implementation mode
With reference to specific embodiment, the present invention is furture elucidated, it should be understood that these embodiments are merely to illustrate the present invention Rather than limit the scope of the invention, after having read the present invention, various equivalences of the those skilled in the art to the present invention It is as defined in the appended claims that the modification of form falls within the application.
Embodiment 1
A kind of light-high-strength glass fiber filter paper is made of two-component hollow glass fibre with adhesive, and feature exists In the two-component hollow glass fibre hollow rate is 0.60, average diameter is 0.8 μm, draw ratio 16, section is circle, The two-component glass fibre forms mixed liquor after two furnaces respectively by the glass raw material of two kinds of components, then passes through 1450 DEG C of thermal-flame injection wire drawings are formed, and wherein the first component glass raw material coefficient of expansion is 4.5 × 10-6/ DEG C, ingredient with Mass Calculation is:76%SiO2, 11%Al2O3, 10%MgO, 3%CaO, 0%FeO, 0%Na2O+K2O;Second of component glass The raw material coefficient of expansion is 8.0 × 10-6, ingredient is calculated by mass to be:70%SiO2, 8%Al2O3, 7%MgO, 6%CaO, 1% FeO, 8%Na2O+K2O。
The first component glass raw material accounts for the 45%wt of the glass raw material of two kinds of components in the two-component glass fibre.
The adhesive position is phenolic resin adhesive.
The invention also discloses a kind of preparation methods of light-high-strength glass fiber filter paper, it is characterised in that including following Step:
(1) glass fibre is added in beater and is disperseed, using water as dispersant and solvent, glass fibre raw material It is dissociated into cotton pulp;
(2) cotton pulp, aqueous solution are delivered in mud pit and stir and carry out slagging-off processing, the solid content control in slurry exists 3, air content is controlled 3% for 0.25%wt, pH control;
(3) mixed slurry stirred evenly is delivered on the filter screen of twin-wire press and is manufactured paper with pulp, thickness control exists 0.1mm, the gains that will manufacture paper with pulp carry out vacuum suction water removal and ground paper are made after squeezing;
(4) adhesive is diluted to 40 times, be equably sprayed on glass fibre ground paper, extra adhesive is by suction box Suction is come back to after knockout drum detaches in cycle glue tank;
(5) will sizing treated that glass fibre ground paper enters baking oven under the conditions of 260 DEG C, dry 1min, that is, obtain light Matter high strength glass fiber filter paper.
Embodiment 2
A kind of light-high-strength glass fiber filter paper is made of two-component hollow glass fibre with adhesive, and feature exists In the two-component hollow glass fibre hollow rate is 0.95, average diameter is 7.2 μm, draw ratio 78, section is ellipse Shape, the two-component glass fibre form mixed liquor after two furnaces respectively by the glass raw material of two kinds of components, then Wire drawing is blown through 1550 DEG C of thermal-flames to be formed, wherein the first component glass raw material coefficient of expansion is 6.0 × 10-6/ DEG C, ingredient It is calculated by mass to be:45%SiO2, 20%Al2O3, 15%MgO, 12%CaO, 5%FeO, 3%Na2O+K2O;Second of component glass The glass raw material coefficient of expansion is 10.0 × 10-6/ DEG C, ingredient is calculated by mass to be:45%SiO2, 17%Al2O3, 15%MgO, 1% CaO, 0%FeO, 22%Na2O+K2O。
The first component glass raw material accounts for the 60%wt of the glass raw material of two kinds of components in the two-component glass fibre.
The adhesive position is melamine and urea-modified phenolic resin adhesive.
The invention also discloses a kind of preparation methods of light-high-strength glass fiber filter paper, it is characterised in that including following Step:
(1) glass fibre is added in beater and is disperseed, using water as dispersant and solvent, glass fibre raw material It is dissociated into cotton pulp;
(2) cotton pulp, aqueous solution are delivered in mud pit and stir and carry out slagging-off processing, the solid content control in slurry exists 7, air content is controlled 6% for 0.6%wt, pH control;
(3) mixed slurry stirred evenly is delivered on the filter screen of twin-wire press and is manufactured paper with pulp, thickness control exists 2mm, the gains that will manufacture paper with pulp carry out vacuum suction water removal and ground paper are made after squeezing;
(4) adhesive is diluted to 40 times, be equably sprayed on glass fibre ground paper, extra adhesive is by suction box Suction is come back to after knockout drum detaches in cycle glue tank;
(5) will sizing treated that glass fibre ground paper enters baking oven under the conditions of 300 DEG C, dry 5min, that is, obtain light Matter high strength glass fiber filter paper.
Two specific implementation modes of the present invention are above are only, but the design concept of the present invention is not limited thereto, all profits The change for carrying out unsubstantiality to the present invention with this design, should all belong to the behavior for invading the scope of protection of the invention.In every case it is Without departing from the content of technical solution of the present invention, according to the technical essence of the invention to any type of letter made by above example Single modification, equivalent variations and remodeling, still fall within the protection domain of technical solution of the present invention.

Claims (1)

1. a kind of light-high-strength glass fiber filter paper is made of two-component hollow glass fibre with adhesive, it is characterised in that The two-component hollow glass fibre hollow rate is 0.60~0.95, average diameter is 0.8~7.2 μm, draw ratio be 16~ 78, section is a kind of or both mixing in round or ellipse, the glass fibre by two kinds of components glass Raw material forms mixed liquor after two furnaces respectively, then is blown wire drawing through 1450~1550 DEG C of thermal-flames and is formed, wherein The first component glass raw material coefficient of expansion is 4.5 × 10-6~6.0 × 10-6/ DEG C, account for the glass raw material of two kinds of components 30~ 60wt%, ingredient is calculated by mass to be:45~76%SiO2, 6~22%Al2O3, 6~20%MgO, 0~3%CaO, 0~2% FeO, 0~2%Na2O+K2O, the sum of mass percent of each ingredient are 100%;Second of component glass raw material coefficient of expansion be 8.0×10-6~10.0 × 10-6/ DEG C, ingredient is calculated by mass to be:45~76%SiO2, 6~22%Al2O3, 6~20%MgO, 0~3%CaO, 0~2%FeO, 8~22%Na2O+K2O, the sum of mass percent of each ingredient are 100%;The adhesive For phenolic resin adhesive or melamine and one kind in urea-modified phenolic resin adhesive;The light-high-strength glass The preparation method of fiber filter paper includes the steps that following sequences:
(1) glass fibre is added in beater and is disperseed, using water as dispersant and solvent, glass fibre raw material is dissociated At cotton pulp;
(2) cotton pulp, aqueous solution are delivered in mud pit and stir and carry out slagging-off processing, the solid content in slurry is controlled 0.25 3~7, air content is controlled 3~6% for~0.6wt%, pH control;
(3) mixed slurry stirred evenly is delivered on the filter screen of twin-wire press and is manufactured paper with pulp, thickness control 0.1~ Between 2mm, the gains that will manufacture paper with pulp carry out vacuum suction water removal and ground paper are made after squeezing;
(4) adhesive is diluted to 10~40 times, be equably sprayed on glass fibre ground paper, extra adhesive is by suction box Suction is come back to after knockout drum detaches in cycle glue tank;
(5) will sizing treated that glass fibre ground paper enters baking oven under the conditions of 260~300 DEG C, dry 1~5min, that is, obtain Obtain light-high-strength glass fiber filter paper.
CN201610834464.1A 2016-09-08 2016-09-08 A kind of light-high-strength glass fiber filter paper and preparation method thereof Active CN106436443B (en)

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CN108166298B (en) * 2017-12-26 2019-06-14 山东鲁阳节能材料股份有限公司 A kind of resurrection glass fibre felt and preparation method thereof
CN108854260A (en) * 2018-06-15 2018-11-23 徐州世润德环保科技有限公司 The preparation method of high tenacity biofilter material
CN112030313A (en) * 2020-08-24 2020-12-04 江苏华跃玻璃制品有限公司 Production process of high-light glass fiber mesh cloth
CN113813698A (en) * 2021-09-24 2021-12-21 南京玻璃纤维研究设计院有限公司 Filter material

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CN104088198A (en) * 2013-03-24 2014-10-08 苏州维艾普新材料股份有限公司 High-strength glass fiber-made air-filter paper and preparation method thereof
CN105274903A (en) * 2015-10-22 2016-01-27 南京航空航天大学 Double-component glass fiber filter paper adopting gradient distribution and preparation method thereof

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CN1292049A (en) * 1998-02-25 2001-04-18 纳幕尔杜邦公司 Cardable blends of dual glass fibers
CN104088198A (en) * 2013-03-24 2014-10-08 苏州维艾普新材料股份有限公司 High-strength glass fiber-made air-filter paper and preparation method thereof
CN105274903A (en) * 2015-10-22 2016-01-27 南京航空航天大学 Double-component glass fiber filter paper adopting gradient distribution and preparation method thereof

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