CN106434004A - Efficient degreasing agent and preparation method thereof - Google Patents
Efficient degreasing agent and preparation method thereof Download PDFInfo
- Publication number
- CN106434004A CN106434004A CN201610857911.5A CN201610857911A CN106434004A CN 106434004 A CN106434004 A CN 106434004A CN 201610857911 A CN201610857911 A CN 201610857911A CN 106434004 A CN106434004 A CN 106434004A
- Authority
- CN
- China
- Prior art keywords
- highly effective
- oil remover
- effective oil
- water
- fatty alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
- C11D1/24—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds containing ester or ether groups directly attached to the nucleus
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides an efficient degreasing agent for polyester/spandex or nylon/spandex yarn or fabric with high oil content, especially with organic silicone oil agent. The efficient degreasing agent is prepared from 25-35% of fatty alcohol sodium sulfosuccinate monoester, 15-25% of sodium lauryl diphenyl ether disulfonate, 5-15% of dipropylene glycol, and 30-50% of water. The invention also provides a preparation method of the above efficient degreasing agent, comprising: adding the components in corresponding parts by weight into water, mixing, and stirring well. The efficient degreasing agent prepared by using the preparation method can provide uniform degreasing and moderate degreasing rate, is excellent in dispersing performance, is efficient in avoiding back-adhesion, is energy-saving and laborsaving and corrosion-free, and is suitable for washing various materials with no combustion or blasting.
Description
Technical field
The invention belongs to field of fine chemical, specifically relate to a kind of highly effective oil remover.
Background technology
Degreaser is with the complex mixture of the organic of water-based and inorganic chemical composition, is using " emulsifying " " saponification "
Principle and the infant industry degreaser developed.In intermetallic composite coating, food, weaving, traffic, ship, building, electrical equipment, medicine, chemical industry
All have been widely used Deng industrial circle although the surface matrix cleaned is not quite similar, but cleaning purpose is consistent, is all extensive
The cleanliness factor of multiple stromal surface and the integrity keeping stromal surface.
Degreaser kind for cotton, terylene, nylon and its blend fabric is few on the market at present, and exists such as once
Some problems：
Cleaning efficiency and residual rate cannot be up to standard, have certain corrosivity to cleaning base material, and the irritant abnormal smells from the patient of degreaser itself is right
Air, environment have certain pollution.
It is frequently found some oil preparationes that some cottons, terylene, nylon and its blend fabric are added in weaving aborning, such as
It is added without degreaser in kiering, will become apparent from out " color flower " in dyeing（Show as uneven red bulk on cloth cover more）,
This be cotton, terylene, nylon and its blend fabric dyeing in through being commonly encountered.If only looking for reason in terms of dyeing, cannot
Tackle the problem at its root.The terylene of greasy dirt weight, chinlon etc. close fine and its blend fabric washing more difficult it is necessary to before dyeing
By oily waste degradation, otherwise after High Temperature Disperse dyeing under the high temperature conditions, greasy dirt and disperse dyes occur chemical reaction to cause difficulty
With the color lake removing.Therefore, it is necessary to by oily waste degradation before dyeing.Some printing and dyeing mills think during oil removing temperature, and the higher the better, but
Actually favorably also there is disadvantage.Because the easily emulsifying under the high temperature conditions of some oil preparationes, but some oil preparationes are really not so.For this reason, it is many
Auxiliary reagent factory is proposed low temperature degreaser one after another, has both reached the purpose of oil removing, and energy saving and time-consuming.
Improve constantly with environmental consciousness and power conservation requirement, be particularly well-suited to cotton and its blending product hand feel finishing, can assign
The excellent softness of arrangement thing, smooth effect and good hydrophilic new degreaser is given just to arise at the historic moment.To reach in cotton
Use in the refine oil removing bleaching process of knitted fabric simultaneously, obtain extraordinary capillary effect and whiteness have again very high substantivity,
Stability, the fabric after process has feel soft, dry and comfortable, that paulin is loose.
Developing a kind of highly effective oil remover makes it have height emulsifying, dispersion, the ability of dissolving.In production practices, have excellent
Good infiltration, concise, emulsifiability, it is doubtful that effectively solving produces the greasy dirt easily encountered, contaminations, color stain, color flower, silicone oil speckle etc.
Difficult problem, suitably neatly uses, it will have an unexpected effect in each production technology.
Content of the invention
The invention provides a kind of highly effective oil remover, as follows for realizing purpose scheme：
The present invention provides a kind of highly effective oil remover, and described highly effective oil remover is grouped into by each group of following percentage ratio：Fatty alcohol amber
Amber acid monoester sodium sulfonate 22%-35%, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate 15%-25%, dipropylene glycol 5%-15%, water 30%-
50%.
Further preferably, described highly effective oil remover is grouped into by each group of following percentage ratio：Fatty alcohol mono succinate sodium sulfonate
25%-32%, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate 16%-22%, dipropylene glycol 7%-13%, water 35%-48%.
Further preferably, described highly effective oil remover is grouped into by each group of following percentage ratio：Fatty alcohol monomester succinate sulphur
Sour sodium 26%-30%, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate 18%-22%, dipropylene glycol 8%-13%, water 38%-45%.
Further preferably, described highly effective oil remover is grouped into by each group of following percentage ratio：Fatty alcohol monomester succinate sulphur
Sour sodium 28%, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate 20%, dipropylene glycol 10%, water 42%.
Described highly effective oil remover also includes strong dirt-removing emulsifying agent 0.3%-1%.
A kind of preparation method of highly effective oil remover, strong dirt-removing emulsifying agent is added to the water, by proportional quantity under high degree of agitation
Fatty alcohol mono succinate sodium sulfonate and disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate add mixing, be evenly stirred until deposit-free,
Prepare highly effective oil remover.
It is an advantage of the current invention that：
1st, test proves that, fatty alcohol mono succinate sodium sulfonate, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate share, and are dissolved in two
In propylene glycol and water, break traditional degreaser to institute's cleaning product（Concise for cotton, terylene, nylon and its blend fabric
Oil removing process）Alkaline corrosion, shorten the time degreasing, there is the effect that significantly degreases；Any two mixing removes
Greasy dirt effect is all not ideal enough.
2nd, the present invention improves the degreasing result of compositionss using strong dirt-removing emulsifying agent, and shortens process time.
3rd, use the highly effective oil remover decontamination of the present invention quickly clean, no any penetrating odor, environmentally safe.
4th, use the highly effective oil remover decontamination of the present invention, corrosion-free to the material cleaned, do not fire not quick-fried, suitable various material
Cleaning.
5th, the present invention is excellent infiltration, concise, emulsifiability degreaser, is suitable for flat spoke oil removing process, improves life
Produce efficiency, and the present invention is under cryogenic（Less than 80 DEG C）Deoiling effect also very outstanding, also there is non-foam characteristic.
Specific embodiment
Below example facilitates a better understanding of the present invention, but does not limit the present invention, the experiment in following embodiments
Method, such as no special circumstances, are accordingly to be regarded as conventional method.
| Fatty alcohol mono succinate sodium sulfonate | Disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate | Dipropylene glycol | Water | Strong dirt-removing emulsifying agent | |
| Embodiment 1 | 2.8kg | 2kg | 1kg | 4.2kg | 0 |
| Embodiment 2 | 2.3kg | 2.4kg | 1kg | 4.3kg | 0 |
| Embodiment 3 | 2.7kg | 2.0kg | 0.9kg | 4.4kg | 0 |
| Embodiment 4 | 2.8kg | 2.1kg | 1.1kg | 3.5kg | 0.5kg |
| Embodiment 5 | 2.1kg | 1.4kg | 0.4kg | 6.1kg | 0 |
| Embodiment 6 | 3.6kg | 2.7kg | 1.7kg | 2kg | 0 |
Through overtesting, the preparation method of the various embodiments above 1-4 equal subordinate present invention, be outward appearance be colourless to light yellow liquid
Body, pH value is 6.0-7.5（1% aqueous solution）Highly effective oil remover.According to continuous way oil removing process（3.0-5.0g/L）And interval
Formula oil removing process（0.5-2.0g/L）, at general 95 DEG C（±3℃）At a temperature of decontaminate 20-30s, find its to cotton, terylene,
Nylon and its blend fabric etc. have powerful degreasing energy, can be completely exfoliated out by greasy dirt, and be stably dispersed in water bath shampoo
In, drain with waste liquid, thus the capillary effect after processing through this product and whiteness have splendid effect；. to face after this product oil removing
Color affects very little；After this product oil removing, no any penetrating odor, environmentally safe, because non-foam only needs wash water be once
Next procedure can be carried out, can using water wisely, improve production efficiency, do not fire not quick-fried guarantee production safety.Especially embodiment 1 is obtained
Highly effective oil remover be preferably best results.And embodiment 5,6 is not belonging to the preparation method of the present invention, do not possess above-mentioned
Deoiling effect.
Finally it should be noted that：The foregoing is only the preferred embodiment of invention, be not intended as limiting the present invention, to the greatest extent
Pipe has been described in detail to the present invention with reference to the foregoing embodiments, and for a person skilled in the art, it is still permissible
Technical scheme described in foregoing embodiments is modified, or equivalent is carried out to wherein some technical characteristics.All
Within the spirit and principles in the present invention, any modification, equivalent substitution and improvement made etc., should be included in the protection of the present invention
Within the scope of.
Claims (5)
1. a kind of highly effective oil remover it is characterised in that；Described highly effective oil remover is grouped into by each group of following percentage ratio：Fatty alcohol
Mono succinate sodium sulfonate 22%-35%, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate 15%-25%, dipropylene glycol 5%-15%, water 30%-
50%.
2. according to claim 1 highly effective oil remover it is characterised in that：Fatty alcohol mono succinate sodium sulfonate 25%-32%, ten
Dialkyl diphenyl ether sodium disulfonate 16%-22%, dipropylene glycol 7%-13%, water 35%-48%.
3. according to claim 1 highly effective oil remover it is characterised in that：Described highly effective oil remover is by each group of following percentage ratio
It is grouped into：Fatty alcohol mono succinate sodium sulfonate 26%-30%, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate 18%-22%, dipropylene glycol
8%-13%, water 38%-45%.
4. according to claim 1 highly effective oil remover it is characterised in that：Described highly effective oil remover also comprises strong dirt-removing emulsifying
Agent 0.3%-1%.
5. highly effective oil remover described in a kind of claim 1-4 any one preparation method it is characterised in that：By strong dirt-removing breast
Agent is added to the water, by the fatty alcohol mono succinate sodium sulfonate of proportional quantity and dodecyl diphenyl oxide disulfonic acid under high degree of agitation
Sodium adds mixing, is evenly stirred until deposit-free, prepares highly effective oil remover.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610857911.5A CN106434004A (en) | 2016-09-28 | 2016-09-28 | Efficient degreasing agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610857911.5A CN106434004A (en) | 2016-09-28 | 2016-09-28 | Efficient degreasing agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106434004A true CN106434004A (en) | 2017-02-22 |
Family
ID=58170413
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610857911.5A Pending CN106434004A (en) | 2016-09-28 | 2016-09-28 | Efficient degreasing agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106434004A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110756996A (en) * | 2019-10-29 | 2020-02-07 | 宁波四维尔工业有限责任公司 | Wire drawing process for automobile label |
| CN111021057A (en) * | 2019-12-10 | 2020-04-17 | 湖北际华针织有限公司 | High-efficiency energy-saving silicon oil spot removing process |
| CN113481066A (en) * | 2021-07-02 | 2021-10-08 | 广东博科新材料有限公司 | Oil removing agent and preparation method thereof |
| CN113755253A (en) * | 2020-06-01 | 2021-12-07 | 上海荷源环保科技有限公司 | Neutral environment-friendly fabric degreaser |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006042316A1 (en) * | 2004-10-12 | 2006-04-20 | Pantheon Chemical, Inc | Composition for cleaning and degreasing, system for using the composition, and methods of forming and using the composition |
| CN103194324A (en) * | 2013-04-01 | 2013-07-10 | 马永才 | Chemical fiber degreaser and preparation method thereof |
| ES2428799A1 (en) * | 2012-05-04 | 2013-11-11 | Javier DÍAZ RODRÍGUEZ | Cleaning product degreaser for multiple surfaces (Machine-translation by Google Translate, not legally binding) |
| CN104371833A (en) * | 2013-08-12 | 2015-02-25 | 陆伟明 | Clothing oil stain removing agent |
-
2016
- 2016-09-28 CN CN201610857911.5A patent/CN106434004A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006042316A1 (en) * | 2004-10-12 | 2006-04-20 | Pantheon Chemical, Inc | Composition for cleaning and degreasing, system for using the composition, and methods of forming and using the composition |
| ES2428799A1 (en) * | 2012-05-04 | 2013-11-11 | Javier DÍAZ RODRÍGUEZ | Cleaning product degreaser for multiple surfaces (Machine-translation by Google Translate, not legally binding) |
| CN103194324A (en) * | 2013-04-01 | 2013-07-10 | 马永才 | Chemical fiber degreaser and preparation method thereof |
| CN104371833A (en) * | 2013-08-12 | 2015-02-25 | 陆伟明 | Clothing oil stain removing agent |
Non-Patent Citations (1)
| Title |
|---|
| 王建平 主编: "《REACH法规与生态纺织品》", 31 August 2009 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110756996A (en) * | 2019-10-29 | 2020-02-07 | 宁波四维尔工业有限责任公司 | Wire drawing process for automobile label |
| CN111021057A (en) * | 2019-12-10 | 2020-04-17 | 湖北际华针织有限公司 | High-efficiency energy-saving silicon oil spot removing process |
| CN113755253A (en) * | 2020-06-01 | 2021-12-07 | 上海荷源环保科技有限公司 | Neutral environment-friendly fabric degreaser |
| CN113481066A (en) * | 2021-07-02 | 2021-10-08 | 广东博科新材料有限公司 | Oil removing agent and preparation method thereof |
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| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170222 |